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Epoxy-nanomaterials offer a promising solution to combat corrosion threatening civil infrastructure. To examine the impact of nano silica on corrosion resistance, varying amounts of nano silica, ranging from 0.0 to 3 wt%, were introduced into the epoxy matrix. Mechanical properties were studied through studying the dog-bone tensile strength and tribological aspects were assessed through mass loss abrasion tests. Corrosion resistance performance was studied using electrochemical impedance spectroscopy (EIS) and salt spray tests. Nano structure of the coated specimens was studied after salt spray tests using SEM-EDX analysis. Micro Chromatography (M-Ct) technique was employed to investigate the pore formation in the epoxy matrix. Besides, atomic force microscopy (AFM) was introduced to study surface roughness. The test results displayed a notable improvement (5–10 %) in tensile strength upon the introduction of nano silica. Taber tester results showed a reduction in mass loss with the addition of nano silica. Electrochemical impedance spectroscopy (EIS) studies further established a significant increase in corrosion resistance, having an impedance of 12 GOhm.cm2 for epoxy matrix samples containing 2.5 % nano silica after a 768-h salt spray test. SEM-EDX analysis revealed the absence of iron content in the epoxy matrix reinforced with uniformly distributed nano silica. Surface roughness assessments illustrated that nanolaminates contributed to an increase in overall roughness, minimizing surface irregularities in the epoxy matrix. Micro-CT scanning results proposed a decrease in epoxy matrix porosity upon the addition of nano silica. AI based prediction model helped to understand the relationship between surface roughness and corrosion. In summary, the experimental findings suggest valuable insights for future advancements in the development of protective coatings for worldwide civil infrastructures. [ABSTRACT FROM AUTHOR]

AbstractParaffin deposition remains a persistent challenge in the petroleum industry, particularly exacerbated in cold environments, necessitating effective mitigation strategies. Among these, pour point depressants (PPDs) stand out as a superior method. Nanomaterials have advantage of their surface properties due to which they are extensively used in petroleum industry. The present study is aimed at synthesizing a nanohybrid polymer tailored for use as a flow improver for Indian crude oil. The synthesized product was characterized by different analytical techniques and evaluated by pour point studies, rheological studies, Cold finger test, microscopic studies and aging studies. Results underscored the substantial potential of the PPD in reducing both pour point and viscosity of the crude oil. Significantly, the most notable achievement was observed at a concentration of 3000 ppm, yielding a remarkable pour point reduction of 18 °C alongside a substantial 95% decrease in viscosity. Microscopic analyses unveiled the presence of dispersed wax crystals after treatment with the nanohybrid polymer, indicative of its interaction with paraffin crystals, thereby impeding their formation or growth. Furthermore, aging studies elucidated the stability and sustained efficacy of nanohybrid polymer over time, crucial considerations for its practical applicability within the Petroleum industry. Overall, this investigation underscores the promising role of nanohybrid polymers as effective pour point depressants, offering tangible solutions to the persistent challenge of paraffin deposition while enhancing operational efficiencies and cost-effectiveness within the industry. [ABSTRACT FROM AUTHOR]

The present study examined the effects of colloidal nanosilica on the performance of cement paste samples exposed to nitric acid for a continuous period of 28 days. Compressive strength and weight losses in paste samples as a result of this attack were determined to be 66% and 27%. The inclusion of nanosilica up to 6% by weight reduced these sample losses by densifying the microstructure with its pore filling and pozzolanic effects. The addition of nanosilica decreased the flow of cement paste by 30%, but improved compressive and flexural strengths at the end of 28 days by up to 45% and 118%. The acid attack on the cement sample resulted in the formation of a degraded layer surrounding the unaltered core material. X‐ray tomography images showed this zone formation, and the scanning electron microscopy images revealed the degraded microstructure. The results of the x‐ray diffraction and nanoindentation tests confirmed the complete decalcification of the main cement hydrates, including calcium silicate hydrate and portlandite, as a result of acid attack. The results obtained suggest that the incorporation of nanosilica strengthens the microstructure of the cement matrix, thus improving the service life of structural concrete operating in chemical environments. [ABSTRACT FROM AUTHOR]

Copyright of Paint & Coatings Industry (0253-4312) is the property of Paint & Coatings Industry Editorial Office and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

The dual nature of asphalt binder necessitates improvements to mitigate rutting and fatigue since it performs as an elastic material under the regime of rapid loading or cold temperatures and as a viscous fluid at elevated temperatures. The present investigation assesses the effectiveness of Nano Alumina (NA), Nano Silica (NS), and Nano Titanium Dioxide (NT) at weight percentages of 0, 2, 4, 6, and 8% in asphalt cement to enhance both asphalt binder and mixture performance. Binder evaluations include tests for consistency, thermal susceptibility, aging, and workability, while mixture assessments focus on Marshall properties, moisture susceptibility, resilient modulus, permanent deformation, and fatigue characteristics. NS notably improves binder viscosity by about 138% and reduces penetration by approximately 40.8% at 8% nanomaterial (NM) content, significantly boosting hardness and consistency. NS also enhances Marshall stability and decreases air voids, increasing the mix's durability. For moisture resistance, NS at 8% NM content elevates the Tensile Strength Ratio (TSR) to 91.0%, substantially surpassing the 80% standard. Similarly, NA and NT also show improved TSR values at 8% NM content, with 88.0% and 84.1%, respectively. Additionally, NS, NA, and NT reduce permanent deformation by 82%, 69%, and 64% at 10,000 cycles at 8% NM content, illustrating their effectiveness in mitigating pavement distress. Notably, while higher NM content generally results in better performance across most tests, the optimal NM content for fatigue resistance is 4% for NS and 6% for both NA and NT, reflecting their peak performance against various types of pavement distresses. These results highlight the significant advantages of nanoparticles in improving asphalt's mechanical properties, workability, stability, and durability. The study recommends further field validation to confirm these laboratory findings and ensure that enhancements translate into tangible improvements in real-world pavement performance and longevity. [ABSTRACT FROM AUTHOR]

The power line insulators are permanently exposed to various environmental pollutants such as dust and fine particles. This may lead to flashovers and therefore widespread power blackouts and heavy economic damage. One way to overcome this problem is to make the insulator surface superhydrophobic. In this research, the superhydrophobic properties of the insulators were improved by applying room-temperature cured composite coatings consisting of epoxy and hydrophobic nano-silica particles. Either octadecyl trichlorosilane (ODTS) or hexamethyldisilazane (HMDS) was used to coat the silica nanoparticles and make them hydrophobic. Then, the hydrophobic silica was added to a mixture of epoxy resin and hardener. The suspension was applied on the surfaces of a commercial porcelain insulator and cold-cured at ambient temperature. The coating increased the water contact angle from 50° to 149°. The samples preserved their hydrophobic properties even after 244 h exposure to the UV light. The coating adhesion was rated as 4B according to the ASTM D3359 standard. The coating decreased the leakage current by 40% and increased the breakdown voltage by 86% compared to the uncoated sample, and it showed promise for making power line insulators self-clean. [ABSTRACT FROM AUTHOR]

The objective of this study was to investigate the combined impact of nano-silica, steel microfibers, and ‎polypropylene microfibers on the mechanical properties, permeability, and resistance to chloride attack ‎of cement composite. To achieve this goal, a 2% weight ratio of nano-silica was used as a cement substitute, ‎while ‎1.0% steel and 0.2% polypropylene microfibers, respectively, by volume of the binders‎ were separately and simultaneously‎ ‎employed as additives in the cement composite. Experimental analyses, including compressive, flexural, and ‎tensile strength tests, were conducted to evaluate the mechanical properties. Additionally, the ultrasonic ‎pulse velocity (UPV) and sorptivity tests were employed to assess permeability, and the durability ‎against chloride attack was examined using the Rapid Chloride Migration Test (RCMT). The results ‎demonstrate that the simultaneous incorporation of nano-silica, steel microfibers, and polypropylene ‎microfibers in the cement composite mixture resulted in a significant enhancement in compressive strength, ‎flexural strength, flexural toughness, and tensile strength by 59.3%, 32.3%, 67.2%, and 25.9%, ‎respectively, compared to the control sample after a curing period of 90 days. Moreover, significant ‎decreases were observed in terms of the initial and secondary water absorption rates. Furthermore, the ‎penetration depth of chloride ions was notably reduced from 33.6 mm (in the control composite) to 14.2 ‎mm (in the composite containing the combined effects of nano-silica, steel microfibers, and polypropylene ‎microfibers) after 90 days. The enhancement of mechanical properties, permeability, and durability ‎against chloride attack in cement composite can be attributed to the synergistic mechanisms promoted by ‎the utilization of nano-silica, steel microfibers, and polypropylene microfibers. The filling effect, ‎nucleation sites, and pozzolanic activity of silica nanoparticles significantly contribute to the reduction of ‎porosity and refinement of the cementitious matrix's microstructure. Simultaneously, the inclusion of ‎steel microfibers and polypropylene microfibers reinforces the cement matrix and effectively controls ‎existing microcracks, thereby impeding the propagation of macrocracks and brittle failure in the cement ‎composite. Furthermore, the bridging effect of steel and polypropylene fibers aids in the control of cracks ‎caused by plastic shrinkage during the early stages and secondary or thermal cracks, thereby further ‎improving the properties of cement composite.

Abstract The power line insulators are permanently exposed to various environmental pollutants such as dust and fine particles. This may lead to flashovers and therefore widespread power blackouts and heavy economic damage. One way to overcome this problem is to make the insulator surface superhydrophobic. In this research, the superhydrophobic properties of the insulators were improved by applying room-temperature cured composite coatings consisting of epoxy and hydrophobic nano-silica particles. Either octadecyl trichlorosilane (ODTS) or hexamethyldisilazane (HMDS) was used to coat the silica nanoparticles and make them hydrophobic. Then, the hydrophobic silica was added to a mixture of epoxy resin and hardener. The suspension was applied on the surfaces of a commercial porcelain insulator and cold cured at ambient temperature. The coating increased the water contact angle from 50° to 149°. Even after 244 h exposure to the UV light, the samples preserved their hydrophobic properties. The adhesion of the coating was rated as 4B according to the ASTM D3359 standard. The coating decreased the leakage current by 40% and increased the breakdown voltage by 86% compared to the uncoated sample and showed promise for making power line insulators self-cleaning.

Roller-compacted concrete pavement (RCCP) is a brittle material with low tensile strength that does not contain steel or dowel bars. This, in addition to the rigidity of the RCCP, causes degradation or cracking before the RCCP reaches its service life. To improve the performance of the RCCP, crumb rubber (CR) can be used as an aggregate. Hence, in this study, CR was used to replace 0, 10, 20, and 30% of the fine aggregate in the RCCP. To mitigate the adverse effect of the CR on the properties of the RCCP, nano-silica (NS) was added by weight of cement in proportions of 0, 1, 2, and 3%. To select an optimal mix based on various performance criteria, multicriteria-based optimization was carried out using techniques such as order of preference by similarity to ideal solution, evaluation based on distance from average solution, weighted sum model, and weighted product model techniques. During experimentation, CR improved the consistency and reduced the mechanical and durability properties of the RCCP, while NS reduced the consistency and improved the mechanical and durability performance of the RCCP. The M2 mix (mix containing 0% CR and 1% NS) is consistently ranked as the best choice for multi-criteria decision-making techniques and sensitivity analyses due to its exceptional physical, mechanical, and durability attributes, ensuring reliability across various decision-making scenarios. This study provides insights into the decision-making process for the choice of appropriate RCCP mix produced with CR and NS for improved performance in pavement applications and the importance of utilizing waste tire rubber in concrete pavements to promote sustainability.

This study aimed to investigate the mechanical properties of epoxy nanocomposites filled with single and binary combination of multiwalled carbon nanotube (MWCNT)-nano silica (NS) nanoparticles. The epoxy nanocomposites were produced using the mold casting method, and different filler ratios were employed to create nanocomposite samples. For the single particle-filled samples, filler ratios of 0.1, 0.3, 0.5, and 0.7 wt.% for MWCNT and 0.5, 1.0, and 1.5 wt.% for NS were used. Additionally, hybrid samples were produced using filler ratios of 1:1, 1:2, and 1:3 (MWCNT: NS). The tensile test results indicated notable enhancements in the tensile behavior of the nanocomposite, attributed to the integration of nanoparticles into the epoxy matrix. Particularly, tensile strength values improved by 28.35% and 21.25% in C3 (0.5 wt.% MWCNT) and S2 (1.0 wt.% NS) composite samples compared to the pure sample, respectively. Additionally, the hybrid nanoparticle-filled composite samples introduced a synergistic effect on the tensile behavior of the nanocomposite. Especially, the hybrid sample H1 (1:1) showed the maximum enhancement in tensile strength by 44.26%. Significant improvements were also observed in tensile strain values. Compared to the control sample, the maximum improvement was recorded as 143% in the H2 hybrid sample (1:2). [ABSTRACT FROM AUTHOR]

A complex of Cu(II) salen was grafted on the surface of KCC-1 nanoparticles using 3-chloropropyltrimethoxysilan as a linker to obtain Cu(II) salen@KCC-1. SEM and TEM images showed the porous, spherical nanosized particles with a 200 nm diameter. EDX and TGA analyses approved the incorporation of Cu(II) salen on the surface of KCC-1, while AAS showed that about 0.68 mmol g−1 of copper content was incorporated on the KCC-1 surface. Since, Cu(II) makes strong complex with salen ligands, they can be acted as useful catalysts. Subsequently, the synthesis of 2-amino-4H-benzochromenes was studied in the presence of Cu(II) salen@KCC-1 at 80 °C. The expected products were formed within very short reaction times in good to high yields. It was understood that Cu(II) salen@KCC-1 is an active heterogeneous recoverable catalyst that can be employed several times with no significant loss in its catalytic activity. [ABSTRACT FROM AUTHOR]

In this study, the influence of nano silica, used in the production of construction materials in recent years, on the durability properties of cement-based mortar has been investigated. Mortars with nano silica additions at 1%, 2%, and 4% ratios were produced; workability, water absorption, compressive strength development, and chloride permeability were examined. Tests were repeated on the 28th and 90th days to reveal the time-dependent behavior of nano-silica-containing mixtures. As a result of the study, it was observed that nano silica adversely affected the workability properties but improved the hardened state properties of mortars. It was determined that with increasing nano silica content, the void ratio and chloride permeability decreased while the compressive strength increased. It was emphasized that with the condition of ensuring the homogeneous distribution of the nano material within the cement matrix, a high addition of nano silica such as 4% is possible and significantly improves the durability properties. [ABSTRACT FROM AUTHOR]

Copyright of Bulletin of the Chinese Ceramic Society is the property of Bulletin of the Chinese Ceramic Society Editorial Office and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Nanoparticles are one of the effective methodologies implemented in concrete technology. The main objective of this research is to study the influence of nano alumina with different percentage variations ranging from 1% to 3% along with the incorporation of PVA fibers. From the mechanical properties test, the optimum dosage was determined to further study the durability behavior. This research work also investigates the hybridization of two nanoparticles such as nano silica (NS) and nano alumina (NA). The results show that the increasing quantity of NA reduces the compressive strength of the mortar due to agglomeration (cluster of particles), which results in a greater molecular attraction force. From the test results, it is concluded that the optimum dosage has been attained with an addition of 2% NA with 0.3% PVA. The compression strength test results at 14 days and 28 days reveal that the addition of NA tends the mineral admixture to react at early ages in the hydration process, which produces a new chemical compound to fill the pores. The rapid chloride penetration (RCPT) test results at 28 days significantly improved with the incorporation of nanoparticles due to their effective size and chemical reaction towards the other compounds. The test results from the hybridization of nanoparticles showed that the compressive strength was significantly enhanced compared to that of the control mortar and mortar with NA. They are effective up to certain limits beyond that addition, and the workability was reduced. Amongst all mixtures, the maximum compression strength has been attained for the mix with the addition of NA 0.5% and NS 2.5% comparatively. The microstructural properties of mortar were also studied through scanning electron microscope (SEM) analysis. The results showed that the incorporation of nanoparticles in the mortar matrix turns homogeneous with fewer pores and greater amount of hydration compounds; thereby, pore refinement has improved the hydration compounds remarkably. [ABSTRACT FROM AUTHOR]

[Display omitted] Ranging from industrial facilities to residential infrastructure, functional surfaces encompassing functionalities such as anti-fouling, fog collection, anti-corrosion, and anti-icing play a critical role in the daily lives of humans, but creating these surfaces is elusive. Bionic dewetting and liquid-infused surfaces have inspired the exploitation of functional surfaces. However, practical applications of these existing surfaces remain challenging because of their inherent shortcomings. In this study, we propose a novel functional slippery lubricated coating (FSLC) based on a simple blend of polysilazane (PSZ), silicone oil, and nano silica. This simple, nonfluorine based, and low-cost protocol promotes not only hierarchical micro-nano structure but also favorable surface chemistry, which facilitates robust silicone oil adhesion and excellent slippery properties (sliding angle: ∼1.6°) on various solid materials without extra processing or redundant treatments. The highly integrated competence of FSLC, characterized by robustness, durability, strong adhesion to substrates, and the ability for large-area preparation, render them ideal for practical production and application. The proposed FSLC holds outstanding application potentials for anti-fouling, self-cleaning, fog collection, anti-corrosion, and anti-icing functionalities. [ABSTRACT FROM AUTHOR]

Nano silica (NS) has been found to have a positive impact on enhancing the microporous structure of Ultra-High-Performance Concrete (UHPC). However, there is a lack of effective methods to accurately characterize the regulatory improvement mechanism of NS on the pore structure of UHPC. In this study, our objective is to investigate the influence of NS on various characteristic parameters of the pore structure in UHPC, including porosity, average pore size, box fractal dimension, and multifractal spectral parameters. To analyze these effects, we employ a combination of X- CT image processing techniques and fractal theory. Furthermore, we conducted regression analysis using linear functions to explore the correlation between these parameters and the 28d compressive strength of UHPC. The experimental results demonstrate that NS promotes the refinement of matrix pore size, leading to a denser microstructure of the matrix. Fractal analysis revealed that the pore structure of NS-modified UHPC exhibited favorable fractal characteristics. The fractal dimension and multiple fractal parameters provided complementary insights into the pore structure of NS-modified UHPC from different perspectives. The fractal dimension described the global information, indicating that NS improved matrix defects and reduced the complexity of the pore structure. On the other hand, the multiple fractal parameters supplemented local information, highlighting how the increase in micropores contributed to the heterogeneity of the pore structure. The results of the correlation analysis indicate that the developed mathematical model has a good fit with the 28d compressive strength of UHPC. [ABSTRACT FROM AUTHOR]

Increasing paddy consumption can be done through efforts to increase yields by improving production technology, one of which is using organic nano silica fertilizer. Food biofortification efforts in paddy are also considered a solution for improving nutrition to help improve community nutrition. This research aims to determine the colour cultivar and dosage of nano silica organic fertilizer and the interaction between the two, which provide high growth and production and determine the nutritional quality of functional paddy. Functional paddy planting occurred in Manakku Village, Labakkang District, Pangkep Regency, South Sulawesi, from May to August 2023. The research was arranged in a separate plot design with the main plot varying doses (kg ha-1) of nano silica organic fertilizer consisting of control (d0), 500 (d1), 1000 (d2), and 1500 (d3), as well as subplots of four cultivars of red rice (Oryza sativa L.), namely Inpari 24 (v1), Pamelen (v2), Pamera (v3) and Inpago 7 (v4) as well as one cultivar of black rice Jeliteng (v5). The results were that the interaction of 1000 kg ha-1 organic nano silica fertilizer and red rice 'Inpago 7' (d2v4) provides the best yield of 5.62 t ha-1. Characters that have a significant positive correlation with yield are plant height (0.64**), number of productive tiller (0.74**), grain total (0.54*), and weight of 1000 grains (0.88**). The quality of functional rice based on glycaemic index (GI) analysis showed that the black rice 'Jeliteng' with a dose of organic nano silica fertilizer of 1000 kg ha-1 (58.9%) had the lowest GI value. [ABSTRACT FROM AUTHOR]

The primary goal of engineering design of buildings is to reduce the weight of the structure and its resistance to earthquakes and explosions because the occurrence of these events is inevitable. In this research, lightweight concrete has been used due to its unique advantages in weight reduction, and attention has also been paid to increasing the resistance and behavior of this concrete in the face of any type of accident and investigating its static and dynamic behavior. The dynamic behavior of concrete has been studied by using Hopkinson compression machine at three strain rates of 100, 200 and 300/s. Static and dynamic properties of concrete include compressive strength, modulus of elasticity, and dynamic increase modulus. For this purpose, a study has been conducted on 8 mixing designs for samples without metal fibers and nanosilica and samples containing different percentages of nanosilica and metal fibers. The results have shown that nanosilica and metal fibers play a role in improving compressive strength and the best results are obtained by adding 3% nanosilica and 1% metal fibers. Nanoparticles are more effective in static loads because the pozzolanic interactions of nanosilica improves the microstructure, and in dynamic loads, nanoparticles are less efficient due to nano's sensitivity to high loads, and also metal fibers prevent cracks in concrete. In this study, a mathematical relationship for the dynamic increase coefficient has also been extracted and compared with the experimental results. [ABSTRACT FROM AUTHOR]

Efficient alkali-activated binder pastes of slag and fly ash-based aqueous nano-silica (FABANS) that provide enhanced strength are used for developing extrusion-based 3D printable concretes. The binder pastes of slag made with FABANS are not suitable for printing due to low yield stress and insufficient thixotropic buildup. Rheology control for enhancing the yield stress and thixotropic buildup is evaluated using bentonite clay and carboxymethyl cellulose (CMC). There is a synergistic enhancement in yield stress and thixotropic buildup provided by the combined use of bentonite and CMC that provides improved printability and buildability. Very rapid increase in yield stress with excess clay content in the presence of CMC, however, produces choking of flow and printability loss. Excess CMC results in a Maxwell-type behavior causing shape instability due to continuous relaxation under stress. The proportion of CMC and clay that provides the required thixotropic buildup for buildability is established. Printability and buildability of concrete mixture made with binder paste of FABANS with the proportion of rheology modifiers is demonstrated. [ABSTRACT FROM AUTHOR]

Concrete, essential to global infrastructure, confronts urgent environmental challenges due to its high carbon footprint and resource-intensive production. In response, researchers are exploring nanoparticles, such as nano-silica (nS) and nano-titanium dioxide (nT), to enhance sustainability and performance. This review examines recent advances in their application. Nano-silica, prized for rapid hydration and enhanced strength, emerges as a promising additive. Studies indicate nS accelerates cement hydration, densifies the matrix, and improves durability and impermeability. Silica-based nano-coatings on glass textile-reinforced composites bolster bond strength and resilience. Similarly, nT offers diverse benefits to concrete. Beyond its traditional applications in photocatalysis, nS has been proven to refine pore structure, increase compressive strength, and enhance resistance to elevated temperatures. Additionally, nT adds to the self-cleaning properties of concrete surfaces, making it a promising additive for sustainable construction practices. Despite these advancements, challenges persist in the effective dispersion of nanoparticles within concrete matrices and ensuring their economic feasibility and regulatory compliance. Addressing these challenges will require interdisciplinary collaboration and innovative approaches to optimize dispersion methods, mitigate health risks, and develop robust regulatory frameworks. Future research directions should focus on developing multifunctional nanomaterials capable of imparting multiple desirable properties to concrete simultaneously, such as self-sensing, self-cleaning, and energy harvesting capabilities. Furthermore, efforts to optimize manufacturing processes and scale up production will be essential to realizing the full potential of nano-modified concrete in addressing the sustainability challenges facing the construction industry.

Various studies and research have been conducted to find alternatives to liquid insulation. One that is considered the most potential is vegetable oil since it has various advantages, including non-toxic, biodegradable, renewable waste products due to reactions in the form of CO2 and water, high flash points, and better thermal characteristics. In this study, Palm Oil Mill Effluent (POME) was used as the raw material for insulation oil with the addition of an additive in the form of nano-silica, which improves the quality of the insulation oil. As for determining the feasibility of insulation oil, characteristic tests were carried out in the form of density, viscosity, moisture content, acid number, pour point, flash point, and breakdown voltage. Based on the results of the tests, it was obtained that the lowest density in pure oil was 0.8757 g / cm³, the lowest viscosity in oil with the addition of 0.13 wt% nano-silica was 4.0248 cSt, and the lowest acid number in pure oil was 0.5797 mgKOH / g. It was also discovered that the pour point value is the same for each sample, the moisture content is 0.05%, the flashpoint is > 104 °C, and the breakdown voltage is ≥ 60 kV for each sample. The data show that the insulation oil made from POME has the potential to be used as an alternative to insulation oil.

The development of nanotechnology has led to the creation of materials with unique properties, and in recent years, numerous attempts have been made to include nanoparticles in concrete in an effort to increase its performance and create concrete with improved qualities. Nanomaterials are typically added to lightweight concrete (LWC) with the goal of improving the composite’s mechanical, microstructure, freshness, and durability qualities. Compressive strength is the most crucial mechanical characteristic for all varieties of concrete composites. For this reason, it is essential to create accurate models for estimating the compressive strength (CS) of LWC to save time, energy, and money. In addition, it provides useful information for planning the construction schedule and indicates when the formwork should be removed. To predict the CS of LWC mixtures made with or without nanomaterials, nine different models were proposed in this study: the gradient-boosted trees (GBT), random forest, tree ensemble, XGBoosted (XGB), Keras, simple regression, probabilistic neural networks, multilayer perceptron, and linear relationship model. A total of 2,568 samples were gathered and examined. The most significant factors influencing CS during the modeling process were taken into account as input variables, including the amount of nanomaterials, cement, water-to-binder ratio, density, the content of lightweight aggregates, type of nano, fine and coarse aggregate content, and water. The performance of the suggested models was assessed using a variety of statistical measures, including the coefficient of determination (R 2), scatter index, mean absolute error, and root-mean-squared error (RMSE). The findings showed that, in comparison to other models, the GBT model outperformed the others in predicting the compression strength of LWC mixtures enhanced with nanomaterials. The GBT model produced the best results, with the greatest value of R 2 (0.9) and the lowest value of RMSE (5.286). Furthermore, the sensitivity analysis showed that the most important factor influencing the prediction of the CS of LWC enhanced with nanoparticles is the water content.

Due to the importance of removing strontium ions in nuclear wastes, in the present work, while synthesizing hydroxybenzaldehyde propyltriethoxysilane ((EtO)3Si-HL) and pyridylmethylidene propyltriethoxysilane ((EtO)3Si-L) ligands, we investigated the properties of silica nanoparticles modified with these ligands as solid adsorbents in The removal of strontium ion from the aqueous solution was investigated and parameters such as pH, time, the mass of adsorbent, temperature, and interfering ions were tested. The adsorption behavior of the adsorbents showed that by modifying the surface of the nano adsorbent, the ability of the adsorbents to adsorb strontium ion at pH=6 increased from 6.31% to 86% and 22.11% using the (EtO)3Si-HL and (EtO)3Si-L ligands, respectively. The results of isotherms and adsorption kinetics indicate that the adsorption process follows the Longmuir isotherm and the pseudo-second-order model, respectively. Also, thermodynamic parameters show that strontium removal from the aqueous solution is an endothermic process. The positive entropy values are the driving force behind the adsorption process.

The extensive use of cement exacerbates the greenhouse effect by increasing carbon dioxide (CO2) emissions. So, many standards recommend using Portland-composite cement in construction as one of the methods for reducing CO2 emissions, especially cement CEM II/A-P. This paper presents an extensive experimental and numerical study to investigate the effect of micro and nano-silica on the flexural behavior and mechanical properties of Self-Compacted High-Performance Concrete (SCHPC) produced by cement CEM II/A-P. The extensive experimental work consisted of eight mixtures: three with micro-silica (MS), four with nano-silica (NS), and a reference mixture without silica. For both MS and NS, different percentages of adding or replacement content were tested to study their effect on the following: (a) the workability of fresh concrete, (b) concrete compressive strength, (c) splitting tensile strength, (d) flexural behavior including flexural tensile strength, and (e) the optimum percentage of each of the MS and NS to get the maximum structural and economic benefits of using for SCHPC with CEM II/A-P. Also, through a statistical program, these experimental results were used to obtain accurate formulae that could predict both the splitting tensile strength (fsp) and modulus of rupture (fctr) for SCHPC with adding nano-silica. In addition, the numerical study verified the experimental results based on the finite element program ANSYS. The flexure behavior of SCHPC beams is verified using the Microplane model (recently added to ANSYS). The experimental results showed that adding NS is more effective than replacing or adding MS for SCHPC mixture with CEM II/A-P to increase the concrete compressive strength, splitting tensile strength, and flexural tensile strength, especially for the mixture with adding NS content of 4 %. The numerical results showed the ability of the coupled damage-plasticity microplane model to simulate the flexural behavior of the tested SCHPC beams with MS or NS well. This research confirms nano-silica's structural and economical efficiency in the behavior of SCHPC beams. It was found that the optimum percentage of adding NS is 4 % for SCHPC mixtures with CEM II/A-P.

The escalating demand for methods to diminish cement usage without compromising the strength and durability of concrete mixtures has led to an intensified exploration of alternative mixture ingredients. Nano silica has emerged as a prominent supplementary cementitious material, recognized for its capability to partially substitute cement. Despite this potential, there was a gap in the literature on the effects of nano silica on the concrete’s fresh and hardened properties, particularly when used in conjunction with silica fume. This gap motivated the current investigation, aiming to capture and compare the effects of incrementally substituting silica fume with nano silica in self-consolidating concrete (SCC). For this purpose, four nano silica dosages—1%, 2%, 3%, and 5%— were considered as replacements for silica fume. A range of experiments, including slump flow, T50 time, and L-box tests, were conducted to assess the workability of the developed SCC mixtures. Subsequent analyses focused on key mechanical attributes, including the static modulus of elasticity, compressive strength, and tensile strength. The research further encompassed water absorption, penetration depth, and electrical resistivity evaluations to understand the durability characteristics of the developed mixtures. The scanning electron microscopy (SEM) analyses complemented these tests, offering a microstructural perspective to further explain the outcomes. This investigation’s findings offer novel insights into leveraging nano silica’s distinctive properties to achieve the desired SCC properties while reducing the environmental impact of this class of mixtures.

This study focuses on the evaluation of the dynamic mechanical properties, molecular structure, density, hardness, swelling behavior of natural rubber blends (NR) and nitrile rubber (NBR) reinforced with carbon black and/or nano-silica. An experimental work has been conducted to study of the effects of increasing NR content and incorporating nano-silica on the mechanical properties and molecular structure were studied using dynamic mechanical analysis (DMA) and Fourier transform infrared (FTIR) spectroscopy. The results show that increasing the NR content and/or incorporating nano-silica into the elastomer leads to a higher storage modulus with no significant change in the glass transition temperature. FTIR analysis indicates the compatibility of the polyblends and the presence of oxidation of the main polymer chain generated during the grinding of the rubber. Additionally, the results of the swelling study demonstrate that stronger molecular interactions occur on the surface of the nano-silica between the nitrile radicals in the NBR and the silanol (Si-OH) radicals. These findings suggest that blending NR and NBR with carbon black and/or nano-silica can improve the mechanical properties and compatibility of the resulting polyblends, with potential applications in the development of advanced elastomeric materials. [ABSTRACT FROM AUTHOR]

The advantages of using geopolymer materials instead of cement in concrete are not limited to high durability properties. geopolymer concrete was introduced to mitigate the environmental damages caused by CO2 emissions and the great level of fossil fuels consumption during cement manufacturing. In the present investigation, a number of experimental studies were conducted on slag-based geopolymer concrete. Accordingly, nano-silica particles were used to improve the geopolymer concrete structure's matrix. In the current study, slag-based geopolymer concrete was used with 0–2% polyolefin fibres and 0–8% nano-silica. They were subjected to water absorption and permeability tests to assess their durability. The addition of nano-silica enhanced the whole properties of the slag-based geopolymer concrete. By using the nano-silica, the concrete paste microstructure became denser and more homogeneous, and the pores decreased. The compressive strength and tensile strength of the concrete increased by up to 22% and 14% respectively. On the other hand, in terms of durability, the nano-silica lowered the water absorption and permeability coefficients by up to 24% and 44%, respectively, by filling the pores of the concrete. In the weight loss test, geopolymer concrete achieved superior results (up to 16%) compared to ordinary concrete. [ABSTRACT FROM AUTHOR]

Local scour is one the leading factors contributing to bridge failures. This phenomenon can be defined as the consequences of the erosion force of the flow of the sediments in the region surrounding the bridge's piers. In this study, an experimental investigation was conducted to develop an innovative method for protecting the bed and reducing the susceptibility of the non-uniform sand bed to erosion by utilizing nanosilica powder. Four nanosilica ratios (0.25, 0.5,0.75, and 1%) were mixed with sand with diverse hydraulic conditions and three diverse pier diameters. Results indicate that the nanosilica can be utilized as an alternative solution to lessen the depth of local scour. Nanosilica can be effectively utilized by mixing it with sand. Experimental observation showed that the maximum reduction ratio of the depth of local scour is 59.6% for the case of a 3 cm pier, 42.6% in the case of a 5 cm pier diameter, and 24.65% in the case of a 7 cm pier diameter. The optimum ratios of the nanosilica are 0.25, 0.5, and 0.75%. Furthermore, the effect of using nanosilica on the other factors for the local scour has been demonstrated in this investigation. [ABSTRACT FROM AUTHOR]

Industrial water glass was used as raw material and CO2 as precipitant, focusing on the research on the process conditions of carbonization reaction to prepare nano silica by carbonization. The average particle size and BET values of the prepared nano silica samples were taken as the main investigation indexes. 2%TTLY+1%TTLX was screened and determined as the more suitable compound dispersant; and the carbonization condition was optimized as: the mass concentration of SiO2 11%, the temperature of carbonization reaction 60 ℃, the modulus of water glass 3.3, and the initial content of Na2CO3 3%.The average particle size of the prepared nano silica sample was 23.43 nm, the BET values reached 422.77 m²/g, and the sample was an amorphous structure, with good particle size uniformity and dispersion. [ABSTRACT FROM AUTHOR]

To functionalize the surface of the NiTi alloy, hybrid layers comprising nanometric silica and titanium oxides were synthesized. The TiO2–SiO2 nanosystem was chemically prepared and utilized for electrophoretic deposition (EPD) to create multifunctional layers on the alloy surface. The impact of pH on Zeta potential and ceramic particle size was explored to ensure a stable colloidal suspension for EPD, with optimal parameters established at a pH of approximately 6. A uniform layer was formed by applying a voltage of 40 V for 3 min, appearing as a thin film interspersed with regularly spaced larger agglomerates. The thin film primarily consisted of a minor fraction of defective rutile nanoparticles, accompanied by silica and carbon agglomerates from the nanosystem synthesis process. Heat treatment at 800 °C for 2 h induced significant structural changes, developing a novel-generation material with a different structure. An interlayer with strong Si–O–Ti connections was formed. Moreover, the mechanism of layer formation was extensively discussed. [ABSTRACT FROM AUTHOR]

This article aims to investigate and optimise the properties of lightweight self-consolidating mortar (LSCM) by using the response surface method (RSM). Silica fume (SF), nano silica (NS), water-cement ratio (W/C) and superplasticiser (SP) were chosen as variables. Also, part of the aggregates was replaced with lightweight expanded clay aggregate (LECA). Due to the advantages of RSM in accommodating multi-response optimisation of LSCM properties, the investigation and analysis were carried out for the stability, segregation and compressive strength. The optimised results recommended acceptable ranges of the required rheological and hardened criteria for LSCM. The mixtures achieved in these ranges include an LSCM with sufficient stability and low segregation. In particular, the results showed that the ultimate segregation must be < 8% for structural concrete. In addition, the results proved that increasing the fraction of NS and SF improves the properties of the LSCM by reducing the segregation and increasing the stability and compressive strength. It was found that adding 6% of NS at a high W/C ratio decreased the segregation by at least 15%. Adding 6% NS and %SF to LSCM within 0.5 W/C increased the compressive strength up to 15.1 MPa for the former and 3.8 MPa for the latter. [ABSTRACT FROM AUTHOR]

In this study, sol–gel derived spray coatings of highly hydrophobic nature consisting of polystyrene (PS) and SiO2 nanoparticles were developed on polished stainless steel 321 (SS) and textured 6061 aluminium (Al) alloy substrates. The micro-structures on the Al surface were created through ultraprecision machining, known as single-point diamond turning (SPDT) machining. The polished SS and micro-structured Al were coated with PS/SiO2 using a spray coating technique by maintaining a pressure of 4–5 kPa, and positioning the nozzle 20–30 cm away from the substrates. The textured surface of Al was characterised using coherent correlational interferometry (CCI). The PS modified SiO2 nanoparticles and their coatings were characterised using Fourier-Transform Infrared Spectroscopy (FTIR) and field-emission scanning electron microscopy (FESEM). The resulting coating exhibited a micro-nano hierarchical roughness due to the presence of SiO2 nanoparticles and their fine size clusters. The polished SS surface showed static water contact angles of 93.3° and 143.5° before and after coating, respectively. Similarly, the polished and coated structured Al surface exhibited water contact angles of 85.6° and 144.3° before and after coatings. Such coatings can exhibit a great potential particularly in the field of self-cleaning technologies. [ABSTRACT FROM AUTHOR]

The use of High Strength Concrete is increasing largely nowadays due to its unique properties. The addition of pozzolanic materials such as silica fume and nano-silica as a partial replacement of cement in concrete is considered beneficial as it improves its properties and in the same time reduces the amount of CO2 emitted in the atmosphere during cement manufactory. Adding steel fiber to high strength concrete can improve its ductility, toughness and impact resistance in addition to its strength. The effect of adding silica fume, amorphous nano-silica and steel fibers to the concrete mix on its compressive and splitting tensile strengths was considered in this study at different cementitious contents. Amounts used were 10 % of silica fume and 1 % of nano-silica by weight of cement as partially replacing the same amounts of cement. 2 % of steel fiber by weight of concrete was also used. 500, 600, and 700 kg/m³ cementitious contents were used. SEM micrograph images and EDX spectrum were made on some concrete specimens. Specimens were tested at the age of 28 and 56 days. Concrete prepared with silica fume and nano-silica showed larger compressive and splitting tensile strengths than the control mix. Adding steel fibers resulted in further increase in strength with even larger percentage in the case of tensile strength and this can be related to their ability to control and bridge these cracks. [ABSTRACT FROM AUTHOR]

This study investigates the effect of nanosilica and plantain leaf ash on the sustainable stabilization of expansive soil. This study conducted various strength tests, including Unconfined Compressive Strength (UCS), direct shear, and California Bearing Ratio (CBR) tests, to analyze the enhancement of mechanical properties by adding nano silica and plantain leaf ash. Scanning Electron Microscopy (SEM) analysis was conducted to investigate the interaction mechanism between the soil and the combination of nano silica and plantain leaf ash. Three different combinations of plantain leaf ash were utilized, ranging from 5% to 15%, alongside nano silica ranging from 0.4% to 1.2%. The reinforced soil's compressive strength, shear strength, and bearing capacity were assessed through UCS, direct shear, and CBR tests. The results demonstrated significant improvements in compressive strength, up to 4.6 times, and enhancements in cohesion and frictional angle, up to 3.3 and 1.6 times, respectively, at 28 days. Moreover, the addition of nano silica and plantain leaf ash led to increased bearing capacity and reduced soil swelling potential, contributing to the overall stability and strength improvement in expansive soil. The SEM test results demonstrate that maximum bonding and compaction occur when 1.2% nano silica and 15% plantain leaf ash are added to the soil. [ABSTRACT FROM AUTHOR]

Nano and micro materials are both effective individually in enhancing the mechanical and microstructural properties of concrete. The combination illustrates an iconic shift in material engineering to produce concrete with distinctive characteristics. In this work, the combined effect of Nano Silica (NS) and Metakaolin (MK) on the mechanical and microstructure properties were examined by conducting compressive strength, split tensile strength, and Field Emission Scanning Election Microscope (FE-SEM) with Energy-dispersive X-ray (EDX) analysis, X-ray Diffraction (XRD) spectroscopy, Fourier Transform Infra-Red (FTIR) spectroscopy, respectively. The concrete matrix was investigated by varying the concentration of NS and MK with different Water-Binder Ratio (WBR). Further, the Response Surface Methodology (RSM) technique was used to identify the complex interaction between NS (1–3 %) and MK (5–20 %) at different WBR (0.35, 0.40 and 0.45). The synergistic effect between NS and MK resulted in enhanced compressive and split tensile strengths of the concrete. The optimum mix proportion of the concrete was found to be 2 % NS and 12.5 % MK at a WBR of 0.4. The compressive strength enhancements for the optimum mix proportion were 35.75 %, 34.4 %, 33.1 %, and 32.5 %, while the split tensile strength enhancements were 26.56 %, 25.92 %, 20.95 %, and 17.8 %, respectively on the 7th, 28th, 56th, and 90th day. The RSM technique developed for all the mixes has been statistically validated to have less than 5 % of mean error. Moreover, the microstructural analysis revealed early hydration, formation of additional Calcium Silicate Hydrate (C-S-H) products, and presence of dense microstructure resulting in improved microstructural properties. The incorporation of NS and MK in the concrete changes the concrete’s configuration at the nano and micro levels, thus paving the way for the development of novel and sustainable construction materials.

In recent years, alkali-activated mortar (AAM) has emerged as a promising alternative to ordinary Portland cement (OPC) due to concerns regarding the environmental impact resulting from cement production, which releases carbon dioxide and degrades the quality of the environment. To address these concerns, researchers have explored the addition of supplementary binder materials to enhance cement properties and mitigate pollution. The effectiveness of these binder materials depends heavily on their chemical composition and fineness. Notably, ground granulated blast furnace slag (GGBS) enhances the strength and durability of the cement. In response to the scarcity of river sand (RS), dredged marine sand (DMS) has gained popularity as a potential substitute within the civil engineering field. Furthermore, the integration of nanomaterials has shown promising improvements in the mechanical and microstructural properties of mortar. Therefore, this study aims to investigate the properties of mortar by incorporating nano silica (NS) within the range of 1% to 7%, varying the molarity from 2 M to 8 M, and substituting RS with DMS. The tests carried out encompass a range of evaluations, including compressive strength, flexural strength, SEM-EDS, XRD, UPV, RCPT, and carbonation analysis, to comprehensively assess the properties of the mortar. The study reveals that the AAM demonstrates optimal performance when 50% of RS is replaced by DMS in the absence of NS. Once this optimal point is determined, further analyses are conducted at this value while varying the concentrations of NS from 1–7%. The experimental results indicate that replacing 50% of RS with DMS and incorporating 6% NS leads to maximum compressive strength (49.2 MPa) and flexural strength (9.36 MPa) in the assessed properties. Furthermore, the incorporation of NS in GGBS-based AAM mixes enhances durability by improving resistance against chloride penetration, reducing water absorption, and minimizing carbonation diffusion. Additionally, the microstructural and mineralogical characterization of GGBS-NS-based AAM specimens demonstrates the formation of C-S-H and C-A-S-H gels as the end products of the reactions.

High-strength concrete (HSC) using supplementary cementitious material of 30% fly ash (FA) and various nano silica (NS) contents were investigated in this study. FA and NS are waste materials collected from local thermal plants and rice husk ash in Southern Vietnam, respectively. Different concentrations of NS at 0%, 0.5%, 1.0%, and 1.5% were incorporated into the base mixture in place of cement and FA. The water-to-binder ratio of 0.32 was constant for all the mixtures. Results indicated that the combination binder of cement, FA, and NS satisfied the setting time as pure cement binder. The slump test value was in the range of 30–40 mm by adjusting the superplasticzer. Mechanical properties of HSC were studied at various curing ages of 3, 7, 28, and 56 days, including compressive strength, flexural strength, elastic modulus, and abrasion resistance. Results indicated that 1% NS can be considered as optimum content for preparing an HSC mixture, which showed the best mechanical properties. Furthermore, a good correlation between compressive strength and flexural strength was obtained from the results. Finally, rigid pavement calculation revealed that the addition of 1% NS resulted in a reduction in the thickness of the concrete slab by 30 mm (around 10.7%) compared to non-NS concrete. These findings suggest that incorporating nano-silica into concrete can lead to thinner concrete slabs with improved performance characteristics.

The study aims to conduct an experimental study through which the efficiency and effectiveness of different methods and materials, whether known traditional or modern materials, are evaluated by making different experimental formulations of these traditional and modern materials in different proportions and different concentrations, as well as making treatments using multiple materials as a mixture or individually in successive steps that are standardized to achieve high effectiveness. Especially in the processes of surface insulation of the roofs of ancient buildings and their application by possible methods, whether traditional or modern methods, so that we can effectively overcome the problems of moisture in ancient buildings. Moisture, its types and its impact on ancient stone buildings, as well as various sources of moisture, have been studied and each source and its impact on ancient buildings has been known. Stone buildings, as well as the factors affecting the moisture content inside the walls of ancient stone buildings, as well as the dynamics and mechanisms of moisture movement inside ancient stone buildings, different methods of measuring moisture, as well as manifestations of damage caused by moisture on stone buildings, as well as the role of fungi, algae and lichens in the damage of ancient stone buildings, and an experimental study was prepared In order to reach the best materials For appropriate concentrations to reduce the rate of moisture absorption in stone buildings, and analyzes of building materials were carried out. The petrographic examination was done by preparing thin section sectors using a polarizing microscope. The examination was also done using X-ray diffraction (XRD) of limestone samples, and it was found that it consists of calcite CaCO3 along with The presence of SIO2 quartz and some other minerals. The experimental study included the use of three types of moisture-insulating materials, which varied between water-based materials and organic-based materials, in order to compare them and obtain the best results, in addition to the nano-silica material Sio2