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Synthesis of gem-Difluorinated Nitroso Compounds.

Authors :
Smirnov, Vladimir O.
Struchkova, Marina I.
Arkhipov, Dmitry E.
Korlyukov, Alexander A.
Dilman, Alexander D.
Source :
Journal of Organic Chemistry. 12/5/2014, Vol. 79 Issue 23, p11819-11823. 5p.
Publication Year :
2014

Abstract

A method for the synthesis of gem-difluorinated nitroso compounds is described. The reaction involves interaction of organozinc reagents with (bromodifluoromethyl)trimethylsilane followed by nitrosation of difluorinated organozinc species with an n-butyl nitrite/chlorotrimethylsilane system. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00223263
Volume :
79
Issue :
23
Database :
Academic Search Index
Journal :
Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
100052823
Full Text :
https://doi.org/10.1021/jo5023537