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An atom-efficient synthetic method: carbosilylations of alkenes, alkynes, and cyclic acetals using Lewis and Brønsted acid catalysts.
- Source :
-
Green Chemistry . 2012, Vol. 14 Issue 3, p565-579. 15p. - Publication Year :
- 2012
-
Abstract
- Carbosilylation is a straightforward procedure to install both silyl and organic functional groups onto organic molecules. For example, allylsilylation of alkenes with allylsilanes affords 5-silyl-1-pentene derivatives. In this review paper, catalytic allylsilylations and arylsilylations of alkenes, alkynes, and cyclic acetals are summarized. Specific catalyses of Lewis and Brønsted acids, such as HfCl4 and proton-exchanged montmorillonite, will be discussed. Intramolecular reactions as well as intermolecular allyl- and arylsilylations have been achieved. In the case of the Brønsted acid catalyst, cationic Si species generated and acted as catalytically active species. The structure of the cationic Si species depends on the type of Brønsted acid used. A disilyl cation was proposed as the catalytically active site for carbosilylations of alkenes and alkynes, while a monomeric Si species was active for allylsilylation of cyclic acetals. [ABSTRACT FROM AUTHOR]
- Subjects :
- *CHEMICAL reactions
*LEWIS acids
*ALKENES
*ALKYNES
*BUTYNE
*ACETAL resins
*CATALYSTS
Subjects
Details
- Language :
- English
- ISSN :
- 14639262
- Volume :
- 14
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- Green Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 100867293
- Full Text :
- https://doi.org/10.1039/c2gc16291a