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Novel zeotype frameworks with soft cyclodiphosphazane linkers and soft Cu4X4 clusters as nodes.

Authors :
Siddiqui, Mujahuddin M.
Balakrishna, Maravanji S.
Mobin, Shaikh M.
Senkovska, Irena
Kaskel, Stefan
Source :
Chemical Communications. 2014, Vol. 50 Issue 82, p12273-12276. 4p.
Publication Year :
2014

Abstract

Two novel cyclodiphosphazane cluster frameworks with Cu4X4 clusters as tetrahedral nodes and ferrocenyl cyclodiphosphazanes [Fe(η5-C5H4)2(PNtBu)2] as ditopic linkers have been synthesized. These frameworks having sodalite topology display a unique integration of porosity and redox activity and offer new opportunities for the synthesis of zeotype frameworks with soft phosphorus-based ligands. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
50
Issue :
82
Database :
Academic Search Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
100188745
Full Text :
https://doi.org/10.1039/c4cc03810j