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Molybdate templated assembly of Ln12Mo4-type clusters (Ln = Sm, Eu, Gd) containing a truncated tetrahedron core.

Authors :
Zheng, Yong
Zhang, Qian-Chong
Long, La-Sheng
Huang, Rong-Bin
Müller, Achim
Schnack, Jürgen
Zheng, Lan-Sun
Zheng, Zhiping
Source :
Chemical Communications. 2013, Vol. 49 Issue 1, p36-38. 3p.
Publication Year :
2013

Abstract

Three heterometallic cluster complexes {Ln12Mo4} featuring an Ln12 core of a distorted truncated tetrahedron were synthesized with the assistance of four MoO42− anions as ancillary ligands. Magnetic studies of the {Gd12Mo4} cluster revealed a large magnetocaloric effect due to the presence of the large number of weakly coupled Gd(iii) ions. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
49
Issue :
1
Database :
Academic Search Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
100867173
Full Text :
https://doi.org/10.1039/c2cc36530h