1. Steam co-gasification of organic solid waste for hydrogen-rich syngas: Synergistic performance and mechanism.
- Author
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Ma, Yuna, Ge, Zefeng, Zeng, Mingxun, Zha, Zhenting, Wu, Yuqing, Hou, Zenghui, and Zhang, Huiyan
- Subjects
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ALKALINE earth metals , *ORGANIC wastes , *SOLID waste , *SYNTHESIS gas , *HIGH temperatures - Abstract
In this paper, poplar sawdust (PS), walnut shell (WS), sugarcane bagasse (SB), polyethylene (PE), and paper napkin (PN) were selected as typical organic solid waste for the study of steam (co-)gasification coupled with on-line analysis of H 2 -rich syngas. The carbon conversion efficiency of PE is only 10.8% and needs to be improved. The mixture of SB + PE exhibited the most pronounced positive synergies, with H 2 /CO reaching 2.40 without catalyst and the synergistic indices of 0.320, 0.298, and 0.226 for H 2 yield, syngas yield, and H 2 /CO, respectively, and these synergies were evident throughout the entire gasification process. The synergistic mechanism was analyzed through the interphase migration of alkali and alkaline earth metals and the morphological properties of the char. Compared with the co-gasification at 900 °C, the synergistic indices of the SB + PE co-gasification parameters at 800 °C were reduced to different degrees, and even the co-gasification at 700 °C showed a remarkable negative synergism. [Display omitted] • Steam co-gasification of various MSWs was carried out online for H 2 -rich syngas. • Co-gasification of SB + PE showed optimal synergy for both H 2 yield and H 2 /CO. • Synergistic mechanism was discussed in terms of AAEMs migration and char structure. • High temperatures of 800∼900 °C contributed to unleashing synergistic potentials. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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