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Synthesis of di- and tetranuclear oxidomolybdenum(V) complexes containing p-toluenesulfonates as ligands: a joint spectroscopic, crystallographic and computational study.
- Source :
-
Dalton Transactions: An International Journal of Inorganic Chemistry . 2014, Vol. 43 Issue 26, p10157-10163. 7p. - Publication Year :
- 2014
-
Abstract
- The 1 : 1 reaction of MoCl5 with 1,4-Me(SO3Me)C6H4 led to the isolation of crystalline Mo2O2Cl6[μ-κ2-1,4-Me(SO3Me)C6H4], 1, in low yields. Attempts to reproduce the synthesis of 1 from MoOCl3/1,4-Me (SO3Me)C6H4 resulted in the good-yield formation of [MoOCl2(μ-Cl)(κ¹-1,4-Me(SO3Me)C6H4)]2, 2. The 1 : 1 reaction of MoCl5 with 1,4-Me(SO3H)C6H4·H2O selectively yielded Mo4O4Cl8[μ3-1,4-Me(SO3)C6H4]4, 3. Compounds 1 and 3 were characterized by X-ray diffractometry; moreover DFT calculations were carried out on 1-3 in order to shed light on their thermodynamic and structural features. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 43
- Issue :
- 26
- Database :
- Academic Search Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 100112656
- Full Text :
- https://doi.org/10.1039/c4dt00796d