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Oxidation of ferrocenylboric acid with hydrogen peroxide in organic and aqueous media.

Authors :
Fomin, V.
Zaitseva, K.
Kozlova, A.
Source :
Russian Journal of General Chemistry. Dec2014, Vol. 84 Issue 12, p2421-2428. 8p.
Publication Year :
2014

Abstract

Oxidation of ferrocenylboric acid with hydrogen peroxide in organic solvents and in aqueous solutions in the presence and in the absence of acids and bases has been investigated by electron absorption spectroscopy. Kinetics of FcB(OH) oxidation in neutral, acidic, and basic media has been studied; possible mechanisms of the reactions accounting for the substituent acting as the Lewis-type acidic center have been suggested. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
10703632
Volume :
84
Issue :
12
Database :
Academic Search Index
Journal :
Russian Journal of General Chemistry
Publication Type :
Academic Journal
Accession number :
100524292
Full Text :
https://doi.org/10.1134/S1070363214120123