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The first purification and unequivocal characterization of the radical form of the carbon-centered quinone ketoxy radical adduct.
- Source :
-
Chemical Communications . 2013, Vol. 49 Issue 57, p6436-6438. 3p. - Publication Year :
- 2013
-
Abstract
- We found, unexpectedly, that the radical form of the carbon-centered quinone ketoxy radical adduct with a recently developed spin-trapping agent BMPO can not only be directly detected and identified using HPLC/high resolution MS, but can also be isolated and purified using semi-preparative HPLC, enabling direct observation of its clean 6-line ESR signal. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 49
- Issue :
- 57
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 100899732
- Full Text :
- https://doi.org/10.1039/c3cc42732c