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This study investigated the interaction between the furfural residue and polyvinyl chloride co-pyrolysis using an infrared heating method. Various analytical techniques including production distribution analysis, thermal behavior, pyrolysis kinetic, simulated distillation and gas chromatography-mass spectrography (GCMS), and X-ray photoelectron spectroscopy were utilized to elucidate the pyrolysis characterization and reaction mechanism during the co-pyrolysis. Initially, the yield of co-pyrolysis oil increased from 35.12% at 5 °C·s−1 to 37.70% at 10 °C·s−1, but then decreased to 32.07% at 20 °C·s−1. Kinetic and thermodynamic parameters suggested non-spontaneous and endothermic behaviors. GCMS analysis revealed that aromatic hydrocarbons, especially mono- and bi-cyclic ones, are the predominant compounds in the oil due to the presence of H radicals in polyvinyl chloride, suggesting an enhancement in oil quality. Meanwhile, the fixed chlorine content increased to 65.11% after co-pyrolysis due to the interaction between inorganic salts in furfural residues and chlorine from polyvinyl chloride. [ABSTRACT FROM AUTHOR]

Due to the high environmental burden of plastics, this study aimed to evaluate the environmental performance of chemical recycling of plastic waste through Life Cycle Assessment (LCA), focusing on pyrolysis oil production as the primary output. A pyrolysis plant in Almería, Spain, was chosen as a case study. The results indicate that the production of 1 L of pyrolysis oil from plastic waste generates about 0.032 kg CO2 eq and a water consumption of 0.031 m3, with other impact categories registering values of less than 0.1 kg/L or 0.01 m2a crop eq/L, reducing impacts in 17 out of 18 categories compared to fossil diesel. In addition, its chemical and physical properties, close to those of fossil diesel, suggest its suitability for internal combustion engines, although as a blend rather than a complete substitute. Chemical recycling also appears to be more environmentally favorable than incineration and landfilling in all 18 impact categories, achieving significant benefits, including a reduction in global warming of −3849 kg CO2 eq/ton, ionizing radiation of −22.4 kBq Co-60 eq/ton, and fossil resource consumption of −1807.5 kg oil eq/ton. These results, thus, highlight the potential dual role of chemical recycling of plastic waste, both in mitigating environmental impacts and in supporting circular economy goals by reducing demand for virgin plastics. However, although it appears to be a promising technology, challenges associated with high energy requirements, raw material variability, and scale infrastructure still need to be addressed to ensure industrial competitiveness and significant environmental benefits. [ABSTRACT FROM AUTHOR]

Reducing maritime greenhouse gas (GHG) emissions is challenging. As efforts to address climate change are gaining momentum, reducing the environmental impact becomes crucial for maritime short-to-medium-term sustainability. The International Maritime Organisation (IMO) has adopted Life Cycle Assessment (LCA) guidelines for estimating GHG emissions associated with alternative fuels. This paper proposes an examination of the latest IMO-adopted LCA guidelines, comparing them with existing methodologies used for the transport sector. By scrutinising these guidelines, the paper aims to provide a better understanding of the evolving landscape for GHG emission estimation within the maritime sector. The paper presents a case study that applies the newly established LCA guidelines to a promising alternative fuel pathway, i.e., waste-wood-derived pyrolysis oil. Pyrolysis oil offers an attractive option, leveraging waste materials to generate a sustainable energy source. The environmental impact of pyrolysis oils is quantified according to the IMO LCA guidelines, offering insights into its viability as a cleaner alternative as marine fuel. The results show the large potential for GHG savings offered by this pathway: upgraded pyrolysis oil can deliver significant GHG savings, and this contribution is linearly dependent of its energy share when blended with standard Heavy Fuel Oil. [ABSTRACT FROM AUTHOR]

Waste tyres are dumped and common kind of abandon solid waste. Almost 3 billion tyres are produced each year and each tyre produced will eventually join the waste products and if not properly handled will become pollutant. In many countries disposal of waste tyres is prohibited; as an alternative they should be recovered and recycled instead. In this review pyrolysis was introduced as an alternative way of recycling waste tyres, Pyrolysis allows the dissolution of the waste and it also produces useful by-products. The products obtained during the process are pyrolysis oil, pyrolysis char and condensable gas. Pyrolysis oil is the major product among them, this paper reviewed pyrolysis oil as an alternative sources of fuel to diesel engines and as well to highlight the chemicals obtained in the waste tyres from the pyrolysis oil which mainly depends on the kind of feedstock (i.e. type of tyres e.g truck, cars, bicycle) used in the pyrolysis process. Most of the compounds obtained are Aliphatic and Aromatic hydrocarbons (especially the Polycyclic Aromatic Hydrocarbon PAHs) such as Naphthalene – NAP, Acenaphthylene – ACY, Acenaphthene –ACE, Fluorene – FLU, Phenanthrene – PHE, Anthracene – ANT, Fluoranthene–FLT, Pyrene–PYR, Benzo[a]anthracene – BAA, Chrysene – CRY, Benzo[b]fluoranthene – BBF, Benzo[k[fluoranthene – BKF, Benzo[a]pyrene – BAP, Dibenzo[a,h]anthracene – DBA, Benzo[g,h,i]perylene – BGP, Indeno[1,2,3-cd]pyrene – IND among others. Consequently, the pyrolysis oil obtained need further upgrading via a reaction pathways are hydrodesulfurization (HDS), hydrodearomatization (HDA) and hydrocracking (HC) which can be achieved through a 2-stage hydroprocessing strategy regarding WTPO composition in terms of HDS, HAD and HC. Pyrolysis oil from waste tyres can be used as a substitute for diesel and as well as sources of raw materials and fuel to organic chemical industries.

Keeping the principles of sustainability in view, this work explores the extraction of indene from pyrolysis oil—a complex by-product of the Ustyurt Gas-Chemical Complex—and its transformation into a novel cationite, highlighting sustainable approaches in chemical engineering and material science. Utilizing advanced analytical techniques, including thermogravimetric analysis (TG), chromato-mass spectrometry, and Fourier-transform infrared spectroscopy (FT-IR), indene was efficiently isolated and characterized. The indene extracted exhibited a principal ion peak at a molecular mass (m/z) of 117.0, confirming its purity and potential for further applications. Following extraction, indene underwent sulfonation and polycondensation with 35% formalin under specific conditions (100–110°C, 30–40 atm), resulting in a cationite with a yield of 71%. This synthesized IESA (indene-based sulfonated aromatic cation exchanger), demonstrated significant chemical–physical properties when compared to commercial equivalents, such as a moisture content significantly lower than the KU-2-8 (29.4% vs. 48–58%), and a dynamic exchange capacity (DEC) competitive with industry standards (472 mmol/m3 vs. 500–520 mmol/m3). The study not only showcases the potential of pyrolysis oil as a valuable feedstock for producing high-value chemical products, but also advances the development of new materials from industrial by-products. [ABSTRACT FROM AUTHOR]

BACKGROUND: The production of value‐added chemicals from pyrolysis oil or its fractions is of great significance for the valorization of biomass. Diols, including ethylene glycol (EG) and 1,2‐propylene glycol (1,2‐PG), are important bulk chemicals with widespread industrial applications. Here we investigated the production of diols from pyrolysis oil water‐soluble fraction (WS) using a hybrid catalyst (Ni + H2WO4). RESULTS: Firstly, levoglucosan, glycolaldehyde and acetol, three main components in WS, were respectively selected as the single model compound, and their respective conversions into diols were investigated at different temperatures for different reaction times. The result showed the optimum reaction temperature and time were 180 °C and 2 h respectively, under which a EG yield of 53.8% and 1,2‐PG yield of 5.2% were obtained from levoglucosan conversion, a EG yield of 98.6% was obtained from glycolaldehyde conversion, and a 1,2‐PG yield of 98.5% was obtained from acetol conversion. The reaction pathway of levoglucosan conversion was analyzed. Secondly, the model mixture of levoglucosan, glycolaldehyde and acetol was used to simulate the real WS, and their conversion was investigated at different ratios of H2WO4 to Ni. The result showed the optimum catalyst composition was 0.15 g H2WO4 and 0.3 g Ni, under which a EG yield of 76.4% and 1,2‐PG yield of 38.4% were obtained. Thirdly, the real original WS was converted under the optimum reaction conditions and the result only gave a EG yield of 19.1% and 1,2‐PG yield of 25.8% (based on the carbon moles of main substrates), which were much less than the two yields of model mixture. That was related to the presences of other types of chemicals in original WS. After the original WS being adsorbed by activated carbon, the yields of EG and 1,2‐PG could be increased to 39.2% and 37.9%, respectively. CONCLUSION: The presences of certain other types of chemicals (such as acids, furans, phenolics and cyclopentanones) in original WS inhibited the production of diols. The activated carbon adsorption could efficiently remove most of furans, phenolics and cyclopentanones in original WS and increased significantly the diols yields. © 2024 Society of Chemical Industry (SCI). [ABSTRACT FROM AUTHOR]

The continuous increase in solid waste materials, such as waste tires, underscores the critical importance of recycling them to mitigate environmental impact and promote sustainable resource management. This research study evaluated the effectiveness of utilizing waste tire pyrolysis oils (WTPOs) as recycling agents for asphalt materials. The chemical composition and thermal behavior of WTPO were analyzed using Fourier transform infrared (FT-IR) spectroscopy and thermogravimetric analysis (TGA). Mechanically, the prepared WTPO binders were assessed by measuring dynamic viscosity and changes in high- and intermediate-temperature performance grades. Additionally, the cracking susceptibility of the binders was evaluated using the Glover-Rowe (G-R) parameter. The findings indicated that WTPOs might contain water and light aromatics in varying percentages, depending on the pyrolysis process. Incorporating WTPOs enhanced the workability of asphalt mixtures and ensured a high degree of blending between recycled/aged asphalt and raw binder. A 12% WTPO dosage was identified as the most effective for enhancing fatigue and low-temperature cracking resistance, facilitating improved interactions between the virgin binder and recycled asphalt materials. Finally, utilizing WTPOs as rejuvenating agents in pavement construction supports sustainable practices by recycling waste materials and significantly improving the performance and durability of asphalt mixtures. [ABSTRACT FROM AUTHOR]

Pyrolysis is a technology that can produce pyrolysis oil by decomposing waste plastic, and has the advantage of being able to process contaminated waste plastic that is impossible to process with other technologies. In Korea, where the amount of waste plastic is increasing and natural resources such as fossil fuels are lacking, pyrolysis technology is attracting attention under the keyword ‘urban oil field’. The Ministry of Environment of the Republic of Korea announced a ‘plan to revitalize waste plastic pyrolysis’ to increase the proportion of waste plastic pyrolysis treatment from 0.1% in 2021 to 10% in 2030. The products of pyrolysis are both fuel and plastic raw materials, but the processing consumes significant energy. Therefore, as criticism continues that the marketability and economic feasibility of pyrolysis technology is poor, questions are being raised about its environmental friendliness. Against this background, this study investigated international trends in pyrolysis technology and performed a detailed comparative analysis with other technologies from an environmental perspective. According to the results of this study, currently environmentally advanced countries are very negative about using pyrolysis oil as fuel, and the following policy directions are suggested. 1) In order to comply with the mandatory use ratio of plastic recycled raw materials and at the same time achieve eco-friendliness, it is recommended to use pyrolysis technology as a plastic recycled raw material production technology rather than fuel conversion. 2) Since pyrolysis emits more greenhouse gases than physical recycling, pyrolysis technology is used as a complementary method to physical recycling to process waste plastics that are difficult to physically recycle. 3) Since physical recycling is very important in the resource circulation of waste plastic, the development of separation and sorting technology is promoted nationally.

In this paper, a way that using Al2[DK](SO4)3 catalyst to esterify those labile components (such as acids and sugars) in pyrolysis oil into fuel compounds was proposed considering that their presences were the main factor restricting pyrolysis oil's direct use as biofuel. Firstly, various metal sulfates catalysts were screened for producing ethyl levulinate from model compound levoglucosan or for producing ethyl acetate from model compound acetic acid. Secondly, the optimal reaction conditions were investigated for producing esters from the model mixture of levoglucosan and acetic acid over Al2[DK](SO4)3 catalyst. Thirdly, the feasibility of producing esters from the real pyrolysis oil over Al2[DK](SO4)3 catalyst under the optimum reaction conditions was validated. The results showed the formation of significant amounts of esters and acetals accompanying the loss of labile acids, sugars and aldehydes. The esters and acetals accounted for 39.5% of the total GC-MS chromatographic area of the esterified pyrolysis oil. This indicated that Al2[DK](SO4)3 could effectively catalyse the esterification of those labile components in pyrolysis oil to fuel compounds, which could provide reference for producing biofuels from pyrolysis oil..

The co-pyrolysis of polyethylene terephthalate (PET) with low-density polyethylene (LDPE) and high-density polyethylene (HDPE) was carried out in a batch steel pyrolyzer in order to convert the PET into pyrolysis oil as its pyrolysis alone resulted in wax and gases. The study also aimed to increase the aromatic content of pyrolysis oil by the interaction of degradation fragments of linear chains of LDPE and HDPE with the benzene ring of PET during the pyrolysis. The reaction conditions were optimized for a higher yield of pyrolysis oil which were found to be 500 °C pyrolysis temperature with a heating rate of 0.5 °Cs−1, 1 h reaction time and 20 g of the initial mass of polymer mixture having 20% PET, 40% LDPE and 40% HDPE. Waste aluminium particles were applied as an economical catalyst in the process. The thermal co-pyrolysis yielded 8% pyrolysis oil, 32.3 wax, 39.7 wt% gases and 20% coke while the catalytic co-pyrolysis produced 30.2% pyrolysis oil, 4.2% wax, 53.6 wt% gases and 12% coke. The fractional distillation of catalytic oil resulted in 46% gasoline range oil, 31% kerosene range oil and 23% diesel range oil. These fractions resembled the standard fuels in terms of their fuel properties as well as FT-IR spectra. The GC-MS analysis revealed that the catalytic co-pyrolysis favoured the formation of relatively short-chain hydrocarbons with olefins and isoparaffins as major components while the thermal co-pyrolysis formed long-chain paraffins. The naphthenes and aromatics were also found in higher amounts in the catalytic oil compared with the thermal oil. [ABSTRACT FROM AUTHOR]

The outcomes of research regarding pyrolysis oils obtained from waste sources (WPO) used to power a compression-ignition engine have been presented in this paper. Oils obtained in an industrial process based on polypropylene (PPO), polystyrene (PSO) and used car tires (TPO) were used. Prior to conducting engine tests, a in-depth examination of the tested fuels parameters was undertaken. An advanced single-cylinder research engine utilizing split fuel injection technique was used for the tests. Emission analysis was performed using multi-compound FTIR analytical system. The WPO were blended with diesel fuel in proportions of 20%, on the mass basis and tested at middle engine load and variable EGR rates. Tests have shown that modern combustion systems compliant with the Tier 4/Stage IV standard with multi-pulse injection can handle fuels with a WPO content of 20% without the need for recalibration. The addition of PPO did not significantly affect the emission, while mixing with PSO resulted in elevated levels of hydrocarbon and carbon monoxide emissions. Regarding to the mixture with TPO, increased levels of particulate matter, sulfur oxides, aromatic compounds and formic acid were observed. [ABSTRACT FROM AUTHOR]

The present study evaluated a solvo-metallurgical technique for metal extraction from industrial solid waste (jarosite) using ionic liquids (ILs) and waste-derived solvents. The jarosite contains a considerable amount of metal ions, namely iron, zinc, and lead. The jarosite was characterized by XRF, XRD, SEM, and FTIR techniques. The parameters affecting metal extraction, such as stirring time, acid molarity, and temperature, have been examined. Aliquat 336 was used to extract metals from fresh and roasted jarosite after equilibration with HCl. The response surface methodology (RSM) was used to optimize the parameters for the maximum metal extraction using [A336] [Cl]. Maximum extraction of iron (86.75%), zinc (51.96%), and lead (94.38%) from roasted jarosite was achieved at optimum conditions (125-min stirring time, 5 M acid molarity, and 20 ml/g liquid-to-solid ratio). Furthermore, the metal extraction was investigated using waste-derived solvents. The results show that waste-derived solvents, such as biomass and plastic pyrolysis oil, can effectively extract metals from fresh and roasted jarosite. Biomass pyrolysis oil achieved the highest extraction at 50 °C for 90 min, while plastic pyrolysis oil achieved the highest extraction at 50 °C for 60 min from roasted jarosite. These solvents are also cost-effective because they are made from waste plastic and biomass. [ABSTRACT FROM AUTHOR]

Oxygenated compounds such as acids in bio-oils (BO) have been related to the corrosion of metals and their storage instability when applied as fuels. Therefore, upgrading BO by removing acids (deacidification) can be a valuable technique to reduce corrosivity using specific separation processes. Therefore, the objective of this paper was to evaluate the effect of the water content in the solvent (aqueous methanol), the carboxylic acid content in the BO and extraction temperature on the deacidification process by liquid–liquid extraction (LLE), as well as the effect of the same parameters on the quality of the deacidified BO through physical–chemical and GC-MS analyses. The results show that an increase in the water content (5 to 25%) in the solvent and an increase in the carboxylic acids content (24.38 to 51.56 mg KOH/g) in the BO reduce the solvent's capacity to extract carboxylic acids while increasing the temperature (25 to 35 °C) of the deacidification process promoted an increase in its capacity to remove them. Consequently, the highest deacidification efficiency (72.65%) is achieved with 5% water in methanol at 25 °C for BO1 (TAN = 24.38 mg KOH/g). Therefore, the deacidification process through LLE using aqueous methanol contributed significantly to BO upgrading. [ABSTRACT FROM AUTHOR]

The steam pyrolysis of end-of-life waste tires is viable technology for obtaining pyrolysis oil, which could be used as fuel. The purpose of current study is determining emission and combustion characteristics of different waste tires pyrolysis oil fractions as well as their chemical properties and composition. The pyrolysis oil was obtained by steam pyrolysis of waste heavy-duty vehicle tires at 500 °C, and distilled into 6 fractions with boiling temperatures varied in range of 60–448 °C. The higher boiling temperature fraction consisted of hydrocarbons with higher molecular weight. The maximal sulfur content was observed for 180–250 °C fraction. Ignition delay times of studied samples were varied in range of 0.58–5.38 s, flaming combustion times—2.16–4.28 s, total combustion times—2.73- 8.41 s. Both ignition delay and total combustion times had been monotonously increasing with boiling temperature of fraction, while flaming combustion times were increasing up to 300–350 °C fraction. Combustion behavior of all samples indicated significant contribution of homogeneous gas-phase reactions. Emission characteristics of pyrolysis oil and its individual fractions were majorly determined by their reactivity and composition. Higher CO, CO2 and NO emissions were observed for fractions with higher boiling temperatures, while SO2 emissions were independent of boiling temperature and were connected to sulfur content. Maximal sulfur oxide emissions were observed for fraction 180–250 °C. The NO emissions of initial pyrolysis oil sample were higher than for any of its fraction, while SO2—lower (with < 180 °C fraction as exception) indicating negative and positive synergistic effects, respectively. [ABSTRACT FROM AUTHOR]

Occurrence, distribution, and toxicity assessment of 16 Polycyclic Aromatic Hydrocarbons (PAHs) prioritized by the US Environmental Protection Agency in pyrolysis products - pyrolysis oil and pyrolysis wax - of different plastics are characterized. PP, HDPE, LDPE, PVC, PS (respectively, polypropylene, high- and low-density polyethylene, polyvinylchloride and polystyrene) and their mixture named 5P are chosen as a feed material for pyrolysis. Pyrolysis process is carried out in a custom-built laboratory batch reactor with the pyrolysis temperature of 450 °C for PP, PVC, PS and 500 °C for HDPE and LDPE. 5P mixture is pyrolyzed at 500 and 700 °C. PAHs quantification is used to determine the toxicity equivalency quantity TEQ (BaP) for each pyrolysis product and to establish the degree of toxicity. The highest total concentration of 16 PAHs in pyrolysis oil is found to decrease in the order of PVC > PP > PS > LDPE > HDPE. According to TEQ (BaP), the toxicity of the most toxic pyrolysis oils correlates with the aforementioned order of the total concentration, i.e., being lowest for HPDE and highest for PVC. For pyrolysis wax, the highest total concentration of 16 PAHs is for PVC > PS > LDPE > PP > HDPE, while TEQ (BaP) value decreases as PVC > LDPE > PP > PS > HDPE. The PAHs concentration and TEQ (BaP) values of 5P mixture show similar trends in both products (oil, wax), i.e., they both increase with increasing pyrolysis temperature. [ABSTRACT FROM AUTHOR]

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Pyrolysis is one of the most widely practiced thermochemical conversion technique to convert biomass into bio fuel. In this investigation, waste surgical masks were taken for pyrolysis process and the pyrolysis oil yield was determined experimentally. The experiments were designed and optimized based on Box Behnken Design (BBD) with operating parameters (feed size, temperature, and time) to study the effect on the yield of the pyrolysis oil and char. Experiments were conducted by varying the feed size (10–50 mm), pyrolysis temperature (400–600°C), and time (30–90 min). A hybrid Response Surface Methodology –Artificial Neural Network‐ Levenberg–Marquardt algorithm (RSM‐ANN‐LM) modelling approach has been to optimize the process parameters for the prediction of pyrolysis oil yield. The optimized network architecture was found to be 3‐10‐1 and the authenticity of the developed model has been evaluated using Regression Co‐efficient (R2) and Mean Squared Error (MSE). The developed RSM‐ANN‐LM model has outperformed the RSM model on predicting the pyrolytic oil yield. For the optimized conditions of 10 mm size, 600°C of pyrolysis temperature and 90 min pyrolysis time, 85.30% oil yield was obtained. [ABSTRACT FROM AUTHOR]

Due to the high environmental burden of plastics, this study aimed to evaluate the environmental performance of chemical recycling of plastic waste through Life Cycle Assessment (LCA), focusing on pyrolysis oil production as the primary output. A pyrolysis plant in Almería, Spain, was chosen as a case study. The results indicate that the production of 1 L of pyrolysis oil from plastic waste generates about 0.032 kg CO2 eq and a water consumption of 0.031 m3, with other impact categories registering values of less than 0.1 kg/L or 0.01 m2a crop eq/L, reducing impacts in 17 out of 18 categories compared to fossil diesel. In addition, its chemical and physical properties, close to those of fossil diesel, suggest its suitability for internal combustion engines, although as a blend rather than a complete substitute. Chemical recycling also appears to be more environmentally favorable than incineration and landfilling in all 18 impact categories, achieving significant benefits, including a reduction in global warming of −3849 kg CO2 eq/ton, ionizing radiation of −22.4 kBq Co-60 eq/ton, and fossil resource consumption of −1807.5 kg oil eq/ton. These results, thus, highlight the potential dual role of chemical recycling of plastic waste, both in mitigating environmental impacts and in supporting circular economy goals by reducing demand for virgin plastics. However, although it appears to be a promising technology, challenges associated with high energy requirements, raw material variability, and scale infrastructure still need to be addressed to ensure industrial competitiveness and significant environmental benefits.

In this study, the sustainable recycling of tire waste, which is frequently formed in the automotive industry, and the transformation of this recycling into valuable materials are in question. Waste tire pyrolysis oil obtained as a result of the pyrolysis of tire wastes was evaluated for the first time as a reinforcement element in nanocellulose-based nanocomposite films. Nanocellulose was produced using the TEMPO method (2,2,6,6-tetramethylpiperidine-1-oxyl radical). 5 %, 10 % and 20 % pyrolysis oil were added to the nanocomposite films. Thermal (thermal gravimetric analysis, differential scanning calorimetry, thermomechanical (dynamic mechanical thermal analysis and morphological (scanning electron microscopy) characterization of the produced nanocomposite films were performed. The highest thermal stability was observed in the nanocellulose/pyrolysis oil-20 sample with 20% pyrolysis oil additive. The pyrolysis oil-reinforced nanocomposites resulted in an excellent increase in storage and loss modulus. The storage modulus of the 20 % pyrolysis oil added sample at 100 °C was exactly 18 times that of pure nanocellulose. Nanocellulose-based nanocomposite films with superior thermal properties and structural compatibility demonstrated by characterized results have been shown to be pioneers in future industrial applications such as pharmacy, coating, green packaging. [ABSTRACT FROM AUTHOR]

The increasing challenge of managing medical waste plastics has spurred the exploration of various waste management strategies. This comprehensive study delves into the environmental and economic aspects of different approaches to medical waste management; incineration, landfilling, and pyrolysis, with a specific focus on plastics-to-fuels conversion. The study provides a critical assessment of these methods, highlighting their sustainability and environmental implications. In this study, it was conducted a Life Cycle Assessment (LCA), with a particular focus on comparing greenhouse gas (GHG) emissions. Notably, landfill, a commonly employed method for medical waste disposal, was found to produce lower GHGs than incineration and pyrolysis. However, it does have the drawback of leaving waste as a final product, and its long-term environmental consequences are uncertain, emphasizing the need to explore new technologies. Moreover, this study envisions the conversion of pyrolysis oil from medical waste plastics into a viable fuel source for circular economy, providing a sustainable solution to the growing problem of medical waste plastics. It predicts that in 2030, 799,163 kg of fuel can be obtained from medical waste plastic pyrolysis in the Adana province. As a result, the implementation of a circular economy through the utilization of medical waste plastic pyrolysis oil is projected to yield annual economic profits of up to $4,794,979. Furthermore, this approach has been verified to effectively reduce greenhouse gas (GHG) emissions compared to incineration. Moreover, this innovative strategy has been scientifically validated to substantially reduce greenhouse gas emissions, making it an environmentally responsible and economically promising solution for the future. [ABSTRACT FROM AUTHOR]

The present study reports on an investigation of teak sawdust pyrolysis oil blended with commercial diesel in a small four-stroke compression ignited engine. The engine performance and emissions were evaluated. The teak sawdust pyrolysis oil was obtained from a single-stage fixed bed pyrolysis reactor at 600 °C. Its physicochemical properties were characterized and found to be acceptable for the engine. Teak sawdust pyrolysis oil blends with diesel at the ratios of 10%, 25%, and 50% by mass were utilized. The small engine was tested at constant speeds from 800 to 2600 r/min. 25% teak sawdust pyrolysis oil blend at 2000 r/min was found to have better brake thermal efficiency with lower brake-specific fuel consumption compared to the other teak sawdust pyrolysis oil blends. Meanwhile, the highest engine load was obtained at 50% teak sawdust pyrolysis oil blend and 2600 r/min to be 8 kW. Furthermore, the emissions of CO, CO2, and hydrocarbon at 50% teak sawdust pyrolysis oil and 2000 r/min were slightly lower than other teak sawdust pyrolysis oil blends, no NOx detection in tested fuels, moreover, at 2600 speed, the smoke opacities of the fuels show lower than those the others. It was noted that a blend of 25% teak sawdust pyrolysis oil with diesel was suitable for the small engine (at 2000 r/min) in terms of performance and CO, CO2, and NOX emission for sustainability in agriculture and rural areas. [ABSTRACT FROM AUTHOR]

This paper presents the results of investigations on the pyrolysis of tyre waste in a laboratory fixed-bed batch reactor. The results regarding the influence of either the reaction temperature (425, 450, 475, and 500 °C) and the flow of the inert gas (0, 100, 300, and 500 mL/min) on product yield (referred to as pyrolysis of waste tyres) are also considered and discussed. On the basis of the abovementioned findings, the most appropriate experimental conditions were selected to contribute to a higher yield of pyrolysis oil. The sample of pyrolysis oil obtained from the experiments carried out in the selected optimal conditions (reaction time 120 min, temperature 450 °C and the inert gas flow of 100 mL/min) was subjected to calorimetric and infrared spectroscopy analysis. [ABSTRACT FROM AUTHOR]

The nucleation kinetics of ice were investigated with four different types of aqueous solutions. The studied aqueous solutions, i.e., sucrose solution, ionic liquid (IL) solution, pyrolysis oil extract (PO) solution, and acetone‐1‐butanol‐ethanol (ABE) solution, were concentrated by batch suspension freeze crystallization. The nucleation kinetics were investigated using a temperature response method which results in data on nucleation rate per crystal. The obtained nucleation rate per crystal value can be used when dimensioning continuous crystallization processes: the nucleation rate per crystal is inversely proportional to the residence time in continuous crystallization. The subcooling degrees for different solutions were in the range of 0.33 °C to 1.89 °C. Aqueous sucrose solutions had the fastest nucleation kinetics. Ice crystallization from non‐ideal aqueous [DBNH][OAc] ionic liquid solutions required higher subcooling degrees and the nucleation rates per crystal were higher as well. Nucleation of ice formed from aqueous pyrolysis oil extract and aqueous ABE solutions occurred at a lower subcooling degree and the obtained nucleation rate per crystal values were lower. [ABSTRACT FROM AUTHOR]

Abstract Pyrolysis, a thermal decomposition without oxygen, is a promising technology for transportable liquids from whole fractions of lignocellulosic biomass. However, due to the hydrophilic products of pyrolysis, the liquid oils have undesirable physicochemical characteristics, thus requiring an additional upgrading process. Biological upgrading methods could address the drawbacks of pyrolysis by utilizing various hydrophilic compounds as carbon sources under mild conditions with low carbon footprints. Versatile chemicals, such as lipids, ethanol, and organic acids, could be produced through microbial assimilation of anhydrous sugars, organic acids, aldehydes, and phenolics in the hydrophilic fractions. The presence of various toxic compounds and the complex composition of the aqueous phase are the main challenges. In this review, the potential of bioconversion routes for upgrading the aqueous phase of pyrolysis oil is investigated with critical challenges and perspectives. Graphical Abstract

The article discusses the research results on the combustion of pyrolysis oil derived from the pyrolysis of HDPE plastics after its distillation. The tests were carried out in a constant-volume combustion chamber in conditions similar to those in a compression-ignition engine with a compression ratio of 17.5:1. The phases of premixed and diffusion combustion and the ignition lag were determined. Then, diesel fuel combustion tests were performed under similar pressure-temperature conditions. Comparative analysis was used to draw conclusions as follows: the percentage fraction of heat released from the premixed combustion phase to total heat for pyrolysis oil was nearly 22%, whereas this parameter is 15% for diesel fuel, the maximum combustion rate for the premixed combustion phase for pyrolysis oil was approximately 27% higher than the premixed combustion rate for diesel fuel, the ignition lag for pyrolysis oil was slightly longer compared to that for diesel fuel. The presented parameters have a significant impact on both the development of combustion and the thermal efficiency of the internal combustion engine. Summing up, one can conclude, that pyrolysis oil can be applied as a substitute for diesel fuel both as a single fuel or blend component with it. [ABSTRACT FROM AUTHOR]

The fast depletion of fossil fuels and growing concerns about environmental sustainability have increased interest in using biomass as a renewable energy source. Fast pyrolysis, a thermochemical conversion process, has emerged as a promising technique for converting biomass into valuable biofuels and bio-based chemicals. The aim of this literature review is to comprehensively analyze recent advances in biomass fast pyrolysis, focusing on the principles, process parameters, product yields, and potential applications of biomass fast pyrolysis. This comprehensive review, based on an in-depth analysis of 61 scientific papers and 4 patents, provides an overview of various biomass technologies (combustion, gasification, pyrolysis) used for biofuel production. It focuses on the principles, benefits and applications of these technologies and serves as a valuable resource for researchers, engineers and policy makers. Based on the wealth of information from rigorously selected sources, we explore the key process parameters and reactor types associated with each technology, providing insight into its efficiency and product composition. [ABSTRACT FROM AUTHOR]

One method of managing used car tires is decomposition by thermochemical conversion methods. By conducting the process at temperatures of 450–750 °C, three fractions are obtained from tires: oil, gas, and solid. The liquid product of the pyrolysis of used car tires is pyrolysis oil, which consists of aromatic, polyaromatic, and aliphatic hydrocarbons. Unconventional building materials were obtained from tire pyrolysis oil and the environmental impact was evaluated. Blocks made from pyrolysis oil showed mechanical strength of up to about 1700 N. No heavy metals or polycyclic aromatic hydrocarbons, which were found in the crude heavy-PO fraction, were detected in the filtrates after incubation of the block obtained from the heavy-PO fraction at 240 °C. The highest inhibition of Sorghum saccharatum shoot (74.4%) and root (57.5%) growth was observed for solid materials from the medium-PO fraction obtained at 240 °C. The most favorable values of the parameters for the process of obtaining blocks based on post-PO were an annealing temperature of 180 °C, time of 20 h, and mass ratio of catalyst to catalyzed oil of 0.045. [ABSTRACT FROM AUTHOR]

Combustion systems can use tire pyrolysis oil (TPO) due to its high energy content. The amount of nitrogen and sulfur present in the TPO should result in NOx and SO2 emissions when combustion occurs. A flameless combustion regime can reduce pollutant emissions, mainly NOx, with greater thermal efficiency. This work aims to analyze the NO and NO2 emission in different diesel fuel mixtures with TPO, 5% (TPO5), and 10% (TPO10) by mass, in a flameless regime. A combustor was used operating with a maximum heat input of 13 kW and an effervescent injector promoting an average Sauter diameter of 33.89 ± 3.77 µm. The uniform temperature profile within the combustor characterizes the flameless combustion regime that was reached after 50 min for diesel and after 40 min for TPO5 and TPO10 from the ignition. TPO5 and TPO10 have similar NO emissions in flameless combustion. The NO2 emission increases with the TPO content in the mixture. [ABSTRACT FROM AUTHOR]

• The financial and ecological viability of power from pyrolysis oil is assessed. • The process has high oil yield and power generation potential. • The project is economically feasible and profitable in China. • Power generation from the project contributes to global warming. • Consumption of power from the project reduces coal usage and global warming. The increased plastic waste generation worldwide poses ponderous issues for public health and the environment. China is the highest generator of plastic waste around the world. The current treatment process (incineration) of the increased plastic waste causes dangerous environmental consequences. Pyrolysis has recently surfaced as an ecologically friendly technique for energy and material recovery from plastic waste. The present study assesses the financial and ecological viability of power production from oil derived from the pyrolysis of mixed plastic wastes in China from 2009 to 2028. The prominent findings show that the amount of plastic waste collected in 2020 (24.16 Mt) increased by 53.19% in 2028.The pyrolysis of mixed plastic wastes during the project period yielded 359.29 Mt oil, which has a power potential of 1,060.86 GWh. The economic analysis indicated the project is viable and profitable with a positive net present value (US$8.80 million) and profitability index (1.26) greater than 1. The project has 10.6 y payback period, US$0.0752/kWh levelized cost of energy, 22.5% return on investment, and 13.0% internal rate of return. The life cycle assessment results show that conversion of mixed plastic waste to pyrolysis oil for electricity generation during the project period has a total global warming potential (GWP) of 1,311.4 kt CO 2 eq. The GWP is mainly from conversion of pyrolysis oil to electricity (73.42%), pyrolysis oil production (15.01%) and upgrading of pyrolysis oil (11.38%). The consumption of power from the project could avoid the combustion of 2,659.0 t coal, minimizing global warming by 11,278.8 kt CO 2 eq. Sensitivity analysis, which examines the influence of variation in sensitive factors on the success of the project, is presented. This paper provides scientific strategies for optimal investment and decision-making on the environmental sustainability of plastic waste-to-energy pyrolysis projects. [ABSTRACT FROM AUTHOR]

Pyrolysis oil can be used as a precursor to synthesize value-added biochemicals. Co-pyrolysis of two or more feedstocks generally improves the selectivity and yield of the target compounds. In this work, oil palm trunk (OPT) was subjected to single-feed pyrolysis and co-pyrolysis with polypropylene (PP) from 500 to 700 °C. The highest pyrolysis oil yield of 26.33 wt.% was obtained from OPT at 700 °C, which mainly contributed by the lignin decomposition in OPT. Phenolics (51.77–57.78%) and oxygenates (36.31–46.99%) were the major compounds detected in the OPT-derived pyrolysis oil. The addition of PP enhanced the formation of hydrocarbons (5.19–10.22%) and decreased the contents of phenolics (34.01–41.85%) in the co-pyrolysis oil. In the case of co-pyrolysis, the intermolecular reactions between PP and OPT-derived radicals led to the formation of ketones and alcohols, which contributed to the increase of oxygenates content. The highest oil yield of 16.17 wt.% was obtained at 600 °C from co-pyrolysis, the oil of which contained mainly phenolic compounds, oxygenated compounds (i.e., ketones and furans), and hydrocarbons. These findings highlighted the potential of oil derived from the pyrolysis of OPT (single feed) and co-pyrolysis of OPT and PP (binary feed) for the production of value-added chemicals.