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Enantioselective desymmetrization of prochiral 1,3-dinitropropanes via organocatalytic allylic alkylation.
- Source :
-
Chemical Communications . 2014, Vol. 50 Issue 1, p121-123. 3p. - Publication Year :
- 2014
-
Abstract
- An enantioselective desymmetrization of prochiral 1,3-dinitropropanes has been developed which proceeds via enantiogroup differentiating organocatalytic allylic alkylation. Densely functionalized products with two vicinal stereocenters were obtained generally with good to excellent diastereoselectivity (up to >20: 1 dr) and superb enantioselectivity (up to >99: 1 er). [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 50
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 100141552
- Full Text :
- https://doi.org/10.1039/c3cc47645f