Search

This study aimed to investigate the potential of antimony-doped tin oxide (ATO) as a reinforcing agent for polyamide 12 (PA12) in 3D printing by examining four mixtures with varying ATO concentrations (2.0 to 8.0 wt.%, with a 2.0 wt.% interval). These mixtures were used to fabricate filaments for the manufacturing of specimens through the material extrusion method. The mechanical properties of the resulting PA12/ATO composites and PA12 pure samples were evaluated through tensile, Charpy impact, flexural, and microhardness tests. Additionally, rheology, structure, morphology, thermal properties, pore size, and consistency in the dimensions of the samples were evaluated. Thermogravimetric analysis, along with differential scanning calorimetry, scanning electron microscopy, energy-dispersive and Raman spectroscopy, and micro-computed tomography, were conducted. The results were correlated and interpreted. The greatest reinforcement was achieved with the PA12/ATO 4.0 wt.% mixture, which exhibited a 19.3% increase in tensile strength and an 18.6% increase in flexural strength compared with pure PA12 (the control samples). The Charpy impact strength and microhardness were also improved by more than 10%. These findings indicate the merit of composites with ATO in additive manufacturing, particularly in the production of components with improved mechanical performance. [ABSTRACT FROM AUTHOR]

Additively manufactured fibre-reinforced polymers are gaining traction. After the development and optimisation of a novel fibre-deposition system in a laser sintering (LS) setup, polyamide 12 specimens were produced with and without glass fibres. In this study, the relation between the crystallinity, porosity, and mechanical properties of LS specimens with and without fibres is investigated. After testing as-built LS specimens, a detrimental effect of the fibres on the specimens' performance was observed with a decrease in UTS of 6%. The degree of crystallinity remained the same; however, a porosity content of 2.6% was observed in specimens with fibres. These pores can have a negative influence on the bonding between the fibres and the matrix. To investigate the influence of the pores, warm isostatic pressing (WIP) was performed on LS specimens with and without fibres. The WIP process shows a positive influence on the specimens without fibres, resulting in an increase in UTS of 8.5%. The influence of the WIP process on specimens with fibres, however, is much less pronounced, with an increase in UTS of only 2%. Neither the crystallinity nor the porosity are the cause of the less-than-expected increase in UTS in LS specimens with fibres. A number of hypotheses and mitigation strategies are provided. [ABSTRACT FROM AUTHOR]

This study aimed to investigate the potential of antimony-doped tin oxide (ATO) as a reinforcing agent for polyamide 12 (PA12) in 3D printing by examining four mixtures with varying ATO concentrations (2.0 to 8.0 wt.%, with a 2.0 wt.% interval). These mixtures were used to fabricate filaments for the manufacturing of specimens through the material extrusion method. The mechanical properties of the resulting PA12/ATO composites and PA12 pure samples were evaluated through tensile, Charpy impact, flexural, and microhardness tests. Additionally, rheology, structure, morphology, thermal properties, pore size, and consistency in the dimensions of the samples were evaluated. Thermogravimetric analysis, along with differential scanning calorimetry, scanning electron microscopy, energy-dispersive and Raman spectroscopy, and micro-computed tomography, were conducted. The results were correlated and interpreted. The greatest reinforcement was achieved with the PA12/ATO 4.0 wt.% mixture, which exhibited a 19.3% increase in tensile strength and an 18.6% increase in flexural strength compared with pure PA12 (the control samples). The Charpy impact strength and microhardness were also improved by more than 10%. These findings indicate the merit of composites with ATO in additive manufacturing, particularly in the production of components with improved mechanical performance.

Background: The mechanical properties of lattice structures have been primarily investigated using uniaxial compression loads. Particularly for polymers, tensile properties are rarely considered because of the difficulties of defining a suitable specimen design in which the fracture occurs within the gauge length. Objective: This work proposes a novel formulation to obtain a specimen for the tensile test with a gradation of the lattice density at the interface with the bulk portion, which realises a uniform stress distribution. The aim is to combine a localisation of the fracture in the gauge length with a specimen geometry accomplishing the EN ISO 527 standard and analyse the correlation between the mechanical performance and the defects induced by the process on such thin structures. Methods: The formulation is experimentally and numerically (FEM) tested by designed specimens with different cell topology, cell size, strut diameter, and number of cells in the sample thickness. Also, results from uniaxial compression tests are used to validate the tensile properties. The specimens are manufactured in different orientations in the building volume by laser powder bed fusion with Polyamide 12. The effects of the pores morphology, distribution, and inherent anisotropy are investigated using X-ray computed tomography analysis. This data is also used to tune a numerical model. Results: The numerical analysis showed a uniform stress distribution; experimentally, the fracture is localised inside the gauge length in respect of the ISO standard. Remarkably, among the different strut-based architectures, the elongation at break is, in the best case, 50% of the corresponding bulk material, while the tensile strengths are comparable. Vertical printed specimens exhibited a slight decrease in tensile strength, and the elongation at break was lower than 50% compared to the counterparts built along the horizontal orientation. Modifying the numerical model according to process-related dimensional deviations between the actual and the nominal structures significantly improved the numerical results. The remaining deviation highlighted the incorrectness of modelling the lattice material from the bulk properties. Conclusion: Density gradation is a reliable approach for describing the tensile behaviour of polymeric lattice structures. However, the lower amount of porosity and the different shape in the lattice led to a different material mechanical performance with respect to the corresponding bulk counterpart. Therefore, for polymeric lattice structures, the relationship between process-design-material appears crucial for correctly representing the structure behaviour. [ABSTRACT FROM AUTHOR]

Additively manufactured fibre-reinforced polymers are gaining traction. After the development and optimisation of a novel fibre-deposition system in a laser sintering (LS) setup, polyamide 12 specimens were produced with and without glass fibres. In this study, the relation between the crystallinity, porosity, and mechanical properties of LS specimens with and without fibres is investigated. After testing as-built LS specimens, a detrimental effect of the fibres on the specimens’ performance was observed with a decrease in UTS of 6%. The degree of crystallinity remained the same; however, a porosity content of 2.6% was observed in specimens with fibres. These pores can have a negative influence on the bonding between the fibres and the matrix. To investigate the influence of the pores, warm isostatic pressing (WIP) was performed on LS specimens with and without fibres. The WIP process shows a positive influence on the specimens without fibres, resulting in an increase in UTS of 8.5%. The influence of the WIP process on specimens with fibres, however, is much less pronounced, with an increase in UTS of only 2%. Neither the crystallinity nor the porosity are the cause of the less-than-expected increase in UTS in LS specimens with fibres. A number of hypotheses and mitigation strategies are provided.

The influence of nanoparticles (NPs) in zirconium oxide (ZrO2) as a strengthening factor of Polylactic Acid (PLA) and Polyamide 12 (PA12) thermoplastics in material extrusion (MEX) additive manufacturing (AM) is reported herein for the first time. Using a melt-mixing compounding method, zirconium dioxide nanoparticles were added at four distinct filler loadings. Additionally, 3D-printed samples were carefully examined for their material performance in various standardized tests. The unfilled polymers were the control samples. The nature of the materials was demonstrated by Raman spectroscopy and thermogravimetric studies. Atomic Force Microscopy and Scanning Electron Microscopy were used to comprehensively analyze their morphological characteristics. Zirconium dioxide NPs showed an affirmative reinforcement tool at all filler concentrations, while the optimized material was calculated with loading in the range of 1.0–3.0 wt.% (3.0 wt.% for PA12, 47.7% increase in strength; 1.0 wt.% for PLA, 20.1% increase in strength). PA12 and PLA polymers with zirconium dioxide in the form of nanocomposite filaments for 3D printing applications could be used in implementations using thermoplastic materials in engineering structures with improved mechanical behavior. [ABSTRACT FROM AUTHOR]

Herein, polytetrafluoroethylene (PTFE) is evaluated as a reinforcement agent in material extrusion (MEX) additive manufacturing (AM), aiming to develop nanocomposites with enhanced mechanical performance. Loadings up to 4.0 wt.% were introduced as fillers of polylactic acid (PLA) and polyamide 12 (PA12) matrices. Filaments for MEX AM were prepared to produce corresponding 3D-printed samples. For the thorough characterization of the nanocomposites, a series of standardized mechanical tests were followed, along with AFM, TGA, Raman spectroscopy, EDS, and SEM analyses. The results showed an improved mechanical response for filler concentrations between 2.0 and 3.0 wt.%. The enhancement for the PLA/PTFE 2.0 wt.% in the tensile strength reached 21.1% and the modulus of elasticity 25.5%; for the PA12/PTFE 3.0 wt.%, 34.1%, and 41.7%, respectively. For PLA/PTFE 2.0 wt.%, the enhancement in the flexural strength reached 57.6% and the modulus of elasticity 25.5%; for the PA12/PTFE 3.0 wt.%, 14.7%, and 17.2%, respectively. This research enables the ability to deploy PTFE as a reinforcement agent in the PA12 and PLA thermoplastic engineering polymers in the MEX AM process, expanding the potential applications. [ABSTRACT FROM AUTHOR]

Additive manufacturing (AM) is a rapidly growing branch of manufacturing techniques used, among others, in the medical industry. New machines and materials and additional processing methods are improved or developed. Due to the dynamic development of post-processing and its relative novelty, it has not yet been widely described in the literature. This study focuses on the surface topography (parameters Sa, Sz, Sdq, Sds, Str, Sdr) of biocompatible polyamide 12 (PA12) samples made by selective laser sintering (SLS) and multi jet fusion (MJF). The surfaces of the samples were modified by commercial methods: four types of smoothing treatments (two mechanical and two chemical), and two antibacterial coatings. The smoothing treatment decreased the values of all analyzed topography parameters. On average, the Sa of the SLS samples was 33% higher than that of the MJF samples. After mechanical treatment, Sa decreased by 42% and after chemical treatment by 80%. The reduction in Sdq and Sdr is reflected in a higher surface gloss. One antibacterial coating did not significantly modify the surface topography. The other coating had a smoothing effect on the surface. The results of the study can help in the development of manufacturing methodologies for parts made of PA12, e.g., in the medical industry. [ABSTRACT FROM AUTHOR]

Polylactide (PLA), a biodegradable polyester produced from renewable resources, has a key position in the very promising market for bioplastics. Unfortunately, for utilization in durable/engineering applications, PLA suffers from some shortcomings such as low rate of crystallization, brittleness, and small ductility. The study proposes the use of PLA having high crystallization ability to tune up the properties of partly bio-based PLA/polyamide 12 (PA12) blends in presence of key additives. First, phenylphosphonic acid zinc salt (PPA-Zn) was selected as one of the most adapted nucleating agents (NAs) for PLA, whereas larger quantities of PLA(NA) have been produced for blending with PA12. The characterizations of PLA(NA) confirm dramatic improvements of PLA crystallization kinetics and an impressive degree of crystallinity (>40%). Blends having different PLA(NA)/PA12 ratios were prepared by melt-mixing with a laboratory micro-­compounder and characterized in terms of morphology, thermal stability, and with focus on the evidence of advanced crystallization properties. All differential scanning calorimetry measurements of PLA(NA)/PA12 blends suggest powerful nucleation and crystallization ability. Furthermore, addition of epoxy-functional styrene-acrylic compatibilizers into selected compositions by reactive extrusion (REX) was found to significantly change their morphology, preserving the properties of crystallization of PLA, with enhancements of mechanical properties (strength, ductility, impact resistance) confirmed by current prospects.

The effect of aluminum oxide (Al2O3) nanoparticles (NPs) as a reinforcing agent of Polyamide 12 (PA12) and Polylactic acid (PLA) in fused filament fabrication (FFF) three-dimensional printing (3DP) is reported herein for the first time. Alumina NPs are incorporated via a melt–mixing compounding process, at four different filler loadings. Neat as well as nanocomposite 3DP filaments are prepared as feedstock for the 3DP manufacturing of specimens which are thoroughly investigated for their mechanical properties. Thermogravimetric analyses (TGA) and Raman spectroscopy (RS) proved the nature of the materials. Their morphological characteristics were thoroughly investigated with scanning electron and atomic force microscopy. Al2O3 NPs exhibited a positive reinforcement mechanism at all filler loadings, while the mechanical percolation threshold with the maximum increase of performance was found between 1.0–2.0 wt.% filler loading (1.0 wt.% for PA12, 41.1%, and 56.4% increase in strength and modulus, respectively; 2.0 wt.% for PLA, 40.2%, and 27.1% increase in strength and modulus, respectively). The combination of 3DP and polymer engineering using nanocomposite PA12 and PLA filaments with low-cost filler additives, e.g., Al2O3 NPs, could open new avenues towards a series of potential applications using thermoplastic engineering polymers in FFF 3DP manufacturing. [ABSTRACT FROM AUTHOR]

Inducing electrical properties in thermoplastic materials and enhancing their mechanical properties with the addition of nanofiller in Fused Filament Fabrication (FFF) is the main purpose of the study. Multiwall carbon nanotubes (MWCNT) at different weight percentage (wt.%) loadings (0.1%, 0.5%, 1.0%, 2.5%, 5.0%, 10.0%) were incorporated into the Polyamide 12 (PA12) matrix. Melt mixing followed by filament extrusion was applied. Filaments were employed to 3D print specimens. A thorough study on the electrically Conductive Polymeric Composites (CPCs) electrical percolation threshold was carried out. Mechanical and thermomechanical response investigations were also conducted. Scanning Electron Microscopy (SEM) was employed to study the morphology of the 3D printed samples. The results showed a mechanical and thermomechanical properties enhancement for 5.0 wt.% filler's ratio. The electrical conductivity increased by increasing the filler loading. The 10% wt.% PA12/MWCNT nanocomposite additionally exhibited an electrothermal Joule-heating behavior. The antibacterial behavior was also tested with the agar well diffusion screening method, for gram-negative Escherichia coli (E. coli) and gram-positive Staphylococcus aureus (S. aureus). A mild antimicrobial performance was observed. It can be concluded that the multi-functional PA12/MWCNT 3D printed lightweight CPCs developed herein could be applied in various applications, e.g. joule-heating devices, flexible conductors, and anti-static enclosures. [ABSTRACT FROM AUTHOR]

Generating multimaterial parts, reaching higher efficiency in powder consumption, and decoupling of powder application behavior from powder properties such as powder flowability are key aspects for using electrophotographic powder application (EPA) in laser-based powder bed fusion of polymers (PBF-LB/P). Moreover, EPA allows the layer thickness to be reduced from around 100–150 μm, depending on respective particle size distribution, in the case of conventional doctor blade or roller-based powder application methods to the diameter of the applied polymer particles (typically between 50 and 130 μm). This can have positive effects on the interlayer connection and, therefore, the mechanical properties of the additively manufactured part because less powder volume has to be fused with the already generated underlying part. Moreover, due to the above-mentioned independence of EPA from powder flowability, the addition of flow aids, such as nano silica, can be reduced to a minimum or even avoided completely. This is the first comprehensive study on resulting properties of parts generated by PBF-LB/P using EPA taking into account both the reduction in layer thickness and reduced addition of flow aids. In addition to improving mechanical properties of generated parts, the independence of powder flowability, in particular, offers the possibility of qualifying currently unsuitable materials for PBF-LB/P. For this purpose, besides widely employed polyamide 12 (PA12), a polypropylene (PP) powder is used that is very difficult to process in conventional PBF-LB/P and can only be applied there with the help of flow aids. [ABSTRACT FROM AUTHOR]

In this work, for the first time, polyamide 12 (PA12) nanocomposites with binary inclusions in material extrusion (MEX) 3D printing were developed. The aim was to achieve an enhanced mechanical response with the addition of titanium nitride (TiN) and antibacterial performance with the addition of copper (Cu) or cuprous oxide (Cu2O), towards the development of multi-functional nanocomposite materials, exploiting the 3D printing process benefits. The prepared nanocomposites were fully characterized for their mechanical properties. The thermal properties were also investigated. Morphological characterization was performed with atomic force microscopy (AFM) and scanning electron microscopy (SEM). The antibacterial performance was investigated with an agar-well diffusion screening process. Overall, the introduction of these nanofillers induced antibacterial performance in the PA12 matrix materials, while at the same time, the mechanical performance was significantly increased. The results of the study show high potential for expanding the areas in which 3D printing can be used. [ABSTRACT FROM AUTHOR]

The influence of nanoparticles (NPs) in zirconium oxide (ZrO2) as a strengthening factor of Polylactic Acid (PLA) and Polyamide 12 (PA12) thermoplastics in material extrusion (MEX) additive manufacturing (AM) is reported herein for the first time. Using a melt-mixing compounding method, zirconium dioxide nanoparticles were added at four distinct filler loadings. Additionally, 3D-printed samples were carefully examined for their material performance in various standardized tests. The unfilled polymers were the control samples. The nature of the materials was demonstrated by Raman spectroscopy and thermogravimetric studies. Atomic Force Microscopy and Scanning Electron Microscopy were used to comprehensively analyze their morphological characteristics. Zirconium dioxide NPs showed an affirmative reinforcement tool at all filler concentrations, while the optimized material was calculated with loading in the range of 1.0–3.0 wt.% (3.0 wt.% for PA12, 47.7% increase in strength; 1.0 wt.% for PLA, 20.1% increase in strength). PA12 and PLA polymers with zirconium dioxide in the form of nanocomposite filaments for 3D printing applications could be used in implementations using thermoplastic materials in engineering structures with improved mechanical behavior.

Herein, polytetrafluoroethylene (PTFE) is evaluated as a reinforcement agent in material extrusion (MEX) additive manufacturing (AM), aiming to develop nanocomposites with enhanced mechanical performance. Loadings up to 4.0 wt.% were introduced as fillers of polylactic acid (PLA) and polyamide 12 (PA12) matrices. Filaments for MEX AM were prepared to produce corresponding 3D-printed samples. For the thorough characterization of the nanocomposites, a series of standardized mechanical tests were followed, along with AFM, TGA, Raman spectroscopy, EDS, and SEM analyses. The results showed an improved mechanical response for filler concentrations between 2.0 and 3.0 wt.%. The enhancement for the PLA/PTFE 2.0 wt.% in the tensile strength reached 21.1% and the modulus of elasticity 25.5%; for the PA12/PTFE 3.0 wt.%, 34.1%, and 41.7%, respectively. For PLA/PTFE 2.0 wt.%, the enhancement in the flexural strength reached 57.6% and the modulus of elasticity 25.5%; for the PA12/PTFE 3.0 wt.%, 14.7%, and 17.2%, respectively. This research enables the ability to deploy PTFE as a reinforcement agent in the PA12 and PLA thermoplastic engineering polymers in the MEX AM process, expanding the potential applications.

In this paper, polyamide 12 (PA12) blends with three types of metallic fillers are tested, which differ in the type of material and its' morphology. Low content mixtures are taken into consideration (0.5, 1.0, 2.0, 5.0 wt%), since a low impact on mechanical properties along with obtaining antibacterial properties are desired. The investigation focuses on filler distribution as well as the influence on microstructural homogeneity of the base material after processing with polymer Laser Sintering. Moreover, the influence of the filler content on the mechanical properties and fracture behaviour were examined. Processability PA12 with bioactive metal fillers was confirmed, and no significant changes in ductile behaviour of PA 12 were observed. An in-depth analysis of the effect of the filler on microstructural homogeneity was conducted. [ABSTRACT FROM AUTHOR]

This study investigates the mechanical response of antibacterial PA12/TiO2 nanocomposite 3D printed specimens by varying the TiO2 loading in the filament, raster deposition angle, and nozzle temperature. The prediction of the antibacterial and mechanical performance of such nanocomposites is a challenging field, especially nowadays with the covid-19 pandemic dilemma. The experimental work in this study utilizes a fully factorial design approach to analyze the effect of three parameters on the mechanical response of 3D printed components. Therefore, all combinations of these three parameters were tested, resulting in twenty-seven independent experiments, in which each combination was repeated three times (a total of eighty-one experiments). The antibacterial performance of the fabricated PA12/TiO2 nanocomposite materials was confirmed, and regression and arithmetic artificial neural network (ANN) models were developed and validated for mechanical response prediction. The analysis of the results showed that an increase in the TiO2% loading decreased the mechanical responses but increased the antibacterial performance of the nanocomposites. In addition, higher nozzle temperatures and zero deposition angles optimize the mechanical performance of all TiO2% nanocomposites. Independent experiments evaluated the proposed models with mean absolute percentage errors (MAPE) similar to the ANN models. These findings and the interaction charts show a strong interaction between the studied parameters. Therefore, the authors propose the improvement of predictions by utilizing artificial neural network models and genetic algorithms as future work and the spreading of the experimental area with extra variable parameters and levels. [ABSTRACT FROM AUTHOR]

The effect of aluminum oxide (Al2O3) nanoparticles (NPs) as a reinforcing agent of Polyamide 12 (PA12) and Polylactic acid (PLA) in fused filament fabrication (FFF) three-dimensional printing (3DP) is reported herein for the first time. Alumina NPs are incorporated via a melt–mixing compounding process, at four different filler loadings. Neat as well as nanocomposite 3DP filaments are prepared as feedstock for the 3DP manufacturing of specimens which are thoroughly investigated for their mechanical properties. Thermogravimetric analyses (TGA) and Raman spectroscopy (RS) proved the nature of the materials. Their morphological characteristics were thoroughly investigated with scanning electron and atomic force microscopy. Al2O3 NPs exhibited a positive reinforcement mechanism at all filler loadings, while the mechanical percolation threshold with the maximum increase of performance was found between 1.0–2.0 wt.% filler loading (1.0 wt.% for PA12, 41.1%, and 56.4% increase in strength and modulus, respectively; 2.0 wt.% for PLA, 40.2%, and 27.1% increase in strength and modulus, respectively). The combination of 3DP and polymer engineering using nanocomposite PA12 and PLA filaments with low-cost filler additives, e.g., Al2O3 NPs, could open new avenues towards a series of potential applications using thermoplastic engineering polymers in FFF 3DP manufacturing.

In this work, for the first time, polyamide 12 (PA12) nanocomposites with binary inclusions in material extrusion (MEX) 3D printing were developed. The aim was to achieve an enhanced mechanical response with the addition of titanium nitride (TiN) and antibacterial performance with the addition of copper (Cu) or cuprous oxide (Cu2O), towards the development of multi-functional nanocomposite materials, exploiting the 3D printing process benefits. The prepared nanocomposites were fully characterized for their mechanical properties. The thermal properties were also investigated. Morphological characterization was performed with atomic force microscopy (AFM) and scanning electron microscopy (SEM). The antibacterial performance was investigated with an agar-well diffusion screening process. Overall, the introduction of these nanofillers induced antibacterial performance in the PA12 matrix materials, while at the same time, the mechanical performance was significantly increased. The results of the study show high potential for expanding the areas in which 3D printing can be used.

In the current study, nanocomposites of medical-grade polyamide 12 (PA12) with incorporated copper (I) oxide (cuprous oxide-Cu2O) were prepared and fully characterized for their mechanical, thermal, and antibacterial properties. The investigation was performed on specimens manufactured by fused filament fabrication (FFF) and aimed to produce multi-purpose geometrically complex nanocomposite materials that could be employed in medical, food, and other sectors. Tensile, flexural, impact and Vickers microhardness measurements were conducted on the 3D-printed specimens. The fractographic inspection was conducted utilizing scanning electron microscopy (SEM), to determine the fracture mechanism and qualitatively evaluate the process. Moreover, the thermal properties were determined by thermogravimetric analysis (D/TGA). Finally, their antibacterial performance was assessed through a screening method of well agar diffusion. The results demonstrate that the overall optimum performance was achieved for the nanocomposites with 2.0 wt.% loading, while 0.5 wt.% to 4.0 wt.% loading was concluded to have discrete improvements of either the mechanical, the thermal, or the antibacterial performance.

During the COVID-19 pandemic, wide use of 3D printing technologies has been enabled. Fused filament fabrication (FFF) is the most widely used technique in 3D printing communities worldwide for the fabrication of medical components such as face shields and respiratory valves. In the current study, the potential of Polyamide 12 (PA12) silver-doped antibacterial nanopowder (AgDANP) nanocomposites is evaluated for everyday FFF usage. Filling loadings of 1.0-2.0-3.0 and 4.0 wt.% were selected for nanocomposite preparation. Mechanical performance analysis was conducted on the basis of tensile, flexural, impact, and Vickers microhardness measurements in FFF 3D-printed specimens. Scanning Electron Microscopy (SEM) images were used for morphology and processing evaluation, as well as thermal performance measurements, conducted by Thermogravimetric Analysis (TGA) tests. Finally, the antibacterial performance was tested using the agar-well diffusion screening method, and the shape effect of the specimens was also investigated. The addition of 2.0 wt.% AgDANPs resulted in an enhancement of approximately 27% for both tensile and flexural stresses, while the antibacterial performance was sufficiently high among the nanocomposites tested. The shape effect exhibited the potential for antibacterial performance at low filling ratios, while the effect was diminished with increasing filler of AgDANPs.

Plastic waste reduction and recycling through circular use has been critical nowadays, since there is an increasing demand for the production of plastic components based on different polymeric matrices in various applications. The most commonly used recycling procedure, especially for thermoplastic materials, is based on thermomechanical process protocols that could significantly alter the polymers’ macromolecular structure and physicochemical properties. The study at hand focuses on recycling of polyamide 12 (PA12) filament, through extrusion melting over multiple recycling courses, giving insight for its effect on the mechanical and thermal properties of Fused Filament Fabrication (FFF) manufactured specimens throughout the recycling courses. Three-dimensional (3D) FFF printed specimens were produced from virgin as well as recycled PA12 filament, while they have been experimentally tested further for their tensile, flexural, impact and micro-hardness mechanical properties. A thorough thermal and morphological analysis was also performed on all the 3D printed samples. The results of this study demonstrate that PA12 can be successfully recycled for a certain number of courses and could be utilized in 3D printing, while exhibiting improved mechanical properties when compared to virgin material for a certain number of recycling repetitions. From this work, it can be deduced that PA12 can be a viable option for circular use and 3D printing, offering an overall positive impact on recycling, while realizing 3D printed components using recycled filaments with enhanced mechanical and thermal stability.

Nylon-12 is an important structural polymer in wide use in the form of fibres and bulk structures. Fused filament fabrication (FFF) is an extrusion-based additive manufacturing (AM) method for rapid prototyping and final product manufacturing of thermoplastic polymer objects. The resultant microstructure of FFF-produced samples is strongly affected by the cooling rates and thermal gradients experienced across the part. The crystallisation behaviour during cooling and solidification influences the micro- and nano-structure, and deserves detailed investigation. A commercial Nylon-12 filament and FFF-produced Nylon-12 parts were studied by differential scanning calorimetry (DSC) and wide-angle X-ray scattering (WAXS) to examine the effect of cooling rates under non-isothermal crystallisation conditions on the microstructure and properties. Slower cooling rates caused more perfect crystallite formation, as well as alteration to the thermal properties.

Selective laser sintering (SLS) is a modern rapid prototyping method with which 3D objects with complex geometries can be manufactured precisely through the sintering of powders’ thin layers using the laser power. The effective manufacturing parameters in SLS are laser power, scanning speed, scan-spacing, and the part-bed temperature. In this work, selective laser sintering (SLS) is used to manufacture a composite material from white cement additives and polyamide 12 (PA12) and then, the influence of energy density (controlled by laser power, scanning speed, and scan-spacing) on the dimensions, density, mechanical properties, and morphology of sintered specimens is investigated. The criteria for obtaining optimum manufacturing parameters are the part dimensional accuracy, maximum density, and maximum strength. Hence, the optimum energy density for producing parts with maximum density and enhanced strength has been determined experimentally. The tensile, compressive, and flexural testing methods are used to evaluate the effects of laser power on the fabricated parts. The results show that the optimum energy density of 0.051 J/mm2 could achieve the highest density of sintered parts without any degradation of binder material. Also, it is found that a combination of a 0.051-J/mm2 energy density and 10% weight fraction of white cement is sufficient enough to enforce significant improvements on the mechanical properties of PA12-sintered specimens. [ABSTRACT FROM AUTHOR]

Selective laser sintering (SLS) of thermoplastic materials is an additive manufacturing process that overcomes the boundary between prototype construction and functional components. This technique also meets the requirements of traditional and established production processes. Crystallization behavior is one of the most critical properties during the cooling process and needs to be fully understood. Due to the huge influence of crystallization on the mechanical and thermal properties, it is important to investigate this process more closely. A commercial SLS polyamide (PA12) powder was measured with differential scanning calorimetry (DSC) to model a wider temperature range. To model isothermal crystallization between 160 and 168 °C, the Avrami model was used to determine the degree of crystallization. For non-isothermal crystallization between 0.2 and 20 K/min, different models were compared including the Ozawa, Jeziory, and Nakamura equations. [ABSTRACT FROM AUTHOR]

Selective laser sintering (SLS) of thermoplastic materials is an additive manufacturing process that overcomes the boundary between prototype construction and functional components. This technique also meets the requirements of traditional and established production processes. Crystallization behavior is one of the most critical properties during the cooling process and needs to be fully understood. Due to the huge influence of crystallization on the mechanical and thermal properties, it is important to investigate this process more closely. A commercial SLS polyamide (PA12) powder was measured with differential scanning calorimetry (DSC) to model a wider temperature range. To model isothermal crystallization between 160 and 168 °C, the Avrami model was used to determine the degree of crystallization. For non-isothermal crystallization between 0.2 and 20 K/min, different models were compared including the Ozawa, Jeziory, and Nakamura equations.

Deposition strategies to obtain low-friction and wear resistant coatings on 3D-printed rough polyamide 12 (PA12, nylon) surfaces were developed via atmospheric pressure plasma deposition. The feedstock materials for the DC plasma torch InoCoat 3 produced by INOCON Technologie GmbH were dry lubricants such as MoS 2 and graphite. In addition, parameter sets that would not thermally damage the heat sensitive polymers were applied. Generally, microtribological characterisation indicates that coating composition and thickness particularly influence the coating performance significantly. Pure MoS 2 coatings wear rapidly, particularly on the roughness tips (mean substrate roughness R a up to 20 μm); this exposes the substrate and leads to friction coefficients similar to those of PA12 and rather limited potential for protection against wear. Composite coatings with graphite in a MoS 2 matrix provide huge potential for wear protection (i.e. >20 times less penetration depth) even for exposed PA12 roughness tips, owing to the transfer of lubricating carbon into these exposed areas. If the thickness is sufficiently high, preventing the wear of tips results in low-friction properties (friction coefficients < 0.1, i.e. four times lower than those for uncoated PA12). • Spray coating carried out via APPD on Polyamide 12 (PA12) • Compound MoS 2 coatings with graphite prepared to improve wear resistance • Coating composition and thickness influence the coating performance significantly • Composite coatings have better tribological properties such as low COF • Selective laser sintering used as the layer-by-layer additive manufacturing process [ABSTRACT FROM AUTHOR]

Abstract: In the framework of environmentally friendly processes and products, polylactide (PLA) represents the best polymeric substitutes for various petropolymers because of its renewability, biodegradability, biocompatibility and good thermomechanical properties. Initially, most of its applications concerned biomedical sector and short-time uses such as packaging, particularly for the biodegradable properties of PLA. Interestingly, due to the depletion of petroleum resources, PLA is now viewing more and more as a valuable biosourced polymer alternative in long-term applications such as automotive and electronics. However, for such applications, PLA suffers from some shortcomings such as low thermal resistance, heat distortion temperature and rate of crystallization, whereas some other specific properties are required by different end-use sectors (flame retardancy, antistatic to conductive electrical characteristics, anti-UV, antibacterial or barrier properties, etc.). Therefore, adding nanofillers represents an interesting way to extend and to improve the properties of PLA. There are many nanofillers (three-dimensional spherical and polyhedral, two-dimensional nanofibers or one-dimensional sheet-like nanoparticles) that have been studied, with satisfactory achievements, in the design of PLA nanocomposites. This review hence highlights the main researches and developments in PLA-based nanocomposites during this last decade. [Copyright &y& Elsevier]

In the current study, nanocomposites of medical-grade polyamide 12 (PA12) with incorporated copper (I) oxide (cuprous oxide-Cu2O) were prepared and fully characterized for their mechanical, thermal, and antibacterial properties. The investigation was performed on specimens manufactured by fused filament fabrication (FFF) and aimed to produce multi-purpose geometrically complex nanocomposite materials that could be employed in medical, food, and other sectors. Tensile, flexural, impact and Vickers microhardness measurements were conducted on the 3D-printed specimens. The fractographic inspection was conducted utilizing scanning electron microscopy (SEM), to determine the fracture mechanism and qualitatively evaluate the process. Moreover, the thermal properties were determined by thermogravimetric analysis (D/TGA). Finally, their antibacterial performance was assessed through a screening method of well agar diffusion. The results demonstrate that the overall optimum performance was achieved for the nanocomposites with 2.0 wt.% loading, while 0.5 wt.% to 4.0 wt.% loading was concluded to have discrete improvements of either the mechanical, the thermal, or the antibacterial performance. [ABSTRACT FROM AUTHOR]

During the COVID-19 pandemic, wide use of 3D printing technologies has been enabled. Fused filament fabrication (FFF) is the most widely used technique in 3D printing communities worldwide for the fabrication of medical components such as face shields and respiratory valves. In the current study, the potential of Polyamide 12 (PA12) silver-doped antibacterial nanopowder (AgDANP) nanocomposites is evaluated for everyday FFF usage. Filling loadings of 1.0-2.0-3.0 and 4.0 wt.% were selected for nanocomposite preparation. Mechanical performance analysis was conducted on the basis of tensile, flexural, impact, and Vickers microhardness measurements in FFF 3D-printed specimens. Scanning Electron Microscopy (SEM) images were used for morphology and processing evaluation, as well as thermal performance measurements, conducted by Thermogravimetric Analysis (TGA) tests. Finally, the antibacterial performance was tested using the agar-well diffusion screening method, and the shape effect of the specimens was also investigated. The addition of 2.0 wt.% AgDANPs resulted in an enhancement of approximately 27% for both tensile and flexural stresses, while the antibacterial performance was sufficiently high among the nanocomposites tested. The shape effect exhibited the potential for antibacterial performance at low filling ratios, while the effect was diminished with increasing filler of AgDANPs. [ABSTRACT FROM AUTHOR]

Plastic waste reduction and recycling through circular use has been critical nowadays, since there is an increasing demand for the production of plastic components based on different polymeric matrices in various applications. The most commonly used recycling procedure, especially for thermoplastic materials, is based on thermomechanical process protocols that could significantly alter the polymers' macromolecular structure and physicochemical properties. The study at hand focuses on recycling of polyamide 12 (PA12) filament, through extrusion melting over multiple recycling courses, giving insight for its effect on the mechanical and thermal properties of Fused Filament Fabrication (FFF) manufactured specimens throughout the recycling courses. Three-dimensional (3D) FFF printed specimens were produced from virgin as well as recycled PA12 filament, while they have been experimentally tested further for their tensile, flexural, impact and micro-hardness mechanical properties. A thorough thermal and morphological analysis was also performed on all the 3D printed samples. The results of this study demonstrate that PA12 can be successfully recycled for a certain number of courses and could be utilized in 3D printing, while exhibiting improved mechanical properties when compared to virgin material for a certain number of recycling repetitions. From this work, it can be deduced that PA12 can be a viable option for circular use and 3D printing, offering an overall positive impact on recycling, while realizing 3D printed components using recycled filaments with enhanced mechanical and thermal stability. [ABSTRACT FROM AUTHOR]

Nylon-12 is an important structural polymer in wide use in the form of fibres and bulk structures. Fused filament fabrication (FFF) is an extrusion-based additive manufacturing (AM) method for rapid prototyping and final product manufacturing of thermoplastic polymer objects. The resultant microstructure of FFF-produced samples is strongly affected by the cooling rates and thermal gradients experienced across the part. The crystallisation behaviour during cooling and solidification influences the micro- and nano-structure, and deserves detailed investigation. A commercial Nylon-12 filament and FFF-produced Nylon-12 parts were studied by differential scanning calorimetry (DSC) and wide-angle X-ray scattering (WAXS) to examine the effect of cooling rates under non-isothermal crystallisation conditions on the microstructure and properties. Slower cooling rates caused more perfect crystallite formation, as well as alteration to the thermal properties. [ABSTRACT FROM AUTHOR]