1. Fabrication plate-like BaBi4Ti4O15 single-crystalline particles by the molten salt synthesis method.
- Author
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Feng, Xiaoying, Xu, Bei, Xu, Xiaoyu, Chen, Penghui, Wu, Zhuozhao, Teng, Duo, Xu, Jie, and Gao, Feng
- Subjects
FUSED salts ,CRYSTAL structure ,TEMPERATURE effect - Abstract
Plate-like single-crystalline BaBi
4 Ti4 O 1 5 particles were synthesized by the molten salt synthesis (MSS) method. The effects of sintering temperature, holding time, and NaCl–KCl molten salt content on the phase structure and morphology of plate-like BaBi4 -Ti4 O 1 5 particles were investigated. The results show that plate-like BaBi4 Ti4 O 1 5 particles can be synthesized when the sintering temperature is above 800 ∘ C. The size of particles increases with increasing sintering temperature and molten salt content. Largely anisotropic plate-like BaBi4 Ti4 O 1 5 particles with diameter ≥ 10 μ m and thickness of ∼ 0.3 μ m can be obtained under the optimum process parameters. The crystal structure of BaBi4 Ti4 O 1 5 was determined as A21 am by TEM, which should be attributed to the Bi 3 + and Ba 2 + diffusing into [TiO6 ] octahedrons. [ABSTRACT FROM AUTHOR]- Published
- 2023
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