Back to Search
Start Over
A donor–acceptor cyclopropene as a dipole source for a silver(i) catalyzed asymmetric catalytic [3+3]-cycloaddition with nitrones.
- Source :
-
Chemical Communications . 2013, Vol. 49 Issue 87, p10287-10289. 3p. - Publication Year :
- 2013
-
Abstract
- Silver(i)-catalyzed asymmetric formal [3+3]-cycloaddition of nitrones with a donor–acceptor cyclopropene, formed in situ from dirhodium acetate-catalyzed dinitrogen extrusion/intramolecular cyclization of enoldiazoacetates, effectively generates 3,6-dihydro-1,2-oxazine derivatives in high yield and with exceptional stereocontrol. [ABSTRACT FROM AUTHOR]
- Subjects :
- *CYCLOPROPENE
*CYCLOALKENES
*TRANSITION metals
*FUNCTIONAL groups
*NITRONES
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 49
- Issue :
- 87
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 100900958
- Full Text :
- https://doi.org/10.1039/c3cc46415f