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Spectroscopic properties and reactivity of a mononuclear oxomanganese(iv) complex.

Authors :
Leto, Domenick F.
Ingram, Rena
Day, Victor W.
Jackson, Timothy A.
Source :
Chemical Communications. 2013 v, Vol. 49 Issue 47, p5378-5380. 3p.
Publication Year :
2013

Abstract

A non-porphyrinic, mononuclear oxomanganese(iv) complex was generated at room temperature and characterized by spectroscopic methods. The MnIV=O adduct is capable of activating C–H bonds by a H-atom transfer mechanism and is more reactive in this regard than most MnIV=O species. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
49
Issue :
47
Database :
Academic Search Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
100865276
Full Text :
https://doi.org/10.1039/c3cc00244f