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The wettability of SiO2 surfaces, crucial for understanding the phase transition processes of water, remains a topic of significant controversy in the literature due to uncertainties in experiments. Molecular dynamics (MD) simulations offer a promising avenue for elucidating these complexities, yet studies specifically addressing water contact angles on hydrophilic and hydrophobic SiO2 surfaces at sub-ambient temperatures are notably absent. In this study, we experimentally measured water contact angles of hydrophilic and hydrophobic SiO2 surfaces at ambient temperature and employed MD to investigate water contact angles on Q3, Q3/Q4, and Q4 SiO2 surfaces across temperatures ranging from 220 to 300 K. We investigated the effects of the distribution of hydroxyl groups, droplet size, and hydroxyl density and found that the hydroxyl density had the largest impact on contact angle. Moreover, hydrogen bond analysis uncovered enhanced water affinities of Q3 and Q3/Q4 SiO2 surfaces at lower temperatures, and the spreading rate of precursor films reduced with decreasing temperature. This comprehensive study sheds light on the intricate interaction between surface properties and water behavior, promoting our understanding of the wettability of SiO2 surfaces. [ABSTRACT FROM AUTHOR]

We present new quantum dynamical results for the reactive scattering of hydrogen molecules from a Cu(111) surface at a surface temperature of 925 K. Reaction, scattering, and diffraction probabilities are compared for results obtained using both an effective Hartree potential (EfHP) and a sudden approximation approach, implemented through the static corrugation model (SCM), to include surface temperature effects. Toward this goal, we show how the SRP48 DFT-functional and an embedded atom potential perform when used to calculate copper lattice constants and thermal expansion coefficients based on lattice dynamics calculations within the quasi-harmonic approximation. The so-calculated phonons are then used in the EfHP approach to replace the normal modes of a fictitious copper cluster used in earlier work. We find that both the EfHP and SCM approaches correctly predict the reaction probability curve broadening effect when the surface temperature is increased. Similarly, results for rovibrationally elastic scattering appear to be improved, predominantly for the SCM model. The behavior of the EfHP results appears to remain much closer to that of a Born–Oppenheimer static surface approach, which excludes any surface temperature effects. Finally, for the diffraction, we show very clear attenuation effects for the SCM approach, significantly decreasing specular diffraction probabilities at 925 K surface temperature. These results demonstrate that state-of-the-art theoretical models are able to reproduce strictly quantum mechanical scattering effects with a sudden approximation model and open up interesting opportunities for further comparisons to experimental diffraction results. [ABSTRACT FROM AUTHOR]

The Martini model, a coarse-grained forcefield for biomolecular simulations, has experienced a vast increase in popularity in the past decade. Its building-block approach balances computational efficiency with high chemical specificity, enabling the simulation of organic and inorganic molecules. The modeling of coarse-grained beads as Lennard-Jones particles poses challenges for the accurate reproduction of liquid–vapor interfacial properties, which are crucial in various applications, especially in the case of water. The latest version of the forcefield introduces refined interaction parameters for water beads, tackling the well-known artifact of Martini water freezing at room temperature. In addition, multiple sizes of water beads are available for simulating the solvation of small cavities, including the smallest pockets of proteins. This work focuses on studying the interfacial properties of Martini water, including surface tension and surface thickness. Employing the test-area method, we systematically compute the liquid–vapor surface tension across various combinations of water bead sizes and for temperatures from 300 to 350 K. These findings are of interest to the Martini community as they allow users to account for the low interfacial tension of Martini water by properly adjusting observables computed via coarse-grained simulations to allow for accurate matching against all-atom or experimental results. Surface tension data are also interpreted in terms of local enrichment of the various mixture components at the liquid–vapor interface by means of Gibbs' adsorption formalism. Finally, the critical scaling of the Martini surface tension with temperature is reported to be consistent with the critical exponent of the 3D Ising universality class. [ABSTRACT FROM AUTHOR]

Thermal driven desorption of surface impurities is probed based on coupled Monte Carlo–heat flow–molecular dynamics simulations. Such adsorbates can lead to plasma formation during the operation of high-power microwave systems with various negative outcomes and so need to be curtailed. Our study attempts to obtain temperature thresholds for desorbing different surface contaminants such as C2, O2, CO, and CO2. The results show that carbon-based adsorbates on copper (chosen as an example anode material) could be ejected at a relatively modest surface temperature of 650 K. On the other hand, reactive species such as oxygen are very stable due to their large cohesive energies. Our calculations further suggest the benefit of using a platinum coating layer, as the noble metal is robust with strong resistance to oxidation. [ABSTRACT FROM AUTHOR]

The laser power mediated changes in the Raman line shape have been considered in terms of interference between discrete phonon states ρ and the electronic continuum states ϰ contributed by Urbach tail states. The laser-induced effects are treated in terms of the increase in the surface temperature and thereby the scaling of electronic disorder, i.e., Urbach energy, which can further contribute to the electron–phonon interactions. Therefore, the visualization of this effect is attempted analytically as a perturbation term in the Hamiltonian, which clearly accounts for the observed changes with laser power. This has been investigated based on the experimental results of laser power dependent Raman spectra of bulk EuFeO3 and silicon nanowires, which are found to provide convincing interpretations. [ABSTRACT FROM AUTHOR]

We construct the effective Hartree potential for H2 on Cu(111) as introduced in our earlier work [Dutta et al., J. Chem. Phys. 154, 104103 (2021), and Dutta et al., J. Chem. Phys. 157, 194112 (2022)] starting from the same gas–metal interaction potential obtained for 0 K. Unlike in that work, we now explicitly account for surface expansion at 925 K and investigate different models to describe the surface vibrational modes: (i) a cluster model yielding harmonic normal modes at 0 K and (ii) slab models resulting in phonons at 0 and 925 K according to the quasi-harmonic approximation—all consistently calculated at the density functional theory level with the same exchange–correlation potential. While performing dynamical calculations for the H2(v = 0, j = 0)–Cu(111) system employing Hartree potential constructed with 925 K phonons and surface temperature, (i) the calculated chemisorption probabilities are the highest compared to the other approaches over the energy domain and (ii) the threshold for the reaction probability is the lowest, in close agreement with the experiment. Although the survival probabilities (v′ = 0) depict the expected trend (lower in magnitude), the excitation probabilities (v′ = 1) display a higher magnitude since the 925 K phonons and surface temperature are more effective for the excitation process compared to the phonons/normal modes obtained from the other approaches investigated to describe the surface. [ABSTRACT FROM AUTHOR]

Prior studies indicate that the reaction wave can propagate from the impact surface, but the possibility and the influencing factors of the reaction wave formation are still unclear. This work investigates the propagation behavior of the shock-induced reaction wave for Ni/Al clad particle composites with varying stoichiometry (from 0.5 to 0.75 of the Ni mole fraction) through molecular dynamics simulations. It is found that the solid-state reaction processes with or without wave propagation strongly depend on the conjunction of stoichiometry and shock intensity. Within the cases of wave propagation, the calculated propagation velocity (in the range of 135–170 m/s) increases linearly or exponentially with the Ni mole fraction. Furthermore, the thermodynamic criteria for the reaction wave formation, including Al melting at the collision surface and higher temperature gradient, are established by analysis of the shock-induced high-entropy layer. In addition, microstructural characterization reveals the intrinsic mechanisms of the propagation of the reaction wave and the formation of additional reaction wave, namely, the dissolution of Ni into Al and the coalescence of reaction zones. Apart from the propagation behavior, the initial stoichiometry influences the crystallization–dissolution of B2–NiAl during reaction processes, notably through an exponential growth relationship between maximum crystallinity and the Ni mole fraction. These findings may provide a physical basis for improving traditional reaction rate models to break through phenomenological understanding. [ABSTRACT FROM AUTHOR]

Organic molecular solids can exhibit rich phase diagrams. In addition to structurally unique phases, translational and rotational degrees of freedom can melt at different state points, giving rise to partially disordered solid phases. The structural and dynamic disorder in these materials can have a significant impact on the physical properties of the organic solid, necessitating a thorough understanding of disorder at the atomic scale. When these disordered phases form at low temperatures, especially in crystals with light nuclei, the prediction of material properties can be complicated by the importance of nuclear quantum effects. As an example, we investigate nuclear quantum effects on the structure and dynamics of the orientationally disordered, translationally ordered plastic phase of the acetylene:ammonia (1:1) co-crystal that is expected to exist on the surface of Saturn's moon Titan. Titan's low surface temperature (∼90 K) suggests that the quantum mechanical behavior of nuclei may be important in this and other molecular solids in these environments. By using neural network potentials combined with ring polymer molecular dynamics simulations, we show that nuclear quantum effects increase orientational disorder and rotational dynamics within the acetylene:ammonia (1:1) co-crystal by weakening hydrogen bonds. Our results suggest that nuclear quantum effects are important to accurately model molecular solids and their physical properties in low-temperature environments. [ABSTRACT FROM AUTHOR]

Changes in the soil freeze–thaw status will inevitably affect the thermal conditions and properties of the Tibetan Plateau (TP), thereby affecting its upper atmosphere, and further afield in East Asia and even globally. In this study, using the soil temperature simulated by the Community Land Model Version 5.0 (CLM5.0), the timing and duration of the soil freeze–thaw status were divided into freeze start‐date, freeze end‐date and freeze duration. Then, using linear trend estimation, correlation analysis and other methods, the changes in the spatiotemporal distribution of the timing and duration of the soil freeze–thaw status from 1979 to 2018 over the TP were analysed, and the relationships between them and surface temperature, altitude and latitude were analysed. The results obtained were as follows: (1) The soil temperature simulated by CLM5.0 can reasonably reproduce the seasonal changes in multilayer soil temperature, and correlated well with observations. Simulated by CLM5.0 of the time and duration of the soil freeze–thaw status also correlated well with observations. (2) The spatial distribution of the soil freeze–thaw status is characterized by a trend of delayed freezing, advanced thawing and shortened freeze duration from northwest to southeast over the TP. From 1979 to 2018, the freeze start‐date postponed by 7.3 days and became delayed at a rate of 1.9 days per decade, while the freeze end‐date advanced by 6.4 days at a rate of 1.7 days per decade, and the freeze duration shortened by 13.7 days at a rate of 3.6 days per decade. The timing and duration of the soil freeze–thaw status vary across different regions of the TP. The freeze start‐date in all areas of the TP has been delayed in the past 39 years. Except for the subcold zone and arid regions of the TP, the freeze end‐date has occurred earlier and the freeze duration has shortened, with the most significant changes in the subcold zone and humid regions, while the freeze end‐date has advanced at a rate of 3.6 days per decade and the freeze duration has shortened at a rate of 6.3 days per decade. (3) The timing and duration of the soil freeze–thaw status are significantly correlated with surface air temperature, elevation and latitude, exceeding the 99% confidence level. The correlation between the timing and duration of the soil freeze–thaw status and surface temperature is strongest, followed by altitude, and correlation with latitude is weaker. The correlation between surface air temperature and the timing and duration of the soil freeze–thaw status in the western TP is stronger than that in the eastern TP. The rate of change in the soil freeze–thaw status increases with altitude to 3000 m above sea level, while this rate decreases with elevation above 3000 m. The rate of change in the soil freeze–thaw status is greatest at 29°N, while the rate of delay in the freeze start‐date is minimal at 33°N and the rates of advancement in the freeze end‐date and shortening of the freeze duration are minimal at 35°N. [ABSTRACT FROM AUTHOR]

The Warm Arctic‐Cold North American (WACNA) pattern features opposing surface temperature anomalies, with centers over the Chukchi‐Bering Seas (CBS) and the North American Great Plains. The pattern is mainly driven by meridional heat transport and damped by the generation of available potential energy through diabatic heating. The Canadian Earth System Model CanESM5, part of the Coupled Model Intercomparison Project Phase 6 (CMIP6), reasonably reproduces this pattern and its formation mechanisms. Future projections under the Shared Socioeconomic Pathway 8.5 (SSP5‐8.5) suggest a significant weakening of WACNA with global warming. Notable changes in pattern intensity and spatial structure are anticipated, particularly a decrease in intensity over the CBS. WACNA changes are also found in 31 CMIP6 multi‐model ensemble simulations. These changes are attributed to Arctic amplification associated with global warming, which diminishes the equator‐to‐pole temperature gradient and consequently reduces meridional heat transport, particularly over the CBS region. Plain Language Summary: The Warm Arctic‐Cold North American (WACNA) pattern shows warming in the Arctic and cooling in North America, with hot spots in the Chukchi‐Bering Seas (CBS) and the Great Plains. This happens because heat moves from one place to another along temperature differences, balanced mainly by the interaction of temperature and diabatic heating. We explore how global warming affects this pattern using the latest Canadian Earth System Model CanESM5 and other 30 CMIP6 models. These models simulate this pattern well and why it occurs. According to climate simulations under a future scenario called SSP5‐8.5, the WACNA pattern will become weaker as the Earth keeps warming up, especially over the CBS. These changes are due to a phenomenon called Arctic amplification, where warming happens faster in the Arctic than in other places. This reduces the movement of heat from the equator to the Arctic, especially in the CBS region, causing changes in the WACNA pattern. Key Points: WACNA variability decreases with global warming, with a faster decline in the Chukchi‐Bering Seas than North AmericaWACNA variability is supported by meridional heat transport and damped by generation of available potential energy through diabatic heatingWACNA changes are driven by changes in meridional heat transport, related to global warming and its featured Arctic amplification [ABSTRACT FROM AUTHOR]

Mercury's low obliquity and 3:2 spin‐orbit resonance create a surface temperature distribution with large latitudinal and longitudinal variations. These propagate via thermal conduction through the thin silicate shell influencing the interior temperature distribution. We use 3‐D thermal evolution models to investigate the effects of lateral variations of surface temperature and crustal thickness on the surface and core‐mantle boundary (CMB) heat fluxes, and elastic thickness distribution. Surface temperature variations cause a long‐wavelength perturbation of the heat fluxes, as well as of the elastic lithosphere thickness, while variations in crustal thickness affect these quantities at small spatial scales. Like the surface temperature, the present‐day CMB heat flux pattern is characterized primarily by spherical harmonics of degrees two and four, which could affect dynamo generation. Placing robust constraints on the thermal evolution based on the available estimates of the age and thickness of the elastic lithosphere remains challenging due to their large uncertainties. Plain Language Summary: The orbit of Mercury around the Sun leads to a specific surface temperature distribution, with some regions receiving more insolation than others. The thickness of Mercury's crust has been derived using gravity and topography data acquired by the MESSENGER mission. Since the rocky mantle of Mercury is rather thin (≈ ${\approx} $400 km), temperature variations driven by the insolation and by crustal properties (i.e., crustal heat sources and thermal conductivity) can affect the entire mantle, down to the core‐mantle boundary. Here we model the global thermal evolution of Mercury, and investigate the influence of surface temperature and crustal thickness variations on the history and present‐day state of the interior. We find that the surface temperature variations are reflected in the variations of Mercury's surface and core‐mantle boundary heat fluxes, as well as in the thickness of the elastic part of its lithosphere. Crustal thickness variations lead to more local temperature differences, thus resulting in smaller scale variations in the lithosphere thickness and heat fluxes. The heat flux pattern at the core mantle boundary induced by the surface temperature distribution could affect magnetic field generation and should be tested by future dynamo models. Key Points: The distribution of Mercury's mantle temperature is strongly influenced by surface temperature and crustal thickness variationsSurface heat flux and elastic thickness are controlled at large scales by surface temperature, and at small scales by crustal thicknessSurface temperature variations influence the CMB heat flux distribution, which we make readily available to test dynamo models [ABSTRACT FROM AUTHOR]

Wildfire is a crucial factor in influencing the earth system. Wildfire activities in the Arctic‐boreal region have received increasing attention particularly with increasing frequency and intensity under rapid climate warming in recent years. In this study, the historical simulation and future projection of the Arctic‐boreal fire carbon emissions and associated surface climate conditions (surface air temperature and precipitation) are examined using 17 CMIP6 Earth System Models. For the historical period, more than half (11 out of 17) of the models underestimate ∼40% of the observed annual mean fire carbon emissions in the Arctic‐boreal region (0.20 PgC/yr) due to a wetter bias in the Arctic‐boreal regions. Spatially, there is common underestimation of the fire centers in the eastern part of Eurasian Continent and overestimation of that in Europe. With respect to the model spread, it mainly shows large spread for fire carbon emissions (surface air temperature) in Europe (high‐latitudes). For the future projection, the fire carbon emissions in the Arctic‐boreal region is projected to exceed 100% (0.5 PgC/yr until the end of the 21st century compared with ∼0.2 PgC/yr at present). The projected precipitation and temperature in the Arctic‐boreal region land also show an upward trend during the 21st century (∼31% for annual mean precipitation and ∼10°C for surface air temperature). There are considerable bias and intra‐model spread among different models in both historical simulation and future projection. Plain Language Summary: Warming in the Arctic receives much attentions since it has been warming much faster than in the rest of the world, known as Arctic amplification. Along with rising temperature the climate system also changes substantially, for example, rapid retreating of the Arctic sea ice and more boreal fires. In this study, the historical simulation and future projection of the Arctic‐boreal fire carbon emissions and associated surface climate conditions (surface air temperature, precipitation) are examined using 17 state‐of‐the‐art Earth System Models in which fire carbon emissions variables are available. We found that more than half (11 out of 17) of the models underestimate ∼40% of the observed annual mean fire carbon emissions in the Arctic‐boreal region (0.20 PgC/yr) due to a wetter bias in the Arctic‐boreal regions. There is common underestimation of the fire centers in the eastern part of the Eurasian continent and overestimation of that in Europe. For future projection, the fire carbon emissions in the Arctic‐boreal region is projected to exceed 100% (0.5 PgC/yr until the end of the 21st century compared with ∼0.2 PgC/yr at present), along with projected increase in precipitation and temperature. Although all models show upward trend, the spread among models are large. Key Points: More than half (11 out of 17) of the models underestimate ∼40% of the observed annual mean fire carbon emissions in the Arctic‐boreal regionThere is common underestimation of the fire centers in the eastern part of the Eurasian continent and overestimation of that in EuropeFire carbon emissions in Arctic‐boreal region is projected to exceed 100% along with projected increase in precipitation and temperature [ABSTRACT FROM AUTHOR]

The formation and distribution of residual stress during the micro-milling process significantly affect the crack resistance and service life of alumina bioceramics. This study aims to optimize the surface residual stress distribution by adjusting machining parameters, thereby improving the machining quality of alumina ceramics. A three-dimensional finite element model of alumina bioceramics was developed, and numerical simulations were conducted to analyze the effects of feed per tooth, cutting depth, and spindle speed on temperature and residual stress. The study further explores the patterns of residual stress variation. The results show that both surface temperature and residual tensile stress exhibit systematic trends with parameter changes. Specifically, surface residual tensile stress increases with cutting depth initially but decreases sharply once the cutting depth exceeds 25 μm. Residual tensile stress increases with spindle speed, reaching its peak at 21,000 r/min before stabilizing. Additionally, the residual tensile stress rises with feed per tooth at first but gradually declines when the value exceeds 25 μm/z. This research reveals the mechanisms by which micro-milling parameters influence surface temperature and residual stress in alumina bioceramics, providing theoretical guidance for optimizing micro-milling processes. The findings can also be extended to the micro-milling of other hard-to-machine materials, offering broad engineering application potential. [ABSTRACT FROM AUTHOR]

The surface temperature of a workpiece during abrasive belt grinding directly affects its surface quality and determines whether the workpiece surface burns. However, the surface temperature of the workpiece during the grinding process is determined by the total heat and the heat carried away by the chips. Under certain grinding parameters, accurately obtaining the heat removed by the chips is one of the key factors to accurately obtain the workpiece surface quality. Therefore, a new method for chip heat monitoring based on audio-visual information decision fusion is proposed in this study. By obtaining visual sparks and sound signals directly related to the chip, a real-time chip quality (i.e., material removal rate, MRR) monitoring model based on convolutional neural network (CNN) and multilayer perceptron (MLP) was established. The heat taken away by the chips in real time was calculated through theoretical formula. The results show that the RMSE of the proposed method for the material removal rate does not exceed 0.006, and the coefficient of determination R2 is not less than 99.4%. The maximum error between the predicted maximum temperature of the grinding surface and the experimental measurement value is 10 °C. The proposed method provides the theoretical basis for the prediction and control of workpiece grinding temperature. [ABSTRACT FROM AUTHOR]

During high-speed continuous casting, the effect of secondary cooling on the quality of the billet is more obvious, and the possibility of quality problems is higher. This study takes the continuous casting machine producing 165 mm × 165 mm billet as the research object. The six different secondary cooling schemes are designed with the 4.5 m/min casting speed. By comparing the shell deformation, surface stress, surface temperature recovery, and metallurgical lengths at different secondary cooling schemes, the secondary cooling scheme applied in the high-speed continuous casting process is selected. The results show that the surface temperature recovery and stress of the billet in Scheme 1 are higher than those of other cooling schemes. The metallurgical length and shell deformation of the billet in Scheme 4 are higher than those of other cooling schemes. In Schemes 2, 3, 5, and 6, the shell deformation of Schemes 3 and 5 is higher than that of Schemes 2 and 6. In Schemes 2 and 6, the maximum surface central stress of the continuous casting billet in the secondary cooling zone is 36.3 MPa and 31 MPa, respectively. Scheme 6 is used as the secondary cooling scheme of high-speed continuous casting in this study. The water quantity in secondary cooling zone 1 ~ 5 segments of Scheme 6 is 28 m3/h, 31 m3/h, 16 m3/h, 10 m3/h, and 6 m3/h, respectively. Finally, the industrial trial is carried out, which proves that Scheme 6 can be applied to high-speed continuous casting. [ABSTRACT FROM AUTHOR]

Poly(N‐vinylcaprolactam) (PNVCL) is a thermoresponsive polymer, which presents a transition from hydrophilic to hydrophobic behavior close to the physiological temperature, being promising for biomedical applications. However, the production of finished products with PNVCL is difficult due to its high mechanical fragility in the solid state. In the present work, in order to prepare a thermoresponsive film with good mechanical properties, a blend of PNVCL with thermoplastic polyurethane (TPU) was prepared. Three compositions of PNVCL/TPU were studied with mass proportions of 90/10, 70/30, and 50/50, respectively. The films were flexible, miscible and presented different thermoresponsive behaviors, with changing from transparent to opaque varying from 31 to 40°C. Contact angle analysis showed significant changes in the hydrophilicity of the films' surfaces with temperature variation. Moreover, it was possible to induce a change in solid films from transparent to opaque by varying the temperature and verify the reversibility of this change. In addition, tensile tests were carried out, which proved, for PNVCL/TPU blends, the reduction of film brittleness with TPU increase. To the best of our knowledge, it is the first work that presents thermoresponsive properties of solid films formed by a blend of PNVCL and TPU. [ABSTRACT FROM AUTHOR]

Historically, meteorological drought in the western United States (WUS) has been driven primarily by precipitation deficits. However, our observational analysis shows that, since around 2000, rising surface temperature and the resulting high evaporative demand have contributed more to drought severity (62%) and coverage (66%) over the WUS than precipitation deficit. This increase in evaporative demand during droughts, mostly attributable to anthropogenic warming according to analyses of both observations and climate model simulations, is the main cause of the increased drought severity and coverage. The unprecedented 2020-2022 WUS drought exemplifies this shift in drought drivers, with high evaporative demand accounting for 61% of its severity, compared to 39% from precipitation deficit. Climate model simulations corroborate this shift and project that, under the fossil-fueled development scenario (SSP5-8.5), droughts like the 2020-2022 event will transition from a one-in-more-than-a-thousand-year event in the pre-2022 period to a 1-in-60-year event by the mid-21st century and to a 1-in-6-year event by the late-21st century. [ABSTRACT FROM AUTHOR]

The oxide surface structure plays a vital role in controlling and utilizing the emergent phenomena occurring at the interface of nanoarchitecture. A complete understanding of ternary oxide surfaces remains challenging due to complex surface reconstructions in various chemical and physical environments. Here a thermodynamic framework is developed to treat the stability of ternary oxide surfaces with finite temperature and chemical environments. Strontium titanate, as a representative ternary oxide, is used to establish the complete energy landscape of SrTiO3 (001) surface. The complete mapping yields a comprehensive understanding of various stable SrTiO3 surfaces with finite temperature and chemical potential or vapor pressure of the constituents, i.e., Sr (or Ti) metal and oxygen. This treatment also reveals a stable surface unknown yet with SrTi2O3 stoichiometry, which unveils the missing link between numerous previous experimental observations and the current understanding of SrTiO3 surface. Interestingly, the new surface shows an anisotropic surface‐localized metallic state originating from the characteristic surface structure. The findings would provide a viable way to understand ternary oxide surfaces and further utilize SrTiO3 surfaces for oxide nanoarchitectures. [ABSTRACT FROM AUTHOR]

High-performance SiC aerogels are sought after for their superior thermal insulation and absorption properties, especially in applications such as electromagnetic stealth for aero engines and high-temperature radar stealth. However, achieving SiC aerogel with both temperature resistance and strong wave absorption while controlling their properties remains a significant challenge. This study investigates the influence of reactant concentrations on the structure, thermal insulation, and absorption performance of SiC aerogels synthesized via the sol-gel method. The aerogel synthesized with a n(C):n(Si) ratio of 1:2 showed superior thermal insulation. Additionally, it showed excellent electromagnetic wave absorption, with a minimum reflection loss of −53.80 dB at 6.16 GHz and a maximum effective absorption bandwidth of 3.10 GHz at a thickness of 2.40 mm. Furthermore, the maximum compressive strength of C/SiC@SiC reached 0.98 MPa, a notable improvement of 81.48 % compared to the pristine C/SiC matrix. The maximum effective absorption bandwidth of C/SiC@SiC was increased to 6.06 GHz at 2.35 mm, and the surface center temperature decreased from 183.1 °C for C/SiC to 130.1 °C for C/SiC@SiC. Overall, this study offers valuable insights into the development of advanced absorption and thermal insulation materials, providing a foundation for further research and innovation in this field. [ABSTRACT FROM AUTHOR]

Heat stress poses a substantial challenge to poultry production worldwide, highlighting the urgent need for effective management strategies. This study investigated the efficacy of probiotics (Saccharomyces cerevisiae) and ascorbic acid as antistress agents using cloacal and body surface temperatures (CT and BST) as heat stress biomarkers in broiler chickens. A total of 56 broiler chicks were used for the experiment and were divided into four distinct groups: control, probiotics (1 g/kg of feed), ascorbic acid (200 mg/kg of feed) and the combination of probiotics and ascorbic acid (1 g/kg and 200 mg/kg of feed, respectively). The study lasted 35 days; measurements were taken for ambient temperature (AT), CT, and BST. The ambient temperature in the pens consistently exceeded the thermoneutral zone (TNZ) established for broiler chickens. The CT values for broiler chickens in the probiotic group were significantly lower (p < 0.05) compared to the control group. Additionally, the BST values in the probiotic and probiotic + ascorbic acid groups were significantly lower (p < 0.05) than those in the control group. The findings suggest that incorporating probiotics, with or without ascorbic acid, can effectively reduce CT and BST values in broiler chickens thereby, enhancing thermoregulation when compared to the control group. This implies that using probiotics in poultry diets may enhance health and growth performance, potentially leading to better feed efficiency and reduced reliance on antibiotics. Implementing these dietary strategies could improve the productivity and welfare of broiler chickens in commercial settings. [ABSTRACT FROM AUTHOR]

Systematic investigation of lunar night-time temperatures can possibly be thought as a stable platform to study Earth's radiation budget and climate change as advocated earlier by several researchers. In this study, we report an interesting observation possibly of changing Earth's climate as experienced by the Moon, utilizing a rare and novel context of COVID-19 global lockdown. Lunar night-time surface temperatures of six different sites on the Moon's nearside were analysed during the period 2017–2023. Results showed an anomalous dip in the lunar night-time surface temperatures for all the sites during April–May 2020, the strict COVID-19 global lockdown period, when compared to the values of the same period during the previous and subsequent years. Since the terrestrial radiation has also showed a significant reduction during that time, the anomalous decrease observed in lunar surface temperatures is attributed to the COVID-19 global lockdown effect. Therefore, our study shows that the Moon has possibly experienced the effect of COVID-19 lockdown, visualized as an anomalous decrease in lunar night-time surface temperatures during that period. These results can be substantiated further from Moon-based observatories in future, thereby making them potential tools for observing Earth's environmental and climate changes. [ABSTRACT FROM AUTHOR]

In this work, a new heat dissipation method based on ultra-thin flattened heat pipe (UTHP) is developed for cooling watch-phones. The UTHP with a 0.4 mm thickness was designed to be a three-dimensional shape according to the watchcase shape. The UTHP cooling module (HPM) was soldered by three copper plates and a UTHP. The heat dissipation performance of the copper sheet cooling module (CSM) with the same dimensions was made for comparison with the HPM. The heat dissipation performance of the HPM was experimentally studied. The results indicate that the maximum heat dissipation powers of CSM and HPM were 0.8 and 0.9 W, respectively, at the surface temperature of the ceramic heater not exceeding 65 °C. At this time, ΔTc and Rhc of them were 9.18 °C and 9.86 °C/W, 3.98 °C and 2.63 °C/W, respectively. When the cooling module was cooled naturally from 65 to 37 °C, the heat dissipation time of HPM was 25 s shorter than that of CSM. The UTHP cooling module has a better heat dissipation performance, which can quickly reduce the chip temperature, eliminate the chip hotspot, and solve the heat dissipation issue of watch-phone. [ABSTRACT FROM AUTHOR]

The Cool Roof concept, known for its efficiency in summer due to high temperatures during this period, employs a light coating that covers the roof to prevent the absorption of heat and maintain lower indoor temperatures. This study integrates a chemical component with biomaterials to enhance performance and reduce CO2 emissions. The composition investigated in this research is recognized for its durability and ability to lower outside temperatures, thereby mitigating the urban heat island effect. This experimental study evaluates the sustainability of CoolRoofs in a cold room located in Signes, France. Temperature measurements are conducted from 25 September 2023 to 27 July 2024, both with and without the coating, to assess energy performance and CO2 emissions. The selection of the building type ensures optimal performance in both summer and winter. Results show that the maximum outside and inside surface temperatures for a Cool Roof are 48.7 °C and 25.6 °C, respectively, compared to 72.9 °C and 32.2 °C for an uncoated roof. Additionally, implementing a CoolRoof reduces thermal load through the cold room by 56%, while CO2 emissions can be reduced by up to 27.31 kg CO2/m2 over a 20-year period. This study presents a solution for enhancing energy and environmental performance year-round using a resilient composite. [ABSTRACT FROM AUTHOR]

Longwave radiation is a crucial factor affecting human thermal comfort and thermal stress, especially in outdoor spaces in summer, owing to the vast effect of longwave radiation emitted from high-heated asphalt roads, building walls, and automobiles. Although controlling the longwave radiation environment to improve thermal comfort in summer is crucial, the prediction of the longwave radiation environment is frequently conducted only at the assessment stage of the final proposal because of the high computational cost of radiation calculations and unsteady heat balance analysis considering multiple reflections. This is a significant constraint for the design of urban and architectural environments. A previous study proposed a method to rapidly estimate the longwave radiation environment based on a point-by-point method with longwave radiation intensity distributions of the heat sources. To use this method, 3D models of the geographical objects in urban areas, such as buildings and trees, must be accurately generated, and these models should have information on the longwave radiation emitted in each direction from each object. However, no specific examples of a 3D model and longwave radiation intensity distribution have been presented. In this study, a 3D modeling method for geographical objects in urban areas with longwave radiation information based on drones and photogrammetric techniques was utilized. Moreover, a 3D model of a small-scale building was generated. A longwave radiation intensity distribution was produced for the building. Based on the distribution data, the directional characteristics of longwave radiation were discussed, and the availability of the proposed method was assessed. [ABSTRACT FROM AUTHOR]

Utilizing CloudSat/CALIPSO satellite data and ERA5 reanalysis data from 2007 to 2016, this study analyzed the distributions of optical and physical characteristics and change characteristics of ice clouds over the Tibetan Plateau (TP). The results show that the frequency of ice clouds in the cold season (November to March) on the plateau is over 80%, while in the warm season (May to September) it is around 60%. The average cloud base height of ice clouds in the warm season is 3–5 km, and mostly around 2 km in the cold season. The average cloud top height in the warm season is around 5–8 km, while in the cold season it is mainly around 4.5 km. The average thickness of ice clouds in both seasons is around 2 km. The statistical results of microphysical characteristics show that the ice water content is around 10−1 to 103 mg/m3, and the effective radius of ice clouds is mainly in the range of 10–90 μm. Both have their highest frequency in the west of the TP and lowest in the northeast. A comprehensive analysis of the change in temperature, water vapor, and ice cloud occurrence frequency shows that the rate of increase in water vapor in the warm season is greater than that in the cold season, while the rates of increase in both surface temperature and ice cloud occurrence are smaller than in the cold season. The rate of increase in temperature in the warm season is around 0.038 °C/yr, and that in the cold season is around 0.095 °C/yr. The growth rate of thin ice clouds in the warm season is around 0.15% per year, while that in the cold season is as high as 1% per year. The results suggest that the surface temperature change may be related to the occurrence frequency of thin ice clouds, with the notable increase in temperature during the cold season possibly being associated with a significant increase in the occurrence frequency of thin ice clouds. [ABSTRACT FROM AUTHOR]

A novel method to derive surface temperatures from aerial thermography is proposed. Its theoretical foundation, details regarding the implementation, relevant sensitivities, and its application on a day and night survey are presented here. The method differs from existing approaches particularly in two aspects: first, a three-dimensional sampling approach is used to determine the reflected thermal radiation component. Different surface classes based on hyperspectral classification with specific properties regarding the reflection and emission of thermal radiation are considered in this sampling process. Second, the method relies on a detailed, altitude-dependent, directionally and spectrally resolved modelling of the atmospheric radiation transfer and considers the spectral sensitivity of the sensor used. In order to accurately consider atmospheric influences, the atmosphere is modelled as a function of altitude regarding temperature, pressure and greenhouse gas concentrations. The atmospheric profiles are generated specifically for the time of the survey based on measurements, meteorological forecasts and generic models. The method was initially developed for application in urban contexts, as it is able to capture the pronounced three-dimensional character of such environments. However, due to the detailed consideration of elevation and atmospheric conditions, the method is also valuable for the analysis of rural areas. The included case studies covering two thermographic surveys of city area of Graz during daytime and nighttime demonstrate the capabilities and feasibility of the method. In relation to the detected brightness temperatures apparent to the sensor, the determined surface temperatures vary considerably and generally cover an increased temperature range. The two processed surface temperature maps of the city area of Graz are finally used to validate the method based on available temperature recordings. [ABSTRACT FROM AUTHOR]

Background and Aim: Keloids cannot be effectively treated using monotherapy regimens. This study aimed to evaluate the efficacy and safety of ablation (a novel needle‐assisted electrocoagulation technique) combined with pharmacotherapy (corticosteroid and 5‐fluorouracil [5‐FU] injections) in removing keloids and to investigate the underlying biological mechanisms. Methods: The effects of energy consumption and duration of needle‐assisted electrocoagulation on the ablation zone were tested in porcine liver tissue, which simulates human skin. The regulatory effects of ablation combined with pharmacotherapy on collagen deposition, cell proliferation, and angiogenesis were analyzed in a keloid‐bearing nude mouse model in vivo. In a clinical trial involving six patients with keloids, the Vancouver Scar Scale (VSS) and Patient and Observer Scar Assessment Scale (POSAS) scores were graded before treatment and 1 month after one cycle of ablation combined with corticosteroid and 5‐FU therapy. Results: Higher energy consumption and longer duration of electrocoagulation resulted in a larger ablation zone and higher surface temperature. Ablation combined with pharmacotherapy significantly reduced keloid volume in nude mice, upregulated MMP‐1 and MMP‐3, downregulated COL I and COL III, and inhibited angiogenesis and proliferation. This combination also significantly reduced the VSS and POSAS scores in patients with keloids after treatment without any obvious adverse events. Conclusion: Our findings show that electroablation combined with pharmacotherapy effectively reduces keloid volume by inhibiting collagen deposition, angiogenesis, and cell proliferation. Thus, this novel combination may serve as a safe therapeutic approach for keloid removal. [ABSTRACT FROM AUTHOR]

In India, where dairy production leads globally, infrared thermography (IRT) and short milking tube thermography specifically are vital for managing mastitis. Therefore, the present study focuses on thermal imaging of the udder and short milking tube (SMT) of the milking machine during the peak milking process of Sahiwal cows and Murrah buffaloes during winter, summer, rainy and autumn seasons to identify sub-clinical (SCM) and clinical mastitis (CM) cases using the Darvi DTL007 camera. The udder health was assessed using the California Mastitis Test, Somatic Cell Count (SCC) and IRT throughout the year. Log10SCC and thermogram analysis revealed a difference (p < 0.01) between healthy, SCM, and CM cases during different seasons in both breeds. Further results showed an increase (p < 0.01) in SMT thermograms of SCM and CM cases compared to healthy quarters in Sahiwal cows during winter, summer, rainy, and autumn were 4.26 and 7.51, 2.37 and 4.47, 2.20 and 3.64, 2.90 and 4.94 ºC, respectively and for Murrah buffaloes were 3.56 and 5.55, 2.70 and 3.81, 1.72 and 3.10, 3.14 and 4.42ºC, respectively. The highest degree of increase in milking udder skin surface temperature and SMT of SCM and CM cases compared to healthy quarters was observed during the winter and the least during the rainy season. Thus, regardless of the seasons examined in this study, SMT thermograms effectively assessed SCM and CM. [ABSTRACT FROM AUTHOR]

Summary: This study explored the feasibility of 3D food printing with zucchini puree‐rice flour mixtures, focussing on factors impacting print quality for home‐based applications. The effects of printing variables, including fill ratio (25%, 50%, 75% and 100%) and printing bed temperature (65 °C, 75 °C and 85 °C), were assessed on the print quality of the samples, along with rice flour ratio and a freeze‐thaw step commonly employed by general consumers. Increasing rice flour content enhanced water retention, leading to improved printability in terms of shape retention and dimensional accuracy. Higher printing surface temperatures promoted starch gelation in the initial layers, resulting in better shape retention and improved print scores at moderate rice flour ratios. The highest print quality, determined by dimensional accuracy and visual observations, was achieved with a rice flour puree ratio of 5:10, printed at a 100% infill ratio and 85°C printing bed temperature. While freeze‐thawing the mixtures preserved printability, it weakened the structure, leading to increased syneresis and spreading. Cooking fresh samples at 170 °C for 20 min after printing caused surface cracks, whereas freeze‐thawed samples retained their smooth surface. Further research is needed to optimise printing parameters, considering typical preparation steps that may be applied to vegetable flour mixtures before and after 3D printing. [ABSTRACT FROM AUTHOR]

In this paper, we present a comprehensive study on the 3D nanoscale topography of LaMnO 3 thin films, focusing on the influence of calcination temperature on surface morphology. The study reveals significant structural, chemical, and morphological changes as a function of the calcination temperature. XRD analysis confirmed the formation of the orthorhombic LaMnO 3 structure at 700 °C, 750 °C, and 800 °C, with increasing unit cell volume and crystallite size observed at higher temperatures. FTIR spectra identified characteristic functional groups associated with molecular vibrations, indicating the perovskite structure. SEM imaging showed grain growth with temperature, while EDS analysis confirmed compound formation and substrate interactions. AFM analysis revealed increased surface roughness with temperature, attributed to nucleation and crystal growth. Morphological and microtextural analyses further detailed changes in surface features, peaks, valleys, and voids. Fractal characterization highlighted variations in surface texture with temperature, with a decrease in dominant wavelength indicating changes in microtexture complexity. Overall, the findings provide insights into the temperature-dependent properties of LaMnO 3 thin films, essential for optimizing growth conditions and understanding their potential applications in various fields. [ABSTRACT FROM AUTHOR]

For a photovoltaic module coupled with thermoelectric generator, a unique wavy cooling channel is proposed, and its performance is numerically assessed by using three-dimensional computations. The cooling channel uses nanofluid of alumina–water with various shaped nanoparticles (spherical, cylindrical and brick). Numerical simulations are performed for a range of parameters for the corrugation amplitude ( 0 ≤ Amp ≤ 0.1 ), wave frequency ( 2 ≤ Nf ≤ 16 ), nanoparticle loading quantity ( 0 ≤ SVF ≤ 0.03 ), and nanoparticle shape (spherical, brick, and cylindrical). We analyze the photovoltaic module's average temperature and temperature uniformity for a variety of parameter variations. When nanofluid and greater channel corrugation amplitudes are utilized, the average panel surface temperature is decreased more. A wavy shape of the cooling channel at the maximum corrugation amplitude yields a cell temperature reduction of 1.88 o C, while frequency has little impact on average cell temperature and its uniformity. The best-performing particles are those with cylindrical shapes, and the drop-in average photovoltaic temperature with solid volume fraction is essentially linear. As utilizing cylindrical-shaped particles, the average temperature of corrugated cooling channels decreases by around 1.9 o C as compared to flat cooling channels with base fluid at the greatest solid volume fraction. As compared to un-cooled photovoltaic, cell temperature drops by around 43.2 o C when employing thermoelectric generator. However, temperature drop value of 59.8 o C can be obtained by using thermoelectric generator and nano-enhanced wavy cooling channel utilizing cylindrical-shaped nanoparticles. An hybrid computational strategy for the fully coupled system of photovoltaic with cooling system is provided, which reduces the computational time by a factor of 75. [ABSTRACT FROM AUTHOR]

Thermal link is an important carrier used to transfer the cooling capacity and suppress the temperature fluctuation in cryostat. To balance these two points, it is usually necessary to find the optimum thermal link parameters. This paper establishes a model for the cryocooler cold head-thermal link-second flange based on a cryostat. Utilizing the response surface method, response equations correlating thermal link parameters with the temperature and its fluctuations of the second stage flange are developed at the lowest temperature of cryocooler. Through dual-objective optimization of cooling capacity transfer and temperature fluctuations at the second flange, the optimal thermal link parameters are determined and experimentally validated based on predicted results. The experimental and predicted values show good agreement with an error of 2 %. The optimized thermal link led a minor temperature increase and a significant temperature fluctuation reduction, decreasing from 230mK at the cold head to 2.900mK at the second flange, achieving a 98.74 % reduction. Furthermore, compared with non-optimization structure, the optimization one has further lowered the temperature fluctuation at the second flange from 4.000mK to 2.900mK with 27.5 % improvement. These results show that the present methods are reliable and useful to help to realize highly stable low-temperature environment in cryostat. [ABSTRACT FROM AUTHOR]

Despite the observation of change in the cavitation regime on a heated surface, the specific section of the wall surface that plays a more dominant role in this transition phenomenon remains unknown. This study experimentally investigated the effect of surface temperature of different regions on the cavitating flow in terms of the cavitation regime. The experiments were conducted using a convergent–divergent Venturi nozzle comprising two parts that could be heated independently. The Venturi nozzle could be fully or selectively heated at either the front, where the leading edge of the cavity sheet was located, or the rear, where the cavity sheet developed. The cavitation behavior under different heating conditions was investigated using high-speed visualization and fluctuating pressure measurements. Compared with the nonheated case, which exhibited sheet-cloud cavitation, the cavitation regime on the fully heated Venturi nozzle exhibited transient cavitation. The same transition phenomenon was also observed when only the front part of the Venturi nozzle was heated. In contrast, heating the rear part alone did not induce a change in the cavitation regime. Therefore, it appeared that the transition of the cavitation regime on a heated surface was mainly influenced by the temperature increase at the leading edge of the cavity sheet. [ABSTRACT FROM AUTHOR]

Depending on the obturation technique, the tooth and surrounding tissues may heat up during root canal filling, particularly with warm methods. This study aimed to analyze the temperature increase in the periradicular and -apical region during various warm obturation techniques with a present simulated periodontal blood flow. Seventy-five extracted human teeth were shortened to 11 mm (cut-grinder Primus diamond cutting device; Walter Messner GmbH, Oststeinbek, Germany) and prepared using the ProTaper Gold system (Dentsply Sirona Inc., Charlotte, NC, USA) ISO size 40/.06. Specimens were prepared to ensure stable fluid circulation in an artificially created periodontal space, and the procedure was recorded with a thermal infrared camera (VarioCAM HD; InfraTec GmbH Infrarotsensorik und Messtechnik, Dresden, Germany). The following obturation methods were applied: I, cold single-cone obturation (control group); II, gutta-percha-coated rigid carrier technique (GuttaFusion); III, squirting technique (injection technique); IV, continuous wave technique; and V, Schilder technique. Statistical analysis was performed using the Kruskal–Wallis test, followed by the Mann–Whitney pairwise test using the sequential Bonferroni procedure for significant differences (p < 0.05). The Schilder technique with 0 mL/min showed the lowest temperature change, with a median of 0.00 °C (max. 0.00 °C, min. 0.00 °C, IQR 0.00 °C). In contrast, the continuous wave technique at a circulation rate of 2.6 mL/min exhibited the highest temperature change, with a median of 3.76 °C (max. 5.33 °C, min. 2.42 °C, IQR 1.46 °C). Although warm obturation techniques can increase surface temperature, none of the methods produced changes that were potentially damaging to the periodontium or surrounding bone. [ABSTRACT FROM AUTHOR]

It is a consensus that Earth's climate has been warming. The impact of global warming is asymmetric, that is, there is more substantial warming in the daily minimum surface air temperature and lower warming in the maximum surface air temperature. Previous studies have reported diurnal temperature differences greatly affecting winter wheat yield. However, only a few studies have investigated the impact of global warming on the growth and yield of winter wheat, yet the influence of night warming on quality has not been deeply evaluated. In this study, two wheat cultivars were used as materials: Jimai 44 (JM44) with strong gluten and Jimai 22 (JM22) with medium gluten, to explore the effects of high nighttime temperatures (HNTs) on the growth, yield, and quality of wheat. The results show that HNTs significantly shortened seedling emergence and anthesis periods in both cultivars compared with ambient temperatures (ATs). In addition, HNTs increased the respiration rate at anthesis and grain-filling stages, impeding wheat pollination and grain maturity. HNTs also accelerated leaf senescence and increased the number of sterile spikelets and plant height, but decreased the effective tiller number, the number of spikes per unit area, and grains per spike. As a result, the grain yield of JM22 and JM44 was decreased by 24.6% and 21.2%, respectively. Moreover, HNTs negatively influenced the flour quality of the two wheat cultivars. The current findings provide new insights into the effects of HNTs on the growth, development, yield, and quality of different wheat genotypes during the whole growth period. [ABSTRACT FROM AUTHOR]

Motivated by the widespread applications of nanofluids, a nanofluid model is proposed which focuses on uniform magnetohydrodynamic (MHD) boundary layer flow over a non-linear stretching sheet, incorporating the Casson model for blood-based nanofluid while accounting for viscous and Ohmic dissipation effects under the cases of Constant Surface Temperature (CST) and Prescribed Surface Temperature (PST). The study employs a two-phase model for the nanofluid, coupled with thermophoresis and Brownian motion, to analyze the effects of key fluid parameters such as thermophoresis, Brownian motion, slip velocity, Schmidt number, Eckert number, magnetic parameter, and non-linear stretching parameter on the velocity, concentration, and temperature profiles of the nanofluid. The proposed model is novel as it simultaneously considers the impact of thermophoresis and Brownian motion, along with Ohmic and viscous dissipation effects, in both CST and PST scenarios for blood-based Casson nanofluid. The numerical technique built into MATLAB's bvp4c module is utilized to solve the governing system of coupled differential equations, revealing that the concentration of nanoparticles decreases with increasing thermophoresis and Brownian motion parameters while the temperature of the nanofluid increases. Additionally, a higher Eckert number is found to reduce the nanofluid temperature. A comparative analysis between CST and PST scenarios is also undertaken, which highlights the significant influence of these factors on the fluid's characteristics. The findings have potential applications in biomedical processes to enhance fluid velocity and heat transfer rates, ultimately improving patient outcomes. [ABSTRACT FROM AUTHOR]

The project aimed to develop a reduced scale test protocol designed to be repeatable and capable of providing the upward fire evaluation for assessing fire risk on external thermal insulation composite system facade samples. The variation of heat flux is simulated by radiant panel. This experimental setup permits the recording of dynamic variables in flame propagation, such as ignition time, flame extinguishing time, and variations in both surface and back temperatures of the insulation panel. Notably, the measurement of back temperature provides a means to assess the thermal insulation efficiency of the external thermal insulation composite system facade. Furthermore, the fire spreading temperature is collected during the test could also be useful for larger-scale testing. [ABSTRACT FROM AUTHOR]

Hydrothermal growth of ZnSn(OH)6 nanograss on ZnO‐coated FTO substrates is demonstrated. Effect of surfactants addition (polyvinylpyrrolidone and polyethylene glycol), precursor concentration, and reaction temperature on surface morphology of ZnSn(OH)6 nanograss are investigated. Addition of surfactant in precursor solution results in growth of approximately 20–30 nm thick nanograss morphology with varying orientation. The nanograss grow longer by increasing the concentration of precursors solution. The grown ZnSn(OH)6, exhibits XRD peaks corresponding to cubic phase ZnSn(OH)6. Optical bandgap of the grown nanograss are calculated in the range from ∼3.0 to 3.5 eV. The nanograss photoanode grown with PEG surfactant (at 200 °C) has shown the highest photocurrent of 2.2 mA/cm2 at RHE 1.23VRHE and photoconversion efficiency of 1.4% at 0.46 VRHE. The longer nanograss has shown lower charge transfer resistance and higher charge carrier concentration, which is favorable for enhancing the PEC performance. [ABSTRACT FROM AUTHOR]

The ability to access physiologically driven signals, such as surface temperature, photochemical reflectance index (PRI), and sun-induced chlorophyll fluorescence (SIF), through remote sensing (RS) are exciting developments for vegetation studies. Accessing this ecophysiological information requires considering processes operating at scales from the top-of-the-canopy to the photosystems, adding complexity compared to reflectance index-based approaches. To investigate the maturity and knowledge of the growing RS community in this area, COST Action CA17134 SENSECO organized a Spatial Scaling Challenge (SSC). Challenge participants were asked to retrieve four key ecophysiological variables for a field each of maize and wheat from a simulated field campaign: leaf area index (LAI), leaf chlorophyll content (Cab), maximum carboxylation rate (Vcmax,25), and non-photochemical quenching (NPQ). The simulated campaign data included hyperspectral optical, thermal and SIF imagery, together with ground sampling of the four variables. Non-parametric methods that combined multiple spectral domains and field measurements were used most often, thereby indirectly performing the top-of-the-canopy to photosystem scaling. LAI and Cab were reliably retrieved in most cases, whereas Vcmax,25 and NPQ were less accurately estimated and demanded information ancillary to RS imagery. The factors considered least by participants were the biophysical and physiological canopy vertical profiles, the spatial mismatch between RS sensors, the temporal mismatch between field sampling and RS acquisition, and measurement uncertainty. Furthermore, few participants developed NPQ maps into stress maps or provided a deeper analysis of their parameter retrievals. The SSC shows that, despite advances in statistical and physically based models, the vegetation RS community should improve how field and RS data are integrated and scaled in space and time. We expect this work will guide newcomers and support robust advances in this research field. [ABSTRACT FROM AUTHOR]

Thermal barrier coatings (TBCs) reduce the surface temperature of superalloy components but may affect the mechanical properties of the substrate. This study investigates the creep-fatigue behavior of TBC-coated single-crystal superalloys under 1 s, 60 s, and 180 s dwell times. The results indicate that TBCs are beneficial at a 1 s dwell time. The comparison of fracture morphology between coated and uncoated samples showed no change in the failure mechanism due to TBCs under creep-fatigue loading. A creep-fatigue lifetime prediction method based on continuous damage mechanics was also proposed. The predicted results were all within a double dispersion coefficient, showing good agreement with the experimental results. This study provides insights into the durability of TBC-coated single-crystal superalloys under creep-fatigue loading. [ABSTRACT FROM AUTHOR]

Introduction: The impacts of climate change can be profound in many ecosystems worldwide, including drylands such as arid and semi-arid scrublands and grasslands. Foundation plants such as shrubs can provide microclimatic refuges for a variety of taxa. These shrubs can directly influence micro6 environmental measures, and indirectly increase the local environmental heterogeneity as a result. We examined the hypothesis that, in comparison to an open gap, foundation shrubs improve the microclimate beneath their canopy and that microclimate is in turn a significant predictor of annual vegetation. The following predictions were made: 1) mean air temperature (NSAT), ground temperature (SGT), and vapour pressure deficit (VPD) will be significantly lower under the shrubs than in the open microsites; 2) shrub canopy size predicts microclimate; 3) site-level aridity estimates and percent shrub cover influence annual plant abundance and richness; and 4) the site13 level mean of NSAT and VPD predict annual plant abundance and richness. Methods: Our study took place in Southwestern California, U.S.A. We used a handheld device with a probe to measure microclimatic variables such as nearsurface air temperature (NSAT), near-surface relative humidity (NSRH), and surface ground temperature (SGT) at the shrub species Ephedra californica and in the open gap, across six sites in California, United States. Air temperature and RH were then used to calculate VPD. The mean number of vascular plant species across each site was also recorded. Results & discussion: Only SGT was significantly reduced under shrub canopies. Canopy volume was not a significant predictor of all three microclimatic variables, demonstrating that even small, low-stature shrubs can have facilitative effects. Furthermore, total shrub cover and aridity at sites significantly predicted mean plant richness and abundance. There were significantly more plants associated with shrubs and there were significantly more species associated with the open. Mean air temperature and VPD at the site-level significantly predicted vegetation abundance and richness, though microsite-level differences were only significant for richness. Foundation shrubs are a focal point of resiliency in dryland ecosystems. Understanding their impact on microclimate can inform us of better management, conservation, and restoration frameworks. [ABSTRACT FROM AUTHOR]

Severe friction on wheel/rail contact interface in the process of a train emergency braking can cause significant thermal and mechanical phenomena. Obvious friction heat and serious material damage will appear on the contact surface. In this article, the variation law of temperature and surface damage during a wheel sliding contact process are investigated. To achieve the research objective, a three-dimensional (3D) thermo-mechanical coupling contact finite element model (FEM) is established, and the temperature-dependent material parameters are used. The FEM is adopted to analyze the temperature distribution law on the contact surface. At the same time, a sliding contact testing machine is used to study the damage of materials in the contact area during the sliding contact. The study results indicate, the highest temperature of wheel and rail material is respectively 1014 ℃ and 461.8 ℃ during sliding contact. High temperatures are located at the subsurface and surface areas of contact region. When the distance to contact surface exceeds 1.4 mm, the temperature changes slightly. The types of damage on wheel surface are grooves and material peeling, while the flaky spalling, corrosive pitting, adhesion and grooves appear on the rail surface. Meanwhile, many cracks can be found on the contact surface, which is a major factor leading to material damage. The research results of this article are of great significance for understanding the thermal and mechanical damage of wheel/rail materials. [ABSTRACT FROM AUTHOR]

We evaluate the vertical turbulent-kinetic-energy (TKE) mixing scheme of the NEMO-SI3 ocean–sea-ice model in sea-ice-covered regions of the Arctic Ocean. Specifically, we assess the parameters involved in TKE mixed-layer-penetration (MLP) parameterization. This ad hoc parameterization aims to capture processes that impact the ocean surface boundary layer, such as near-inertial oscillations, ocean swells, and waves, which are often not well represented in the default TKE scheme. We evaluate this parameterization for the first time in three regions of the Arctic Ocean: the Makarov, Eurasian, and Canada basins. We demonstrate the strong effect of the scaling parameter that accounts for the presence of sea ice. Our results confirm that TKE MLP must be scaled down below sea ice to avoid unrealistically deep mixed layers. The other parameters evaluated are the percentage of energy penetrating below the mixed layer and the length scale of its decay with depth. All these parameters affect mixed-layer depth and its seasonal cycle, surface temperature, and salinity, as well as underlying stratification. Shallow mixed layers are associated with stronger stratification and fresh surface anomalies, and deeper mixed layers correspond to weaker stratification and salty surface anomalies. Notably, we observe significant impacts on sea-ice thickness across the Arctic Ocean in two scenarios: when the scaling parameter due to sea ice is absent and when the TKE mixed-layer-penetration process vanishes. In the former case, we observe an increase of several meters in mixed-layer depth, along with a reduction in sea-ice thickness ranging from 30 to 40 cm, reflecting the impact of stronger mixing. Conversely, in the latter case, we notice that a shallower mixed layer is accompanied by a moderate increase in sea-ice thickness, ranging from 10 to 20 cm, as expected from weaker mixing. Additionally, interannual variability suggests that experiments incorporating a scaling parameter based on sea-ice concentration display an increased mixed-layer depth during periods of reduced sea ice, which is consistent with observed trends. These findings underscore the influence of enhanced ocean mixing, through specific parameterizations, on the physical properties of the upper ocean and sea ice. [ABSTRACT FROM AUTHOR]

In this study, a quenching experiment was conducted at atmospheric pressure to investigate the flow and heat-transfer characteristics of cylindrical rods made from SS, FeCrAl, and Zr-4 under various subcooling degrees (ΔTsub). The inverse heat-conduction problem (IHCP) method and image-processing technique were utilized to determine the surface temperature and heat flux, vapor film thickness, and quench front propagation. The results show that smaller solid kρcp and larger ΔTsub result in relatively more efficient quenching boiling heat transfer, thinner vapor film thickness, and greater quench front propagation velocity. The quench front originates at the bottom of the test specimen and becomes progressively larger in velocity with time. It eventually converges with the downward-propagating quench front in the upper middle of the test specimen. Moreover, at the beginning of quench front propagation, the SS and FeCrAl test specimens have a constant velocity region. However, because the Zr-4 test specimen has a small kρcp, the velocities gradually increase from the onset of quench front generation. Furthermore, the measured average quench front velocities are consistent with the experimental datum from the literature. However, the predicted model proposed by Duffey underestimates the propagation velocity due to ignoring the cooling effect of film boiling. [ABSTRACT FROM AUTHOR]

This study investigates the impact of vertical greenery systems (VGSs) applied to several typical wall configurations on indoor thermal conditions in a building module situated in the Mediterranean climate of Catania, Italy. By means of dynamic simulations in TRNSYS vers.18, the research compares the thermal behavior of walls made of either hollow clay blocks (Poroton) or lava stone blocks against a lightweight wall setup already in place at the University of Catania. The primary focus is on evaluating the VGSs' capability of reducing peak inner surface temperatures and moderating heat flux fluctuations entering the building. The findings indicate that adding an outer vertical greenery layer to heavyweight walls can decrease the peak inner surface temperature by up to 1.0 °C compared to the same bare wall. However, the greenery's positive impact is less pronounced than in the case of the lightweight wall. This research underscores the potential of green facades in enhancing the indoor thermal environment in buildings in regions with climates like the Mediterranean one, providing valuable insights for sustainable building design and urban planning. [ABSTRACT FROM AUTHOR]

As electronics become more powerful and compact, laminated microchannel heat sinks (MCHSs) are essential for handling high heat flux. This study aims to optimize the MCHS design for improved heat dissipation and structural strength. An orthogonal experiment was established with the average surface temperature of the heat source as the evaluation metric, and the optimal structure was determined through simulation. Finally, cooling uniformity, fluidity, and performance evaluation criterion (PEC) analyses were carried out on the optimal structure. It was determined that the optimal combination was the triangular cavity microchannel (MCTC), with a microchannel width of 0.5 mm, a microchannel distribution density of 60%, and the presence of surface undulation on the microchannels. The result shows that the optimal structure's peak inter-layer stress is just 34.8% of its longitudinal tensile strength. Compared to the traditional parallel straight microchannel (MCPS), this structure boasts an 8.6 K decrease in the average surface temperature and a temperature variation along specific paths that is only 9.9% of that in traditional designs. Moreover, the optimal design cuts the velocity loss at the microchannel entrance from 75% to 59%. Thus, this research successfully develops an effective optimization strategy for MCHSs. [ABSTRACT FROM AUTHOR]

In this study, carbon nanotube (CNT)/carbon nanofiber (CNF) composite electrothermal films were prepared by electrospinning, and the effects of the CNT content and carbonization temperature on the electrothermal properties of the CNT/CNF composite films were investigated. The experimental results demonstrated that the conductivity of the CNT/CNF composite electrothermal film (0.006–6.89 S/cm) was directly affected by the CNT content and carbonization temperature. The electrothermal properties of the CNT/CNF positively correlated with the CNT content, carbonization temperature, and applied voltage. The surface temperature of CNT/CNF can be controlled within 30–260 °C, and continuously heated and cooled 100 times without any loss. The convective heat transfer with air is controllable between 0.008 and 31.75. The radiation heat transfer is controllable between 0.29 and 1.92. The prepared CNT/CNF exhibited a heat transfer efficiency of up to 94.5%, and melted a 1 cm thick ice layer within 3 min by thermal convection and radiation alone. [ABSTRACT FROM AUTHOR]

Inversion of the photoplethysmographic (PPG) signal is a rarely reported case. This signal anomaly can have implications for PPG-based cardiovascular assessments. The conditions for PPG signal inversion in the vicinity of the dorsalis pedis (DPA) artery of the foot were investigated. Wireless multi-wavelength PPG sensing with skin-probe contact pressure and local skin temperature were studied at different sensor positions, and the occurrence of inversion (OOI) was investigated. Twelve healthy adult volunteers were studied over four LED wavelengths at three levels of contact pressure for 11 probe positions. A novel algorithm quantified the proportion of inverted samples with respect to the abovementioned variables. Our algorithm classifying inverted vs. non-inverted pulses achieved 98.3% accuracy. Ten of the participants had at least one inverted signal identified. The impact of interindividual variation on inversion prevalence was large, but different LEDs, relative position to the DPA and sensor contact pressure also affected OOI. Skin surface and room temperatures showed no impact on OOI. Lateral measurements showed 39.6% more inversion at maximum compared to minimum contact pressure. Mechanical capillary bed variations and arterial reflections during venous engorgement are considered viable explanations for our observations. These findings motivate an expanded study of the occurrence of PPG signal inversion. [ABSTRACT FROM AUTHOR]