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Palladium/sulfoxide--phosphine-catalyzed highly enantioselective allylic etherification and amination.

Authors :
Bin Feng
Hong-Gang Cheng
Jia-Rong Chen
Qiao-Hui Deng
Liang-Qiu Lu
Wen-Jing Xiao
Source :
Chemical Communications. 2014, Vol. 50 Issue 67, p9550-9553. 4p.
Publication Year :
2014

Abstract

The Pd/sulfoxide--phosphine-catalyzed highly enantioselective allylic etherification and amination with a wide range of O- and N-nucleophiles have been developed (up to 97% yield, 98.5% ee). The products can also be conveniently transformed into biologically active chiral heterocycles. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
50
Issue :
67
Database :
Academic Search Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
100149182
Full Text :
https://doi.org/10.1039/c4cc03920c