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The near-infrared (NIR) emission of the youngest protostars still needs to be characterized to better understand the evolution of their accretion and ejection activity. We analyze James Webb Space Telescope NIRSpec 1.7 -- 5.3 $\mu$m observations of two deeply embedded sources in the S68N protostellar core in Serpens. The North Central (NC) source exhibits a highly obscured spectrum (A_K ~ 4.8 mag) that is modeled with a pre-main-sequence photosphere and a hot disk component. The photospheric parameters are consistent with a young, low-mass photosphere, as suggested by the low surface gravity, log g of 1.94 $\pm$ 0.15 cm s$^{-2}$. The hot disk suggests that accretion onto the central protostellar embryo is ongoing, although prototypical accretion-tracing emission lines HI are not detected. The South Central (SC) source, which is even more embedded (A_K ~ 8 mag; no continuum is detected shortward of 3.6 $\mu$m) appears to be driving the large-scale S68N protostellar outflow, and launches a collimated hot molecular jet detected in \Ht and CO ro-vibrational lines. Shock modeling of the \Ht (ro)vibrational lines establishes that fast $C$-type shocks ($\geq$ 30 km s$^{-1}$), with high pre-shock density ($\geq$ $10^7$ cm$^{-3}$), and strong magnetic field (b ~ 3--10, where $B = b\,\times\,\sqrt{\textrm{n}_{\textrm{H}} (\textrm{cm}^{-3})}\,\mu\textrm{G}$) best match the data. The bright CO fundamental line forest suggests energetic excitation, with the contribution of non-LTE effects, ie irradiation pumping. Detected OH and CH$^{+}$ ro-vibrational lines support this hypothesis. These two Class 0 protostars seem to be in very young evolutionary stages and still have to acquire the bulk of their final stellar masses. These results demonstrate that JWST enables unprecedented diagnostics of these first stages of the protostellar evolutionary phase.

Sulfur is depleted with respect to its cosmic standard abundance in dense star-forming regions. It has been suggested that this depletion is caused by the freeze-out of sulfur on interstellar dust grains, but the observed abundances and upper limits of sulfur-bearing ices remain too low to account for all of the missing sulfur. Toward the same environments, a strong absorption feature at 6.85 $\mu$m is observed, but its long-standing assignment to the NH4+ cation remains tentative. We investigate the plausibility of NH4SH salt serving as a sulfur reservoir and a carrier of the 6.85 $\mu$m band in interstellar ices by characterizing its IR signatures and apparent band strengths in water-rich laboratory ice mixtures and using this laboratory data to constrain NH4SH abundances in observations of 4 protostars and 2 cold dense clouds. The observed 6.85 $\mu$m feature is fit well with the laboratory NH4SH:H2O ice spectra. NH4+ column densities obtained from the 6.85 $\mu$m band range from 8-23% with respect to H2O toward the sample of protostars and dense clouds. The redshift of the 6.85 $\mu$m feature correlates with higher abundances of NH4+ with respect to H2O in both the laboratory data presented here and observational data of dense clouds and protostars. The apparent band strength of the SH- feature is likely too low for the feature to be detectable in the spectrally busy 3.9 $\mu$m region, but the 5.3 $\mu$m NH4+ $\nu_{4}$ + SH- R combination mode may be an alternative means of detection. Its tentative assignment adds to mounting evidence supporting the presence of NH4+ salts in ices and is the first tentative observation of the SH- anion toward interstellar ices. If the majority ($\gtrsim$80-85%) of the NH4+ cations quantified toward the investigated sources in this work are bound to SH- anions, then NH4SH salts could account for up to 17-18% of their sulfur budgets., Comment: Accepted for publication in A&A. 20 pages, 14 figures, and 7 tables in the main text; 15 pages, 17 figures, and 10 tables in the appendix

The removal of angular momentum from protostellar systems drives accretion onto the central star and may drive the dispersal of the protoplanetary disk. Winds and jets can contribute to removing angular momentum from the disk, though the dominant process remain unclear. To date, observational studies of resolved disk winds have mostly targeted highly inclined disks. We report the detection of extended H2 and [Ne II] emission toward the young stellar object SY Cha with the JWST Mid-InfraRed Instrument Medium Resolution Spectrometer (MIRI-MRS). This is one of the first polychromatic detections of extended H2 toward a moderately inclined, i=51.1 degrees, Class II source. We measure the semi-opening angle of the H2 emission as well as build a rotation diagram to determine the H2 excitation temperature and abundance. We find a wide semi-opening angle, high temperature, and low column density for the H2 emission, all of which are characteristic of a disk wind. These observations demonstrate MIRI-MRS's utility in expanding studies of resolved disk winds beyond edge-on sources., Comment: 16 pages, 13 figures, 4 tables, submitted to ApJ Letters

Stable isotopic ratios constitute powerful tools for unraveling the thermal and irradiation history of volatiles. In particular, we can use our knowledge of the isotopic fractionation processes active during the various stages of star, disk and planet formation to infer the origins of different volatiles with measured isotopic patterns in our own solar system. Observations of planet-forming disks with the Atacama Large Millimeter/submillimeter Array (ALMA) now readily detect the heavier isotopologues of C, O and N, while the isotopologue abundances and isotopic fractionation mechanisms of sulfur species are less well understood. Using ALMA observations of the SO and SO2 isotopologues in the nearby, molecule-rich disk around the young star Oph-IRS 48 we present the first constraints on the combined 32S/34S and 32S/33S isotope ratios in a planet-forming disk. Given that these isotopologues likely originate in relatively warm gas (>50 K), like most other Oph-IRS 48 volatiles, SO is depleted in heavy sulfur while SO2 is enriched compared to solar system values. However, we cannot completely rule out a cooler gas reservoir, which would put the SO sulfur ratios more in line with comets and other solar system bodies. We also constrain the S18O/SO ratio and find the limit to be consistent with solar system values given a temperature of 60 K. Together these observations show that we should not assume solar isotopic values for disk sulfur reservoirs, but additional observations are needed to determine the chemical origin of the abundant SO in this disk, inform on what isotopic fractionation mechanism(s) are at play, and aid in unravelling the history of the sulfur budget during the different stages of planet formation., Comment: Accepted AJ on 30th August 2024

The inner disk of the young star PDS 70 may be a site of rocky planet formation, with two giant planets detected further out. Solids in the inner disk may inform us about the origin of this inner disk water and nature of the dust in the rocky planet-forming regions. We aim to constrain the chemical composition, lattice structure, and grain sizes of small silicate grains in the inner disk of PDS 70, observed both in JWST/MIRI MRS and Spitzer IRS. We use a dust fitting model, called DuCK, based on a two-layer disk model. We use Gaussian Random Field and Distribution of Hollow Spheres models to obtain two sets of dust opacities. The third set of opacities is obtained from aerosol spectroscopy. We use stoichiometric amorphous silicates, forsterite, and enstatite in our analysis. We also used iron-rich and magnesium-rich amorphous silicate and fayalite dust species to study the iron content. The Gaussian Random Field opacity agrees well with the observed spectrum. In both MIRI and Spitzer spectra, amorphous silicates are the dominant dust species. Crystalline silicates are dominated by iron-poor olivine. We do not find strong evidence for enstatite. Moreover, the MIRI spectrum indicates larger grain sizes than the Spitzer spectrum, indicating a time-variable small grain reservoir. The inner PDS 70 disk is dominated by a variable reservoir of optically thin warm amorphous silicates. We suggest that the small grains detected in the inner PDS 70 disk are likely transported inward from the outer disk as a result of filtration and fragmentation at the ice line. In addition, the variation between MIRI and Spitzer data can be explained by the grain growth over 15 years and a dynamical inner disk where opacity changes occur resulting from the highly variable hot innermost dust reservoir., Comment: 18 pages, 13 figures, Accepted by A&A

Mid-infrared imaging of exoplanets and disks is now possible with the coronagraphs of the MIRI on the JWST. This wavelength range unveils new features of young directly imaged systems and allows us to obtain new constraints for characterizing the atmosphere of young giant exoplanets and associated disks. These observations aim to characterize the atmosphere of the planet HD 95086 b by adding mid-infrared information so that the various hypotheses about its atmospheric parameters values can be unraveled. Improved images of circumstellar disks are provided. We present the MIRI coronagraphic imaging of the system HD 95086 obtained with the F1065C, F1140, and F2300C filters at central wavelengths of 10.575, 11.3, and 23 microns, respectively. We explored the method for subtracting the stellar diffraction pattern in the particular case when bright dust emitting at short separation is present. Furthermore, we compared different methods for extracting the photometry of the planet. Using the atmospheric models Exo-REM and ATMO, we measured the atmospheric parameters of HD 95086 b. The planet HD 95086 b and the contribution from the inner disk are detected at the two shortest MIRI wavelengths F1065C and F1140C. The outer colder belt is imaged at 23 microns. The mid-infrared photometry provides better constraints on the atmospheric parameters. We evaluate a temperature of 850-1020 K, consistent with one previous hypothesis that only used NIR data. The radius measurement of 1.0-1.13 RJup is better aligned with evolutionary models, but still smaller than predicted. These observations allow us to refute the hypothesis of a warm circumplanetary disk. HD 95086 is one of the first exoplanetary systems to be revealed at mid-infrared wavelengths. This highlights the interests and challenges of observations at these wavelengths., Comment: Accepted for publication in A&A

We present James Webb Space Telescope (JWST) Mid-InfraRed Instrument (MIRI) observations of warm CO and H$_2$O gas in emission toward the low-mass protostar IRAS 15398-3359, observed as part of the CORINOS program. The CO is detected via the rovibrational fundamental band and hot band near 5 $\mu$m, whereas the H$_2$O is detected in the rovibrational bending mode at 6-8 $\mu$m. Rotational analysis indicates that the CO originates in a hot reservoir of $1598\pm118$ K, while the water is much cooler at $204\pm 7$ K. Neither the CO nor the H$_2$O line images are significantly spatially extended, constraining the emission to within $\sim$40 au of the protostar. The compactness and high temperature of the CO are consistent with an origin in the embedded protostellar disk, or a compact disk wind. In contrast, the water must arise from a cooler region and requires a larger emitting area (compared to CO) to produce the observed fluxes. The water may arise from a more extended part of the disk, or from the inner portion of the outflow cavity. Thus, the origin of the molecular emission observed with JWST remains ambiguous. Better constraints on the overall extinction, comparison with realistic disk models, and future kinematically-resolved observations may all help to pinpoint the true emitting reservoirs., Comment: 15 pages, 13 figures. Accepted for publication in ApJ

We investigate the chemical history of interstellar OCS and SO2 by deriving a statistically-significant sample of gas-phase column densities towards massive protostars and comparing to observations of gas and ices towards other sources spanning from dark clouds to comets. We analyze a subset of 26 line-rich massive protostars observed by ALMA as part of the ALMAGAL survey. Column densities are derived for OCS and SO2 from their rare isotopologues O13CS and 34SO2 towards the compact gas around the hot core. We find that gas-phase column density ratios of OCS and SO2 with respect to methanol remain fairly constant as a function of luminosity between low- and high-mass sources, despite their very different physical conditions. The derived gaseous OCS and SO2 abundances relative to CH3OH are overall similar to protostellar ice values, with a significantly larger scatter for SO2 than for OCS. Cometary and dark-cloud ice values agree well with protostellar gas-phase ratios for OCS, whereas higher abundances of SO2 are generally seen in comets compared to the other sources. Gaseous SO2/OCS ratios are consistent with ices toward dark clouds, protostars, and comets, albeit with some scatter. The constant gas-phase column density ratios throughout low and high-mass sources indicate an early stage formation before intense environmental differentiation begins. Icy protostellar values are similar to the gas phase medians, compatible with an icy origin of these species followed by thermal sublimation. The larger spread in SO2 compared to OCS ratios w.r.t. CH3OH is likely due to a more water-rich chemical environment associated with the former, as opposed to a CO-rich origin of the latter. Post-sublimation gas-phase processing of SO2 can also contribute to the large spread. Comparisons to ices in dark clouds and comets point to a significant inheritance of OCS from earlier to later evolutionary stages., Comment: Accepted for publication in Astronomy and Astrophysics on July 17th 2024

With the advent of JWST, we acquire unprecedented insights into the physical and chemical structure of the inner regions of planet-forming disks where terrestrial planet formation occurs. The very low-mass stars (VLMS) are known to have a high occurrence rate of the terrestrial planets around them. Exploring the chemical composition of the gas in these inner regions of the disks can aid a better understanding of the connection between planet-forming disks and planets. The MIRI mid-Infrared Disk Survey (MINDS) project is a large JWST Guaranteed Time program to characterize the chemistry and physical state of planet-forming and debris disks. We use the JWST-MIRI/MRS spectrum to investigate the gas and dust composition of the planet-forming disk around the very low-mass star Sz28 (M5.5, 0.12\,M$_{\odot}$). We use the dust-fitting tool (DuCK) to determine the dust continuum and to get constraints on the dust composition and grain sizes. We use 0D slab models to identify and fit the molecular spectral features, yielding estimates on the temperature, column density and the emitting area. To test our understanding of the chemistry in the disks around VLMS, we employ the thermo-chemical disk model {P{\tiny RO}D{\tiny I}M{\tiny O}} and investigate the reservoirs of the detected hydrocarbons. We explore how the C/O ratio affects the inner disk chemistry. JWST reveals a plethora of hydrocarbons, including \ce{CH3}, \ce{CH4}, \ce{C2H2}, \ce{^{13}CCH2}, \ce{C2H6}, \ce{C3H4}, \ce{C4H2} and \ce{C6H6} suggesting a disk with a gaseous C/O\,>\,1. Additionally, we detect \ce{CO2}, \ce{^{13}CO2}, \ce{HCN}, and \ce{HC3N}. \ce{H2O} and OH are absent in the spectrum. We do not detect PAHs. Photospheric stellar absorption lines of \ce{H2O} and \ce{CO} are identified. Notably, our radiation thermo-chemical disk models are able to produce these detected hydrocarbons in the surface layers of the disk when the ..., Comment: accepted for publication in A&A

The MRS mode of the JWST-MIRI instrument gives insights into the chemical richness and complexity of the inner regions of planet-forming disks. Here, we analyse the H$_2$O-rich spectrum of the compact disk DR Tau. We probe the excitation conditions of the H$_2$O transitions observed in different wavelength regions across the entire spectrum using LTE slab models, probing both the rovibrational and rotational transitions. These regions suggest a radial temperature gradient, as the excitation temperature (emitting radius) decreases (increases) with increasing wavelength. To explain the derived emitting radii, we require a larger inclination for the inner disk (i~20-23 degrees) compared to the outer disk (i~5 degrees), agreeing with our previous analysis on CO. We also analyse the pure rotational spectrum (<10 micron) using a large, structured disk (CI Tau) as a template, confirming the presence of the radial gradient, and by fitting multiple components to further characterise the radial and vertical temperature gradients present in the spectrum. At least three temperature components (T~180-800 K) are required to reproduce the rotational spectrum of H$_2$O arising from the inner ~0.3-8 au. These components describe a radial temperature gradient that scales roughly as ~R$^{-0.5}$ in the emitting layers. As the H$_2$O is mainly optically thick, we derive a lower limit on the abundance ratio of H$_2$O/CO~0.17, suggesting a potential depletion of H$_2$O. Similarly to previous work, we detect a cold H$_2$O component (T~180 K) originating from near the snowline. We cannot conclude if an enhancement of the H$_2$O reservoir is observed following radial drift. A consistent analysis of a larger sample of compact disks is necessary to study the importance of drift in enhancing the H$_2$O abundances., Comment: Accepted for publication in Astronomy & Astrophysics on 05/07/2024

JWST gives a unique access to the physical and chemical structure of inner disks ($<10$~au), where the majority of the planets are forming. However, the interpretation of mid-infrared (mid-IR) spectra requires detailed thermo-chemical models able to provide synthetic spectra readily comparable to spectroscopic observations. Our goal is to explore the potential of mid-IR emission of OH to probe H$_2$O photodissociation. We include in the DALI disk model prompt emission of OH following photodissociation of H$_2$O in its $\tilde{B}$ electronic state ($\lambda < 144$~nm). This model allows to compute in a self-consistent manner the thermo-chemical structure of the disk and the resulting mid-IR line intensities of OH and H$_2$O. The OH line intensities in the $9-13~\mu$m range are proportional to the total amount of water photodissociated. As such, these lines are a tracer of the amount of water exposed to the FUV field, which depends on the temperature, density, and strength of the FUV field reaching the upper molecular layers. In particular, the OH line fluxes primarily scale with the FUV field emitted by the star in contrast with H$_2$O lines in the 10-20$~\mu$m range which scale with the bolometric luminosity. OH is therefore a key diagnostic to probe the effect of Ly$\alpha$ and constrain the dust FUV opacity in the upper molecular layers. A strong asymmetry between the A' and A'' components of each rotational quadruplet is also predicted. OH mid-IR emission is a powerful tool to probe H$_2$O photodissociation and infer the physical conditions in disk atmospheres. As such, the inclusion of OH mid-IR lines in the analysis of JWST-MIRI spectra will be key for robustly inferring the composition of planet-forming disks. The interpretation of less excited OH lines requires additional quantum calculations of the formation pumping of OH levels by O+H$_2$ and the collisional rate coefficients., Comment: Accepted for publication in Astronomy & Astrophysics

Most stars form in multiple systems whose properties can significantly impact circumstellar disk evolution. We investigate the physical and chemical properties of the equal-mass, small separation (~66 mas, ~9 au) DF Tau binary system. Previous observations indicated that only DF Tau A has a circumstellar disk. We present JWST-MIRI MRS observations of DF Tau. The MIRI spectrum shows a forest of H2O lines and emission from CO, C2H2, HCN, CO2, and OH. LTE slab models are used to determine the properties of the gas, and we analyze high angular spatial and spectral resolution data from ALMA, VLTI-GRAVITY, and IRTF-iSHELL to aid in the interpretation of the JWST data. The 1.3 mm ALMA continuum data show two equal-brightness sources of compact (R<3 au) emission, with separations and movement consistent with astrometry from VLTI-GRAVITY and the known orbit. This is interpreted as a robust detection of a disk around DF Tau B, which we suggest may host a small (~1 au) cavity to reconcile all observations. The disk around DF Tau A is expected to be a full disk, and spatially and spectrally resolved dust and gas emission points to hot, close-in (<0.2 au) material. Hot (~500-1000 K) H2O, HCN, and C2H2 emission in the MIRI data likely originate in the DF Tau A disk, while a cold (<200 K) H2O component with an extended emitting area is consistent with an origin from both disks. Despite the very compact outer disks, the inner disk composition and conditions are similar to isolated systems, suggesting that the close binary nature is not a driving factor in setting the inner disk chemistry. However, constraining the geometry of the disks, for instance, via higher resolution ALMA observations, would provide additional insight into the mid-infrared gas emission. JWST observations of spatially resolved binaries will be important for understanding the impact of binarity on inner disk chemistry more generally., Comment: Accepted to A&A on June 15th, 2024. Calibrated ALMA data are available at https://zenodo.org/records/11215003. Reduced JWST-MIRI MRS spectra will be available at Spexodisks.com and available by request to the corresponding author

This work aims to utilize the increased sensitivity and resolution of the JWST to quantify the HDO/H$_{2}$O ratio in ices toward young stellar objects (YSOs) and to determine if the HDO/H$_{2}$O ratios measured in the gas phase toward massive YSOs (MYSOs) are representative of the ratios in their ice envelopes. Two protostars observed in the Investigating Protostellar Accretion (IPA) program using JWST NIRSpec were analyzed: HOPS 370, an intermediate-mass YSO (IMYSO), and IRAS 20126+4104, a MYSO. The HDO ice toward these sources was detected above the 3$\sigma$ level and quantified via its 4.1 $\mu$m band. The contributions from the CH$_{3}$OH combination modes to the observed optical depth in this spectral region were constrained via the CH$_{3}$OH 3.53 $\mu$m band to ensure that the integrated optical depth of the HDO feature was not overestimated. H$_{2}$O ice was quantified via its 3 $\mu$m band. From these fits, ice HDO/H$_{2}$O abundance ratios of 4.6$\pm$1.8$\times$10$^{-3}$ and 2.6$\pm$1.2$\times$10$^{-3}$ are obtained for HOPS 370 and IRAS 20126+4104, respectively. The simultaneous detections of both crystalline HDO and crystalline H$_{2}$O corroborate the assignment of the observed feature at 4.1 $\mu$m to HDO ice. The ice HDO/H$_{2}$O ratios are similar to the highest reported gas HDO/H$_{2}$O ratios measured toward MYSOs as well as the hot inner regions of isolated low-mass protostars, suggesting that at least some of the gas HDO/H$_{2}$O ratios measured toward massive hot cores are representative of the HDO/H$_{2}$O ratios in ices. The need for an H$_{2}$O-rich CH$_{3}$OH component in the CH$_{3}$OH ice analysis supports recent experimental and observational results that indicate that some CH$_{3}$OH ice may form prior to the CO freeze-out stage in H$_{2}$O-rich ice layers., Comment: Accepted for publication in A&A. 23 pages, 17 figures, 10 tables

This work aims to measure the mass accretion rate, the accretion luminosity, and more generally the physical conditions of the warm emitting gas in the inner disk of the very low-mass star 2MASS-J16053215-1933159. We investigate the source mid-infrared spectrum for atomic and molecular hydrogen line emission. We present the full James Webb Space Telescope (JWST) Mid-InfraRed Instrument (MIRI) Medium Resolution Spectrometer (MRS) spectrum of the protoplanetary disk around the very low-mass star 2MASS-J16053215-1933159 from the MINDS GTO program, previously shown to be abundant in hydrocarbon molecules. We analyzed the atomic and molecular hydrogen lines in this source by fitting one or multiple Gaussian profiles. We then built a rotational diagram for the H2 lines to constrain the rotational temperature and column density of the gas. Finally, we compared the observed atomic line fluxes to predictions from two standard emission models. We identify five molecular hydrogen pure rotational lines and 16 atomic hydrogen recombination lines. The spectrum indicates optically thin emission for both species. We use the molecular hydrogen lines to constrain the mass and temperature of the warm emitting gas. The HI (7-6) recombination line is used to measure the mass accretion rate and luminosity onto the central source. HI recombination lines can also be used to derive the physical properties of the gas using atomic recombination models. The JWST-MIRI MRS observations for the very low-mass star 2MASS-J16053215-1933159 reveal a large number of emission lines, many originating from atomic and molecular hydrogen because we are able to look into the disk warm molecular layer. Their analysis constrains the physical properties of the emitting gas and showcases the potential of JWST to deepen our understanding of the physical and chemical structure of protoplanetary disks, Comment: 11 pages, 9 figures, 2 tables

Using the MIRI/MRS spectrometer on JWST, we have detected pure rotational, suprathermal OH emissions from the vicinity of the intermediate-mass protostar HOPS 370 (OMC2/FIR3). These emissions are observed from shocked knots in a jet/outflow, and originate in states of rotational quantum number as high as 46 that possess excitation energies as large as $E_U/k = 4.65 \times 10^4$ K. The relative strengths of the observed OH lines provide a powerful diagnostic of the ultraviolet radiation field in a heavily-extinguished region ($A_V \sim 10 - 20$) where direct UV observations are impossible. To high precision, the OH line strengths are consistent with a picture in which the suprathermal OH states are populated following the photodissociation of water in its $\tilde B - X$ band by ultraviolet radiation produced by fast ($\sim 80\,\rm km\,s^{-1}$) shocks along the jet. The observed dominance of emission from symmetric ($A^\prime$) OH states over that from antisymmetric ($A^{\prime\prime}$) states provides a distinctive signature of this particular population mechanism. Moreover, the variation of intensity with rotational quantum number suggests specifically that Ly$\alpha$ radiation is responsible for the photodissociation of water, an alternative model with photodissociation by a 10$^4$ K blackbody being disfavored at a high level of significance. Using measurements of the Br$\alpha$ flux to estimate the Ly$\alpha$ production rate, we find that $\sim 4\%$ of the Ly$\alpha$ photons are absorbed by water. Combined with direct measurements of water emissions in the $\nu_2 = 1 -0$ band, the OH observations promise to provide key constraints on future models for the diffusion of Ly$\alpha$ photons in the vicinity of a shock front., Comment: 30 pages, 7 figures. Accepted for publication in ApJ Letters

The MRS mode of the JWST-MIRI instrument has been shown to be a powerful tool to characterise the molecular gas emission of the inner region of planet-forming disks. Here, we analyse the spectrum of the compact T-Tauri disk DR Tau, which is complemented by high spectral resolution (R~60000-90000) CO ro-vibrational observations. Various molecular species, including CO, CO$_2$, HCN, and C$_2$H$_2$ are detected in the JWST-MIRI spectrum, for which excitation temperatures of T~325-900 K are retrieved using LTE slab models. The high-resolution CO observations allow for a full treatment of the line profiles, which show evidence for two components of the main isotopologue, $^{12}$CO: a broad component tracing the Keplerian disk and a narrow component tracing a slow disk wind. Rotational diagrams yield excitation temperatures of T>725 K for CO, with consistently lower temperatures found for the narrow components, suggesting that the disk wind is launched from a larger distance. The inferred excitation temperatures for all molecules suggest that CO originates from the highest atmospheric layers close to the host star, followed by HCN and C$_2$H$_2$, which emit, together with $^{13}$CO, from slightly deeper layers, whereas the CO$_2$ originates from even deeper inside or further out in the disk. Additional analysis of the $^{12}$CO line wings hint at a misalignment between the inner (i~20 degrees) and outer disk (i~5 degrees). Finally, we emphasise the need for complementary high-resolution CO observations, as in combination with the JWST-MIRI observations they can be used to characterise the CO kinematics and the physical and chemical conditions of the other observed molecules with respect to CO., Comment: Accepted for publication in Astronomy & Astrophysics on 20/03/2024

The study of protoplanetary disks has become increasingly important with the Kepler satellite finding that exoplanets are ubiquitous around stars in our galaxy and the discovery of enormous diversity in planetary system architectures and planet properties. High-resolution near-IR and ALMA images show strong evidence for ongoing planet formation in young disks. The JWST MIRI mid-INfrared Disk Survey (MINDS) aims to (1) investigate the chemical inventory in the terrestrial planet-forming zone across stellar spectral type, (2) follow the gas evolution into the disk dispersal stage, and (3) study the structure of protoplanetary and debris disks in the thermal mid-IR. The MINDS survey will thus build a bridge between the chemical inventory of disks and the properties of exoplanets. The survey comprises 52 targets (Herbig Ae stars, T Tauri stars, very low-mass stars and young debris disks). We primarily obtain MIRI/MRS spectra with high S/N (~100-500) covering the complete wavelength range from 4.9 to 27.9 {\mu}m. For a handful of selected targets we also obtain NIRSpec IFU high resolution spectroscopy (2.87-5.27 {\mu}m). We will search for signposts of planet formation in thermal emission of micron-sized dust - information complementary to near-IR scattered light emission from small dust grains and emission from large dust in the submillimeter wavelength domain. We will also study the spatial structure of disks in three key systems that have shown signposts for planet formation, TW Hya and HD 169142 using the MIRI coronagraph at 15.5 {\mu}m and 10.65 {\mu}m respectively and PDS70 using NIRCam imaging in the 1.87 {\mu}m narrow and the 4.8 {\mu}m medium band filter. ..., Comment: accepted for publication in PASP

Accretion and ejection sets the outcome of the star and planet formation process. The mid-infrared wavelength range offers key tracers of those processes that were difficult to detect and spatially resolve in protostars until now. We aim to characterize the interplay between accretion and ejection in the low-mass Class I protobinary system TMC1, comprising two young stellar objects: TMC1-W and TMC1-E with 85 au separation. With the {\it James Webb} Space Telescope (JWST) - Mid-Infrared Instrument (MIRI) observations in 5 - 28 $\mu$m range, we measure intensities of emission lines of H$_2$, atoms and ions, e.g., [Fe II] and [Ne II], and HI recombination lines. We detect H$_2$ outflow coming from TMC1-E, with no significant H$_2$ emission from TMC1-W. The H$_2$ emission from TMC1-E outflow appears narrow and extends to wider opening angles with decreasing E$_{up}$ from S(8) to S(1) rotational transitions, indicating a disk wind origin. The outflow from TMC1-E protostar shows spatially extended emission lines of [Ne II], [Ne III], [Ar II], and [Ar III], with their line ratios consistent with UV radiation as a source of ionization. With ALMA, we detect accretion streamer infalling from $>$ 1000 au scales onto the TMC1-E component. TMC1-W protostar powers a collimated jet, detected with [Fe II] and [Ni II] consistent with energetic flow. A much weaker ionized jet is observed from TMC1-E. TMC1-W is associated with strong emission from hydrogen recombination lines, tracing the accretion onto the young star. Observations of a binary Class I protostellar system show that the two processes are clearly intertwined, with accretion from the envelope onto the disk influencing a wide-angle wind ejected on disk scales, while accretion from the protostellar disk onto the protostar is associated with the source launching a collimated high-velocity jet within the innermost regions of the disk., Comment: 18 pages, 13 figures, accepted for publication in Astronomy and Astrophysics

The structure and composition of simple ices can be modified during stellar evolution by protostellar heating. Key to understanding the involved processes are thermal and chemical tracers that can diagnose the history and environment of the ice. The 15.2 $\mu$m bending mode of $^{12}$CO$_2$ has proven to be a valuable tracer of ice heating events but suffers from grain shape and size effects. A viable alternative tracer is the weaker $^{13}$CO$_2$ isotopologue band at 4.39 $\mu$m which has now become accessible at high S/N with the $\textit{James Webb}$ Space Telescope (JWST). We present JWST NIRSpec observations of $^{13}$CO$_2$ ice in five deeply embedded Class 0 sources spanning a wide range in luminosities (0.2 - 10$^4$ L$_{\odot}$ ) taken as part of the Investigating Protostellar Accretion Across the Mass Spectrum (IPA) program. The band profiles vary significantly, with the most luminous sources showing a distinct narrow peak at 4.38 $\mu$m. We first apply a phenomenological approach and show that a minimum of 3-4 Gaussian profiles are needed to fit the $^{13}$CO$_2$ absorption feature. We then combine these findings with laboratory data and show that a 15.2 $\mu$m $^{12}$CO$_2$ band inspired five-component decomposition can be applied for the isotopologue band where each component is representative of CO$_2$ ice in a specific molecular environment. The final solution consists of cold mixtures of CO$_2$ with CH$_3$OH, H$_2$O and CO as well as segregated heated pure CO$_2$ ice. Our results are in agreement with previous studies of the $^{12}$CO$_2$ ice band, further confirming that $^{13}$CO$_{2}$ is a useful alternative tracer of protostellar heating events. We also propose an alternative solution consisting only of heated CO$_2$:CH$_3$OH and CO$_2$:H$_2$O ices and warm pure CO$_2$ ice for decomposing the ice profiles of the two most luminous sources in our sample.

Observations of disks with the Atacama Large Millimeter/submillimeter Array (ALMA) allow us to map the chemical makeup of nearby protoplanetary disks with unprecedented spatial resolution and sensitivity. The typical outer Class II disk observed with ALMA is one with an elevated C/O ratio and a lack of oxygen-bearing complex organic molecules, but there are now some interesting exceptions: three transition disks around Herbig Ae stars all show oxygen-rich gas traced via the unique detections of the molecules SO and CH3OH. We present the first results of an ALMA line survey at 337 to 357 GHz of such disks and focus this paper on the first Herbig Ae disk to exhibit this chemical signature - HD 100546. In these data, we detect 19 different molecules including NO, SO and CH3OCHO (methyl formate). We also make the first tentative detections of H213CO and 34SO in protoplanetary disks. Multiple molecular species are detected in rings, which are, surprisingly, all peaking just beyond the underlying millimeter continuum ring at 200 au. This result demonstrates a clear connection between the large dust distribution and the chemistry in this flat outer disk. We discuss the physical and/or chemical origin of these sub-structures in relation to ongoing planet formation in the HD 100546 disk. We also investigate how similar and/or different the molecular make up of this disk is to other chemically well-characterised Herbig Ae disks. The line-rich data we present motivates the need for more ALMA line surveys to probe the observable chemistry in Herbig Ae systems which offer unique insight into the composition of disk ices, including complex organic molecules., Comment: Accepted to AJ, 25 pages, 11 figures

The Atacama Large Millimeter/submillimeter Array (ALMA) can probe the molecular content of planet-forming disks with unprecedented sensitivity. These observations allow us to build up an inventory of the volatiles available for forming planets and comets. Herbig Ae transition disks are fruitful targets due to the thermal sublimation of complex organic molecule (COM) and likely H2O-rich ices in these disks. The IRS 48 disk shows a particularly rich chemistry that can be directly linked to its asymmetric dust trap. Here, we present ALMA observations of the IRS 48 disk where we detect 16 different molecules and make the first robust detections of H213CO, 34SO, 33SO and c-H2COCH2 (ethylene oxide) in a protoplanetary disk. All of the molecular emissions, aside from CO, are colocated with the dust trap and this includes newly detected simple molecules such as HCO+, HCN and CS. Interestingly, there are spatial offsets between different molecular families, including between the COMs and sulphur-bearing species, with the latter being more azimuthally extended and located radially further from the star. The abundances of the newly detected COMs relative to CH3OH are higher than the expected protostellar ratios, which implies some degree of chemical processing of the inherited ices during the disk lifetime. These data highlight IRS 48 as a unique astrochemical laboratory to unravel the full volatile reservoir at the epoch of planet and comet formation and the role of the disk in (re)setting chemical complexity., Comment: Accepted to AJ, 21 pages, 7 figures

Water is a key ingredient for the emergence of life as we know it. Yet, its destruction and reformation in space remains unprobed in warm gas. Here, we detect the hydroxyl radical (OH) emission from a planet-forming disk exposed to external far-ultraviolet (FUV) radiation with the James Webb Space Telescope. The observations are confronted with the results of quantum dynamical calculations. The highly excited OH infrared rotational lines are the tell-tale signs of H2O destruction by FUV. The OH infrared ro-vibrational lines are attributed to chemical excitation via the key reaction O+H=OH+H which seeds the formation of water in the gas-phase. We infer that the equivalent of the Earth ocean's worth of water is destroyed per month and replenished. These results show that under warm and irradiated conditions water is destroyed and efficiently reformed via gas-phase reactions. This process, assisted by diffusive transport, could reduce the HDO/H2O ratio in the warm regions of planet-forming disks., Comment: Version submitted to Nature Astronomy

We investigate the bright CO fundamental emission in the central regions of five protostars in their primary mass assembly phase using new observations from JWST's Near-Infrared Spectrograph (NIRSpec) and Mid-Infrared Instrument (MIRI). CO line emission images and fluxes are extracted for a forest of $\sim$150 ro-vibrational transitions from two vibrational bands, $v=1-0$ and $v=2-1$. However, ${}^{13}$CO is undetected, indicating that ${}^{12}$CO emission is optically thin. We use H$_2$ emission lines to correct fluxes for extinction and then construct rotation diagrams for the CO lines with the highest spectral resolution and sensitivity to estimate rotational temperatures and numbers of CO molecules. Two distinct rotational temperature components are required for $v=1$ ($\sim600$ to 1000 K and 2000 to $\sim 10^4$ K), while one hotter component is required for $v=2$ ($\gtrsim 3500$ K). ${}^{13}$CO is depleted compared to the abundances found in the ISM, indicating selective UV photodissociation of ${}^{13}$CO; therefore, UV radiative pumping may explain the higher rotational temperatures in $v=2$. The average vibrational temperature is $\sim 1000$ K for our sources and is similar to the lowest rotational temperature components. Using the measured rotational and vibrational temperatures to infer a total number of CO molecules, we find that the total gas masses range from lower limits of $\sim10^{22}$ g for the lowest mass protostars to $\sim 10^{26}$ g for the highest mass protostars. Our gas mass lower limits are compatible with those in more evolved systems, which suggest the lowest rotational temperature component comes from the inner disk, scattered into our line of sight, but we also cannot exclude the contribution to the CO emission from disk winds for higher mass targets., Comment: 31 pages, 7 figures, 4 tables, received to ApJ December 10 2023, accepted to ApJ August 4 2024

SY Cha is a T Tauri star surrounded by a protoplanetary disk with a large cavity seen in the millimeter continuum but has the spectral energy distribution (SED) of a full disk. Here we report the first results from JWST-MIRI Medium Resolution Spectrometer (MRS) observations taken as part of the MIRI mid-INfrared Disk Survey (MINDS) GTO Program. The much improved resolution and sensitivity of MIRI-MRS compared to Spitzer enables a robust analysis of the previously detected H2O, CO, HCN, and CO2 emission as well as a marginal detection of C2H2. We also report the first robust detection of mid-infrared OH and ro-vibrational CO emission in this source. The derived molecular column densities reveal the inner disk of SY Cha to be rich in both oxygen and carbon bearing molecules. This is in contrast to PDS 70, another protoplanetary disk with a large cavity observed with JWST, which displays much weaker line emission. In the SY Cha disk, the continuum, and potentially the line, flux varies substantially between the new JWST observations and archival Spitzer observations, indicative of a highly dynamic inner disk., Comment: 19 pages, 10 figures, 5 tables, accepted for publication in ApJ

WASP-107b is a warm ($\sim$740 K) transiting planet with a Neptune-like mass of $\sim$30.5 $M_{\oplus}$ and Jupiter-like radius of $\sim$0.94 $R_{\rm J}$, whose extended atmosphere is eroding. Previous observations showed evidence for water vapour and a thick high-altitude condensate layer in WASP-107b's atmosphere. Recently, photochemically produced sulphur dioxide (SO$_2$) was detected in the atmosphere of a hot ($\sim$1,200 K) Saturn-mass planet from transmission spectroscopy near 4.05 $\mu$m, but for temperatures below $\sim$1,000 K sulphur is predicted to preferably form sulphur allotropes instead of SO$_2$. Here we report the 9$\sigma$-detection of two fundamental vibration bands of SO$_2$, at 7.35 $\mu$m and 8.69 $\mu$m, in the transmission spectrum of WASP-107b using the Mid-Infrared Instrument (MIRI) of the JWST. This discovery establishes WASP-107b as the second irradiated exoplanet with confirmed photochemistry, extending the temperature range of exoplanets exhibiting detected photochemistry from $\sim$1,200 K down to $\sim$740 K. Additionally, our spectral analysis reveals the presence of silicate clouds, which are strongly favoured ($\sim$7$\sigma$) over simpler cloud setups. Furthermore, water is detected ($\sim$12$\sigma$), but methane is not. These findings provide evidence of disequilibrium chemistry and indicate a dynamically active atmosphere with a super-solar metallicity.

[Abridged] The inner few AU of disks around young stars are best probed in the infrared. The James Webb Space Telescope (JWST) is now starting to characterize the chemistry of these regions in unprecedented detail. One peculiar subset of sources are the so-called ``CO2-only sources'', in which only a strong 15 $\mu$m CO2 feature was detected in the spectrum. One scenario that could explain the weak emission from H2O is the presence of a small, inner cavity in the disk. If this cavity were to extend past the H2O snowline, but not past the CO2 snowline, this could strongly suppress the H2O line flux w.r.t. that of CO2. In this work, we aim to test the validity of this statement. Using the thermo-chemical code Dust And LInes (DALI), we created a grid of T Tauri disk models with an inner cavity, meaning we fully depleted the inner region of the disk in gas and dust starting from the dust sublimation radius and ranging until a certain cavity radius. We present the evolution of the CO2 and H2O spectra of a disk with inner cavity size, showing that, when a large-enough cavity is introduced, a spectrum that was initially dominated by H2O lines can become CO2-dominated instead. However, the cavity size needed for this is around 4-5 AU, exceeding the nominal position of the CO2 snowline in a full disk. The cause of this is most likely the alteration of the thermal structure by the cavity, which pushes the snowlines outward. Alternative explanations for bright CO2 emission are also briefly discussed. Our modeling work shows that it is possible for the presence of a small inner cavity to explain strong CO2 emission in a spectrum. However, the cavity needed to do so is larger than what was initially expected. As such, this scenario will be easier to test with sufficiently high angular resolution (millimeter) observations., Comment: 28 pages, 24 figures, accepted for publication in A&A

Brown dwarfs serve as ideal laboratories for studying the atmospheres of giant exoplanets on wide orbits as the governing physical and chemical processes in them are nearly identical. Understanding the formation of gas giant planets is challenging, often involving the endeavour to link atmospheric abundance ratios, such as the carbon-to-oxygen (C/O) ratio, to formation scenarios. However, the complexity of planet formation requires additional tracers, as the unambiguous interpretation of the measured C/O ratio is fraught with complexity. Isotope ratios, such as deuterium-to-hydrogen and 14N/15N, offer a promising avenue to gain further insight into this formation process, mirroring their utility within the solar system. For exoplanets only a handful of constraints on 12C/13C exist, pointing to the accretion of 13C-rich ice from beyond the disks' CO iceline. Here we report on the mid-infrared detection of the 14NH3 and 15NH3 isotopologues in the atmosphere of a cool brown dwarf with an effective temperature of 380 K in a spectrum taken with the Mid-InfraRed Instrument of the James Webb Space Telescope. As expected, our results reveal a 14N/15N value consistent with star-like formation by gravitational collapse, demonstrating that this ratio can be accurately constrained. Since young stars and their planets should be more strongly enriched in the 15N isotope, we expect that 15NH3 will be detectable in a number of cold, wide-separation exoplanets., Comment: Accepted by Nature. 28 pages, 7 figures, uses nature3.cls

Investigating Protostellar Accretion (IPA) is a JWST Cycle~1 GO program that uses NIRSpec IFU and MIRI MRS to obtain 2.9--28~$\mu$m spectral cubes of young, deeply embedded protostars with luminosities of 0.2 to 10,000~L$_{\odot}$ and central masses of 0.15 to 12~M$_{\odot}$. In this Letter, we report the discovery of a highly collimated atomic jet from the Class~0 protostar IRAS~16253$-$2429, the lowest luminosity source ($L_\mathrm{bol}$ = 0.2 $L_\odot$) in the IPA program. The collimated jet is detected in multiple [Fe~II] lines, [Ne~II], [Ni~II], and H~I lines, but not in molecular emission. The atomic jet has a velocity of about 169~$\pm$~15~km\,s$^{-1}$, after correcting for inclination. The width of the jet increases with distance from the central protostar from 23 to~60 au, corresponding to an opening angle of 2.6~$\pm$~0.5\arcdeg. By comparing the measured flux ratios of various fine structure lines to those predicted by simple shock models, we derive a shock {speed} of 54~km\,s$^{-1}$ and a preshock density of 2.0$\times10^{3}$~cm$^{-3}$ at the base of the jet. {From these quantities and using a suite of jet models and extinction laws we compute a mass loss rate between $0.4 -1.1\times10^{-10}~M_{\odot}$~yr~$^{-1}$.} The low mass loss rate is consistent with simultaneous measurements of low mass accretion rate ($2.4~\pm~0.8~\times~10^{-9}~M_{\odot}$~yr$^{-1}$) for IRAS~16253$-$2429 from JWST observations (Watson et al. in prep), indicating that the protostar is in a quiescent accretion phase. Our results demonstrate that very low-mass protostars can drive highly collimated, atomic jets, even during the quiescent phase., Comment: Accepted to ApJL. Comments and feedback welcome

Investigating Protostellar Accretion is a Cycle 1 JWST program using the NIRSpec+MIRI integral field units to obtain 2.9--28 $\mu$m spectral cubes of five young protostars with luminosities of 0.2-10,000 L$_{\odot}$ in their primary accretion phase. This paper introduces the NIRSpec 2.9--5.3 $\mu$m data of the inner 840-9000 au with spatial resolutions from 28-300 au. The spectra show rising continuum emission; deep ice absorption; emission from H$_{2}$, H~I, and [Fe~II]; and the CO fundamental series in emission and absorption. Maps of the continuum emission show scattered light cavities for all five protostars. In the cavities, collimated jets are detected in [Fe~II] for the four $< 320$~L$_{\odot}$ protostars, two of which are additionally traced in Br-$\alpha$. Knots of [Fe~II] emission are detected toward the most luminous protostar, and knots of [FeII] emission with dynamical times of $< 30$~yrs are found in the jets of the others. While only one jet is traced in H$_2$, knots of H$_2$ and CO are detected in the jets of four protostars. H$_2$ is seen extending through the cavities, showing that they are filled by warm molecular gas. Bright H$_2$ emission is seen along the walls of a single cavity, while in three cavities narrow shells of H$_2$ emission are found, one of which has an [Fe~II] knot at its apex. These data show cavities containing collimated jets traced in atomic/ionic gas surrounded by warm molecular gas in a wide-angle wind and/or gas accelerated by bow shocks in the jets., Comment: 26 pages, 12 figures

We study the stellar population properties of 182 spectroscopically-confirmed (MUSE/VLT) Lyman-$\alpha$ emitters (LAEs) and 450 photometrically-selected Lyman-Break galaxies (LBGs) at z = 2.8 - 6.7 in the Hubble eXtreme Deep Field (XDF). Leveraging the combined power of HST and JWST NIRCam and MIRI observations, we analyse their rest-frame UV-through-near-IR spectral energy distributions (SEDs) with MIRI playing a crucial role in robustly assessing the LAE's stellar mass and ages. Our LAEs are low-mass objects (log$_{10}$(M$_\star$[M$_\odot$]) ~ 7.5), with little or no dust extinction (E(B - V) ~ 0.1) and a blue UV continuum slope ($\beta$ ~ -2.2). While 75% of our LAEs are young (< 100 Myr), the remaining 25% have significantly older stellar populations (> 100 Myr). These old LAEs are statistically more massive, less extinct and have lower specific star formation rate (sSFR) compared to young LAEs. Besides, they populate the M$_\star$ - SFR plane along the main-sequence (MS) of star-forming galaxies, while young LAEs populate the starburst region. The comparison between the LAEs properties to those of a stellar-mass matched sample of LBGs shows no statistical difference between these objects, except for the LBGs redder UV continuum slope and marginally larger E(B - V) values. Interestingly, 48% of the LBGs have ages < 10 Myr and are classified as starbursts, but lack detectable Ly$\alpha$ emission. This is likely due to HI resonant scattering and/or selective dust extinction. Overall, we find that JWST observations are crucial in determining the properties of LAEs and shedding light on the properties and similarities between LAEs and LBGs., Comment: 22 pages, 15 figures, 5 tables. Accepted for publication in APJ

The Cryogenic IR echelle Spectrometer (CRIRES) instrument at the Very Large Telescope (VLT) was in operation from 2006 to 2014. Great strides in characterizing the inner regions of protoplanetary disks were made using CRIRES observations in the L- and M-band at this time. The upgraded instrument, CRIRES+, became available in 2021 and covers a larger wavelength range simultaneously. Here we present new CRIRES+ Science Verification data of the binary system S Coronae Australis (S CrA). We aim to characterize the upgraded CRIRES+ instrument for disk studies and provide new insight into the gas in the inner disk of the S CrA N and S systems. We analyze the CRIRES+ data taken in all available L- and M-band settings, providing spectral coverage from 2.9 to 5.5 $\mu$m. We detect emission from $^{12}$CO (v=1-0, v=2-1, and v=3-2), $^{13}$CO (v=1-0), hydrogen recombination lines, OH, and H$_2$O in the S CrA N disk. In the fainter S CrA S system, only the $^{12}$CO v=1-0 and the hydrogen recombination lines are detected. The $^{12}$CO v=1-0 emission in S CrA N and S shows two velocity components, a broad component coming from $\sim$0.1 au in S CrA N and $\sim$0.03 au in S CrA S and a narrow component coming from $\sim$3 au in S CrA N and $\sim$5 au in S CrA S. We fit local thermodynamic equilibrium slab models to the rotation diagrams of the two S CrA N velocity components and find that they have similar column densities ($\sim$1-7$\times$10$^{17}$ cm$^{-2}$), but that the broad component is coming from a hotter and narrower region. Two filter settings, M4211 and M4368, provide sufficient wavelength coverage for characterizing CO and H$_2$O at $\sim$5 $\mu$m, in particular covering low- and high-$J$ lines. CRIRES+ provides spectral coverage and resolution that are crucial complements to low-resolution observations, such as those with JWST, where multiple velocity components cannot be distinguished., Comment: 15 pages, 13 figures, accepted to A&A

The accretion of material from protoplanetary disks onto their central stars is a fundamental process in the evolution of these systems and a key diagnostic in constraining the disk lifetime. We analyze the relationship between the stellar accretion rate and the disk mass in 32 intermediate-mass Herbig Ae/Be systems and compare them to their lower-mass counterparts, T Tauri stars. We find that the $\dot{M}$--$M_{\rm{disk}}$ relationship for Herbig Ae/Be stars is largely flat at $\sim$10$^{-7}$ M$_{\odot}$ yr$^{-1}$ across over three orders of magnitude in dust mass. While most of the sample follows the T Tauri trend, a subset of objects with high accretion rates and low dust masses are identified. These outliers (12 out of 32 sources) have an inferred disk lifetime of less than 0.01 Myr and are dominated by objects with low infrared excess. This outlier sample is likely identified in part by the bias in classifying Herbig Ae/Be stars, which requires evidence of accretion that can only be reliably measured above a rate of $\sim$10$^{-9}$ M$_{\odot}$ yr$^{-1}$ for these spectral types. If the disk masses are not underestimated and the accretion rates are not overestimated, this implies that these disks may be on the verge of dispersal, which may be due to efficient radial drift of material or outer disk depletion by photoevaporation and/or truncation by companions. This outlier sample likely represents a small subset of the larger young, intermediate-mass stellar population, the majority of which would have already stopped accreting and cleared their disks., Comment: 16 pages, 3 figures, accepted to AJ

The [CII] 157.74 $\mu$m fine structure transition is one of the brightest and most well-studied emission lines in the far-infrared (FIR), produced in the interstellar medium (ISM) of galaxies. We study its properties in sub-pc resolution hydrodynamical simulations for an ISM patch with gas surface density of $\Sigma_{\rm{g}}=10\;M_{\odot}\;\rm{pc}^{-2}$, coupled with time-dependent chemistry, far-ultraviolet (FUV) dust and gas shielding, star formation, photoionization and supernova (SN) feedback, and full line-radiative transfer. We find a [CII]-to-H$_2$ conversion factor that scales weakly with metallicity $X_{\rm{[CII]}}=6.31\times 10^{19} \;Z^{\prime\;0.17}\; \rm{cm}^{-2}\;(\rm{K}\;\rm{km}\;\rm{s}^{-1})^{-1}$, where $Z^{\prime}$ is the normalized metallicity relative to solar. {The majority of [CII] originates from atomic gas with hydrogen number density $n\sim 10~{\rm cm^{-3}}$.} The [CII] line intensity positively correlates with the star formation rate (SFR), with a normalization factor that scales linearly with metallicity. We find that this is broadly consistent with $z\sim0$ observations. As such, [CII] is a good SFR tracer even in metal-poor environments where molecular lines might be undetectable. Resolving the clumpy structure of the dense ($n=10-10^3\;\rm{cm}^{-3}$) interstellar medium (ISM) is important as it dominates [CII] 157.74 $\mu$m emission. We compare our full radiative transfer computation with the optically-thin limit and find that the [CII] line becomes marginally optically thick only at super-solar metallicity for our assumed gas surface density., Comment: Accepted for publication in ApJ

The understanding of planet formation has changed recently, embracing the new idea of pebble accretion. This means that the influx of pebbles from the outer regions of planet-forming disks to their inner zones could determine the composition of planets and their atmospheres. The solid and molecular components delivered to the planet-forming region can be best characterized by mid-infrared spectroscopy. With Spitzer low-resolution (R=100, 600) spectroscopy, this approach was limited to the detection of abundant molecules such as H2O, C2H2, HCN and CO2. This contribution will present first results of the MINDS (MIRI mid-IR Disk Survey, PI: Th. Henning) project. Due do the sensitivity and spectral resolution (R~1500-3500) provided by JWST we now have a unique tool to obtain the full inventory of chemistry in the inner disks of solar-types stars and brown dwarfs, including also less abundant hydrocarbons and isotopologues. The Integral Field Unit (IFU) capabilities enable at the same time spatial studies of the continuum and line emission in extended sources such as debris disks, the flying saucer and also the search for mid-IR signatures of forming planets in systems such as PDS70. These JWST observations are complementary to ALMA and NOEMA observations of the outer disk chemistry; together these datasets provide an integral view of the processes occurring during the planet formation phase., Comment: 14 pages, 8 figures, authors version of the manuscript submitted 22.1.2023 for the Faraday Discussion "Astrochemistry at high resolution", accepted 21.3.2023

We present a JWST/MRS spectrum of the quasar J1120+0641 at z=7.0848, the first spectroscopic observation of a reionisation-era quasar in the rest-frame infrared ($0.6<\lambda<3.4\mu$m). In the context of the mysterious fast assembly of the first supermassive black holes at z>7, our observations enable for the first time the detection of hot torus dust, the H$\alpha$ emission line, and the Paschen-series broad emission lines in a quasar at z>7. Hot torus dust is clearly detected as an upturn in the continuum emission at $\lambda_{\text{rest}}\simeq1.3\mu$m, leading to a black-body temperature of $T=1413.5^{+5.7}_{-7.4}$K. Compared to similarly-luminous quasars at 06 ($2\sigma$ significance). We measure the black hole mass of J1120+0641 based on the H$\alpha$ Balmer line, $M_{\text{BH}}=1.52\pm0.17\cdot 10^9 M_\odot$, which is in good agreement with the previous rest-UV MgII black hole mass measurement. The black hole mass based on the Paschen-series lines is also consistent, indicating no significant extinction in the rest-frame UV measurement. The broad H$\alpha$, Pa-$\alpha$ and Pa-$\beta$ emission lines are consistent with an origin in a common broad-line region (BLR) with density log$N_H/\text{cm}^{-3}\geq 12$, ionisation parameter $-7<$log$U<-4$, and extinction E(B-V)$\lesssim 0.1$mag. These BLR parameters are consistent with similarly-bright quasars at 0

Early results from the JWST-MIRI guaranteed time programs on protostars (JOYS) and disks (MINDS) are presented. Thanks to the increased sensitivity, spectral and spatial resolution of the MIRI spectrometer, the chemical inventory of the planet-forming zones in disks can be investigated with unprecedented detail across stellar mass range and age. Here data are presented for five disks, four around low-mass stars and one around a very young high-mass star. The mid-infrared spectra show some similarities but also significant diversity: some sources are rich in CO2, others in H2O or C2H2. In one disk around a very low-mass star, booming C2H2 emission provides evidence for a ``soot'' line at which carbon grains are eroded and sublimated, leading to a rich hydrocarbon chemistry in which even di-acetylene (C4H2) and benzene (C6H6) are detected (Tabone et al. 2023). Together, the data point to an active inner disk gas-phase chemistry that is closely linked to the physical structure (temperature, snowlines, presence of cavities and dust traps) of the entire disk and which may result in varying CO2/H2O abundances and high C/O ratios >1 in some cases. Ultimately, this diversity in disk chemistry will also be reflected in the diversity of the chemical composition of exoplanets., Comment: 17 pages, 8 figures. Author's version of paper submitted to Faraday Discussions January 18 2023, Accepted March 16 2023

MIRI/MRS on board the JWST allows us to probe the inner regions of protoplanetary disks. Here we examine the disk around the classical T Tauri star Sz 98, which has an unusually large dust disk in the millimetre with a compact core. We focus on the H$_2$O emission through both its ro-vibrational and pure rotational emission. Furthermore, we compare our chemical findings with those obtained for the outer disk from Atacama Large Millimeter/submillimeter Array (ALMA) observations. In order to model the molecular features in the spectrum, the continuum was subtracted and LTE slab models were fitted. The spectrum was divided into different wavelength regions corresponding to H$_2$O lines of different excitation conditions, and the slab model fits were performed individually per region. We confidently detect CO, H$_2$O, OH, CO$_2$, and HCN in the emitting layers. The isotopologue H$^{18}_2$O is not detected. Additionally, no other organics, including C$_2$H$_2$, are detected. This indicates that the C/O ratio could be substantially below unity, in contrast with the outer disk. The H$_2$O emission traces a large radial disk surface region, as evidenced by the gradually changing excitation temperatures and emitting radii. The OH and CO$_2$ emission are relatively weak. It is likely that H$_2$O is not significantly photodissociated; either due to self-shielding against the stellar irradiation, or UV-shielding from small dust particles. The relative emitting strength of the different identified molecular features point towards UV-shielding of H$_2$O in the inner disk of Sz 98, with a thin layer of OH on top. The majority of the organic molecules are either hidden below the dust continuum, or not present. In general, the inferred composition points to a sub-solar C/O ratio (<0.5) in the inner disk, in contrast with the larger than unity C/O ratio in the gas in the outer disk found with ALMA., Comment: Updated to accepted version. Accepted by A&A on September 23 2023. 18 pages, 11 figures

The atmospheric composition of planets is determined by the chemistry of the disks in which they form. Studying the gas-phase molecular composition of disks thus allows us to infer what the atmospheric composition of forming planets might be. Recent observations of the IRS 48 disk have shown that (asymmetric) dust traps can directly impact the observable chemistry, through radial and vertical transport, and the sublimation of ices. The asymmetric HD 142527 disk provides another good opportunity to investigate the role of dust traps in setting the disk's chemical composition. In this work, we use archival ALMA observations of the HD 142527 disk to obtain an as large as possible molecular inventory, which allows us to investigate the possible influence of the asymmetric dust trap on the disk's chemistry. We present the first ALMA detections of [C I], 13C18O, DCO+, H2CO and additional transition of HCO+ and CS in this disk. In addition, we have acquired upper limits for non-detected species such as SO and CH3OH. For the majority of the observed molecules, a decrement in the emission at the location of the dust trap is found. For the main CO isotopologues continuum over-subtraction likely causes the observed asymmetry, while for CS and HCN we propose that the observed asymmetries are likely due to shadows cast by the misaligned inner disk. As the emission of the observed molecules is not co-spatial with the dust trap and no SO or CH3OH are found, thermal sublimation of icy mantles does not appear to play a major role in changing the gas-phase composition of the outer disk in HD 142527 disk. Using our observations of 13C18O and DCO+ and a RADMC-3D model, we determine the CO snowline to be located beyond the dust traps, favouring cold gas-phase formation of H2CO, rather than the hydrogenation of CO-ice and subsequent sublimation., Comment: Accepted for publication in A&A on 12/04/2023

Twenty-six years ago a small committee report, building on earlier studies, expounded a compelling and poetic vision for the future of astronomy, calling for an infrared-optimized space telescope with an aperture of at least $4m$. With the support of their governments in the US, Europe, and Canada, 20,000 people realized that vision as the $6.5m$ James Webb Space Telescope. A generation of astronomers will celebrate their accomplishments for the life of the mission, potentially as long as 20 years, and beyond. This report and the scientific discoveries that follow are extended thank-you notes to the 20,000 team members. The telescope is working perfectly, with much better image quality than expected. In this and accompanying papers, we give a brief history, describe the observatory, outline its objectives and current observing program, and discuss the inventions and people who made it possible. We cite detailed reports on the design and the measured performance on orbit., Comment: Accepted by PASP for the special issue on The James Webb Space Telescope Overview, 29 pages, 4 figures

The elemental carbon-to-oxygen ratio (C/O) in the atmosphere of a giant planet is a promising diagnostic of that planet's formation history in a protoplanetary disk. Alongside efforts in the exoplanet community to measure C/O in planetary atmospheres, observational and theoretical studies of disks are increasingly focused on understanding how the gas-phase C/O varies both with radial location and between disks. This is mostly tied to the icelines of major volatile carriers such as CO and H2O. Using ALMA observations of CS and SO, we have unearthed evidence for an entirely novel type of C/O variation in the protoplanetary disk around HD 100546: an azimuthal variation from a typical, oxygen-dominated ratio (C/O=0.5) to a carbon-dominated ratio (C/O>1.0). We show that the spatial distribution and peculiar line kinematics of both CS and SO molecules can be well-explained by azimuthal variations in the C/O ratio. We propose a shadowing mechanism that could lead to such a chemical dichotomy. Our results imply that tracing the formation history of giant exoplanets using their atmospheric C/O ratios will need to take into account time-dependent azimuthal C/O variations in a planet's accretion zone., Comment: Accepted in Nature Astronomy

Nearby dwarf irregular galaxies are ideal laboratories for studying the interstellar medium (ISM) at low metallicity, which is expected to be common for galaxies at very high redshift being observed by the James Webb Space Telescope. We present the first high-resolution ($\sim 0.2$~pc) hydrodynamical simulations of an isolated low-metallicity ($0.1~Z_\odot$) dwarf galaxy coupled with a time-dependent chemistry network and a dust evolution model where dust is locally produced and destroyed by various processes. To accurately model carbon monoxide (CO), we post-process the simulations with a detailed chemistry network including the time-dependent effect of molecular hydrogen (H$_2$). Our model successfully reproduces the observed star formation rate and CO(1-0) luminosity ($L_{\rm CO}$). We find that dust growth in dense gas is required to reproduce the observed $L_{\rm CO}$ as otherwise CO would be completely photodissociated. In contrast, the H$_2$ abundance is extremely small and is insensitive to dust growth, leading to a CO-to-H$_2$ conversion factor that is only slightly higher than the Milky Way value despite the low metallicity. An observationally inferred dust-to-gas ratio is thus underestimated if adopting the metallicity-dependent CO-to-H$_2$ conversion factor. The newly-produced dust in dense gas mixes with the ISM through supernova feedback without being completely destroyed by sputtering, which leads to galactic outflows 20% - 50% dustier than the ISM, providing a possible source for intergalactic dust., Comment: ApJ accepted. 19 pages, 10 figures

We present JWST-MIRI MRS spectra of the protoplanetary disk around the low-mass T Tauri star GW Lup from the MIRI mid-INfrared Disk Survey (MINDS) GTO program. Emission from $^{12}$CO$_{2}$, $^{13}$CO$_{2}$, H$_{2}$O, HCN, C$_{2}$H$_{2}$, and OH is identified with $^{13}$CO$_{2}$ being detected for the first time in a protoplanetary disk. We characterize the chemical and physical conditions in the inner few au of the GW Lup disk using these molecules as probes. The spectral resolution of JWST-MIRI MRS paired with high signal-to-noise data is essential to identify these species and determine their column densities and temperatures. The $Q$-branches of these molecules, including those of hot-bands, are particularly sensitive to temperature and column density. We find that the $^{12}$CO$_{2}$ emission in the GW Lup disk is coming from optically thick emission at a temperature of $\sim$400 K. $^{13}$CO$_{2}$ is optically thinner and based on a lower temperature of $\sim$325 K, may be tracing deeper into the disk and/or a larger emitting radius than $^{12}$CO$_{2}$. The derived $N_{\rm{CO_{2}}}$/$N_{\rm{H_{2}O}}$ ratio is orders of magnitude higher than previously derived for GW Lup and other targets based on \textit{Spitzer}-IRS data. This high column density ratio may be due to an inner cavity with a radius in between the H$_{2}$O and CO$_{2}$ snowlines and/or an overall lower disk temperature. This paper demonstrates the unique ability of JWST to probe inner disk structures and chemistry through weak, previously unseen molecular features., Comment: 15 pages, 10 figures. Accepted to ApJL

Determining the atomic and molecular content of the interstellar medium (ISM) as a function of environmental parameters is of fundamental importance to understand the star-formation process across the epochs. Although there exist various three-dimensional hydro-chemical codes modelling the ISM at different scales and redshifts, they are computationally expensive and inefficient for studies over a large parameter space. Building on our earlier approach, we present PDFchem, a novel algorithm that models the cold ISM at moderate and large scales using functions connecting the quantities of the local ($A_{\rm V,eff}$) and the observed ($A_{\rm V,obs}$) visual extinctions, and the local number density, $n_{\rm H}$, with probability density functions (PDF) of $A_{\rm V,obs}$ on cloud scales typically tens-to-hundreds of pc as an input. For any given $A_{\rm V,obs}$-PDF, sampled with thousands of clouds, the algorithm instantly computes the average abundances of the most important species (HI, H$_2$, CII, CI, CO, OH, OH$^+$, H$_2$O$^+$, CH, HCO$^+$) and performs radiative transfer calculations to estimate the average emission of the most commonly observed lines ([CII]~$158\mu$m, both [CI] fine-structure lines and the first five rotational transitions of $^{12}$CO). We examine two $A_{\rm V,obs}$-PDFs corresponding to a non star-forming and a star-forming ISM region, under a variety of environmental parameters combinations. These cover FUV intensities in the range of $\chi/\chi_0=10^{-1}-10^3$, cosmic-ray ionization rates in the range of $\zeta_{\rm CR}=10^{-17}-10^{-13}\,{\rm s}^{-1}$ and metallicities in the range of $Z=0.1-2\,{\rm Z}_{\odot}$. PDFchem is fast, easy to use, reproduces the PDR quantities of the time-consuming hydrodynamical models and can be used directly with observed data to understand the evolution of the cold ISM chemistry., Comment: 33 pages, 27 figures. Accepted in MNRAS. The algorithm can be found in: https://github.com/tbisbas/PDFchem. Comments welcome!

Molecular line observations are powerful tracers of the physical and chemical conditions across the different evolutionary stages of star, disk and planet formation. Using the high angular resolution and unprecedented sensitivity of the Atacama Large Millimeter Array (ALMA) there is now a drive to detect small-scale gas structures in protoplanetary disks that can be attributed directly to forming planets. We report high angular resolution ALMA Band 7 observations of sulphur monoxide (SO) in the nearby planet-hosting disk around Herbig star HD 100546. SO is rarely detected in evolved protoplanetary disks but in other environments, it is most often utilised as a tracer of shocks. The SO emission from the HD 100546 disk is primarily originating from gas within the approx. 20 au mm-dust cavity and shows a clear azimuthal brightness asymmetry of a factor of 2. In addition, we see a significant difference in the line profile shape when comparing these new Cycle 7 data to Cycle 0 data of the same SO transitions. We discuss the different physical/chemical mechanisms that could be responsible for this asymmetry and time variability including disk winds, disk warps, and a shock triggered by a (forming) planet. We propose that the SO is enhanced in the cavity due to the presence of a giant planet. The SO asymmetry complements evidence for hot circumplanetary material around the giant planet HD 100546 c traced via CO ro-vibrational emission. This work sets the stage for further observational and modelling efforts to detect and understand the chemical imprint of a forming planet on its parent disk., Comment: Accepted A&A 24th October

This work presents ground-based spectrally-resolved water emission at R = 30000-100000 over infrared wavelengths covered by JWST (2.9-12.8 $\mu$m). Two new surveys with iSHELL and VISIR are combined with previous spectra from CRIRES and TEXES to cover parts of multiple ro-vibrational and rotational bands observable within telluric transmission bands, for a total of $\approx160$ spectra and 85 disks (30 of which are JWST targets in Cycle 1). The general expectation of a range of regions and excitation conditions traced by infrared water spectra is for the first time supported by the combined kinematics and excitation as spectrally resolved at multiple wavelengths. The main findings from this analysis are: 1) water lines are progressively narrower from the ro-vibrational bands at 2-9 $\mu$m to the rotational lines at 12 $\mu$m, and partly match a broad (BC) and narrow (NC) emission components, respectively, as extracted from ro-vibrational CO spectra; 2) rotation diagrams of resolved water lines from upper level energies of 4000-9500 K show vertical spread and curvatures indicative of optically thick emission ($\approx 10^{18}$ cm$^{-2}$) from a range of excitation temperatures ($\approx 800$-1100 K); 3) the new 5 $\mu$m spectra demonstrate that slab model fits to the rotational lines at $> 10$ $\mu$m strongly over-predict the ro-vibrational emission bands at $< 9$ $\mu$m, implying non-LTE vibrational excitation. We discuss these findings in the context of emission from a disk surface and a molecular inner disk wind, and provide a list of guidelines to support the analysis of spectrally-unresolved JWST spectra., Comment: Accepted for publication on AJ

Water photodissociation in the 114 - 144 nm UV range forms excited OH which emits at mid-infrared wavelengths via highly excited rotational lines. These lines have only been detected with Spitzer in several proto-planetary disks and shocks. Previous studies have shown they are a unique diagnostic for water photodissociation. Thanks to its high sensitivity and angular resolution, the James Webb Space Telescope (JWST) could be able to detect them in other environments such as interstellar Photo-Dissociation Regions (PDRs). In order to predict the emerging spectrum of OH, we use the Meudon PDR Code to compute the thermal and chemical structure of PDRs. The influence of thermal pressure ($P_{\rm th}/k$ = $n_{\rm H} T_{\rm K}$) and UV field strength on the integrated intensities, as well as their detectability with the JWST are studied in details. OH mid-IR emission is predicted to originate very close to the H$^0$/H$_2$ transition and is directly proportional to the column density of water photodissociated in that layer. Because neutral gas-phase formation of water requires relatively high temperatures ($T_{\rm K} \gtrsim 300~$K), the resulting OH mid-IR lines are primarily correlated with the temperature at this position, and are therefore brighter in regions with high pressure. This implies that these lines are predicted to be only detectable in strongly irradiated PDRs ($G_0^{\rm incident}$ $>$ 10$^3$) with high thermal pressure ($P_{\rm th}/k$ $\gtrsim$ 5$\times$10$^7$ K cm$^{-3}$). In the latter case, OH mid-IR lines are less dependent on the strength of the incident UV field. The detection in PDRs like the Orion bar, which should be possible, is also investigated. To conclude, OH mid-IR lines observable by JWST are a promising diagnostics for dense and strongly irradiated PDRs., Comment: Accepted on the 17/10/2022 by Astronomy & Astrophysics (A&A)

In recent years, high-angular-resolution observations of the dust and gas in circumstellar discs have revealed a variety of morphologies, naturally triggering the question of whether these substructures are driven by forming planets. While it remains difficult to directly image embedded planets, a promising method to distinguish disc-shaping mechanisms is to study the gas kinematics as characterising deviations from Keplerian rotation can be used to probe underlying perturbations such as planets. Creating spiral structures, the latter can also be traced in the brightness temperature. Here we analyse the brightness temperatures and kinematics of a sample of 36 transition discs observed with ALMA to search for substructures possibly tracing companions. We use archival Band 6 and 7 observations of different CO isotopologues and fit Keplerian disc models to the velocity fields. After subtraction of an azimuthally averaged brightness temperature and Keplerian rotation model from the data, we find significant substructures in both residuals of eight sources. Other sources show tentative features, while half of our sample does not show any substructures that may be indicative of planet-disc interactions. For the first time, we compare the substructures from our analysis with various other indicators of planets. About 20% of discs show strong features such as arcs or spirals, possibly associated with the presence of planets, while the majority do not present as clear planet-driven signatures. Almost all discs that exhibit spirals in near-infrared scattered light show at least tentative features in the CO data. The present data are able to reveal only very massive bodies and a lack of features may suggest that, if there are planets, they are of lower mass (<1-3Mj) or located closer to the star within deep cavities. Dedicated observations and modelling efforts are needed to confirm such scenarios., Comment: 31 pages, 22 figures; accepted for publication in A&A

Turbulent motions are believed to regulate angular momentum transport and influence dust evolution in protoplanetary disks. Measuring the strength of turbulence is challenging through gas line observations because of the requirement for high spatial and spectral resolution data, and an exquisite determination of the temperature. In this work, taking the well-known HD 163296 disk as an example, we investigated the contrast of gaps identified in high angular resolution continuum images as a probe for the level of turbulence. With self-consistent radiative transfer models, we simultaneously analyzed the radial brightness profiles along the disk major and minor axes, and the azimuthal brightness profiles of the B67 and B100 rings. By fitting all the gap contrasts measured from these profiles, we constrained the gas-to-dust scale height ratio $\Lambda$ to be $3.0_{-0.8}^{+0.3}$, $1.2_{-0.1}^{+0.1}$ and ${\ge}\,6.5$ for the D48, B67 and B100 regions, respectively. The varying gas-to-dust scale height ratios indicate that the degree of dust settling changes with radius. The inferred values for $\Lambda$ translate into a turbulence level of $\alpha_{\rm turb}\,{<}\,3\times10^{-3}$ in the D48 and B100 regions, which is consistent with previous upper limits set by gas line observations. However, turbulent motions in the B67 ring are strong with $\alpha_{\rm turb}\,{\sim}1.2\,{\times}\,10^{-2}$. Due to the degeneracy between $\Lambda$ and the depth of dust surface density drops, the turbulence strength in the D86 gap region is not constrained., Comment: 13 pages, 7 figures, accepted for publication in Science China Physics, Mechanics & Astronomy