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The zinc metal anodes are liable to experience detrimental dendrite growth and side reactions, thereby limiting the lifespan of aqueous Zn‐ion batteries. Here, a readily available supramolecule, dimethoxypillar[5]arene (DP[5]), is utilized as a shielding layer to stabilize the Zn anode by exploiting its zincophilicity derived from the ─OCH3 functional groups and its hydrophobicity from the hydrophobic backbone. The DP[5] shielding layer regulates the solvation sheath of Zn2+ and facilitates uniform zinc deposition. Swelling and dendrite formation are obviously suppressed in both the symmetric and full cells. The DP[5]‐Zn symmetrical cell cycles stably for 5500 h, and achieves a coulombic efficiency of 99.76% in a DP[5]‐Zn||Cu half‐cell after 2200 cycles. The DP[5]‐Zn||V2O5 full cell maintains 92.03% of initial capacity after 6000 cycles. Given the cost‐effective fabrication and environmental friendliness of DP[5] films, this material may pave the way for practical applications of zinc anodes. [ABSTRACT FROM AUTHOR]

Oligo‐adenine (polyA) is primarily known for its critical role in mRNA stability, translational status, and gene regulation. Beyond its biological functions, extensive research has unveiled the diverse applications of polyA. In response to environmental stimuli, single polyA strands undergo distinctive structural transitions into diverse secondary configurations, which are reversible upon the introduction of appropriate counter‐triggers. In this review, we systematically summarize recent advances of noncanonical structures derived from polyA, including A‐motif duplex, A‐cyanuric acid triplex, A‐coralyne‐A duplex, and T ⋅ A‐T triplex. The structural characteristics and mechanisms underlying these conformations under specific external stimuli are addressed, followed by examples of their applications in stimuli‐responsive DNA hydrogels, supramolecular fibre assembly, molecular electronics and switches, biosensing and bioengineering, payloads encapsulation and release, and others. A detailed comparison of these polyA‐derived noncanonical structures is provided, highlighting their distinctive features. Furthermore, by integrating their stimuli‐responsiveness and conformational characteristics, advanced material development, such as pH‐cascaded DNA hydrogels and supramolecular fibres exhibiting dynamic structural transitions adapting environmental cues, are introduced. An outlook for future developments is also discussed. These polyA derived, stimuli‐responsive, noncanonical structures enrich the arsenal of DNA "toolbox", offering dynamic DNA frameworks for diverse future applications. [ABSTRACT FROM AUTHOR]

The design of photocatalytic supramolecular systems composing of semiconductors and molecular metal complexes for CO2 reduction has attracted increasing attention. The supramolecular system combines the structural merits of semiconductors and metal complexes, where the semiconductor harvests light and undertakes the oxidative site, while the metal complex provides activity for CO2 reduction. The intermolecular charge transfer plays crucial role in ensuring photocatalytic performance. Here, we review the progress of photocatalytic supramolecular systems in reduction of CO2 and highlight the interfacial charge transfer pathways, as well as their state‐of‐the‐art characterization methods. The remaining challenges and prospects for further design of supramolecular photocatalysts are also presented. [ABSTRACT FROM AUTHOR]

The translational diffusivity of covalent open‐[60]fullerene dimers in an organic solvent was found to be well describable by a prolate ellipsoid model while a monomeric open‐[60]fullerene behaves like a sphere model. The water association dynamics were examined for two open‐[60]fullerene dimers, showing a higher water affinity for the sp3‐linked dimer relative to sp2‐linked dimer owing to an effective orbital–orbital overlap identified by π(fullerene)→σ*(H2O) interactions as suggested by theoretical calculations. [ABSTRACT FROM AUTHOR]

[Display omitted] • P N flame retardant HEPFR can be simply synthesized by supramolecular assembly. • HEPFR has the modification effect of "one stone, three birds" on PVA. • Flame-retardant, transparent and robust PVA film can be easily fabricated. Supramolecular flame retardants have attracted increasing attention recently due to their simple and eco-friendly preparation process. In this study, a novel flame retardant HEPFR was prepared using supramolecular self-assembly technology between piperazine and 1-hydroxy ethylidene-1,1-diphosphonic acid (HEDP). It was introduced into polyvinyl alcohol (PVA) matrix to form PVA/HEPFR composite film. Subsequently, the transparency, mechanical properties, thermal stability, and flame retardancy of PVA/HEPFR films were studied. Due to the hydrogen bonded cross-linked network structure between PVA and HEPFR, the mechanical properties of PVA/HEPFR films have been improved, while maintaining good transparency. With 10 wt% addition of HEPFR, PVA films can reach the VTM-0 level in UL-94 testing. And the limiting oxygen index can be increased from 18.5% of pure PVA to 26.5%. The peak heat release rate was reduced by 61.5%. The flame retardancy and thermal stability of PVA/HEPFR films have been greatly improved. This study provides a "one stone, three birds" strategy for preparing flame-retardant, transparent, and robust PVA film. [ABSTRACT FROM AUTHOR]

Recently, π–π stacked antiaromatic π‐systems have received considerable attention because they can exhibit stacked‐ring aromaticity due to substantial intermolecular orbital interactions. Here, we report three antiaromatic norcorrole dimers that self‐assemble to form supramolecular architectures through chiral self‐sorting. A 2,2'‐linked norcorrole dimer with 3,5‐di‐tert‐butylphenyl groups forms a π‐stacked dimer both in solid and solution states via homochiral self‐sorting. Its association constant in solution is (3.6±1.7)×105 M−1 at 20 °C. In the solid state, 3,3'‐linked norcorrole dimers with 3,5‐di‐tert‐butylphenyl and phenyl groups afford macrocyclic and helical supramolecular assemblies via heterochiral and homochiral self‐sorting, respectively. Notably, the subtle modification in the substituent resulted in a complete change in the structure of the aggregates and the chiral self‐sorting mode. The present findings demonstrate that structural manipulation in antiaromatic monomer units leads to the formation of various supramolecular assemblies on the basis of the attractive interactions between antiaromatic π‐systems. [ABSTRACT FROM AUTHOR]

Chemical warfare agents (CWAs) pose a severe threat to both civilians and military personnel due to their extreme toxicity. The urgent necessity of creating a portable device for rapid on-site quantification of CWAs is evident. This article presents the design and synthesis of a specialized material, calix[4]-pyrrole R2 modified zinc oxide nanohybrid material (R2-ZnO), and its utilization in crafting a smart portable electrochemical device (SPED). The detection capability of the R2-ZnO nanohybrid material was evaluated using various electrochemical techniques, specifically targeting the identification of CWAs' mimic compound, diethyl chlorophosphate (DCP). Upon interaction with the R2-ZnO nanohybrid material, DCP gets entrapped within the pyrrolic cavity of the R2-ZnO nanohybrid material and transforms into hydrolyzed, nontoxic compounds, resulting in a significant increase in current intensity. The interaction of DCP with the R2-ZnO nanohybrid material generates a quick response by enhancing the remarkable current density of the material. Surprisingly, when the R2-ZnO nanohybrid material was exposed to other organophosphates, there was no observable change in the current. Additionally, the developed SPED was tailored for the quantification of DCP, demonstrating fast response times within seconds of exposure. This pioneering research offers a promising pathway to develop a cost-effective, portable device for the rapid on-site quantification of hazardous CWAs. [ABSTRACT FROM AUTHOR]

Molecules with curved architecture can exhibit unique optoelectronic properties due to the concave‐convex π‐surface. However, synthesizing negatively curved saddle‐shaped aromatic systems has been challenging due to the internal structural strain. Herein, we report the facile synthesis of two polyhexagonal molecular systems, 1 and 2, with saddle shape geometry by judiciously varying the aromatic moiety, avoiding the harsh synthetic methods as that of heptagonal aromatic saddle systems. The unique geometry preferences of B, N, and S furnish suitable curvature to the molecules, featuring saddle shape. The saddle geometry also enables them to interact with fullerene C60, and the supramolecular interactions of fullerene C60 with 1 and 2 modify their optoelectronic properties. Crystal structure analysis reveals that 1, with a small π‐surface, forms a double columnar array of fullerenes in the solid state. In contrast, 2 with a large π‐surface produces a supramolecular capsule entrapping two discrete fullerenes. The intermolecular interactions between B, N, S, and the aryl‐π surface of the host and C60 guest are the stabilizing factors for creating these supramolecular structures. Comprehensive computational, optical, and Raman spectroscopic studies establish the charge transfer interactions between B−N doped heterocycle host and fullerene C60 guest. [ABSTRACT FROM AUTHOR]

Molecules with curved architecture can exhibit unique optoelectronic properties due to the concave‐convex π‐surface. However, synthesizing negatively curved saddle‐shaped aromatic systems has been challenging due to the internal structural strain. Herein, we report the facile synthesis of two polyhexagonal molecular systems, 1 and 2, with saddle shape geometry by judiciously varying the aromatic moiety, avoiding the harsh synthetic methods as that of heptagonal aromatic saddle systems. The unique geometry preferences of B, N, and S furnish suitable curvature to the molecules, featuring saddle shape. The saddle geometry also enables them to interact with fullerene C60, and the supramolecular interactions of fullerene C60 with 1 and 2 modify their optoelectronic properties. Crystal structure analysis reveals that 1, with a small π‐surface, forms a double columnar array of fullerenes in the solid state. In contrast, 2 with a large π‐surface produces a supramolecular capsule entrapping two discrete fullerenes. The intermolecular interactions between B, N, S, and the aryl‐π surface of the host and C60 guest are the stabilizing factors for creating these supramolecular structures. Comprehensive computational, optical, and Raman spectroscopic studies establish the charge transfer interactions between B−N doped heterocycle host and fullerene C60 guest. [ABSTRACT FROM AUTHOR]

Copyright of China Surfactant Detergent & Cosmetics (2097-2806) is the property of China Surfactant Detergent & Cosmetics Editorial Office and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

A novel supramolecular complex C44H71Cl2N26O22 (CB[6]@Pipa·2HCl) of the “host-guest” type has been synthesized. It is based on cucurbit[6]uril (CB[6]) with dihydrochloride 1,4-bis(2-hydroxyethyl)piperazine (Pipa·2HCl) localized within the portals of the macrocycle. Based on 1H NMR and X-ray crystallography, the host–guest ratio in the complex under the specified conditions was determined to be 1:1. Further evidence of complex formation was observed through IR spectroscopy, where a shift in the absorption band of carbonyl vibrational frequencies of cucurbit[6]uril by 36 cm−1 towards the longer wavelength region was detected in CB[6]@Pipa·2HCl compared to the original CB[6]. TGA/DSC analysis results indicated an increase in thermal stability by 55 °C for the obtained CB[6]@Pipa·2HCl complex compared to the initial 1,4-bis(2-hydroxyethyl)piperazine dihydrochloride. The structure of the synthesized CB[6]@Pipa·2HCl complex was confirmed using single-crystal XRD.

Liquid-liquid phase separation (LLPS) is a captivating phenomenon in which a uniform mixture spontaneously divides into two liquid phases with differing component concentrations. It is prevalent in soft matter, is observed in systems involving polymers, organic molecules, and proteins, and is influenced by environmental factors and component properties. Recent recognition of LLPS within living organisms reveals its role in creating cellular compartments to orchestrate complex biochemical reactions, requiring distinct boundaries and unhindered molecular movement. Nonmembrane compartments, stemming from cytoplasmic LLPS, such as nucleoli, hold promise for synthetic cell engineering and cellular function insights. Under certain conditions, LLPS is linked to diseases such as sickle-cell disease, cancer, and neurodegenerative diseases. This review offers a concise overview of LLPS in soft matter, emphasizing its relevance in soft material engineering. We delve into fundamental mechanisms, focusing on biological systems, and explore the implications of LLPS, spanning organelles, substance exchange, molecular diffusion, and disease associations. LLPS enables soft material engineering, with applications in biomedicine and bioengineering, shaping future possibilities in bioengineering, from foundational cellular constructs to intricate artificial tissue development.

[Display omitted] • Low-cost melamine-boric acid (MBA) supramolecular hydrogels are self-assembled with a superfast speed in dozens of seconds under room temperature. • In-situ real-time observation of the nucleation and growth of MBA supramolecules is constructed by using polarizing microscope. • The boron nitride and bacterial cellulose (BN/BC) composite aerogel shows excellent flame-retardant performance, electrolyte-wetting ability and high mechanical property. • The BN/BC composite aerogel as the separator enable the derived lithium ion battery with excellent electrochemical property and high safty. Traditional polyolefin separators for lithium-ion batteries (LIBs) often experience limited thermal stability and intrinsic flammability, resulting in great safety risks during their usage. Therefore, it is highly important to develop novel flame-retardant separators for safe LIBs with high performance. In this work, we report a flame-retardant separator derived from boron nitride (BN) aerogel with a high BET surface area of 1127.3 m2 g−1. The aerogel was pyrolyzed from a melamine-boric acid (MBA) supramolecular hydrogel, which was self-assembled at an ultrafast speed. The in-situ evolution details of the nucleation-growth process of the supramolecules could be observed in real-time using a polarizing microscope under ambient conditions. The BN aerogel was further composited with bacterial cellulose (BC) to form a BN/BC composite aerogel with excellent flame-retardant performance, electrolyte-wetting ability and high mechanical property. By using the BN/BC composite aerogel as the separator, the developed LIBs exhibited high specific discharge capacity of 146.5 mAh g−1 and excellent cyclic performance, maintaining 500 cycles with a capacity degradation of only 0.012% per cycle. The high-performance flame-retardant BN/BC composite aerogel represents a promising candidate for separators not only in LIBs but also in other flexible electronics. [ABSTRACT FROM AUTHOR]

Copyright of Journal of Jilin University (Science Edition) / Jilin Daxue Xuebao (Lixue Ban) is the property of Zhongguo Xue shu qi Kan (Guang Pan Ban) Dian zi Za zhi She and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

[Sn(OSO3)2(TPyHP)](HSO4)2∙8H2O (1), an ionic Sn(IV)-porphyrin complex, was prepared by reacting [Sn(OH2)2TPyP] with dilute sulfuric acid. X-ray structural analysis revealed that the zwitterionic [Sn(OSO3)2TPyHP]2+ species consists of two anionic axial Sn–O–SO3 units and four peripheral pyridinium moieties, with an overall dicationic charge balanced by two hydrogen sulfate (HSO4−) counter-anions. Ionic hydrogen bonding between the oxygen atoms of axial sulfato ligands and the peripheral pyridinium groups of adjacent Sn(IV)-porphyrin cations led to the formation of a 1D channel filled with counter-anions and water molecules. The supramolecular self-assembly of 1 was further characterized using various spectroscopic techniques, including 1H NMR spectroscopy, elemental analysis, ESI-mass spectrometry, UV-vis spectroscopy, fluorescence spectroscopy, FT-IR spectroscopy, thermogravimetric analysis (TGA), and powder X-ray diffractometry. The zwitterionic [Sn(OSO3)2TPyHP]2+ complex is a structurally well-defined complementary scaffold involved in supramolecular self-assembly. This novel class of ion-assembled metalloporphyrin is a potential functional porphyrin material used in ion exchange applications. [ABSTRACT FROM AUTHOR]

The properties of asphalt binder play an essential role in the design life of asphalt pavement. Analysis of asphalt mechanical behaviors based on the chemical structures provides the theoretical basis for the improvement of asphalt performance in service life. Intermolecular interactions have a significant impact on the macroscopic properties of asphalt, a colloidal material, resulting in the parameters characterizing asphalt molecular structures fail to directly connect with mechanical properties of asphalt. This paper introduces the supramolecular theory, presents a brief review of existing supramolecular models and research methods of asphalt, aiming to explore a new methodology for the investigation between asphalt microstructures and macroscopic properties. Results showed the supramolecular theory focuses on the intermolecular interactions, providing more accurate indicators for the investigation on the asphalt supramolecules. Supramolecular analysis of asphalt has proposed feasible methods and established favorable connections with asphalt properties, giving a new view of understanding asphalt microstructure and a new approach to capture mechanical behaviors of asphalt.

[Sn(OSO3)2(TPyHP)](HSO4)2∙8H2O (1), an ionic Sn(IV)-porphyrin complex, was prepared by reacting [Sn(OH2)2TPyP] with dilute sulfuric acid. X-ray structural analysis revealed that the zwitterionic [Sn(OSO3)2TPyHP]2+ species consists of two anionic axial Sn–O–SO3 units and four peripheral pyridinium moieties, with an overall dicationic charge balanced by two hydrogen sulfate (HSO4−) counter-anions. Ionic hydrogen bonding between the oxygen atoms of axial sulfato ligands and the peripheral pyridinium groups of adjacent Sn(IV)-porphyrin cations led to the formation of a 1D channel filled with counter-anions and water molecules. The supramolecular self-assembly of 1 was further characterized using various spectroscopic techniques, including 1H NMR spectroscopy, elemental analysis, ESI-mass spectrometry, UV-vis spectroscopy, fluorescence spectroscopy, FT-IR spectroscopy, thermogravimetric analysis (TGA), and powder X-ray diffractometry. The zwitterionic [Sn(OSO3)2TPyHP]2+ complex is a structurally well-defined complementary scaffold involved in supramolecular self-assembly. This novel class of ion-assembled metalloporphyrin is a potential functional porphyrin material used in ion exchange applications.

Macrocyclization of the bendable 2,7‐dimethoxythianthrene with methylene linkages afforded a pair of homochiral macrocycles featuring a hex‐nut‐like geometry. Their structures were fully characterized by NMR spectroscopy, mass spectrometry, and single‐crystal X‐ray diffraction analysis. Their stable planar chirality facilitates efficient resolution of the pair of enantiomers which could be readily derivatized. Installing phenylethynyl groups on their rims leads to luminescent tubular macrocycles exhibiting circularly polarized luminescence with a large dissymmetry value |glum| of 5×10−3. Supramolecular binding of electron‐deficient guests by the tube results in fluorescence quenching, which proved its potential for the future development of switchable chiroptical systems. [ABSTRACT FROM AUTHOR]

Axially polar-ferroelectric columnar liquid crystals (AP-FCLCs) consist of nanosized axially polarized columnar molecular aggregates arranged in parallel, in which their polar directions can be switched by applying an electric field and maintained after removal of the electric field. However, the problem remains that the induced polarity can be disturbed by external stimuli because liquid crystals are fluid. To solve this problem, we planned to realize a smooth phase transition system from an AP-FCLC phase to a crystal phase without disturbing the induced polar structure. Thus, we designed a urea compound with two biphenyl groups and four 2-butyloctyl groups to achieve the system. As a result, we succeeded in realizing an AP-FCLC compound that transitions from the FCLC phase to the crystal phase at room temperature while maintaining the polarization induced in the FCLC phase, which is expected to enable long-term maintenance of polarization information. [ABSTRACT FROM AUTHOR]

Trisubstituted 1,3,5‐tri(benzimidazolyl)benzene derivatives were synthesized from l‐alanine, l‐valine, d‐valine and glycine, and their self‐assembling behavior and stimuli‐response in solution and gel states were evaluated. Circular dichroism/UV‐vis absorption spectroscopic and dynamic light scattering measurements revealed that the compounds formed H‐aggregates via intramolecular hydrogen bonding and π‐π stacking interactions in nonpolar solvents such as CHCl3, whereas collapse of the aggregates was confirmed by MeOH addition. Quantum mechanical calculations and molecular dynamics simulations also supported aggregation in CHCl3. Rheological analysis and morphology observation revealed the formation of a fibril like structure by further assembling of aggregates at a high concentration in CHCl3. [ABSTRACT FROM AUTHOR]

Tinidazole (TNZ), a 5-nitroimidazole derivative, has received increasing attention due to its pharmacological activities in treatment for amebic and parasitic infections. In this paper, we synthesized three novel drug supramolecular compounds successfully based on TNZ. The three compounds discussed were formed by TNZ and 2,6-dihydroxybenzoic acid (2,6-DHBA), 4-methylsalicylic acid (4-MAC), and 5-chloro-2-hydroxybenzoic acid (5-C-2-HBA). The N-H···O and O-H···O hydrogen bonds and weak C-H···O hydrogen bonds are the primary intermolecular forces in the construction of the three compounds. Crystal structure analysis revealed that all the compounds exhibit three-dimensional frameworks consisting of non-covalent interactions. Furthermore, six primary synthons, Ⅰ R22 (8), Ⅱ R21(6), Ⅲ R22(12), Ⅳ R33(9), Ⅴ R22(12), Ⅵ R33(9), formed through various hydrogen bonds are found in the three compounds. Moreover, the resulting pharmaceutical supramolecular compounds show improved stability. Single-crystal X-ray diffraction analysis, infrared spectroscopy (IR), element analysis, and thermogravimetric analysis (TGA) are reported. [ABSTRACT FROM AUTHOR]

Highlights The N/S co-doped lignin-derived porous carbon (NSLPCs) with ultra-high heteroatom doping was prepared through a novel supramolecule-mediated pyrolysis strategy. Covalently bonded graphitic carbon/amorphous carbon intermediates induce the formation of high heteroatom doping. The high heteroatom doping of NSLPC could provide abundant defective active sites for the adsorption of K+.

Herein, three novel cocrystals of 1-hydroxy-2-naphthoic acid: tetramethylpyrazine, 1-hydroxy-2-naphthoic acid:1,10-phenanthroline, and 1-hydroxy-2-naphthoic acid:1,4-bis(imidazol-1-ylmethyl)benzene (L2) were obtained by crystallization in methanol–water mixed solvent via a slow evaporation method. The cocrystalline products 1−3 were carried out by a range of techniques, including single-crystal X-ray diffraction, Fourier transform–infrared spectroscopy, elemental analysis, and thermogravimetric testing. We analyzed the crystal structures of the cocrystals 1−3 and found that weak interactions C–H···X (X = O or π) were of great importance in the process of self-assembly as well as strong and conventional hydrogen bonds (N–H···O, O–H···N, O–H···O), leading to a stable and diverse multidimensional supramolecular architecture. It is worth noting that a series of ring motifs with different sizes were explored in the crystal structures of the above complexes, such as R22(5), R22(7), R22(8), R23(13), R24(16), R44(16), R44(22), and so on. The classical and robust supramolecular synthon intermolecular bond between acid and pyridine (acid···pyridine) heterosynthon R22(7), commonly found in organic solids containing carboxylic acids with other N-containing heteroaromatics, was further demonstrated to be involved in the construction of the hydrogen-bond networks of cocrystal 1. The thermogravimetric technique used in this study proved that the mass losses of these three cocrystals were closely related to the strength of the hydrogen bonds in the package fraction. [ABSTRACT FROM AUTHOR]

To simplify the preparation of dendritic materials, host–guest molecular recognition and self‐assembly are utilized to form a supramolecular dendritic gene vector (DNCVP). DNCVP is constructed from an amino dendron‐conjugated naphthol, viologen containing pH‐sensitive hydrazone‐bond‐linked PEG, and CB[8] with a molar ratio of 1:1:1. The pH‐ and reducing‐sensitivity of DNCVP is verified, and the stimuli‐responsive capacity enables the vector tumor targeting gene delivery ability. Owing to the protection of surface PEG, the supramolecular engineering endows the delivery vector with low cytotoxicity and good biocompatibility that are confirmed by the MTT assay. The excellent delivery ability of genes is investigated by in vitro transfection of pEGFP, pGL3, and silencing of siGAPDH. In vivo studies demonstrate promoted tumor accumulation of genes mediated by the dual‐responsive DNCVP and the transfection efficiency at the tumor site is greatly improved benefiting from the dynamic nature of noncovalent interactions. This study reveals DNCVP is a promising supramolecular dendritic gene delivery vector, providing a sophisticated strategy for precise gene therapy.

The inner and interfacial environments of self-assemblies provide fascinating nano-space for selective and efficient chemical reactions and processes. In biological systems, various chemical reactions, molecular recognition, and transport occur precisely and selectively by virtue of effective molecular interactions on biological membranes and proteins. Considering these advantages and the concept of nanoarchitectonics, we demonstrated that the photochromism of a lophine dimer was accelerated by using confined nano-spaces formed by surfactant micelles. The photoresponsive micelles were used for the rapid controlled release of a model drug upon ultraviolet light irradiation. Furthermore, selective ion recognition inside the self-assembled molecular films at the interfaces was investigated. The anion-π interaction between the anion and an electron-deficient aromatic ring was evaluated on a solid substrate modified with a naphthalenediimide (NDI) analog. Force curve measurements afforded a quantitative analysis of anion-π interactions on the NDI film. The strength of anion-π interactions is regulated by the electric fields on the electrode. An optical probe was developed to visualize the distribution of Cs ions in the soil, plant bodies, and aqueous media using an optode system. Advances in the development of molecular functional systems are expected based not only on molecular structures but also on the spaces and environments produced by them. [ABSTRACT FROM AUTHOR]

Highlights: The N/S co-doped lignin-derived porous carbon (NSLPCs) with ultra-high heteroatom doping was prepared through a novel supramolecule-mediated pyrolysis strategy. Covalently bonded graphitic carbon/amorphous carbon intermediates induce the formation of high heteroatom doping. The high heteroatom doping of NSLPC could provide abundant defective active sites for the adsorption of K+. Amorphous carbons are promising anodes for high-rate potassium-ion batteries. Most low-temperature annealed amorphous carbons display unsatisfactory capacities. Heteroatom-induced defect engineering of amorphous carbons could enhance their reversible capacities. Nevertheless, most lignocellulose biomasses lack heteroatoms, making it a challenge to design highly heteroatom-doped carbons (> 10 at%). Herein, we report a new preparation strategy for amorphous carbon anodes. Nitrogen/sulfur co-doped lignin-derived porous carbons (NSLPC) with ultra-high nitrogen doping levels (21.6 at% of N and 0.8 at% of S) from renewable lignin biomacromolecule precursors were prepared through a supramolecule-mediated pyrolysis strategy. This supermolecule/lignin composite decomposes forming a covalently bonded graphitic carbon/amorphous carbon intermediate product, which induces the formation of high heteroatom doping in the obtained NSLPC. This unique pyrolysis chemistry and high heteroatom doping of NSLPC enable abundant defective active sites for the adsorption of K+ and improved kinetics. The NSLPC anode delivered a high reversible capacity of 419 mAh g‒1 and superior cycling stability (capacity retention of 96.6% at 1 A g‒1 for 1000 cycles). Potassium-ion hybrid capacitors assembled by NSLPC anode exhibited excellent cycling stability (91% capacity retention for 2000 cycles) and a high energy density of 71 Wh kg–1 at a power density of 92 W kg–1. [ABSTRACT FROM AUTHOR]

Graphene and carbon quantum dot (GQD and CQD) nanoparticles as well as their related supramolecules, entitled as poly(3-hexylthiophene) (P3HT) nanofiber NF/GQD and P3HT NF/CQD, were prepared via decoration of QDs onto P3HT nanofibers, and applied in CH3NH3PbI3 perovskite solar cells. CH3NH3PbI3 photovoltaic cells represented performance of 10.61%, but completely lost function after 150 days air exposure. Instead, P3HT NF/QD supramolecules considerably promoted and stabilized perovskite photovoltaics. Efficacies of (20.15 and 18.90%) and (12.73 and 10.96%) were reached within 0 and 150 days exposure to air at 30°C and 35% humidity for P3HT NF/GQD and P3HT NF/CQD modified devices, respectively. [ABSTRACT FROM AUTHOR]

A novel mixed-valence octanuclear rhenacycle incorporating rhenium +1 and +7 sates as fac-ReI(CO) 3 and perrhenate anion ReVIIO 4 − was isolated, serendipitously, which showed a potential fluorescent chemical sensing towards nitro aromatic compounds. [Display omitted] • A novel mixed-valence octanuclear metallosupramolecule. • Rhenacycle incorporating rhenium +1 and +7 sates as fac -ReI(CO) 3 and perrhenate anion ReVIIO 4 −. • Host–guest interaction of metallosupramolecule and organic guest molecules. • Fluorometric chemical studies of poly hydrocarbon (PHC), biologically relevant molecules amino acid (glycine) and large biomolecules like adenosine triphosphate, ATP at ppm level. A novel coordination-driven neutral octanuclear rhenium tricarbonyl metallosupramolecule [{(CO) 3 Re(µ-O) 4 (ReO 2) 2 Re(CO) 3 (pz)} 2 ] (SD3), (where pz = pyrazine) rectangle integrating perrhenate ion within its core structure was synthesized. An in situ perrhenate ion generation was observed suggesting the superoxidation of Re(I) to Re(VII). The metallorectangle SD3 was characterized by IR, NMR, and Mass spectroscopies. The structure was established by Single Crystal X-ray diffraction and was found to be triclinic P -1. The thermal stability of SD3 was studied using Thermogravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC). UV–Vis and Fluorescence spectrophotometries were used to study the photophysical properties and chemical sensing potential of SD3 for biomolecules, hazardous polycyclic aromatic hydrocarbons (PAHs), and aromatic molecules. [ABSTRACT FROM AUTHOR]

[Display omitted] • Non-canonical polyT-MA supramolecular structures respond to five external stimuli. • Multi-stimuli-responsive DNA hydrogels bridged by the supramolecules are developed. • PolyT-MA acts as supramolecular glue to engineer macroscopic hydrogel blocks. • Reprogrammable LEGO constructs are achieved. The arbitrary, modular, and reprogrammable engineering of macroscopic objects by DNA interactions remains a challenge, despite the well-established use of DNA to drive constructs at nano/micro-scale. Moreover, achieving adaptive responsiveness in assembled architectures under dynamic environmental triggers has yet to be realized. In this study, we introduce the association of oligo-thymine strands (polyT) and melamine (MA), as a low-molecular-weight cofactor, into a supramolecular DNA duplex, termed polyT-MA nanobridge. This unique nanostructure exhibits responsiveness to five external stimuli, including temperature, DNA strand, small molecule, acidic pH, and alkaline pH. The polyT-MA nanobridge is developed as the dynamic crosslinking elements for constructing multi-stimuli responsive DNA hydrogels, which exhibit physiochemical properties changes (e.g., rigidity, thermal stability) and hydrogel-to-liquid phase transitions in response to the five external triggers. Notably, the assembly of macroscopic hydrogel blocks at millimeter scale (cubes in 5 × 5 × 5 mm dimensions) into diverse architectures, e.g., linear type, cross, P-shape, T-shape, or heteromorphy, is achieved by using the non-canonical supramolecular polyT-MA nanobridges. Sequential, dynamic, and selective disassembly of polyT-MA bridged hydrogel constructs is triggered by multiple external stimuli and the rearrangement of these separated individual cubes into other architectures in LEGO styles is presented. This study provides insights into the development of advanced materials and devices with reconfigurable architectures and functionalities for intelligent nanoengineering applications. [ABSTRACT FROM AUTHOR]

Using a variety of physicochemical characterization techniques, we have determined the composition and chemical formula of lanthanum and neodymium compounds with phthalic acid, synthesized for the first time. The compounds have been shown to have similar chemical formulas: La2(L)3·7H2O and Nd2(L)3·6H2O. We have examined the thermal destruction of the synthesized compounds. The proposed schematic structure of the La complex consists of zigzag 2D polymer layers, which are cross-linked by water molecules to form a 3D structure—a supramolecule. [ABSTRACT FROM AUTHOR]

This paper reviews the most stable conformation of crystalline three-dimensional cyclophane (CP) achieved by self-assembling based on changing the type of aromatic compound or regulating the type and number of bridging groups. [3n]cyclophanes (CPs) were reported to form supramolecular compounds with bind organic, inorganic anions, or neutral molecules selectively. [3n]cyclophanes ([3n]CPs) have stronger donor capability relative to compound [2n]cyclophanes ([2n]CPs), and it is expected to be a new type of electron donor for the progress of fresh electron conductive materials. The synthesis, conformational behavior, and properties of crystalline multi-bridge rings are summarized and discussed. [ABSTRACT FROM AUTHOR]

[Display omitted] • O-doped porous rod-like carbon nitride was obtained from formic acid and melamine. • The morphology of carbon nitride is controlled by hydrothermal time. • The catalyst has a high photocatalytic H 2 production rate of 12766 μmol h−1 g−1. Rod-like carbon nitrides synthesized by calcinating supramolecular precursors prepared from acid (or alkali) and melamine have attracted great attention because they have large surface area and abundant accessible active sites. However, they are highly inefficient in separating charges, which limits their photocatalytic activity. Here, we prepared porous, rod-shaped carbon nitrides doped with oxygen by calcinating the precursors prepared from melamine and formic acid. The porous O-doped g-C 3 N 4 nanorods have a large surface area of 81.4 m2 g−1. In particular, the oxygen doped into the catalyst enables it to have high efficiency in utilizing light in a range of 420–600 nm, and significantly improves its ability to separate photogenerated carriers. Under light irradiation (λ ≥ 420 nm), the prepared catalyst exhibits high photocatalytic activity with a hydrogen production rate of 12,766 μmol g-1h-1, which is 18.3 times that of pure carbon nitride. This research provides a novel way of preparing highly active non-metallic photocatalysts. [ABSTRACT FROM AUTHOR]

A novel high-throughput array analytical platform based on derived β-cyclodextrin supramolecular imprinted polymer (SMIP) fibers was constructed to achieve selective enrichment and removal of parabens. SMIP fiber arrays have abundant imprinting sites and introduce the host–guest inclusion effect of the derived β-cyclodextrin, which is beneficial to significantly improve the adsorption ability of fiber for parabens. Upon combination with HPLC, a specific and sensitive recognition method was developed with a low limit of detection (0.003–0.02 µg/L, S/N = 3) for parabens analysis in environmental water. This method has a good linearity (R > 0.9994) in the linear range of 0.01–200 µg/L. The proposed SMIP fiber array with high-throughput adsorption capacity has great potential in monitoring water pollution, which also provides a reliable reference for the analysis of more categories of pharmaceutical and personal care product pollutants. [ABSTRACT FROM AUTHOR]

The design of photocatalytic supramolecular systems composing of semiconductors and molecular metal complexes for CO 2 reduction has attracted increasing attention. The supramolecular system combines the structural merits of semiconductors and metal complexes, where the semiconductor harvests light and undertakes the oxidative site, while the metal complex provides activity for CO 2 reduction. The intermolecular charge transfer plays crucial role in ensuring photocatalytic performance. Here, we review the progress of photocatalytic supramolecular systems in reduction of CO 2 and highlight the interfacial charge transfer pathways, as well as their state-of-the-art characterization methods. The remaining challenges and prospects for further design of supramolecular photocatalysts are also presented., (© 2024 Wiley-VCH GmbH.)

The venom of the Habu snake Protobothrops flavoviridis ( P. flavoviridis ) is known to contain a diverse array of proteins and peptides, with a notable presence of phospholipase A 2 (PLA 2 ) enzymes. These PLA 2 enzymes have been extensively studied for their function and molecular evolution. Nevertheless, several aspects, such as the physical properties and the self-assembly mechanism of hierarchical structure from the nanoscale to the microscale with different chemical compounds, remain poorly understood. This study aims to fill this knowledge gap by investigating the behavior of enzyme components purified from P. flavoviridis venom in the presence of anionic [Pt(CN) 4 ] 2- complexes, which have the potential for soft metallophilic interactions and interesting optical properties. The purified PLA 2 isozymes were diluted in Dulbecco's phosphate buffered saline (D-PBS (-)) and combined with the anionic metal complex, resulting in the formation of microstructures several micrometers in size, which further grew to form fibrous structures. This novel approach of combining PLA 2 enzymes with discrete functional metal complexes opens up exciting possibilities for designing flexible and functional supramolecular and biomolecular hybrid systems in aqueous environments. These findings shed light on the potential applications of snake venom enzymes in nanotechnology and bioengineering.

The light-responsive nanochannel of rhodopsin gained wider research interest from its crucial roles in light-induced biological functions, such as visual signal transduction and energy conversion, though its poor stability and susceptibility to inactivation in vitro have limited its exploration. However, the fabrication of artificial nanochannels with the properties of physical stability, controllable structure, and easy functional modification becomes a biomimetic system to study the stimulus-responsive gating properties. Typically, light-responsive molecules of azobenzene (Azo), retinal, and spiropyran were introduced into nanochannels as photo-switches, which can change the inner surface wettability of nanochannels under the influence of light; this ultimately results in the photoresponsive nature of biomimetic nanochannels. Furthermore, the fine-tuning of their stimulus-responsive properties can be achieved through the introduction of host–guest systems generally combined with a non-covalent bond, and the assembling process is reversible. These host–guest systems have been introduced into the nanochannels to form different functions. Based on the host–guest system of light-responsive reversible interaction, it can not only change the internal surface properties of the nanochannel and control the recognition and transmission behaviors but also realize the controlled release of a specific host or guest molecules in the nanochannel. At present, macrocyclic host molecules have been introduced into nanochannels including pillararenes, cyclodextrin (CD), and metal–organic frameworks (MOFs). They are introduced into the nanochannel through chemical modification or host–guest assemble methods. Based on the changes in the light-responsive structure of azobenzene, spiropyran, retinal, and others with macrocycle host molecules, the surface charge and hydrophilic and hydrophobic properties of the nanochannel were changed to regulate the ionic and molecular transport. In this study, the development of photoresponsive host and guest-assembled nanochannel systems from design to application is reviewed, and the research prospects and problems of this photo-responsive nanochannel membrane are presented.

Tinidazole (TNZ), a 5-nitroimidazole derivative, has received increasing attention due to its pharmacological activities in treatment for amebic and parasitic infections. In this paper, we synthesized three novel drug supramolecular compounds successfully based on TNZ. The three compounds discussed were formed by TNZ and 2,6-dihydroxybenzoic acid (2,6-DHBA), 4-methylsalicylic acid (4-MAC), and 5-chloro-2-hydroxybenzoic acid (5-C-2-HBA). The N-H···O and O-H···O hydrogen bonds and weak C-H···O hydrogen bonds are the primary intermolecular forces in the construction of the three compounds. Crystal structure analysis revealed that all the compounds exhibit three-dimensional frameworks consisting of non-covalent interactions. Furthermore, six primary synthons, Ⅰ R22 (8), Ⅱ R21(6), Ⅲ R22(12), Ⅳ R33(9), Ⅴ R22(12), Ⅵ R33(9), formed through various hydrogen bonds are found in the three compounds. Moreover, the resulting pharmaceutical supramolecular compounds show improved stability. Single-crystal X-ray diffraction analysis, infrared spectroscopy (IR), element analysis, and thermogravimetric analysis (TGA) are reported.

Flexible ligands and multinuclear complexes were assembled into nanoscale {P2W18O62} polyoxometalates (POMs) to generate two phosphotungstate hybrid derivatives, (H2bip)2{H2P2 W18O62}·2H2O (1) and (bipy)0.5{Ag-(bipy)2}-{Ag4(bipy)7}-{NaP2W18O62}·H2O (2) (bip = 1,5-bis-(imidazole-1-yl)-pentane; bipy = 2,2′-bipy), via a precursor hydrothermal method. Compound 1 is a bip ligand modified 4,8-connected supramolecular net with {415;612;8}-{45;6}2 topology. In compound 2, the monocore complexes {Ag-(bipy)2} and tetranuclear complexes {Ag4(bipy)7} self-associate to generate two supramolecular chains A and B, respectively, which are further alternately joined together to form a unique metal–organic framework with irregular cavities via weak actions and π–π stacking. The Na-linked {P2W18O62} dipolymers as guest units were embedded into the holes, leading to a 3D supramolecular host–guest assemblies. The capacitive performance test reveals that 2-GCE/-CPE presents improved specific capacitance (802.4 and 752.1 F/g at 3 A/g), cycle efficiency (93.6 and 94.8% after the 5000th cycle), and electrical conductivity compared to the precursor and bip ligand modified compound 1. The electrocatalytic comparative data shows that 2-GCE has enhanced electrochemical redox capacity compared to the precursor and compound 1. Further sensing tests display that 2-GCE shows strong electrochemical responses to H2O2/AA at voltages of −0.41/0.36 V with a lower detection line of 0.33/0.05 μM, a wider linear range of 1.0 μM to 3.18 mM/0.15 μM to 2.33 mM, merit selectivity, and reproducibility. The excellent capacitive and sensing performances are related to increased redox centers, improved ion/electron conversion efficiency, and host–guest structural stability resulting from the introduction of multinuclear complexes, irregular holes, and abundant π–π stacking. This study not only enriches the variety of Dawson-type POMs but also provides a feasible idea for enhancing their electrochemical capacitance and sensing performance. [ABSTRACT FROM AUTHOR]

The electro-Fenton (EF) process is regarded as an efficient and promising sewage disposal technique for sustainable water environment protection. However, current developments in EF are largely restricted by cathode electrocatalysts. Herein, a supramolecular self-assembly strategy is adopted for synthetization, based on melamine–cyanuric acid (MCA) supramolecular aggregates integrated with carbon fixation using 5-aminosalicylic acid and zinc acetylacetonate hydrate. The prepared carbon materials characterize an ordered lamellar microstructure, high specific surface area (595 m2 g−1), broad mesoporous distribution (4~33 nm) and high N doping (19.62%). Such features result from the intrinsic superiority of hydrogen-bonded MCA supramolecular aggregates via the specific molecular assembly process. Accordingly, noteworthy activity and selectivity of H2O2 production (~190.0 mg L−1 with 2 h) are achieved. Excellent mineralization is declared for optimized carbon material in several organic pollutants, namely, basic fuchsin, chloramphenicol, phenol and several mixed triphenylmethane-type dyestuffs, with total organic carbon removal of 87.5%, 74.8%, 55.7% and 54.2% within 8 h, respectively. This work offers a valuable insight into facilitating the application of supramolecular-derived carbon materials for extensive EF degradation. [ABSTRACT FROM AUTHOR]

• Self-assembly of fac-[M(CO)3] (M = Mn or Re)-based neutral heteroleptic metallocages. • 5,6-di-(methoxycarbonyl)-benzimidazolyl substituted N donor-based tripodal ligand. • Metallocalix[3]arenes capped with ester functionalized flexible tritopic framework. A flexible tritopic ligand, 1,3,5-tri(5,6-di-(methoxycarbonyl)-benzimidazol-1-ylmethyl)-2,4,6-trimethylbenzene (Tebim) was designed, synthesized and characterized. Six neutral heteroleptic fac -[M(CO) 3 ]-based capped metallacalix[3]arenes with/without six or twelve ester decorated motifs were synthesized via one-pot approach using M 2 (CO) 10 (M = Mn or Re), rigid angular bidentate ligand (benzimidazole (H-bim) or 5,6-di-(methoxycarbonyl)-benzimidazole (H-ebim)), and tritopic ligand (1,3,5-tri(benzimidazol-1-ylmethyl)-benzene (Tbim) or Tebim). All capped metallacalix[3]arenes are characterized using FT-IR, 1H NMR spectroscopy and mass spectrometry. The 1H NMR spectra for all the complexes displayed a simple and symmetrical pattern with characteristic upfield and downfield shifts for the protons of both the coordinated ligands, which signifies that synthesized capped metallacalix[3]arenes retains the structural framework in the solution. Further, the molecular structures of 1 and 3b were confirmed by single crystal X-ray diffraction analysis. [ABSTRACT FROM AUTHOR]

Using supramolecules for protein function regulation is an effective strategy in chemical biology and drug discovery. However, due to the presence of multiple binding sites on protein surfaces, protein function regulation via selective binding of supramolecules is challenging. Recently, the functions of 14-3-3 proteins, which play an important role in regulating intracellular signaling pathways via protein–protein interactions, have been modulated using a supramolecular tweezer, CLR01. However, the binding mechanisms of the tweezer molecule to 14-3-3 proteins are still unclear, which has hindered the development of novel supramolecules targeting the 14-3-3 proteins. Herein, the binding mechanisms of the tweezer to the lysine residues on 14-3-3σ (an isoform in 14-3-3 protein family) were explored by well-tempered metadynamics. The results indicated that the inclusion complex formed between the protein and supramolecule is affected by both kinetic and thermodynamic factors. In particular, simulations confirmed that K214 could form a strong binding complex with the tweezer; the binding free energy was calculated to be −10.5 kcal·mol−1 with an association barrier height of 3.7 kcal·mol−1. In addition, several other lysine residues on 14-3-3σ were identified as being well-recognized by the tweezer, which agrees with experimental results, although only K214/tweezer was co-crystallized. Additionally, the binding mechanisms of the tweezer to all lysine residues were analyzed by exploring the representative conformations during the formation of the inclusion complex. This could be helpful for the development of new inhibitors based on tweezers with more functions against 14-3-3 proteins via modifications of CLR01. We also believe that the proposed computational strategies can be extended to understand the binding mechanism of multi-binding sites proteins with supramolecules and will, thus, be useful toward drug design.

[Display omitted] • A strategy focused on precursor selection was proposed to achieve high thermal conductivity. • Additional modifications for cellulose matrix or carbon nitride filler were not required. • Resultant cellulose/carbon nitride films showed obvious improvement on flame retardancy. • The application of carbon nitride for thermal management was further expanded. The fabrication of polymer composites with excellent thermal conductivity typically involves complex matrix or fillers modifications. This study proposed a simple technique based on precursor selection for obtaining highly thermally conductive cellulose nanofiber (CNF)/supramolecule-synthesized carbon nitride (SCN) composites. Fourier-transform infrared tests demonstrated the construction of hydrogen bonds between CNF and SCN; a highly ordered structure and relatively compact in-plane stacking were confirmed via scanning electron microscopy and X-ray diffraction characterizations. Consequently, the resultant CNF/SCN composites exhibited remarkable in-plane thermal conductivity of 11.83 ± 0.41 W m−1 K−1 at 30 wt% SCN content, which was attributed to the significantly reduced interfacial phonon scattering. It also showed evident improvements in electrical insulation and flame retardancy compared with the pure CNF film, where the volume resistivity, peak heat release rate, and total heat release were remarkably enhanced by 1242% and reduced by 59.9% and 15.8%, respectively. Further analysis of char residuals revealed a relatively dense surface, high concentration of carbon materials, and a high degree of graphitization, indicating that the char residual functioned as a robust physical barrier to effectively inhibit combustion. This study provides a facile approach to achieving high-efficiency improvements in thermal conductivity and flame retardancy, and simultaneously facilitating broader applications of carbon nitride in thermal management. [ABSTRACT FROM AUTHOR]

Bacterial infection is one of the greatest threats to public health. In vivo real‐time monitoring and effective treatment of infected sites through non‐invasive techniques, remain a challenge. Herein, we designed a PtII metallacycle‐based supramolecular photosensitizer through the host‐guest interaction between a pillar[5]arene‐modified metallacycle and 1‐butyl‐4‐[4‐(diphenylamino)styryl]pyridinium. Leveraging the aggregation‐induced emission supramolecular photosensitizer, we improved fluorescence performance and antimicrobial photodynamic inactivation. In vivo studies revealed that it displayed precise fluorescence tracking of S. aureus‐infected sites, and in situ performed image‐guided efficient PDI of S. aureus without noticeable side effects. These results demonstrated that metallacycle combined with host‐guest chemistry could provide a paradigm for the development of powerful photosensitizers for biomedicine. [ABSTRACT FROM AUTHOR]

Confined and unconfined crystallizations of poly(3-hexylthiophene) (P3HT) were studied in the solution-grown supramolecules and melt-grown systems using a differential scanning calorimeter. The carbon nanotube (CNT) and reduced graphene oxide (rGO) and their functionalized (CNT-f-COOTh and rGO-f-TAA) and grafted (CNT-g-PDDT and rGO-g-PDDT) derivatives were employed to develop the samples. The absorbance, structure details via Scherrer formula, fusion enthalpy (ΔHm) and crystallinity (Xc) were measured in two distinct confined/unconfined crystallization environments. Although the functionalized-CNT/rGO precursors partially reduced the crystallite qualities with respect to the pristine CNT and rGO ones in the solution-grown supramolecules, they did not affect the structural properties in the melt-grown samples. Grafted carbonic materials could be considered as appropriate seeds for the arrangement of P3HTs in both solution and melt crystallizations. The best absorbances, larger and more compact crystals, and higher melting point, ΔHm, and Xc values were recorded for the pre-developed CNT-g-PDDT/P3HT stem-leaf (6.09–22.51 nm, 3.52–13.89 Å, 239.8 °C, 30.86 J/g and 83.40%) and rGO-g-PDDT/P3HT coarse-patched (5.96–20.76 nm, 3.57–13.95 Å, 237.6 °C, 29.13 J/g and 78.73%) supramolecules. Although the melt-grown CNT-g-PDDT/P3HT (201.4 °C, 215.3 °C, 16.22 J/g and 43.84%) and rGO-g-PDDT/P3HT (205.4 °C, 218.8 °C, 18.06 J/g and 48.81%) nanostructures were not as perfect as the respective solution-grown nano-hybrids, they were well-arranged with respect to the CNT/P3HT, CNT-f-COOTh/P3HT, rGO/P3HT and rGO-f-TAA/P3HT samples

Herein, three novel cocrystals of 1-hydroxy-2-naphthoic acid: tetramethylpyrazine, 1-hydroxy-2-naphthoic acid:1,10-phenanthroline, and 1-hydroxy-2-naphthoic acid:1,4-bis(imidazol-1-ylmethyl)benzene (L2) were obtained by crystallization in methanol–water mixed solvent via a slow evaporation method. The cocrystalline products 1−3 were carried out by a range of techniques, including single-crystal X-ray diffraction, Fourier transform–infrared spectroscopy, elemental analysis, and thermogravimetric testing. We analyzed the crystal structures of the cocrystals 1−3 and found that weak interactions C–H···X (X = O or π) were of great importance in the process of self-assembly as well as strong and conventional hydrogen bonds (N–H···O, O–H···N, O–H···O), leading to a stable and diverse multidimensional supramolecular architecture. It is worth noting that a series of ring motifs with different sizes were explored in the crystal structures of the above complexes, such as R22(5), R22(7), R22(8), R23(13), R24(16), R44(16), R44(22), and so on. The classical and robust supramolecular synthon intermolecular bond between acid and pyridine (acid···pyridine) heterosynthon R22(7), commonly found in organic solids containing carboxylic acids with other N-containing heteroaromatics, was further demonstrated to be involved in the construction of the hydrogen-bond networks of cocrystal 1. The thermogravimetric technique used in this study proved that the mass losses of these three cocrystals were closely related to the strength of the hydrogen bonds in the package fraction.