'Auto-click' functionalization for diversified copper(I) and gold(I) NHCs.

Authors :: Ibrahim, Houssein
Gibard, Clémentine
Hesling, Cédric
Guillot, Régis
Morel, Laurent
Gautier, Arnaud
Cisnetti, Federico
Source :: Dalton Transactions: An International Journal of Inorganic Chemistry. 2014, Vol. 43 Issue 19, p6981-6989. 9p.
Publication Year :: 2014
Abstract: Azide-tagged CuI-NHC reacts in an 'auto-click' process to furnish complexes functionalized by 1,2,3-triazoles bearing diverse substituents. The resulting CuI complexes are amenable to further transmetallation to AuI. The whole strategy proceeds with mild conditions and constitutes an efficient entry to functionalised metal-NHCs with biorelevant moieties. [ABSTRACT FROM AUTHOR]

Subjects :: *AZIDES
*MOIETIES (Chemistry)
*GOLD
*INORGANIC compounds
*INORGANIC chemistry

Language :: English
ISSN :: 14779226
Volume :: 43
Issue :: 19
Database :: Academic Search Index
Journal :: Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :: Academic Journal
Accession number :: 100079161
Full Text :: https://doi.org/10.1039/c4dt00429a