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In a well-known paper, Jeremy England derived a bound on the free energy dissipated by a self-replicating system [J. L. England, "Statistical physics of self-replication," J. Chem. Phys. 139, 121923 (2013)]. This bound is usually interpreted as a universal relationship that connects thermodynamic dissipation to replicator per-capita decay and growth rates. We argue from basic thermodynamic principles against this interpretation. In fact, we suggest that such a relationship cannot exist in principle, because it is impossible for a thermodynamically consistent replicator to undergo both per-capita growth and per-capita decay back into reactants. Instead, replicator may decay into separate waste products, but in that case, replication and decay are two independent physical processes, and there is no universal relationship that connects their thermodynamic and dynamical properties. [ABSTRACT FROM AUTHOR]

Vegetable oils and fatty acid esters (FAEs) are commonly used in various industrial and commercial applications. However, the presence of contaminants in these oils can severely affect their functionality and suitability. Conventional refining techniques for vegetable oils typically involve degumming, neutralization, bleaching and deodorization. Meanwhile, refining of FAEs often utilize wet or dry washing processes. These are often resource-intensive, producing substantial waste products, causing neutral oil loss, and can also result in the loss of micronutrients. To address these challenges, researchers have explored the use of nano-adsorbents and electrostatic field (E-field) technologies as alternatives in purifying industrial dielectric oils by removing polar particles and contaminants. Nano-adsorbents demonstrated increased efficiency in removing polar contamination while minimizing neutral oil loss. However, removal of these spent adsorbents can be challenging due to their nano-size, and physicochemical properties. The use of these materials combined with E-field technologies offers a novel and sustainable solution for removing spent nano-adsorbents and contaminants. This review provides an overview of current traditional and novel refining technologies for vegetable oils and FAEs, including their associated limitations. Compared to conventional methods, E-field treatment offers several advantages, making it an attractive alternative to conventional approaches in food processing and oil refining. [ABSTRACT FROM AUTHOR]

The swift growth of the automobile industry has resulted in the generation of huge quantities of waste rubber from end‐of‐life tires. Incidentally, the humungous quantities of waste plastics that are an integral part of the legacy landfills/dumpsites, lying unattended and about which not many valorization schemes are available, pose various geoenvironmental issues apart from occupying a lot of landfill space. These situations might end up being a blessing in disguise if a strategy to utilize both waste rubber and waste plastic, segregated post landfill/dumpsite biomining, in tandem by manufacturing polymer composites by resorting to extrusion process followed by the injection molding, for different engineering applications. Thus, the physical, mechanical, thermal, morphological, and leaching properties of the manufactured polymer composites were evaluated in this study. The tensile strength and impact resistance of polymer composites were between 4.3–26.9 MPa and 9.4–20 kJ/m2, respectively. Their glass transition temperature lies between −81.13 and − 50.04°C. The leachable concentration of heavy metals and organic compounds was within acceptable limits for drinking water and permissible limits for inland surface water disposal. Therefore, this study contributes valuable insights into using waste materials for polymer composites manufacturing, which would be further helpful in achieving sustainable development goals and circular economy. [ABSTRACT FROM AUTHOR]

In today's world, the use of paper and cardboard increasing but the availability of raw materials and the environmental impact on the paper industry is a big concern. To address these concerns, researchers are exploring the potential of agricultural waste products as raw materials for pulp production. This study uses morphological, chemical composition, FTIR, XRD, and thermogravimetric analysis to examine the potential of banana pseudo-stem as a raw material for paper pulp to address environmental concerns and raw material shortages in the paper industry. The study reveals favorable characteristics for papermaking, including long fiber length (1750 μm), thin cell wall thickness (9.7 μm), and large lumen diameter (22.15 μm). The chemical composition of banana pseudo-stem contains cellulose (44.93 %), hemicellulose (23.7 %), and Klason lignin (11.1) showing its suitability for pulp production. FTIR analysis highlights the functional groups present on the banana pseudo-stem. The XRD analysis shows that it has a similar cellulosic peak and crystallinity index with common raw materials used in pulp production. The thermogravimetric analysis shows that the banana pseudo-stem has high thermal stability. The findings demonstrate that banana pseudo-stem, both by itself and in combination with other raw materials, might be a potential raw material for the pulp production. [ABSTRACT FROM AUTHOR]

The article discusses the partnership of the Office of Research and Development within the U.S. Environmental Protection Agency with local, regional, and federal partners to advance remedies for excess nutrients and co-pollutants across the U.S. Partners are pursuing sewer extension, treatment plant upgrades, and advanced septic systems known as innovative/alternative (IA) OTIS to meet estuarine total maximum daily load targets. Remedies and preventive measures for OWTS pollution are discussed.

Amino acids form peptides and proteins and are therefore considered the main building blocks of life. The kidney has an important but under-appreciated role in the synthesis, degradation, filtration, reabsorption and excretion of amino acids, acting to retain useful metabolites while excreting potentially harmful and waste products from amino acid metabolism. A complex network of kidney transporters and enzymes guides these processes and moderates the competing concentrations of various metabolites and amino acid products. Kidney amino acid metabolism contributes to gluconeogenesis, nitrogen clearance, acid–base metabolism and provision of fuel for tricarboxylic acid cycle and urea cycle intermediates, and is thus a central hub for homeostasis. Conversely, kidney disease affects the levels and metabolism of a variety of amino acids. Here, we review the metabolic role of the kidney in amino acid metabolism and describe how different diseases of the kidney lead to aberrations in amino acid metabolism. Improved understanding of the metabolic and communication routes that are affected by disease could provide new mechanistic insights into the pathogenesis of kidney diseases and potentially enable targeted dietary or pharmacological interventions. The kidney has an important role in the handling of amino acids, facilitated by a complex network of kidney transporters and enzymes. This Review provides an overview of the role of the kidney in the synthesis, degradation, filtration, reabsorption and excretion of different amino acids and the relevance of these functions in the context of kidney physiology and disease. Key points: The kidney has an important role in the synthesis, reabsorption, metabolism and excretion of amino acids and their products. A variety of inter-organ processes are dependent on amino acid metabolism in the kidneys, including acid–base balance, gluconeogenesis and energy production. Metabolic processes occur parallel to physiological processes in disease, consistent with our understanding of metabolism as a pathophysiological driver of disease. Distinct pathophysiological processes contribute to the rewiring of specific metabolic pathways and the development of vulnerabilities. Cross-organ communication on a metabolome level may contribute to kidney disease-associated vulnerabilities and cardiovascular disease. Modulation of amino acid metabolism in kidney disease is a promising avenue for novel therapeutic strategies. [ABSTRACT FROM AUTHOR]

The objective of this study is to utilize cost-effective renewable substrates derived from agro-food wastes for the production of biosurfactant by Bacillus megaterium, which was isolated from petroleum sludge. Various agro-food waste materials, namely potato peelings (PP), rice cooking water (RW), biscuit by products (BB), carob pods (CP), and eggshells, were evaluated as nutrient sources for bacterial growth compared to a synthetic medium (SM). The results indicate that the medium comprising carob pods, potato peels supplemented with eggshells promoted the growth of the bacteria and the production of Biosurfactants at a rate of 150 mg/l and 140 mg/l respectively. The biosurfactant exhibited an emulsification index (E24) of 55.23 ± 0.32%, 46.47 ± 3% 43.80 ± 0.4%, 18.33 ± 0.25% and 20 ± 0.11% for PP, CP, SM, BB and RW respectively. The biosurfactant produced from PP had the ability to decrease the surface tension of water from 74 to 39.38 mN/m, with a critical micelle concentration (CMC) of 15 mg/L. The chemical characterization of purified biosurfactant was done using Fourier-transform infrared spectroscopy (FTIR) and Thermal gravity (TG), as well as differential scanning calorimetry (DSC) analysis (TG/DSC), revealing the functional groups and thermostability of the biosurfactant. The DSC spectrum for PP biosurfactant showed the highest thermostability with crystalline temperature (Tc) of 150 °C and melting point (Tm) of 295 °C. The extracted biosurfactant was mixed with petroleum sludge, composed of heavy oil, 40.64 ± 0.19% of extracted oil was obtained after 5 h of reaction while using PP based medium. [ABSTRACT FROM AUTHOR]

The world has been facing a growing crisis in textile waste due to global population growth and improved living conditions, combined with a decrease in the life cycles of textile products. Textile recycling is one of the key aspects for reducing the massive waste problem generated by the fashion and textile industries. Despite the need to develop textile waste recycling industries, acceptable practical interim measures still need to be taken. Textile waste can affect people's lives economically and environmentally. Producing apparel from natural or synthetic origin can produce pollutants and waste at each stage. In this review article, the effects of the fashion and textile industry have been studied from economic and environmental perspectives. The available technologies and methods for waste recovery and recycling at each stage have been studied, and the uses of products after recycling have been systematically investigated. Despite all the progress made in the waste recycling processes of the fashion industry, many deficiencies and challenges still need to be addressed. Among the most critical challenges are the large scale of industries, the problems of collecting and classifying waste materials, and the presence of contaminants including blends and chemicals. There is also need for more awareness among consumers about the importance of fiber-to-fiber recycling processes, because to date the progress in this field is out of proportion to its necessity. Overall, this article is a valuable resource for anyone interested in understanding the current state of recycling and recovery in the textiles, garment, and fashion industries. [ABSTRACT FROM AUTHOR]

Ashes from biomass combustion (BAs) are waste materials that contain valuable nutrients, making them suitable for reuse in plant fertilization. The application of ash positively impacts soil properties, including the reduction of excessive acidification, which enhances nutrient absorption. However, the use of ash can also introduce potentially toxic elements into the soil in excessive amounts. This study analyzed the effect of different doses of BAs on the accumulation of zinc (Zn), copper (Cu), nickel (Ni), chromium (Cr), lead (Pb), and cadmium (Cd) in the surface layer of Haplic Luvisol soil and in various parts of spring barley plants. The research was conducted over three years under field experiment conditions. Throughout the three-year study period, no significant changes were observed in the content of individual elements in the soil or in various parts of the spring barley plants. The analyzed elements tended to accumulate more in the roots of the plants than in their above-ground parts. When considering the average content of individual elements for the entire study period, no significant increase was noted in their levels within the analyzed soil. However, when examining each year of the experiment separately, significant dynamics in the content of individual elements in both plants and soil were identified. These fluctuations were likely influenced by variations in weather conditions, as the highest concentrations of the analyzed elements were typically recorded in the second year of the study, which coincided with the highest total rainfall of 792.4 mm. The findings indicate that analyzing changes in the content of elements introduced via biomass combustion ashes necessitates comprehensive studies conducted under both controlled and realworld conditions. Without such thorough investigations, conclusions regarding the release of components contained in BAs, particularly concerning their potential toxicity, may be misleading. [ABSTRACT FROM AUTHOR]

Even though concrete structures are safer than steel structures in terms of fire resistance, the risk exists in concrete structures by spalling or exploding, especially in high-strength concrete. This study aims to produce a particular type of concrete using waste ceramics as fine aggregate and waste glass as coarse aggregate and compare data with normal aggregate concrete. Studies show that using waste ceramic and glass increases the fire resistance of concrete. After fire exposure in the control mix, the residual compressive strength was 10 MPa. The waste aggregate concrete was found to be 26.9 MPa after 800 centigrade exposures, which was an excellent result. Waste materials decreased construction costs and led to a clean environment. [ABSTRACT FROM AUTHOR]

ABSTRACT Bituminized waste products (BWPs) were produced by conditioning in bitumen the co‐precipitation sludge resulting from the industrial reprocessing of nuclear spent fuel. For some intermediate level long‐lived (ILW‐LL) classified BWPs, a long‐term disposal solution in France is underground geological disposal. One of the challenges for BWPs in geological disposal conditions is their swelling behavior due to water uptake. This swelling, if sufficiently important, could lead to mechanical coupling with the host rock, resulting in the application of pressure that could damage it. Consequently, the swelling behavior of BWPs must be considered in safety studies for the underground storage facility after site closure. The present work is a continuation of a previous one and focuses on investigating both experimentally and numerically the BWPs’ swelling behavior due to water uptake under confined leaching conditions. The swelling of simplified BWPs was experimentally monitored for about 2.5 years during leaching tests under constant counterpressure. The numerical model is extended from a previous work that incorporates coupled homogenization of transport terms (diffusion, permeation, osmosis) with mechanics via Maxwell's viscoelastic model. An original nonlinear poro‐viscoelastic model taking into account large strains is proposed in this paper to better model the BWPs leaching behavior under confined conditions. The experimental results of leaching tests under constant counterpressure are generally well predicted by the resulting numerical model. The role of the poorly soluble salts BaSO4 within the solid BWP matrix is investigated. [ABSTRACT FROM AUTHOR]

Microalgae are widely recognized for their capacity to generate value‐added products in a variety of sectors, including the pharmaceutical and food industries, bioenergy industries and wastewater industries. The quality of a microalga is significantly influenced by its proliferation. Along with growth, the biochemical profile may also vary based on the nutrient that is supplemented. The majority of the supplemented nutrients utilized are not in a functional state, as they are typically extracted in liquid form or pretreated prior to use. Parallel to numerous commonly applied pretreatment processes, including chemical, mechanical and biological, thermal pretreatment appears to receive less attention. Hence it is crucial to comprehend the potential for thermal pretreatment as well as its mechanism in militating the solid waste to release additional nutrients in order to enhance the biochemical profile of microalgae. The current review takes a closer look at the impact of various thermal pretreatments on solid waste on influencing microalgal performance in terms of their overall biochemical profiles such as carbohydrates, proteins and lipids. This approach is likely to enhance the circular economy by utilizing waste products and effectively closing the loop on waste. © 2024 Society of Chemical Industry. [ABSTRACT FROM AUTHOR]

The current research introduces a novel in-situ and visibly-active heterojunction formation concept to fabricate a sustainable antimicrobial cementitious material. To achieve this, cement mortar incorporating iron-rich industrial waste products (FWPs) was outer-coated with photocatalyst Titanium dioxide (TiO 2). The proposed technique forms a novel surface-active Fe 2 TiO 5 heterojunction oxide layer, which considerably improves the photocatalytic and antimicrobial properties of TiO 2 under the visible spectrum of light. Primarily, the study evaluated the structural suitability of the developed iron-rich cementitious material in terms of its durability and strength properties. The findings indicate that the iron-rich cementitious material performed better than conventional cementitious material. After this, the effectiveness and novelty of the proposed research were examined, such that the Fe 2 TiO 5 photocomposite was subjected to detailed microscopic investigations such as XRD, HRTEM, UV-DRS, XPS, FESEM, etc. The results verified the production of the inherent Fe 2 TiO 5 heterojunction through the presence of Fe in the photocatalyst TiO 2 lattice via the formation of ITO complex bonds. It also revealed that the Fe 2 TiO 5 photocomposite functions effectively under visible light with an energy band gap of 2.57 eV. The antimicrobial activity of the Fe 2 TiO 5 photocomposite was also assessed by neutralizing E.coli bioaerosols. The disinfection results indicated that the Fe 2 TiO 5 photocomposite exhibits excellent antimicrobial properties. It achieved 69.33 % and 95–98 % antibacterial efficiency under dark and visible light, respectively. Thus, the study establishes a Fe 2 TiO 5 photocomposite material that combines photocatalytic and antimicrobial properties, making it suitable for use as a sustainable building material. Also, it contributes to environmental sustainability by promoting a circular economy and green building practices. • The design and manufacturing of an antibacterial and photocatalytic sustainable building material. • Utilization of cement mortar incorporating FWPs to make the surface active Fe 2 TiO 5 heterojunction photocomposite. • Fe from FWPs enhances TiO 2 's photocatalytic action via the inherent concept of Fe 2 TiO 5 heterojunction formation. • The Fe 2 TiO 5 photocomposite potentially inactivates E.coli bioaerosols under visible light. [ABSTRACT FROM AUTHOR]

Due to their detrimental and persistent impacts on the environment, it is imperative to manage and dispose of hazardous wastes (HW) in a secure manner. This study investigates the combustion characteristics and environmental impacts of using HW as alternative fuels in clinker production. The HW categories analyzed include industrial hazardous waste (IHW), medical hazardous waste (MHW), and household hazardous waste (HHW). Specifically, IHW consists mainly of waste mineral oils, waste organic solvents, organic resin wastes, waste residues, and waste coatings. MHW primarily consists of medical plastic products. HHW mainly includes packaging from waste pharmaceuticals, waste pesticides, disinfectants, and waste paints. Compared to traditional pulverized coal, hazardous waste alternative fuel (HWAF) exhibits a lower fixed carbon content, with its heat generation primarily dependent on volatile substances, and a higher ash content, chemically similar to coal ash. The combustion process of HWAF involves three stages: moisture evaporation (0 °C–150 °C), volatile matter combustion (150°C–400 °C), and fixed carbon combustion (400 °C–550 °C). The primary emissions from this process include CO 2 , CO, trace amounts of SO 2 , NO 2 , H 2 O, and various complex organic compounds such as carboxylic acids, alcohols, ketones, and aldehydes. While HWAF ignites more readily than pulverized coal, it burns more slowly and less completely. The incorporation of combustion by-products into the cement clinker formulation does not interfere with the clinker's hydration processes or reactions. HWAF ensures a reduced heavy metal input rate in the firing system without significantly impacting the heavy metal content in the clinker. Mortar samples produced with this clinker meet the heavy metal leaching standards, affirming the environmental safety of the cement product. Increasing the proportion of HWAF results in a reduction in standard coal consumption and an increase in CO 2 reduction, achieving a maximum coal saving of 3.67 kgce/t.cl and a CO 2 emission reduction of 10.11 kg/t.cl. This study presents a clean production model for the co-processing of HWAF, effectively transforming waste into valuable resources by using hazardous waste materials as alternative fuels. [ABSTRACT FROM AUTHOR]

AbstractThe environment has been damaged due to anthropogenic activities related to the production and consumption of cattle. The present study investigated the pollution potentials of slaughterhouse effluents on groundwater qualities in Ebonyi State Southeast Nigeria, with the specific objectives to determine the effect of slaughterhouse effluents on both microbiological, physicochemical and heavy metal parameters on the quality of groundwater. Eighty-four well water samples were taken in 2022 and 2023 from slaughterhouse locations, and a control location for the determination of physicochemical properties and microbiological contents using standard analytical methods. Datasets were analyzed using Fisher’s Significance Least Difference (F-LSD) at 0.05 probability level. The study recorded higher levels of physicochemical, BOD, COD, Salinity, bacterial and fungal counts in the slaughterhouses well waters when compared to the control well water. With the exception of chloride, ammonia, copper and electrical conductivity, all water parameters were significant in both years. The result of the study also demonstrated that, with the exception of ammonia, lead, biological oxygen demand, chemical oxygen demand, salinity, salmonella spp, shigella spp, E. coli, and other coliforms, the majority of the analysed parameters were within the World Health Organisation recommended standard. In addition, as compared to the first year of study, the well water parameters were generally higher in the second year. In order to prevent groundwater pollution, the present study suggests that slaughterhouse effluents be disposed of in an environmentally responsible manner through the segregation of waste materials to prevent groundwater pollution. [ABSTRACT FROM AUTHOR]

Recyclable construction waste can be used as a low-cost material to reduce stormwater pollution caused by various pollutants. In recent years, studies have reported increased water contamination from chlorine and chlorine compounds and its negative impact on aquatic ecosystems. When assessing the need for waste recycling, circularity, and stormwater reuse, it is worth evaluating the capacities of construction waste materials to reduce stormwater pollution from residual chlorine. Laboratory experiments using bentonite waste material (bentonite clay) and sodium hypochlorite solutions were carried out to analyze the potential of bentonite clay to retain residual chlorine in stormwater and evaluate its capacity to be applied as filtration media in green infrastructure. In the first stage, the particle size distribution and texture of bentonite clay were assessed using laboratory sieve analysis and microscopy. The results of the experiments indicated that the optimal grain size to retain pollutants was 0.8–2.0 mm. The microstructure analysis showed the capacity of bentonite to retain residual chlorine. The results of the static and dynamic experiments (leaching and filtration tests) show that the bentonite clay retained up to 44% of the residual chlorine. The obtained results indicate that bentonite clay might be suitable for application as filtration media in green infrastructure to reduce stormwater contamination. [ABSTRACT FROM AUTHOR]

Excess fluoride intake from drinking water is a serious concern for human health posing mainly dental/skeletal fluorosis and other multiorgan manifestation. Recent research is being focus on developing a new biosorbent from calcium-rich waste materials with thermal treatment for F − removal from water since it has high affinity and greater potential for deflouridation. The present research developed a new biosorbent from waste eggshell for deflourdation from water. Taguchi's L 16 orthogonal array was used for process variables optimization to acquire the maximum F − removal. The fluoride uptake capacity of 10.69 mg / g and fluoride removal percentage of 86.67% were acquired for the eggshell sorbent at optimum values of process variables of pH: 7 ± 0.1, adsorbate concentration: 15 mg / L , agitation time: 60 min, eggshell dose: 14 g / L and temperature: 303 K. ANOVA analysis indicates the contribution of process variables in descending order as adsorbate concentration 39.76% > pH 39.33% > temperature 12.34% > biosorbent dose 6.42% > agitation time 2.14%. Freundlich isotherm and second-order kinetic model were best fitted for the sorption of fluoride. Thermodynamic parameters (ΔH = 42.33 kJ / mol , and ΔS = 0.240 kJ / mol. K ) indicate endothermic and spontaneous fluoride sorption. The sorption elution studies with 0.1 N NaOH suggest the eggshell sorbent could be reused up to three cycles. The influence of co-ions was obtained as Cl − < NO 3 − < SO 4 2 − < PO 4 3 − . The eggshell sorbent was also shown feasibility for defluoridation from real water samples. [ABSTRACT FROM AUTHOR]

Soil stabilisation by waste materials has been recently employed to enhance soil engineering properties. The purpose of this study is to compare the impact of utilising sawdust in its raw form versus sawdust ash as a soil stabiliser. This is to determine if sawdust (SD) can be considered as a substitute for sawdust ash (SDA) in order to reduce incineration and air pollution. To fulfil this aim, the Atterberg limits, modified Proctor test, and Direct Shear test were performed on both stabilised and non-stabilised mixtures of clayey soil. The soil was treated with 2%, 5%, 8%, 12%, 15%, and 20% by soil dry weight of both SD and SDA. The findings show that the use of SD and SDA leads to a reduction in the plasticity index and the maximum dry unit weight of the soil while increasing its optimum moisture content. The bearing capacity of the soil was greatest at 5% for both SD and SDA, with SD exhibiting a greater enhancement (31.89%) than SDA. Therefore, it is recommended to utilise SD instead of SDA for soil stabilisation due to its superior effectiveness and less harmful environmental impact. [ABSTRACT FROM AUTHOR]

AbstractTechnology alignment in managing end-of-life products to overcome sustainability issues has drawn increasing attention in the food and hospitality industry. Recent literature on sustainable and agile practices in the food and hospitality industry recognizes the importance of reusing food waste materials at their end of life. The current study examines the mediating role that end-of-life food waste management plays in the relationship between agile practices and sustainable consumption and production from the viewpoint of food hospitality companies. The research employs a sequential mixed method design involving quantitative and qualitative analysis. The suggested model was empirically tested using information gathered from 298 respondents recruited through Prolific. After that, post hoc qualitative exploration was carried out by analyzing 24 interviews of the respondents identified out of the 298 respondents of the quantitative study. We discover that agile management practices are antecedents for responsible consumption and production. The findings highlight that food and hospitality firms must consider agile management practices to achieve more sustainable and socially responsible food waste management practices. Further, we find that information technology alignment is not a necessary condition to enhance or weaken the indirect effect of sustainable end-of-life (food waste) management between agile practices and sustainable consumption and production practices within the food and hospitality industry. This work advances theoretical and practical knowledge of conservation and natural resource management in the food and hospitality industry. [ABSTRACT FROM AUTHOR]

Nowadays, with the mechanization of human societies, the demand for energy production and storage has also increased. Fossil fuels are running out, and thus, clean energy production using non-toxic and accessible sources is desirable. The valorization of waste materials into useful compounds is among the most important research subjects. Increasing interest in cost-effective raw materials and environmentally friendly precursors has brought agricultural residues up as promising, widespread biowaste all around the world. Rice husks (RHs), corn husks, wheat straws, sugarcane bagasse, fruit nut residues, and many other agricultural wastes have been broadly applied for designing novel materials, which can be applicable for energy conversion and storage. Agricultural waste contains useful chemical compounds, which may act as reducing, stabilizing, or capping agents, templates, precursors, etc., to produce various compounds viz. carbonaceous and (nano)materials. This review paper discusses the compounds that can be applicable for electrocatalytic applications for energy conversion in addition to energy storage. In fact, in this review, reports concerning agricultural waste-derived (carbon/nano)materials for energy conversion as well as energy storage devices such as different types of batteries, supercapacitors, and solar cell systems have been reviewed. The application of agricultural waste for energy conversion and storage is a very important issue due to the increase in the human population in the future, resulting in energy shortage problems. Therefore, suitable solutions must be developed for energy conversion and storage. On the other hand, the application of natural and environmentally friendly agricultural waste is very important for energy production and storage in addition to preventing the accumulation of this waste in the environment. [ABSTRACT FROM AUTHOR]

Predators can alter the movement of nutrients through ecosystems by depositing waste products following predation. Whilst the benefits of predator waste for large predators (e.g. bears) or dense accumulations of predators (e.g. seabirds on islands) seem clear, less is known about whether smaller, solitary predators can have measurable effects on local ecosystem processes. In separate experiments with web‐building and wandering spiders, we tested if the presence of predators affected soil nutrient content, soil respiration, soil microbial communities, and plant growth. In the first experiment with black widow spiders, total nitrogen and nitrate were not affected by spider presence, but ammonia and phosphorus were higher from soil under the edge of the spider web than soil away from the spider. Soil respiration and plant growth were both higher in soil collected from under the spider retreat compared with soil collected away from the spider web. In a second experiment with wolf spiders, we tested for interactions between spiders and soil microbial communities. There were positive effects of wolf spider presence on all soil nutrients and there were interactions between spiders and soil type (i.e. field‐collected versus autoclaved) for total carbon, total nitrogen, nitrate, and pH. Spider presence and soil type also affected soil respiration and spider presence had a large effect on the composition of the microbial community of the soil. There were also positive effects of wolf spider presence on plant biomass and plant height, with a significant interaction between spiders and soil type for plant height. Overall, our results show that two spiders with different life histories (i.e. web‐building and wandering) both have significant positive effects on plant growth through the deposition of their waste products. These effects may occur through the direct deposition of nutrients and changes in soil microbial communities. Although, further work is needed to resolve these interactions. Read the free Plain Language Summary for this article on the Journal blog. [ABSTRACT FROM AUTHOR]

Rhodanese, the primary cyanide-detoxifying enzyme, plays a crucial role in mitigating the harmful effects of cyanide present in various industrial waste materials, such as battery manufacturing effluents. The bioremediation of cyanide-contaminated environments relies on efficient detoxification mechanisms, making rhodanese a valuable enzyme for biotechnological applications. This research aimed to investigate the biochemical properties of purified rhodanese produced by Aspergillus welwitschiae LOT1, a fungal strain with promising cyanide detoxification capabilities. The purified rhodanese was obtained through fermentation, precipitation, and chromatographic separations, resulting in a homogeneous band of approximately 58 kDa with a specific activity of 374 RU/mg, 28-fold purification, and 14% recovery. The enzyme exhibited optimal cyanide detoxification at pH 7 and 60 °C, with stability observed between 30 and 50 °C and pH 8–10. All metal ions examined except for Cu2+ enhanced the cyanide-degrading ability of rhodanese. Notably, the enzyme demonstrated a high substrate preference for Na2S2O3 and followed a first-order kinetic model and free energy, ΔG of 61.3 kJ/mol, making it a promising candidate for biotechnological applications. Overall, this study provides valuable insights into the biochemical properties of rhodanese from A. welwitschiae LOT1, highlighting its potential for efficient cyanide detoxification and bioremediation. [ABSTRACT FROM AUTHOR]

There is a real demand for sustainable lightweight structures because of the growing environmental concerns. One important solution is developing structures through recycled scrap/waste thermoplastic materials. The current work studies the friction stir spot weldability of recycled thermoplastics, which will help to analyze the potential of friction stir-based welding techniques towards developing these sustainable structures. The combined behavior of recycling-welding procedures is investigated, as they may cause degradations; to ensure that the base thermoplastic polymer's chemical, thermal, and mechanical properties are retained. Scrapped milk bottles made from HDPE material are used as a case study. The highest lap-shear load of 1528 N was achieved at the optimum welding conditions of 1600 rpm rotational speed, 1 mm plunge depth, and 60 s dwell time. Fractographic studies (macroscopic and SEM-based) suggested four types of fracture morphologies depending on welding conditions used. The DSC results showed no significant differences in melting temperature and crystalline content of the polymeric material. The TGA tests showed no significant thermal degradations. The FTIR analysis of all the samples (bottle, recycled sheet, weld material) exhibited characteristic HDPE peaks. All these results suggest combined-welding recycling had a minimal impact on the polymeric structure. Thus, friction stir spot welding (FSSW) technique joins recycled thermoplastic scrap/waste materials with high lap-shear load and without any significant polymer degradations. [ABSTRACT FROM AUTHOR]

Waste material classification is critical for efficient recycling and waste management. This study proposes a novel, low-cost material classification system based on a single, voltage-tunable Ge-on-Si photodetector operating across the visible and short-wave infrared (SWIR) spectral regions. Thanks to its tunability, the sensor is able to extract spectral information, and the system effectively distinguishes between seven different materials, including plastics, aluminum, glass, and paper. The system operates with a broadband illuminator, and material identification is obtained through the processing of the photocurrent signal at different bias voltages with classification algorithms. Here, we demonstrate the basic system functionality and near real-time classification of different waste materials. [ABSTRACT FROM AUTHOR]

Reducing maritime greenhouse gas (GHG) emissions is challenging. As efforts to address climate change are gaining momentum, reducing the environmental impact becomes crucial for maritime short-to-medium-term sustainability. The International Maritime Organisation (IMO) has adopted Life Cycle Assessment (LCA) guidelines for estimating GHG emissions associated with alternative fuels. This paper proposes an examination of the latest IMO-adopted LCA guidelines, comparing them with existing methodologies used for the transport sector. By scrutinising these guidelines, the paper aims to provide a better understanding of the evolving landscape for GHG emission estimation within the maritime sector. The paper presents a case study that applies the newly established LCA guidelines to a promising alternative fuel pathway, i.e., waste-wood-derived pyrolysis oil. Pyrolysis oil offers an attractive option, leveraging waste materials to generate a sustainable energy source. The environmental impact of pyrolysis oils is quantified according to the IMO LCA guidelines, offering insights into its viability as a cleaner alternative as marine fuel. The results show the large potential for GHG savings offered by this pathway: upgraded pyrolysis oil can deliver significant GHG savings, and this contribution is linearly dependent of its energy share when blended with standard Heavy Fuel Oil. [ABSTRACT FROM AUTHOR]

One of the key trends affecting the future of the construction industry is the issue of ecology; therefore, current activities in construction aim to reduce the use of raw materials, which is made possible by including recycled materials in composites, among other methods. This article describes the results of tests conducted using four types of epoxy composites, i.e., composites modified with waste rubber (WR), composites modified with waste polyethylene (PE) agglomerate, glycolysate obtained using polyethylene terephthalate (PET) waste, and control unmodified mortars (CUM). Selected properties of the mortars were monitored during their maturation under laboratory conditions, as well as after post-curing at elevated temperatures in the range of 60 °C–180 °C. With the increase in the reheating temperature, an increase in the flexural strength of all types of mortars was noted, with the highest more than twofold stronger than the unmodified composites. The compressive strength increased up to a temperature of 140 °C, and then decreased slightly. The highest value of 139.8 MPa was obtained using PET mortars. Post-curing also led to a slight loss of mass of all samples in the range of 0 to 0.06%. Statistical methods were employed, which made it possible to determine the post-curing temperature and composite composition for which the determined properties are simultaneously the most beneficial, especially for the prefabricated elements. [ABSTRACT FROM AUTHOR]

The storage and management of nuclear waste materials require the detection of uranium, but traditional analytical methods are unsuitable for radioactive environments. The enhancement methods of uranium in glass matrices using fiber-optic laser-induced breakdown spectroscopy are still underdeveloped. Using an optical diagnostic system coupled with fast photography, shadowgraphy, and optical emission spectroscopy, the evolution of laser-induced plasma generated from a glass matrix under spatial confinement is studied. The plasma evolution image illustrates the temporal consistency between the compression of plasma width and the enhancement of luminescence intensity. Two enhancements were observed when the plate spacing was smaller than the plasma, which might be due to the high density of the core plasma or a synergistic effect of plasma expansion and shockwave confinement. Under spatial confinement, there is a 3–4-times enhancement in the intensity of uranium spectral lines and a 2–4 times enhancement in the signal-to-noise ratio. Several calibration curves are established under spatial confinement based on U II 409.01 nm, U II 367.01 nm and U I 358.48 nm. The lowest limit of detection (LOD) of uranium reaches 95 ppm, which supports the application of FO-LIBS in the detection of uranium-containing nuclear waste materials. [ABSTRACT FROM AUTHOR]

The larval excretions/secretions (ES) of blowflies contain proteolytic enzymes and bacteria that assist with tissue breakdown. Decomposition fluid (DF) contains organic and inorganic waste products from cell death. This study investigated if human DNA recovery from blood was impacted by exposure to ES and DF over time. Lucilia sericata ES were collected daily from 50 larvae, and all available DF was collected from two fetal piglets left to decompose for 2 weeks. Daily for 3–5 days, 28 μL‐30 μL of ES, DF, or a 1:1 mixture of the fluids was added to 30 μL of blood on cotton. Three bloodstains per treatment were sampled every 12 h up to 3 days and at 1 and 2 weeks after initial addition of fluid. No PCR inhibition was detected, but DNA degradation increased over time, primarily in samples exposed to ES and ES/DF mixtures. The amount of DNA recovered decreased over time, but generally more DNA was recovered from DF samples than other samples. Full profiles, or partial profiles suitable for routine database searching (14–39 alleles), were generated from all DF and ES samples and at least one mixture sample at all timepoints. Partial profiles of between 1 and 13 alleles were obtained from all other mixture samples, except one mixture sample which generated no profile. These findings indicate bloodstain evidence recovered from maggot‐infested and/or decomposing bodies may generate forensically useful DNA evidence and should be analyzed as quickly as possible after collection or stored appropriately to prevent further degradation. [ABSTRACT FROM AUTHOR]

This article presents the unique research results of the comprehensive analysis of the porous structure of activated carbons obtained from biomass waste materials from the wood industry during activation in an air atmosphere. The porous structure was analysed on the basis of nitrogen and argon adsorption isotherms via complementary multi-method analysis, i.e. the new numerical clustering-based adsorption analysis, the non-local density functional theory and the quenched solid density functional theory methods. The analytical results for the prepared activated carbons were compared with analogous results obtained for commercial activated carbon. On the basis of the conducted studies it has been determined that the new numerical clustering-based adsorption analysis method gives credible and valuable information on the textural properties of activated carbons which are in strict correlation and mutually complement with the results of the analysis with the use of the quenched solid density functional theory method. The research results obtained in this paper, it has also been shown that from waste materials of the wood industry, in a relatively cheap and cleaner production process, it is possible not only to obtain carbonaceous materials almost comparable to commercial activated carbon, but also to manage the waste in accordance with the principles of a closed-loop economy and sustainable development. The paper pays also attention to the often overlooked economic and ecological aspects, which should nevertheless be taken into account when comparing different adsorbents, rather than their textural properties alone. [ABSTRACT FROM AUTHOR]

This paper investigated waste management practices of small businesses in the selected townships of Gauteng province, South Africa. Surveys were conducted by means of questionnaire-administered interviews and primary data were analysed by descriptive and inferential statistics. Results indicated that most businesses generated wastes in the form of plastics (59–75%), cardboards (31–61%), and food remains (21–37%). Approximately 64–68% of small businesses relied on the municipality for waste collection and disposal. By contrast, 10–20% of businesses gave away their recyclable materials to informal waste reclaimers while only a few were recycling (7–14%) or reusing (6–12%) their wastes, respectively. The survey found a significant association between the formality of businesses and certain types of wastes that they were generating, namely, office paper, glass, metals, food items, and other waste materials. Based on these findings, some recommendations are suggested for improving existing waste management practices and maximising waste reduction efforts in the townships. [ABSTRACT FROM AUTHOR]

The mounting global concern over the environmental consequences of petroleum-based plastics has prompted significant research into sustainable alternatives, with bioplastics emerging as a forerunning solution. This systematic review elucidates the multifaceted synthesis processes of bioplastics, which are derived from renewable sources such as plant starches, cellulose, and waste materials. The synthesis encompasses stages from raw material selection, pre-treatment, to the incorporation of various additives, with the aim to achieve specific properties in the resultant bioplastics. A substantial focus of this review lies in comprehensively understanding the role of additives, which serve as the pivotal agents in tailoring the mechanical and thermal characteristics of bioplastics. Additives, including cross-linking agents, plasticizers, fillers, compatibilizers, and reinforcement agents, are critically examined for their influence on attributes such as tensile strength, flexibility, thermal stability, and biodegradability. Factors such as intermolecular interactions, hydrogen bonding, and moisture content, play a determining role towards the resultant properties. The prospects for bioplastics are rapidly expanding, signalling a transformative shift in various applications ranging from eco-friendly packaging to advanced biomedical devices. This article serves as a comprehensive guide to both researchers and industry stakeholders, providing deep insights into the synthesis of bioplastics and the transformative role additives play in their functional properties. [ABSTRACT FROM AUTHOR]

In an attempt to promote a cleaner environment, the deployment of waste materials in soil amendment protocols has been a major concern for civil engineers. Recent discoveries in the study of soil mechanics have revealed the pozzolanic tendencies demonstrated by these waste materials, which are beneficial in the development of road infrastructure. This has necessitated the need for this research to document the impacts of exploring the usage of combined solid waste derivatives in ameliorating the geotechnical parameters of deficient soil. The current stabilization exercise was geared towards the improvement of the mechanical properties of soil and surpassing the detrimental tendencies especially caused by seasonal variations. Moving forward, the microstructural response of the unaltered and additive ameliorated soil was investigated via qualitative means such as scanning electron microscopy (SEM) and Fourier transform infrared (FTIR) spectroscopy. The additives including cement kiln dust (CKD) and rice husk ash (RHA), were added by air-dried weight of the soil and compacted based on the standards of British Standard Light (BSL), West African Standard (WAS) and British Standard Heavy (BSH). With regard to the compaction exercise, the incorporation of these additive materials into the soil facilitated a gradual increase in the maximum dry density (MDDs) followed by a decrease in the optimum moisture contents (OMCs). In view of these research findings, soil treatment studies facilitated a substantial upsurge in the strength (California bearing ratio (CBR) and unconfined compressive strength (UCS)) values of the ameliorated soil, in agreement with the requirements of Nigeria's general specification for all compactive efforts. Finally, the usefulness and efficacy of combining these wastes in deficient soil treatment were validated qualitatively via the SEM and FTIR strategies. The results of the SEM analysis revealed some disparities between the unaltered and altered soil specimens, providing insights into the direction of calcite formation in the additive-treated soil. [ABSTRACT FROM AUTHOR]

Copyright of Materiały Budowlane is the property of Wydawnictwo SIGMA-NOT and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

The document provides an overview of anaerobic fermentation and high-value bioproducts, emphasizing the need for sustainable waste management practices to transform waste into valuable resources. The global scientific community is exploring integrated biorefineries to extract valuable substances from renewable materials efficiently. The document discusses the challenges faced by anaerobic fermentation technologies in terms of production efficiency, feedstock heterogeneity, and product quality, highlighting the importance of further research to overcome these obstacles and enhance process efficiency and resource utilization. [Extracted from the article]

In the current study, the agricultural waste materials Date Seed Ash (DSA) is investigated. Various concentrations of DSA (5%, 10%, 15%, and 20%) were applied, and the impact of DSA on the surface morphology and chemical composition of the tested soil (soft clay) was examined using scanning electron microscopy and energy dispersive X-ray. The results indicated that soft clay soil treated with DSA exhibited increased overall strength. By adding 15% DSA, the unconfined compression strength improves to more than double that of the sample without any treatment. Moreover, examining the morphology of soil samples treated with 10% and 15% DSA uncovered the formation of hydrated particles and cement-like compounds resulting from the interaction between the soil and DSA. In addition, as the DSA % grows, the compressibility and volume change factors decrease. The California Bearing Ratio and unconfined compression strength tests confirmed that DSA was an effective stabilizer of soft clay soil. In this study, the most effective amount of Date Seeds Ash (DSA) was 15% by adding weight to enhance the fundamental properties, and strength of soft clay soil. [ABSTRACT FROM AUTHOR]

Organophosphates are a type of emerging environmental contaminant, which can be removed effectively by adsorption. Here, modified steel slag was examined for its adsorptive performance in the removal of hydroxyethylidene diphosphonic acid (HEDP) from water. Compared to acid (55.3%, maximum removal rate) and base (85.5%) modification, high-temperature modification (90.6%) significantly enhanced steel slag's adsorption capacity for HEDP, surpassing that of unmodified slag (71.2%). Kinetic analyses elucidated a two-phase adsorption process—initial rapid adsorption followed by a slower equilibrium phase. The results of adsorption energy analysis showed that modified steel slag preferentially occupied the sites with higher energy, which promoted the adsorption. After five regeneration cycles, the adsorption properties of the material were not significantly reduced, which indicates that the material has good application potential. Microscopic and spectroscopic techniques, including SEM-EDS, FTIR, and XPS, were employed to uncover the surface chemistry and structural changes responsible for the enhanced adsorption efficiency. The adsorption mechanism of HEDP on steel slag is a complete process guided by hydrogen bonding interactions, strengthened surface complexation, and optimized ligand exchange. This study advances the sustainable utilization of industrial waste materials and contributes significantly to the development of innovative water treatment technologies. [ABSTRACT FROM AUTHOR]

With the advent of various technological advancements, companies can now recycle unique waste materials that would otherwise be dumped into landfills (e.g., coffee grounds) and highlight their engagement in sustainable business practices. Using four scenario‐based experimental studies alongside analyses of variance (ANOVA) and regression methodologies, we investigated the role of perceived recycling innovativeness in consumers' responses to recycled product advertisements. Our results revealed that consumers are less likely to purchase recycled products made from unique waste materials that are considered more innovative compared to products made from typical waste materials. Furthermore, our findings showed that inferences of low quality mediate the negative effect of innovative recycling on purchase intention. This effect was attenuated by consumers' purchase goals and the availability of recycling process information. This work's theoretical contribution is its expansion of knowledge on how consumers infer recycled products' performance based on information about the source materials. Practically, this work offers recommendations on ways to prevent the negative influence of disclosing source materials used in a recycled product. [ABSTRACT FROM AUTHOR]

The major challenge for the construction industry is to design and produce sustainable construction materials that are efficient in their performance and can be affordable for construction projects. The objective of this study is to determine the viability of incorporating waste products such as sugarcane bagasse ash (SCBA) to produce concrete with polypropylene (PP) fibers. SCBA is an industry waste that has certain pozzolanic properties, however, it shows limited mechanical properties when used as a cement replacement. To improve the mechanical and durability performance, metakaolin (15%) and PP fiber (0.5%, 1%, and 1.5%) were incorporated in the SCBA blend as a ternary additive. Some of the important characteristics explored include compressive strength, tensile strength, density, water absorption, acid resistance, and sorptivity. The study reveals that the incorporation of 15% metakaolin in the composite enhanced the compressive strength by 7%, 8.2%, and 9.1% for PP fiber additions of 0.5%, 1%, 1.5%, while the acid resistance enhanced by 4%, 6% and 8% relative to the control mix for the same value of pp fiber. Furthermore, cost evaluation confirms that the overall costs of concrete with 15% metakaolin and 5% SCBA were 12.2% less than the control concrete, thus making this option economically feasible. This research proves that the inclusion of SCBA, metakaolin, and PP fibers into the concrete mixture brings a sustainable approach that enhances mechanical properties and durability while assisting sugar manufacturing plants in the proper disposal of wastes. [ABSTRACT FROM AUTHOR]

Medical waste management is a crucial issue due to its potential health risks to humans and harm to the environment. The World Health Organization (WHO) advises separating medical waste into seven groups based on its type. However, despite the implementation of color-coded bin bags, cases of missegregation still occur frequently, leading to injuries and spreading diseases. Infectious waste such as sharps, human tissue, and body parts are often found mixed in waste bins, posing a severe threat to waste employees. To address this issue, this paper proposes exploring the potential of digitalization in waste segregation. The literature on current segregation methods and technology applications is analysed and compared, and a framework for utilizing barcode tagging and scanning to ensure waste is correctly categorized is presented. The barcodes and scanner will be connected through a monitoring system, which can notify waste generators and collectors of misplacing or mixed waste. This digitalization system is expected to serve as a monitoring agent for segregating waste before it is collected from any health facilities. Additionally, the exchanged data from waste generator bins can inform collectors and other waste stakeholders about the waste's condition, potentially opening up opportunities for recycling companies to purchase used plastics or metals from hospital wastes. By implementing digitalization in medical waste management, waste segregation can improve, reduce the spread of diseases and injuries, and promote the recycling of hospital waste materials. [ABSTRACT FROM AUTHOR]

Copyright of Low-Carbon Materials & Green Construction is the property of Springer Nature and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Pyrolysis of waste furniture wood, mixed plastics and waste tyres was examined separately and in different combinations from the perspective of improved value products and energy production. The effect of different combinations of furniture wood, plastics and tyres on the product distribution during co-pyrolysis was analyzed. The experimental work throughout this study was performed at a temperature of 500 °C. Prior to the pyrolysis experiments, thermogravimetric analysis was done to assess the thermal degradation behavior of all selected feedstocks. During individual pyrolysis, mixed plastic wastes produced 70.6 wt% of pyrolysis liquid, which is 37.9% and 33.4% more than furniture wood and waste tyres. During co-pyrolysis, a binary blend of mixed plastics and waste tyres produced 63.3 wt% of pyrolysis liquid, which is 7.65% more than the logarithmic mean value, indicating a positive synergistic interaction on liquid production. The liquid yield of the ternary blend was observed to be as low as 54.4 wt% due to the lower volatiles present in the blend. The presence of volatiles in the feedstock is correlated with the production of liquids by individual and co-pyrolysis. For feed-flexible, more efficient, and cleaner operating systems, the increased liquid production offers crucial information. With the use of Fourier transform infrared spectroscopy (FT-IR) and gas chromatography/mass spectroscopy (GC–MS), the impact of different combinations on product characterization was investigated. The characterization study of the pyrolysis liquid obtained from mixed plastics showed the presence of different aromatic and aliphatic compounds. The findings offered viable options for efficiently utilizing waste materials, particularly plastics and tyres to improve the quality and substance of products. [ABSTRACT FROM AUTHOR]

AbstractIn recent years, driven by increasing consumer demand for natural and healthy convenient foods, the food industry has been shifting from synthetic to natural products. This shift is also reflected in the growing popularity of non-conventional extraction methods for pigments, which are favored for sustainability and environment-friendliness compared to conventional processes. This review aims to investigate the extraction of carotenoids from a variety of natural sources, including marine sources like fungus, microalgae, and crustaceans, as well as widely studied plants like tomatoes and carrots. Additionally, it delves into the recovery of valuable carotenoids from waste products like pomace and peels, highlighting the nutritional and environmental benefits. The review also emphasizes the role of green solvents such limonene, vegetable oils, ionic liquids, supercritical fluids, and natural deep eutectic solvents in effective and ecologically friendly carotenoid extraction. These technologies support the ideas of a circular and sustainable economy in addition to having a smaller negative impact on the environment. Overall, the present study highlights the crucial importance of green extraction technologies in achieving the dual goals of sustainability and public safety. [ABSTRACT FROM AUTHOR]

Brain injuries, such as ischemic stroke, cause cell death. Although phagocytosis of cellular debris is mainly performed by microglia/macrophages (MGs/MΦs), excessive accumulation beyond their phagocytic capacities results in waste product buildup, delaying brain cell regeneration. Therefore, it is essential to increase the potential for waste product removal from damaged brains. Lipocalin-type prostaglandin D synthase (L-PGDS) is the primary synthase for prostaglandin D2 (PGD2) and has been reported as a scavenger of waste products. However, the mechanism by which the L-PGDS–PGD2 axis exerts such an effect remains unelucidated. In this study, using a mouse model of ischemic stroke, we found that L-PGDS and its downstream signaling pathway components, including PGD2 and PGD2 receptor DP1 (but not DP2), were significantly upregulated in ischemic areas. Immunohistochemistry revealed the predominant expression of L-PGDS in the leptomeninges of ischemic areas and high expression levels of DP1 in CD36+ MGs/MΦs that were specifically present within ischemic areas. Furthermore, PGD2 treatment promoted the conversion of MGs/MΦs into CD36+ scavenger types and increased phagocytic activities of CD36+ MGs/MΦs. Because CD36+ MGs/MΦs specifically appeared within ischemic areas after stroke, our findings suggest that the L-PGDS–PGD2–DP1 axis plays an important role in brain tissue repair by regulating phagocytic activities of CD36+ MGs/MΦs. [ABSTRACT FROM AUTHOR]

The black soldier fly (BSF) Hermetia Illucens can grow rapidly and on a wide variety of organic materials, and it is extensively used as a means of disposing of household organic waste. Different phases of the life cycle of BSF larvae (BSFL) are used in this work to extract chitin after the removal of lipids, mineral salts, and proteins. Multiple techniques, such as X-ray diffractometry, infrared spectroscopy, solid-state Nuclear Magnetic Resonance (13C ss-NMR) and thermogravimetric analysis, are used to investigate the chemical and physical characteristics of the extracted samples of chitin, which shows a high degree of acetylation (from 78% to 94%). The extracted chitin shows an increase of the thermal stability of 20 °C in the initial stage of life and 35 °C at the end of the life cycle if compared with a commercial standard. Moreover, the extracted chitin shows an increase in the crystallinity degree during the BSFL growth time (from 72% to 78%). [ABSTRACT FROM AUTHOR]

This article studies the practical road performance of recycled materials from construction waste, relying on the paving test section of the supporting project for the Qingdao Cross-Sea Bridge. The research focuses on the construction technology and road performance of using recycled construction waste materials in urban road sub-base construction. Through indoor tests such as sieving and unconfined compressive strength tests, relevant technical indicators were obtained and analyzed. Additionally, periodic core sampling, compaction tests, and rebound deflection tests were conducted on-site according to relevant standards to thoroughly investigate the specific effects of using construction waste in practice and to analyze and evaluate the actual feasibility of the materials for road use. The results indicate that the particle gradation of the construction mix in the test section aligns well with the target gradation, and the dosage of the mixing agent meets the design requirements. The 7-day unconfined compressive strength already satisfied the technical requirements for heavy and extremely heavy traffic on highways as specified in the "Technical Specifications for Construction of Highway Pavement Subbase" (JTG/T F20-2015), with the 14-day strength generally reaching 7 MPa. Core sampling revealed good aggregate gradation, smooth and straight profiles, and the thickness and strength of all parts meet the specifications. The compaction levels met the testing requirements, the surface deflection values showed a decreasing trend, and the deformation resistance was good, consistent with the general development patterns of semi-rigid sub-bases. [ABSTRACT FROM AUTHOR]

Biomass ash is currently attracting the attention of science and industry as an inexhaustible eco-friendly alternative to pozzolans traditionally used in commercial cement manufacture (fly ash, silica fume, natural/calcined pozzolan). This paper explores a new line of research into Marabou weed ash (MA), an alternative to better-known conventional agro-industry waste materials (rice husk, bagasse cane, bamboo, forest waste, etc.) produced in Cuba from an invasive plant harvested as biomass for bioenergy production. The study entailed full characterization of MA using a variety of instrumental techniques, analysis of pozzolanic reactivity in the pozzolan/lime system, and, finally its influence on the physical and mechanical properties of binary pastes and mortars containing 10% and 20% MA replacement content. The results indicate that MA has a very low acid oxide content and a high loss on ignition (30%) and K2O content (6.9%), which produces medium–low pozzolanic activity. Despite an observed increase in the blended mortars' total and capillary water absorption capacity and electrical resistivity and a loss in mechanical strength approximately equivalent to the replacement percentage, the 10% and 20% MA blended cements meet the regulatory chemical, physical, and mechanical requirements specified. Marabou weed ash is therefore a viable future supplementary cementitious material. [ABSTRACT FROM AUTHOR]

Freeze drying (FD) is a technique used to preserve the bioactive content and flavor of samples. Foods with a short shelf life due to nature have been preserved via FD in recent years. The success of the drying technique is thanks to the high retention ability of the bioactive compounds and the flavor of the sample. However, the high cost and energy consumption of FD limit its usage in several fields. Freezing, primary drying, and secondary drying, which take place in the same device, are the stages of FD. In addition, several parameters, including pretreatment, size, temperature, sample species, time, and pressure, affect the FD process. These parameters are controlled to increase the effectiveness of FD on the samples. Moreover, FD has been compared with other drying techniques including hot air drying, microwave drying, vacuum drying, and solar drying to determine its protective capability. It has also been applied to the valorization of waste products, which is a common problem worldwide. For valorization, microencapsulation and powder production have been achieved using FD. In recent years, studies on the effects and use of FD on various materials increased, providing new aspects for the future of science and food industry. [ABSTRACT FROM AUTHOR]

Background: Exposure to military burn pit smoke during deployment is associated with different respiratory and non-respiratory diseases. However, information linking smoke exposure to human pulmonary health is lacking. This study examined the effects of simulated burn pit smoke condensates on human airway epithelial cells (HAECs) from twelve donors (smokers/non-smokers, biological female/male) cultured at an air-liquid interface and exposed to condensates from three simulated burn pit waste materials (cardboard, plywood, and plastic) incinerated at two combustion conditions: smoldering and flaming. Cellular gene expression was analyzed using bulk RNA sequencing, and basolateral media cytokine levels were assessed using multiplex immunoassay. Results: Flaming smoke condensates caused more significant differentially expressed genes (DEGs) with plywood flaming smoke being the most potent in altering gene expression and modulating cytokine release. Cardboard and plywood flaming condensates primarily activated detoxification pathways, whereas plastic flaming affected genes related to anti-microbial and inflammatory responses. Correlation analysis between smoke condensate chemicals and gene expression to understand the underlying mechanism revealed crucial role of oxygenated polycyclic aromatic hydrocarbons (PAHs) and aluminum, molybdenum, and silicon elements; IL6 expression was positively correlated with most PAHs. Stratification of data based on HAEC donor demographics suggests that these affect gene expression changes. Enrichment analysis indicated similarity with several deployment-related presumptive and reported diseases, including asthma, emphysema, and cancer of different organs. Conclusions: This study highlights that simulated burn pit smoke exposure of HAECs causes gene expression changes indicative of deployment-related diseases with more pronounced effects seen in smokers and females. Future studies are needed to further characterize how sex and smoking status affect deployment-related diseases. [ABSTRACT FROM AUTHOR]

Introduction/purpose: This study aimed to develop a cost-effective manual plastic brick extruder for manufacturing composite bricks from recycled polypropylene and brick powder. The goal was to address housing challenges in developing countries while promoting sustainable waste management. Methods: A single screw extruder with a 60 mm die was fabricated, featuring a manual crank, a heating system, and a hopper. Composite specimens with varying polypropylene (30-80 weight percentages) and brick powder (20-70 weight percentages) ratios were produced. Mechanical testing was conducted, including compressive strength, flexural strength, impact resistance, and density measurements. Results: The 40:60 polypropylene:brick powder mixture exhibited optimal compressive strength, ranging from 23.76-24.90 MPa. Flexural strength peaked at the 50:50 ratio (11.86-12.5 MPa). Impact resistance decreased with increasing brick powder content. Density increased linearly with brick powder content, ranging from 1.48-1.77 g/cm³. The extruder successfully produced uniform composite specimens across all mixtures. Conclusions: The study demonstrated the feasibility of producing composite bricks using a low-cost, manually operated extruder. Two optimal mixture compositions were identified: 40:60 polypropylene:brick powder for maximum compressive strength and 50:50 for optimal flexural strength. This approach offers a promising solution for affordable housing construction while addressing plastic waste management in developing regions. Future research should focus on optimizing the extrusion process, exploring additional waste materials, and conducting long-term durability studies of composite bricks. [ABSTRACT FROM AUTHOR]