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Background: Using infection control barriers (ICBs) on light curing units (LCUs) became mandatory to achieve proper infection control measures without jeopardizing the integrity of the restorations, especially at deeper layers. This study explored the effect of two ICBs on the irradiance of the LCU, as well as the degree of conversion (DC) and flexural strength (FS) of two types of bulk-fill composites. Water vapor permeability (WVP) of both barriers was also assessed to evaluate the capability of such barriers to prevent transmission of blood and saliva droplets and aerosols. Methods: Two bulk-fill composites (X-tra fil and Tetric N- ceram) and two ICBs (Pinnacle Cure sleeve and Sanita wrapping film) were used in this study. Light irradiance was recorded per experimental condition using spectroradiometer. For DC and FS, specimens of 4 mm thickness were prepared. Each specimen was composed of two separable upper and lower layers of thickness 2 mm. DC and FS were measured using Infra-red spectroscopy and three-point loading test respectively. WVP was investigated using the cup method. Means and standard deviations were calculated, and the data were statistically analyzed using factorial analysis of variance test (α = 0.05). Results: Light irradiance showed highest values using no ICBs and lowest values using Pinnacle curing sleeve. Both bulk-fill composites showed higher DC mean values without ICBs and when using Sanita wrapping film for both upper and lower layers of the specimens compared to Pinnacle curing sleeve. The upper layers of composite specimens showed higher DC compared to lower layers for all experimental conditions. Both ICBs had no adverse effect on FS of both composites' upper layers. Pinnacle sleeve significantly reduced FS of both composites' lower layers. X-tra fil showed higher DC and FS compared to Tetric N-Ceram for all experimental conditions. Regarding WVP; the wrapping film showed higher WVP compared to the curing sleeve. Conclusions: Sanita wrapping film can be used as a successful ICB, without jeopardizing the concept of bulk-fill composites. Pinnacle cure sleeve can be considered an effective ICB, however its influence on properties and serviceability of bulk-fill composites remains questionable. [ABSTRACT FROM AUTHOR]

The impact of incorporation of Physalis leaf extract (PLE) at various levels on properties and characteristics of the gelatin based three-layer film (Poly (lactic acid)/Gelatin/Poly (butylene adipate-co-terephthalate) was investigated. Three-layer films were developed by a three-step casting process and each layer of film was incorporated with PLE at 0–15% (w/w). Young's Modulus (525.19-164.24 MPa) and tensile strength (22.38–8.38 MPa) of three-layer films decreased with augmented level of PLE (p < 0.05), in contrast elongation at break (13.80-142.56%) was increased (p < 0.05). In general, the incorporation of PLE resulted the three-layer films with lower water vapor permeability ranged from 1.442 to 1.019 × 10–11 g.m.m− 2.s− 1.Pa− 1 than the control counterpart (P/G/B-PLE-0%) (without PLE) (1.473 × 10–11 g.m.m− 2.s− 1.Pa− 1) (p < 0.05). Greenness (-a* value) of the resulting films increased with augmenting incorporation ratios of PLE (p < 0.05). The lower transparency value (7.41) was recorded for control film (without extract) (p < 0.05). However, PLE incorporated three-layer film exhibited compact structure as revealed by SEM micrographs. Thermal properties of obtained three-layer film were impacted by the addition of plant extract. Thus, the enhanced water vapor barrier property and improved elasticity were obtained for PLA/Gelatin/PBAT films incorporated with PLE. [ABSTRACT FROM AUTHOR]

Biodegradable films based on natural molecules are used for food production protection to extend shelf life. The current work aimed to fabricate and characterize bionanocomposite films. The biodegradable films were prepared from a mixture of tapioca starch/bovine gelatin (TB) with the loading of roselle calyx extract (RCE) and zinc oxide nanorod (ZnO-N). The incorporation of ZnO-N and RCE improved the mechanical and barrier properties of films. ZnO-N/RCE and RCE incorporated composite films indicated lower water vapor permeability (WVP) than neat film, 3.36 ×10-7, 3.96×10-7, and, 4.2×10-7 g/mPah respectively. Elongation at break, Young's modulus, and tensile strength of TB film, TB/RCE, and TB/RCE/ZnO-N film were measured as follows: 18.44%, 14.56%, and 10.69%; 0.79 MPa, 1.52 MPa, and 2.65 MPa; and 14.4 MPa, 21.85 MPa, and 28.22 MPa, respectively. The solubility of the active films decreased from 40.33% to 33.68% by the addition of RCE and ZnO-N into the composite matrix. This study indicated composite films based on starch/protein incorporated RCE and ZnO-N have the positive potential for applications in bionanocomposite packaging. [ABSTRACT FROM AUTHOR]

Ca2+ can boost protein-protein interactions and, if present at an appropriate level, can potentially improve some physicochemical properties of protein-based gels and films. This study aimed to determine the effects of CaCl2 (0%–0.05% w/w) on the microstructural, optical, water affinity, and mechanical characteristics of glycerol (Gly)- and sorbitol (Sor)-plasticized pea protein isolate (PPI)-based films. CaCl2 caused darkening and a color shift of the films from yellow to yellow-green. Additionally, decreased light transmission, particularly in the UV range, acidification, and reduced moisture content were observed. CaCl2 decreased the water vapor permeability of the Gly plasticized film by an average of 20% with no effect on the Sor-plasticized film. All films were completely soluble in water. CaCl2 negatively impacted the mechanical integrity of the films, reducing the tensile strength of the Gly- and Sor-plasticized films by ~16% and 14%–37%, respectively. Further increases in CaCl2 content (0.1% and 0.2% w/w) led to concentration-dependent microvoids resulting from protein over-crosslinking and/or coagulation. In summary, the incorporation of CaCl2 into PPI-based films did not provide significant benefits and actually worsened key properties, such as transparency and mechanical strength. The type of plasticizer influenced how CaCl2 affected some properties of the PPI-based film. [ABSTRACT FROM AUTHOR]

Abstract Background Using infection control barriers (ICBs) on light curing units (LCUs) became mandatory to achieve proper infection control measures without jeopardizing the integrity of the restorations, especially at deeper layers. This study explored the effect of two ICBs on the irradiance of the LCU, as well as the degree of conversion (DC) and flexural strength (FS) of two types of bulk-fill composites. Water vapor permeability (WVP) of both barriers was also assessed to evaluate the capability of such barriers to prevent transmission of blood and saliva droplets and aerosols. Methods Two bulk-fill composites (X-tra fil and Tetric N- ceram) and two ICBs (Pinnacle Cure sleeve and Sanita wrapping film) were used in this study. Light irradiance was recorded per experimental condition using spectroradiometer. For DC and FS, specimens of 4 mm thickness were prepared. Each specimen was composed of two separable upper and lower layers of thickness 2 mm. DC and FS were measured using Infra-red spectroscopy and three-point loading test respectively. WVP was investigated using the cup method. Means and standard deviations were calculated, and the data were statistically analyzed using factorial analysis of variance test (α = 0.05). Results Light irradiance showed highest values using no ICBs and lowest values using Pinnacle curing sleeve. Both bulk-fill composites showed higher DC mean values without ICBs and when using Sanita wrapping film for both upper and lower layers of the specimens compared to Pinnacle curing sleeve. The upper layers of composite specimens showed higher DC compared to lower layers for all experimental conditions. Both ICBs had no adverse effect on FS of both composites’ upper layers. Pinnacle sleeve significantly reduced FS of both composites’ lower layers. X-tra fil showed higher DC and FS compared to Tetric N-Ceram for all experimental conditions. Regarding WVP; the wrapping film showed higher WVP compared to the curing sleeve. Conclusions Sanita wrapping film can be used as a successful ICB, without jeopardizing the concept of bulk-fill composites. Pinnacle cure sleeve can be considered an effective ICB, however its influence on properties and serviceability of bulk-fill composites remains questionable.

This purpose of the present study was to develop and characterizing edible films composed of a starch matrix incorporated with varying percentages of rice bran oil (RBO). The incorporation of oil into starch films led to changes in their physical, morphological, optical, barrier, and mechanical properties. Glycerol, serving as the plasticizer, was added in a ratio of 0.1g/g of starch, while RBO and Tween 80 as an emulsifying agent were incorporated in a 2:1 (V/V) ratio, respectively. The addition of RBO, along with Tween 80 to the starch suspension improved the films' mechanical properties. Specifically, there was a significant increase (P < 0.05) observed in elongation at break (EAB) values, tensile strength, water solubility, optical properties, and moisture content of the films. The inclusion of RBO at a concentration of 1ml, reduced water vapor permeability (WVP), with values decreasing from 3.95×10gm-1s-1Pa-1 (WVP) to 3.47×10gm-1s-1Pa-1. The findings demonstrate that the synthesized films exhibited uniformity, homogeneity, and consistency. Scanning electron microscopy (SEM) and Fourier-transform infrared spectroscopy (FTIR) analysis revealed morphological and functional characteristics of the films. The shifting of the peak intensity at 1640 cm-1 and 2844 cm-1 indicated the bond formation of RBO and starch polymer. Compact cross-section of the films, indicating strong compatibility, minimized film desiccation, and oil loss. [ABSTRACT FROM AUTHOR]

Petroleum-based general-purpose polymers, like polyethylene and polypropylene, have become the most economical and practical solution for packaging applications due to their characteristics, such as low cost, excellent optical, mechanical, and barrier properties. However, the significant environmental issues associated with the extensive use of these synthetic polymers have prompted searches for new sustainable alternatives. In pursuit of a carbon–neutral economy, the aim of this work is to develop a nanocomposite film combining high barrier property and transparency, suitable for packaging purpose, utilizing commercial cellulose derivatives (carboxymethyl cellulose, CMC) and 2D non-toxic layered double hydroxide nanosheets (LDH-NSs). Employing a simple, eco-friendly method, the nanocomposite films (CMC/LDH-NS) are fabricated by mixing and casting a mixed suspension from a CMC solution and an LDH-NS suspension, facilitated by a non-toxic exfoliation method in an aqueous amino acid solution. The effects of different ratios of LDH-NS on the barrier properties and transparency of the nanocomposite films are studied, along with the related mechanism through comprehensive analysis of micromorphology, X-ray diffraction, and Fourier-transform infrared spectroscopy. The CMC/LDH-NS films present a remarkable 252-fold increase of oxygen barrier and a 51% improvement in water vapor barrier performance compared to the pure CMC film. Moreover, the nanocomposite films maintain high light transmittance, with values exceeding 80% at 600 nm, even at a 50% LDH-NS:CMC ratio. These outstanding attributes underscore the potential of CMC/LDH-NS nanocomposite films for broad application in food and pharmaceutical packaging, as well as in electronic encapsulation, marking a significant step forward in the development of sustainable packaging solutions. [ABSTRACT FROM AUTHOR]

Metal cans, while boasting excellent barrier properties, raise concerns about leaching and environmental impacts. This study explored plastic trays, a potential alternative for canned food packaging. First we delved into the plastic tray's characteristics, including its composition and permeability to oxygen and water vapor. Secondly, we conducted a comparison between the newly introduced plastic packaging and traditional metal cans, focusing on their interactions with food during the sterilization process and their effects on the quality of Tunisian pea sauce. The composition analysis revealed that the plastic tray was composed of polypropylene (PP) (with a single endothermic peak at 168 °C), while the film was found to have a mixture of PP internally and polyethylene terephthalate (PET) externally (with two endothermic peaks at 161.96 °C and 243.81 °C). Plastic trays showed good results in water vapor permeability (0.832 g/m2.d) but exhibited higher oxygen permeability (190 g/m2.d), raising oxidation concerns. Migration testing confirmed plastic packaging safety (<10 mg/dm2), while some simulants exceeded limits in metal cans. pH levels remained consistent between both packaging types, but varied significantly over a 28-day storage. Total Volatile Basic Nitrogen (TVBN) levels differed significantly between plastic and metal packaging, with notable variations observed over time with maximums of 0.3 mg/100 g for plastic trays and 0.17 mg/100 g for metal cans. Sensory evaluation revealed that tasters were adept at differentiating between canned pea sauce in plastic trays and metal cans (83%, 10/12), with taste and color exhibiting significant differences (p < 0.05). This underlines the impact of packaging material on canned food quality and consumer preference, with minimal influence on other sensory aspects. This data empowers manufacturers to make informed packaging decisions for a diverse range of canned foods. [ABSTRACT FROM AUTHOR]

A sustainable polylactide (PLA)‐based multilayer food packaging film was developed to improve neat PLA films' modest mechanical, thermal, and water/gas barrier properties. To improve the desired properties and impart antimicrobial aspects to the composite films, graphene nanoplatelets (GNP), and geraniol (GER) were reinforced into single‐layered PLA films. The project aimed to assemble three monolayers into multilayer films (MLF) through a coextrusion process, keeping the PLA‐GER layer in the core. X‐ray diffractograms, micrographs, and roughness parameters of the films demonstrated the dispersion of GNP in the film. Thermogravimetric analysis confirmed an enhancement in the thermal stability of the MLF by around 8°C when compared against single‐layer PLA films. An improvement in mechanical rigidity was supported by tensile (>87%) and rheological measurements. The polymers exhibit liquid‐like behavior in melts. Barrier properties did not improve for the MLF due to the agglomeration of GNP. The excellent antimicrobial properties of the MLFs for 3 weeks of storage at refrigerated conditions against both gram‐positive and gram‐negative pathogens were attributed to the release of GER from the film into the packed chicken samples and proved their potential for use in the food industry. [ABSTRACT FROM AUTHOR]

Anthocyanins are amazing plant-derived colorants with highly valuable properties; however, their chemical and color instability issues limit their wide application in different food industry-related products such as active and intelligent packaging. In a previous study, it was demonstrated that anthocyanins could be stabilized into green plasticizers namely deep eutectic solvents (DESs). In this work, the fabrication of edible films by integrating anthocyanins along with DESs into biocompatible chitosan (CHT)-based formulations enriched with polyvinyl alcohol (PVA) and PVA nanoparticles was investigated. CHT/PVA-DES films' physical properties were characterized by scanning electron microscopy, water vapor permeability, swelling index, moisture sorption isotherm, and thermogravimetry analysis. Innovative red-to-blue formulation films were achieved for CHT/PVA nanoparticles (for 5 min of sonication) at a molar ratio 1:1, and with 10% of ternary DES (TDES)-containing malvidin-3-glucoside (0.1%) where the physical properties of films were enhanced. After immersion in solutions at different pH values, films submitted to pHs 5–8 were revealed to be more color stable and resistant with time than at acidic pH values. [ABSTRACT FROM AUTHOR]

Comfort is the prime need in clothing. It is affected by the properties of fibers, yarns, and fabrics. A good understanding of these factors is essential in the design and conception of functional clothes. Fabric design serves as a manufacturing tool to meet several end-use requirements. The construction specifications and design of knitted fabrics greatly influence the comfort level of the end-use garment. This study aims to investigate the effect of the knitting stitch type and the dyeing process on the clothing comfort of knitted fabrics. For this purpose, five structures were prepared by combining plain, float and tuck stitches: plain jersey, cross miss 1 × 1, single cross tuck, weft lock knit and Lacoste. Then, yellow, and black dyeing were applied. The investigated wear comfort properties were the drying time, the air permeability and the relative water vapor permeability. Tests were conducted on the finished and on domestically washed fabrics. The data obtained were statistically evaluated with Pearson correlation, paired t -test, analysis of variance analysis and the Tukey test. The results showed that tucked fabrics have the longest drying time combined with the lowest air and water vapor permeability. Black variants showed better drying behavior and higher water vapor permeability. Analysis of variance results showed that the structure has a significant effect on clothing comfort. However, the dyeing process exerts a significant influence only on the drying time and the relative water vapor permeability. The paired t -test results indicate that the domestic washing cycles significantly change the drying time and the air permeability of knitted fabrics. [ABSTRACT FROM AUTHOR]

The purpose of this study was to obtain a biodegradable film based on polyvinyl alcohol with reduced water vapor permeability. The hydrophobic character of the films was achieved by incorporating beeswax, vegetable bio-surfactant, citric acid as a cross-linking agent, and glycerol to provide elasticity, along with the application of thermal treatment. Water vapor permeability was determined gravimetrically. The results indicated that all films produced had lower water vapor permeability compared to unmodified or untreated polyvinyl alcohol films. The barrier to water vapor varied directly with the mass of beeswax used, and the homogeneous dispersion of beeswax in the polyvinyl alcohol matrix was essential for achieving an efficient hydrophobic film. The best performing-material exhibited a water vapor permeability 5.15 times lower than that of the neat polyvinyl alcohol and 15 times higher than that of polyethylene. Considering the fact that the water vapor barrier property of neat polyvinyl alcohol was 78 times lower than that of polyethylene, the combination of beeswax, citric acid, and vegetable bio-surfactant—along with thermal treatment—can be a viable solution to reduce the hygroscopicity of polyvinyl alcohol-based films. [ABSTRACT FROM AUTHOR]

This study presents an analysis of films which consist of two layers; one layer is PVDF as the matrix, along with fillers BaTiO3 (BT), and the second is one bacterial nanocellulose (BNC) filled with Fe3O4. The mass fraction of BT in PVDF was 5%, and the samples were differentiated based on the duration of the mechanical activation of BT. This innovative PVDF laminate polymer with environmentally friendly fillers aligns with the concept of circular usage, resulting in a reduction in plastic content and potential improvement of the piezoelectric properties of the entire composite. This work presents new, multifunctional "green" packaging materials that potentially could be a good alternative to specific popular materials used for this purpose. The synthesis of the films was carried out using the hot press method. Tensile tests, water vapor permeability examination, and structural analyses using SEM-EDS and FTIR have been conducted. The sample PVDF/BT20/BNC/Fe3O4 exhibited the best barrier properties (impermeability to water vapor), while the highest tensile strength and toughness were exhibited by the PVDF/BT5/BNC/Fe3O4 sample. [ABSTRACT FROM AUTHOR]

Active packaging is an innovative approach to prolonge the shelf-life of food products while ensuring their quality and safety. Carbon dots (CDs) from biomass as active fillers for biopolymer films have been introduced to improve their bioactivities as well as properties. Gelatin/chitosan (G/C) blend films containing active guava leaf powder carbon dots (GL-CDs) at various levels (0–3%, w/w) were prepared by the solvent casting method and characterized. Thickness of the control increased from 0.033 to 0.041 mm when 3% GL-CDs were added (G/C-CD-3%). Young's modulus of the resulting films increased (485.67–759.00 MPa), whereas the tensile strength (26.92–17.77 MPa) and elongation at break decreased (14.89–5.48%) as the GL-CDs' level upsurged (p < 0.05). Water vapor barrier property and water contact angle of the film were enhanced when incorporated with GL-CDs (p < 0.05). GL-CDs had a negligible impact on film microstructure, while GL-CDs interacted with gelatin or chitosan, as determined by FTIR. The release of GL-CDs from blend films was more pronounced in water than in alcoholic solutions (10–95% ethanol). The addition of GL-CDs improved the UV light barrier properties and antioxidant activities of the resultant films in a dose-dependent manner. Thus, GL-CD-added gelatin/chitosan blend films with antioxidant activities could be employed as potential active packaging for the food industry. [ABSTRACT FROM AUTHOR]

The thermal, rheological, mechanical, and barrier properties of flat biopolymeric films processed by extrusion with different proportions of plasticizer and surfactant were evaluated. In the first stage, pellets were developed through twin-screw extrusion using a temperature profile in the ascending step process. These samples were analyzed using rotational rheology analysis to understand the viscoelastic transitions through the behavior of the storage and loss modulus, as well as the incidence of complex viscosity concerning concentration. The interaction among the components was analyzed under infrared spectroscopy after the two processing stages, revealing the miscibility of the mixture due to the action of the surfactant. The degradation temperatures increased by more than 20 °C, generating thermal stability, and the temperatures related to polymer transitions were determined. In the second stage, co-extrusion was carried out using pellets from the blend with a melt flow index (MFI) suitable for this process. The samples TPS50-PLA50-T5 and TPS75-PLA25-T5-A10 presented MFI values of 2.27 and 1.72 g/10 min, respectively. These samples were co-extruded for the production of films, impacting the physical properties. The resistance to traction, Young's modulus, and elongation showed limited effectiveness of plasticizer and surfactant, with high resistance and elongation values (4.276 MPa and 2.63%) in the TPS50-PLA50-T5 film. Additionally, morphological analysis showed the detailed action of the plasticizer on the regular shapes of threads as a product of deformation during material processing. The barrel properties exhibited limited biopolymer–plastic–tensile miscibility, resulting in different water vapor permeability for the TPS75-PLA25-T5-A10 film on each side (a difference of two orders of magnitude). The contact angle corroborated the effect, with values in each case ranging from 103.7° to 30.3°. In conclusion, we assert that biopolymeric films, when modified with plasticizers and surfactants, can be tailored for various applications within the packaging sector while maintaining control over each film. [ABSTRACT FROM AUTHOR]

This article presents analyzed data on the antimicrobial, barrier, and mechanical properties inherent to films created by blending carrot pomace with wheat gluten and polyglycerol-3 plasticizer and combined with varying contents (0 wt.%, 3 wt.%, and 5 wt.%) of eugenol, a natural antimicrobial compound derived from essential oils. The integration of carrot pomace, wheat gluten, plasticizer, and eugenol involved meticulous mortar and pestle processing, ensuring a homogenous blend. Subsequently, the mixture was compression-molded in a hydraulic press to fabricate the films. Standard bacteria strains—Escherichia coli ATCC 25922 and Staphylococcus aureus ATCC 6538—are used in the antimicrobial evaluation, and antimicrobial efficacy is measured using OD600 measurements. Water vapor permeability (WVP) measurement effectively defines the films' potential to prevent water vapor infiltration. Mechanical properties are assessed by determining elastic modulus, tensile strength, and elongation at break, which together reveal the films' adaptive flexibility and durability. The dataset presented herein holds substantial promise for food packaging applications. Researchers in the food packaging industry can leverage the antimicrobial and barrier property data to design novel packaging materials, potentially enhancing shelf-life and food safety. Engineers and material scientists can utilize the mechanical properties data to develop structurally robust and flexible materials.

We prepared polysaccharide films from silylated chitosan cross-linked with starch using six kinds of carboxylic acids (oxalic, maleic, citric, succinic, azelaic and sebacic acids) to explore the effects of molecular structures of cross-linkers on the mechanical, hydrophobic and water vapor permeability properties of these hydrophobicity-enhanced films. The films were analyzed by FT-IR, SEM, mechanical tests (stress versus strain, tensile strength and elongation at break curves) as well as the measurements of water contact angle, water solubility and water vapor permeability rate. We observed that the cross-linkers with a long chain provide a large mechanical strength; the tensile strength increases from 6 to 27 MPa with the chain length of dicarboxylates. The hydrophobicity, evaluated by the contact angle (ranging 80° ∼ 120°), increased with the chain length of the cross-linkers and was correlated well with the decreases of the solubility (94 ∼ 17%) and vapor permeability rate of water (14.5 ∼ 1.5 × 10−12 g s−1 m−1 Pa−1). We demonstrate that these mechanical, hydrophobic and water permeability properties are varied considerably only by the choice of the cross-linking acid also in the hydrophobicity-enhanced film by pre-silylation, which may widen the range of potential applications of polysaccharide film such as food packaging.

Nowadays, as consumer expectations have increased worldwide, the importance of polymer materials performance has been raised to a new level. Efforts are required to produce a high-quality product that maintains its quality despite aging factors in certain geographical locations. In the experimental part of this study, polyester materials produced from conventional and recycled yarns, further intended for the production of sportswear, were exposed to natural weathering. Before and after the exposure, the following material properties were investigated: material surface appearance, material thickness, mass per unit area, horizontal and vertical density, surface roughness, tensile properties (force at break, elongation at break), water vapor permeability, liquid dispersion and drying of the material. The results indicate that the surface mass and thickness of all exposed polyester materials decreased after aging due to material shrinkage. The results indicated that prolonged aging negatively affected the values of elongation and force at break. The recycled material exhibited the highest overall decreases in elongation and force at break, but lower surface roughness. In addition, recycled material exhibited a shorter drying time than that of conventional material, both before and after aging. [ABSTRACT FROM AUTHOR]

H2O(g) adsorption-desorption of cementitious materials and their permeability is a vital indicator for their durability designs, which significantly affects the occurrences of corrosion, carbonization and freeze–thawing, but its quantitative characterization has yet to be investigated in depth. In this study, H2O(g) adsorption-desorption of cementitious materials with various w/c ratios (0.35–0.55) and its induced permeability were investigated using a self-created cup apparatus under isothermal steady-state flow and compared with N2 gas permeability by the modified Cembureau method. The results showed that the cementitious materials with a low w/c ratio have stronger water-holding characteristics, and there is an obvious inflection point in the adsorption curve [i.e., relative humidity (RH)=70%]·H2O(g) permeability measurement of cementitious materials was successfully carried out using a self-created cup apparatus, which is fundamentally an exponential function relationship to its N2 gas permeability. The conversion relation is helpful to enhance the multimedium evaluations of durability for cementitious materials. [ABSTRACT FROM AUTHOR]

Processing residues are still one of the main obstacles in the fishing industry due to waste and environmental impact. With that, ways of reusing these residues are researched to generate new products with different applications. The objective of this work was to develop and evaluate protein films obtained from mechanically separated meat (MSM) of Nile tilapia (Oreochromis niloticus) filleting residues. To get the films, the casting technique was used, varying their composition in relation to the amount of protein (1.0, 1.5 and 2.0%) and glycerol (0.0, 0.1 and 0.2%), creating a 3² factorial plan, with 9 treatments. The films were characterized in terms of color, opacity, water solubility, mechanical properties and water vapor permeability (WVP). In the end, a yield of 18.70% of Nile tilapia myofibrillar proteins (MPs) and a post-lyophilization protein content of 87.33% were obtained. It was concluded that the film that presented the best result in all the characteristics analyzed was the one with 1.0% of MPs and 0.1% of glycerol. [ABSTRACT FROM AUTHOR]

Three-layer eco-packaging films from fish skin gelatin, poly (lactic acid) (PLA) and poly (butylene adipate-co-terephthalate) (PBAT) were developed at different dry weight ratios and referred to as 'P5/G90/B5, P10/G80/B10, P15/G70/B15, P20/G60/B20 and P25/G50/B25' and analyzed for their properties with their corresponding control films (G100, P100 and B100). Thickness of three-layer films reduced with increased ratio of PLA and PBAT (p < 0.05). Elasticity of three-layer films was improved by the addition of PBAT layer. In general, control gelatin film showed the highest water vapor permeability (6.161 × 10− 11 g.m.m− 2.s− 1.Pa− 1) (p < 0.05). Lightness value (L*) of three-layer films increased when compared with PLA and gelatin film. Highest transparency value of 20.41 was found for control PBAT film (p < 0.05). Solubility of three-layer films in water reduced with the inclusion of bioplastics. The functional groups and secondary structure of developed films were observed by ATR-FTIR spectra. TGA and DSC analyses confirmed the improved thermal properties of resulted three-layer film. Thus, the addition of bioplastics enhanced the properties of films and developed three-layer eco-packaging materials might gradually replace the synthetic plastic packaging in near future. [ABSTRACT FROM AUTHOR]

Banana pseudo-stem, often considered as an underutilized plant part was explored as a potential reinforced material to develop an eco-friendly biofilm for food packaging applications. In this study, Microcrystalline cellulose (MCC) was extracted from banana pseudo-stem by alkali and acid hydrolysis treatment. The extracted MCC was used as a reinforced material in different concentrated polyvinyl alcohol (PVA) matrix alone as well as both PVA and Carboxymethyl Cellulose (CMC) matrix to develop biofilm by solvent casting method. The synthesized MCC powder was characterized by scanning electron microscope to ensure its microcrystalline structure and to observe surface morphology. The biofilms composed of MCC, PVA, and CMC were assessed through Fourier-transform infrared spectroscopy (FTIR), mechanical properties, water content, solubility, swelling degree, moisture barrier property (Water Vapor Permeability - WVP), and light barrier property (Light Transmission and Transparency). The FTIR analysis showed the rich bonding between the materials of the biofilms. The film incorporating a combination of PVA, CMC, and MCC (S6) exhibited the highest tensile strength at 26.67 ± 0.152 MPa, making it particularly noteworthy for applications in food packaging. MCC incorporation increased the tensile strength. The WVP content of the films was observed low among the MCC-induced films which is parallel to other findings. The lowest WVP content was showed by 1% concentrated PVA with MCC (S4) (0.223 ± 0.020 10−9 g/Pahm). The WVP content of S6 film was also considerably low. MCC-incorporated films also acted as a good UV barrier. Transmittance of the MCC induced films at UV range were observed on average 38% (S2), 36% (S4) and 6% (S6) which were almost 6% lower than the control films. The S6 film demonstrated the lowest swelling capacity (1.42%) and water content, indicating a significantly low solubility of the film. The film formulated with mixing of PVA, CMC and MCC (S6) was ahead in terms of food packaging characteristics than other films. Also, the outcomes of this study point out that MCC can be a great natural resource for packaging applications and in that regard, banana pseudo-stem proves to be an excellent source for waste utilization.

ABSTRACT Processing residues are still one of the main obstacles in the fishing industry due to waste and environmental impact. With that, ways of reusing these residues are researched to generate new products with different applications. The objective of this work was to develop and evaluate protein films obtained from mechanically separated meat (MSM) of Nile tilapia (Oreochromis niloticus) filleting residues. To get the films, the casting technique was used, varying their composition in relation to the amount of protein (1.0, 1.5 and 2.0%) and glycerol (0.0, 0.1 and 0.2%), creating a 32 factorial plan, with 9 treatments. The films were characterized in terms of color, opacity, water solubility, mechanical properties and water vapor permeability (WVP). In the end, a yield of 18.70% of Nile tilapia myofibrillar proteins (MPs) and a post-lyophilization protein content of 87.33% were obtained. It was concluded that the film that presented the best result in all the characteristics analyzed was the one with 1.0% of MPs and 0.1% of glycerol.

Anthocyanins are amazing plant-derived colorants with highly valuable properties; however, their chemical and color instability issues limit their wide application in different food industry-related products such as active and intelligent packaging. In a previous study, it was demonstrated that anthocyanins could be stabilized into green plasticizers namely deep eutectic solvents (DESs). In this work, the fabrication of edible films by integrating anthocyanins along with DESs into biocompatible chitosan (CHT)-based formulations enriched with polyvinyl alcohol (PVA) and PVA nanoparticles was investigated. CHT/PVA-DES films’ physical properties were characterized by scanning electron microscopy, water vapor permeability, swelling index, moisture sorption isotherm, and thermogravimetry analysis. Innovative red-to-blue formulation films were achieved for CHT/PVA nanoparticles (for 5 min of sonication) at a molar ratio 1:1, and with 10% of ternary DES (TDES)-containing malvidin-3-glucoside (0.1%) where the physical properties of films were enhanced. After immersion in solutions at different pH values, films submitted to pHs 5–8 were revealed to be more color stable and resistant with time than at acidic pH values.

In the evolving landscape of food packaging, lipid-based edible films and coatings are emerging as a sustainable and effective solution for enhancing food quality and prolonging shelf life. This critical review aims to offer a comprehensive overview of the functional properties, roles, and fabrication techniques associated with lipid-based materials in food packaging. It explores the unique advantages of lipids, including waxes, resins, and fatty acids, in providing effective water vapor, gas, and microbial barriers. When integrated with other biopolymers, such as proteins and polysaccharides, lipid-based composite films demonstrate superior thermal, mechanical, and barrier properties. The review also covers the application of these innovative coatings in preserving a wide range of fruits and vegetables, highlighting their role in reducing moisture loss, controlling respiration rates, and maintaining firmness. Furthermore, the safety aspects of lipid-based coatings are discussed to address consumer and regulatory concerns.

Abstract Natural origin products are an appealing substitute for nonbiodegradable materials in the production of new materials to improve the packaging properties and to extend the shelf life quality of foods. The objective of this study was to formulate, elaborate, select, partially characterize, and evaluate the biological properties of an edible film based on pectin, candelilla wax, and glycerol, added with pomegranate peel polyphenols (PPP). An exploratory design 2k Box Hunter and Hunter was made, followed by a Box‐Behnken design 3k to evaluate the properties of water vapor permeability (WVP) of the film, resulting in the film with 0.75% w/v of pectin, 0.2% w/v of candelilla wax, 0.05% v/v of glycerol and 0.02% w/v of PPP with one of the lowest values of WVP (1.78E−10 g/m.s.Pa). After characterization, this treatment showed good structural and optical properties and low humidity values compared to a control film. PPP showed the inhibitory capacity for DPPH (61.2%) and ABTS (48.5%) radicals and reducing activity with the reduction of ferric ion (FRAP) reaching a value of 1676.5 mg TE/g PPP.

The aim of the present work is the development and characterization of new formulation of emulsified films based on soluble starch/sodium alginate blend and microcrystalline wax. The developed films were studied in order to use them as new formulations to produce food packaging. The obtained films were generally homogeneous, thin, and slightly flexible. These films appeared more opaque compared to the non-emulsified film. Incorporation of microcrystalline wax was caused modifications of mechanical properties of films; these modifications were principally due to the formation of amylose–lipid complex. It was found that microcrystalline significantly reduced film water vapor permeability (WVP) of emulsified films. Atomic force microscope (AFM) was used to evaluate surface topography and roughness of the films. The surface topography was significantly affected, in the other word high roughness values were obtained. Microemultion formation in which the microcrystalline wax particles are distributed homogeneously within the polymer matrix was investigated by scanning electron microscopy (SEM). Moreover, the polysaccharides blend/microcrystalline wax emulsified films can be useful as a biodegradable packaging material to maintain the quality of food products. [ABSTRACT FROM AUTHOR]

Passion fruit (Passiflora edulis f. flavicarpa Degener) is not widely traded due to its short shelf life. Edible coatings can be used to extend the postharvest life of fruits. The objective of this study was to develop a candelilla wax-based coating (Euphorbia antisyphilitica Zucc) for the preservation of passion fruit. Three coating formulations (C1, C2, and C3) were made with pectin, glycerol, and candelilla wax and applied by immersion. Weight loss and changes in physical appearance were used to assess shelf life under two storage conditions: room temperature (32 °C/6 days) and refrigeration (6.6 °C/32 days). Uncoated fruit in both storage conditions served as controls. Furthermore, a physicochemical characterization of the coatings was performed. Coated fruit at room temperature showed an improvement in weight retention compared to controls, but no differences in physical appearance were observed. In fruits stored under refrigeration, only C2 had less weight loss compared to the control, while C3 maintained a better physical appearance. In terms of coating characterization, C3 presented the lowest moisture content and thickness. C1 obtained the highest density value, while C1 also had the highest water vapor permeability rate (TPVA) value. The application of the C2 coating was effective in preserving the fruit for a longer period of time, and this coating has the lowest TPVA value, which is related to the decrease in weight loss in the fruit. [ABSTRACT FROM AUTHOR]

The current work focuses on the synthesis of the biodegradable film made from Sodium alginate (S.A), and then the addition of magnesium oxide nanoparticles (MgO-NPs) was synthesized by sol-gel technique. Glycerol which is a plasticizer is used to enhance the tensile strength (TS) and film expansion due to a decrease in intermolecular forces in the polymer chain. With the addition of olive oil (OE), the functional properties of control films were improved, which results in a lowering of water solubility, and moisture content but the tensile strength slightly decreased. The opacity, moisture absorption, and solubility of the film, thickness, tensile strength (TS), elongation (EB), ultraviolet-vis spectroscopy, scanning electron microscope (SEM), transmission electron microscopy (TEM) were used to characterize sodium alginate biofilm with the addition of MgO-NPs (SA1) and without the addition of MgO-NPs (SA2). But considering all other factors, the film (SA1) revealed a slower rate of degradation than the film (SA2). The film's TS and opacity are enhanced by MgO-NPs addition, while moisture content (WVP), solubility, and elongation at break are decreased. [ABSTRACT FROM AUTHOR]

In recent years, there has been a growing attempt to manipulate various properties of biodegradable materials to use them as alternatives to their synthetic plastic counterparts. Alginate is a polysaccharide extracted from seaweed or soil bacteria that is considered one of the most promising materials for numerous applications. However, alginate potential for various applications is relatively limited due to brittleness, poor mechanical properties, scaling-up difficulties, and high water vapor permeability (WVP). Choosing an appropriate plasticizer can alleviate the situation by providing higher flexibility, workability, processability, and in some cases, higher hydrophobicity. This review paper discusses the main results and developments regarding the effects of various plasticizers on the properties of alginate-based films during the last decades. The plasticizers used for plasticizing alginate were classified into different categories, and their behavior under different concentrations and conditions was studied. Moreover, the drawback effects of plasticizers on the mechanical properties and WVP of the films are discussed. Finally, the role of plasticizers in the improved processing of alginate and the lack of knowledge on some aspects of plasticized alginate films is clarified, and accordingly, some recommendations for more classical studies of the plasticized alginate films in the future are offered. [ABSTRACT FROM AUTHOR]

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The purpose of this study was to obtain a biodegradable film based on polyvinyl alcohol with reduced water vapor permeability. The hydrophobic character of the films was achieved by incorporating beeswax, vegetable bio-surfactant, citric acid as a cross-linking agent, and glycerol to provide elasticity, along with the application of thermal treatment. Water vapor permeability was determined gravimetrically. The results indicated that all films produced had lower water vapor permeability compared to unmodified or untreated polyvinyl alcohol films. The barrier to water vapor varied directly with the mass of beeswax used, and the homogeneous dispersion of beeswax in the polyvinyl alcohol matrix was essential for achieving an efficient hydrophobic film. The best performing-material exhibited a water vapor permeability 5.15 times lower than that of the neat polyvinyl alcohol and 15 times higher than that of polyethylene. Considering the fact that the water vapor barrier property of neat polyvinyl alcohol was 78 times lower than that of polyethylene, the combination of beeswax, citric acid, and vegetable bio-surfactant—along with thermal treatment—can be a viable solution to reduce the hygroscopicity of polyvinyl alcohol-based films.

Edible film biopolymers are gaining attention to tackle problems of plastic waste and food safety to alleviate environmental problems associated with plastic products in food packaging. In this study, caseinate–carboxymethyl chitosan (CA–CMCH) composite films were made with the incorporation of soybean oil (SO) using a casting technique. The influence of different soybean oil concentrations at 0, 0.5, and 1% (w/w) on physical, mechanical, barrier, and surface characteristics of films composed of caseinate–carboxymethyl chitosan (CA–CMCH) was evaluated. The brightest film (L* value of 95.95 ± 0.30) was obtained with the edible film made from the control group of samples with sodium caseinate (NaCA-100; 100% NaCA). The results also indicated that samples with 1% SO in NaCA-75 and CaCA-75 had lower water vapor permeability (WVP), while those with NaCA-50 and CaCA-50 showed higher values of WVP. For mechanical properties, this study found that incorporating soybean oil into the caseinate–carboxymethyl (CA–CMCH) composite films led to an enhancement of both tensile strength and elongation at break. The morphological structures, determined using SEM, of control and composite films showed compact and homogenous surfaces. Overall, the addition of soybean oil contributed to the improvement of the functional properties of the edible films, offering potential solutions to the environmental issues associated with plastic packaging and enhancing the safety and performance of food packaging.

Active packaging is an innovative approach to prolonge the shelf-life of food products while ensuring their quality and safety. Carbon dots (CDs) from biomass as active fillers for biopolymer films have been introduced to improve their bioactivities as well as properties. Gelatin/chitosan (G/C) blend films containing active guava leaf powder carbon dots (GL-CDs) at various levels (0–3%, w/w) were prepared by the solvent casting method and characterized. Thickness of the control increased from 0.033 to 0.041 mm when 3% GL-CDs were added (G/C-CD-3%). Young’s modulus of the resulting films increased (485.67–759.00 MPa), whereas the tensile strength (26.92–17.77 MPa) and elongation at break decreased (14.89–5.48%) as the GL-CDs’ level upsurged (p < 0.05). Water vapor barrier property and water contact angle of the film were enhanced when incorporated with GL-CDs (p < 0.05). GL-CDs had a negligible impact on film microstructure, while GL-CDs interacted with gelatin or chitosan, as determined by FTIR. The release of GL-CDs from blend films was more pronounced in water than in alcoholic solutions (10–95% ethanol). The addition of GL-CDs improved the UV light barrier properties and antioxidant activities of the resultant films in a dose-dependent manner. Thus, GL-CD-added gelatin/chitosan blend films with antioxidant activities could be employed as potential active packaging for the food industry.

This study presents an analysis of films which consist of two layers; one layer is PVDF as the matrix, along with fillers BaTiO3 (BT), and the second is one bacterial nanocellulose (BNC) filled with Fe3O4. The mass fraction of BT in PVDF was 5%, and the samples were differentiated based on the duration of the mechanical activation of BT. This innovative PVDF laminate polymer with environmentally friendly fillers aligns with the concept of circular usage, resulting in a reduction in plastic content and potential improvement of the piezoelectric properties of the entire composite. This work presents new, multifunctional “green” packaging materials that potentially could be a good alternative to specific popular materials used for this purpose. The synthesis of the films was carried out using the hot press method. Tensile tests, water vapor permeability examination, and structural analyses using SEM-EDS and FTIR have been conducted. The sample PVDF/BT20/BNC/Fe3O4 exhibited the best barrier properties (impermeability to water vapor), while the highest tensile strength and toughness were exhibited by the PVDF/BT5/BNC/Fe3O4 sample.

The expected impact of this study is to propose a bio-sourced composite material coupling mechanical and hygrothermal performances. This paper deals with the prediction of hygric properties of compacted raw-earth material reinforced with the flax fibers. New experiments have been performed on fibers and earth composite specimens. Then two modeling approaches have been applied using mixing theory and asymptotic homogenization. It was showed, that besides adding flax fibers improves the mechanical behavior of raw earth as strength and shrinkage reduction, their impact on the hygric property as water vapor permeability was also proved. For longitudinal arrangement of flax fibers with different fibers contents, experimental and modeling results are in good agreement. [ABSTRACT FROM AUTHOR]

Nano and micro-pores of the electrospun webs present good moisture vapor transmission rate, while it maintains resistance to pressured air and resistance to liquid for some type of clothing. Laminating a nanofiber web to any textile structure could improve the desired resistance to air permeability with providing excellent breathability. In the present study, hydrophobic thermoplastic polyurethane (TPU) and hydrophilic poly (vinyl alcohol) (PVA) nanofiber webs were produced onto three different chromium sieve wires and then laminated to an interlining fabric and compared in means of pore size, breathability, and air permeability. Mesh count of the wires affected the pore size and smallest pore size are belong to 90 mesh wire. The water vapor permeability of the samples varied between 80% and 90% as well as providing relatively low air permeability values. With increasing nanofiber amount, air permeability decreased dramatical [ABSTRACT FROM AUTHOR]

Water vapor permeability of building materials is a crucial parameter for analysing and optimizing the hygrothermal performance of building envelopes and built environments. Its measurement is accurate but time-consuming, while data mining methods have the potential to predict water vapor permeability efficiently. In this study, six data mining methods—support vector regression (SVR), decision tree regression (DT), random forest regression (RF), K-nearest neighbor (KNN), multi-layer perceptron (MLP), and adaptive boosting regression (AdaBoost)—were compared to predict the water vapor permeability of cement-based materials. A total of 143 datasets of material properties were collected to build prediction models, and five materials were experimentally determined for model validation. The results show that RF has excellent generalization, stability, and precision. AdaBoost has great generalization and precision, only slightly inferior to the former, and its stability is excellent. DT has good precision and acceptable generalization, but its stability is poor. SVR and KNN have superior stability, but their generalization and precision are inadequate. MLP lacks generalization, and its stability and precision are unacceptable. In short, RF has the best comprehensive performance, demonstrated by a limited prediction deviation of 26.3% from the experimental results, better than AdaBoost (38.0%) and DT (38.3%) and far better than other remaining methods. It is also found that data mining methods provide better predictions when cement-based materials' water vapor permeability is high. [ABSTRACT FROM AUTHOR]

The air permeability, thermal resistance, water vapor permeability, water absorption, and Stiffness were measured to determine the comfort property of the fabric. For this study, the plain, twill, and satin structures were produced from warp ring-spun yarn and weft open-end spinning yarns. Using ANOVA statistical analysis, the weave structures on the comfort properties of these fabrics were investigated. The finding of this study revealed that from plain to twill and satin structure the result leads to an increasing of Water Vapor Permeability, Water absorption rate, and air permeability. On the contrary, from plain to twill and satin the thermal resistance and stiffness of fabrics were reduced. Plain weave structure was superior thermal resistance and stiffness, whereas Satin weaves have higher air permeability, water vapor permeability, and water absorption rate.

Bacterial cellulose is one of the high potential sustainable materials with numerous applications. This research work analyses the moisture handling ability of the alkali-treated (purified), bleached and dyed bacterial cellulose after glycerol treatment focusing on fashion application. The developed samples are dried at room temperature and evaluated for water absorbency, wicking, water vapor transmission properties, and moisture management indices. Glycerol treated bacterial cellulose nonwovens showed a better absorbency than the dried non-woven. A faster absorbency of 1.48 minutes was noted for the glycerol treated bleached sample. In the case of wicking, bleached and dyed dry samples showed minimum wicking of 5 and 8 mm. No other samples showed wicking ability including the glycerol treated samples. The water vapor permeability results also increased notably after glycerol treatment. An increment of 55% water vapor permeability was noted with purified sample and a 36.9% increment with bleached sample after glycerol treatment. Though the glycerol treated dyed sample showed a similar vapor transmission to the glycerol treated bleached sample, the untreated dyed sample had a maximum vapor permeability of 621.10 g/m2/day. The moisture management analysis results indicated that the glycerol treatment improved the waterproof nature of bacterial cellulose nonwoven to fast-absorbing slow drying fabric. The subjective analysis on the nonwoven fabric handle showed that the glycerol treatment statistically increased the smoothness, softness, flexibility, and draping nature of the sample than the dried sample. However, the subjective analysis also reported that the glycerol treatment significantly increased the stickiness of the nonwoven.

The water vapor permeability (WVP) and thermal conductivity of polymers are of great significance in personal cooling and even in responding to energy crises. This review attempts to discuss the factors that affecting these two properties at first, and then discusses the relationship between them from the aspects of hydrophilicity, porous structure, biomimetic layered structure, and so on. Generally, porous structure or hydrophilicity is beneficial to water vapor permeation, while dense structure is more conducive to the formation of heat conduction path and network, that is, to heat conduction. Of course, thermal conductive filler is the decisive factor for high thermal conductivity of polymer composites. Interestingly, the transmission process of water vapor also positively affects the heat conduction of polymer to a certain extent. Especially, the biomimetic fiber membrane with multi‐branch network following Murray's law, which integrates high WVP and high thermal conductivity, is one of the development directions of special concern. Finally, the related problems to be solved are put forward and prospected. It is hoped that this review will have positive guiding significance for developing polymer membranes and functional textile coatings with high moisture permeability and high thermal conductivity. [ABSTRACT FROM AUTHOR]

This article investigates the performance of special knitwear made and recommended for sufferers of atopic dermatitis. Atopic dermatitis is a condition that causes dry, itchy and inflamed skin. Generally, fabrics with hygienic, antimicrobial, and mechanical non-irritating properties are recommended for sufferers from atopic dermatitis. The idea is to find the optimal textile structure that eliminates pain and wearing discomfort (both sensorial and thermo-physiological components). Based on a questionnaire survey of the needs of people with dermatitis, a group of properties was determined that crucially influence total wearing comfort. The measurement of these properties was conducted on eight commercially used knitwear types. Sensorial comfort was represented by parameters of total hand value, subjective wearing value, and warm/cold feeling value; physiological comfort by thermal conductivity, moisture management, water vapor and air permeability, and drying efficiency. The decision-making method Technique for Order of Preference by Similarity to Ideal Solution was used to determine the best solution considering the combination of the properties mentioned above. In summary, high air and water vapor permeability, hand feeling, and especially surface roughness fundamentally affect atopic customer decisions. Further, fabrics made from natural fibers (silk and linen) have a high potential to meet the needs of people with atopic dermatitis conditions. Both materials (M1, M7) show a combination of the high level of air permeability (more than 530 (mm . s-1 )), a low level of water vapor resistance (in the range of 1.4–3.5 (m² . Pa .W-1 )) and provide very good subjective wearing comfort. Therefore, they can be substituted for traditional expert-recommended cotton. [ABSTRACT FROM AUTHOR]

The aim of this research was to prepare a nanocomposite film based on Barhang (Plantago major L) seed mucilage. Zinc oxide (ZnO) and cellulose nanofiber (CNF) nanoparticles at the concentrations of 4 and 8% w/w were incorporated for improving the morphological, structural, thermal, water vapor permeability and mechanical properties of films. The F T -IR results confirmed the occurring of new interactions between nanoparticles and mucilage polysaccharides. XRD results indicated that the effect of ZnO on semi -crystalline structure of Barhang film is higher than the effect of CNF. The neat film has a smooth surface, but the roughness increased by addition of nanoparticles. According to TGA results, the thermal stability of films was affected by incorporation of nanoparticles, but the effect of CNF on improving the thermal stability of film was more than ZnO. The addition of nanoparticles at the concentration of 4% had no effect on the thickness of films but by increasing to 8%, the thickness increased. Moisture content and moisture absorption of films was also decreased significantly by incorporation of nanoparticles. The water vapor permeability of films was dependent on the concentration of nanoparticles and at 4%, it decreased significantly but at 8% concentration, the permeability increased again due to the aggregation of nanoparticles and their hydrophilic nature. The water contact angle of films’ surface increased by addition of ZnO but the CNF caused to decrease this value due to its hydrophilicity. The effect of CNF on improving the mechanical properties of films was better than ZnO. The CNF had the most effect on increasing tensile strength, elastic modulus and elongation to break. The effect of CNF on the improving of the barrier and mechanical properties of Barhang seed mucilage based films was more than ZnO due to its better compatibility. In general, this research indicated that the Barhang seed mucilage based film incorporated with organic and inorganic nanoreinforcements, has desired physicochemical properties and can be introduced as a suitable candidate for food packaging applications. [ABSTRACT FROM AUTHOR]

Biopolymers of different natures (carbohydrates, proteins, etc.) recovered from by-products of industrial processes are increasingly being studied to obtain biomaterials as alternatives to conventional plastics, thus contributing to the implementation of a circular economy. The food industry generates huge amounts of by-products and waste, including unsold food products that reach the end of their shelf life and are no longer usable in the food chain. Milk proteins can be easily separated from dairy waste and adapted into effective bio-based polymeric materials. Firstly, this review describes the relevant properties of milk proteins and the approaches to modifying them for subsequent use. Then, we provide an overview of recent studies on the development of films and coatings based on milk proteins and, where available, their applications in food packaging. Comparisons among published studies were made based on the formulation as well as production conditions and technologies. The role of different additives and modifiers tested for the performances of films and coatings, such as water vapor permeability, tensile strength, and elongation at break, were reviewed. This review also outlines the limitations of milk-protein-based materials, such as moisture sensitivity and brittleness. Overall, milk proteins hold great potential as a sustainable alternative to petroleum-based polymers. However, their use in food packaging materials at an industrial level remains problematic. [ABSTRACT FROM AUTHOR]

In this paper, the authors propose a case study on the energy efficiency of a house built in accordance with sustainable development directions. Thus, the envelope is made of ecological materials, namely the resistance structure and finishes are made of wood, and the thermal insulation of sheep's wool. It is a modular, prefabricated house, designed so that energy consumption is reduced both in the construction and exploitation phase. Having a built area of 31.5 m², it can be used as a residential house or a holiday home. For this, the thermotechnical properties of the envelope elements were studied. [ABSTRACT FROM AUTHOR]