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Synthesis, crystal structures and luminescent properties of tetranuclear Zn molecular clusters with aroylhydrazone ligand.
- Source :
-
CrystEngComm . 2013, Vol. 15 Issue 40, p8069-8073. 5p. - Publication Year :
- 2013
-
Abstract
- Two kinds of tetranuclear Zn(ii) molecular clusters with the designed aroylhydrazone Schiff base ligand (H3L), [Zn4(HL)4]·3(DMF)·3(H2O) (1) and [Zn4(HL)2(CH3COO)4]·2(DMF)·2(CH3OH) (2), have been synthesized and studied. Molecular cluster 1 displayed a Zn4O4 boat-shaped core and 2 presented a discrete linear tetranuclear Zn(ii) structure. The luminescent properties of the two molecular clusters have been investigated, which exhibit a wide range of photo-luminescence in different organic solvents. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14668033
- Volume :
- 15
- Issue :
- 40
- Database :
- Academic Search Index
- Journal :
- CrystEngComm
- Publication Type :
- Academic Journal
- Accession number :
- 100892217
- Full Text :
- https://doi.org/10.1039/c3ce41034j