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Rhodium/phospholane-phosphite catalysts give unusually high regioselectivity in the enantioselective hydroformylation of vinyl arenes.

Authors :
Noonan, Gary M.
Cobley, Christopher J.
Mahoney, Thomas
Clarke, Matthew L.
Source :
Chemical Communications. 2014, Vol. 50 Issue 12, p1475-1477. 3p.
Publication Year :
2014

Abstract

Using the phospholane-phosphite ligand, BOBPHOS, almost perfect regioselectivities and high enantioselectivities (up to 92% ee) are observed in Rh catalysed enantioselective hydroformylation of vinyl arenes. This can be achieved under solvent-free conditions. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
50
Issue :
12
Database :
Academic Search Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
100141647
Full Text :
https://doi.org/10.1039/c3cc48823c