Descriptor: "variable spin properties" - Searchworks@Jio Institute Digital Library Search Results

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Author: Ivanova, T., Mingalieva, L., Ovchinnikov, I., Turanova, O., Ivanova, G., and Gilmutdinov, I.
Subjects: *SALICYLATES, *ETHYL group, *IMINE synthesis, *ACETYL compounds, *IMIDAZOLES, *CHEMICAL synthesis
Abstract: [FeLX]Y [L = N,N'-ethylenebis(salicylimine) (salen), N,N'-ethylenebis(acetylacetonylimine) (acen), or N,N'-ethylenebis(3-methyloxysalicylimine) (vanen); X = imidazole or N-methylimidazole; Y = BF, ClO, or BPh] compounds have been prepared and studied by means of EPR and magnetic susceptibility measurements at 5-300 K. It has been shown that the different electron-donating properties of acen and salen planar ligands result in different spin states of Fe(III) ions. Intermolecular π-interactions of the outer-sphere BPh ion affect the complexes spin state as well. [ABSTRACT FROM AUTHOR]
Published: 2016
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Author: Ivanova T., Mingalieva L., Ovchinnikov I., Turanova O., Ivanova G., and Gilmutdinov I.
Subjects: variable spin properties, Fe(III) complex, EPR spectroscopy, magnetic susceptibility
Abstract: © 2016, Pleiades Publishing, Ltd.[FeLX2]Y [L = N,N'-ethylenebis(salicylimine) (salen), N,N'-ethylenebis(acetylacetonylimine) (acen), or N,N'-ethylenebis(3-methyloxysalicylimine) (vanen); X = imidazole or N-methylimidazole; Y = BF4, ClO4, or BPh4] compounds have been prepared and studied by means of EPR and magnetic susceptibility measurements at 5–300 K. It has been shown that the different electron-donating properties of acen and salen planar ligands result in different spin states of Fe(III) ions. Intermolecular π-interactions of the outer-sphere BPh4 ion affect the complexes spin state as well.
Published: 2016

Author: Ivanova T., Mingalieva L., Ovchinnikov I., Turanova O., Ivanova G., Gilmutdinov I., Ivanova T., Mingalieva L., Ovchinnikov I., Turanova O., Ivanova G., and Gilmutdinov I.
Abstract: © 2016, Pleiades Publishing, Ltd.[FeLX2]Y [L = N,N'-ethylenebis(salicylimine) (salen), N,N'-ethylenebis(acetylacetonylimine) (acen), or N,N'-ethylenebis(3-methyloxysalicylimine) (vanen); X = imidazole or N-methylimidazole; Y = BF4, ClO4, or BPh4] compounds have been prepared and studied by means of EPR and magnetic susceptibility measurements at 5–300 K. It has been shown that the different electron-donating properties of acen and salen planar ligands result in different spin states of Fe(III) ions. Intermolecular π-interactions of the outer-sphere BPh4 ion affect the complexes spin state as well.

Author: Ivanova T., Mingalieva L., Ovchinnikov I., Turanova O., Ivanova G., Gilmutdinov I., Ivanova T., Mingalieva L., Ovchinnikov I., Turanova O., Ivanova G., and Gilmutdinov I.
Abstract: © 2016, Pleiades Publishing, Ltd.[FeLX2]Y [L = N,N'-ethylenebis(salicylimine) (salen), N,N'-ethylenebis(acetylacetonylimine) (acen), or N,N'-ethylenebis(3-methyloxysalicylimine) (vanen); X = imidazole or N-methylimidazole; Y = BF4, ClO4, or BPh4] compounds have been prepared and studied by means of EPR and magnetic susceptibility measurements at 5–300 K. It has been shown that the different electron-donating properties of acen and salen planar ligands result in different spin states of Fe(III) ions. Intermolecular π-interactions of the outer-sphere BPh4 ion affect the complexes spin state as well.

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