1. Chemo-mechanical characterization of hydrated calcium-hydrosilicates with coupled Raman- and nanoindentation measurements
- Author
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Günter Beuchle, Krassimir Garbev, Peter Stemmermann, Thibaut Divoux, Michael Haist, Biliana Gasharova, Karlsruhe Institute of Technology (KIT), Leibniz University Hannover, Multiscale Material Science for Energy and Environment (MSE 2), Massachusetts Institute of Technology (MIT), and MIT Department of Civil and Environmental Engineering (CEE)
- Subjects
Dewey Decimal Classification::500 | Naturwissenschaften::550 | Geowissenschaften ,Technology ,Hydration ,Applied Physics (physics.app-ph) ,[SPI.MECA.MSMECA]Engineering Sciences [physics]/Mechanics [physics.med-ph]/Materials and structures in mechanics [physics.class-ph] ,010501 environmental sciences ,010502 geochemistry & geophysics ,01 natural sciences ,Nanoindentation ,[SPI.MAT]Engineering Sciences [physics]/Materials ,law.invention ,Nanoscale mechanical properties ,chemistry.chemical_compound ,law ,ddc:550 ,Reaction kinetics ,Condensed Matter - Materials Science ,nanotechnology ,silicate ,Hydrated lime ,nanoparticle ,Calcium oxide ,Physics - Applied Physics ,[CHIM.MATE]Chemical Sciences/Material chemistry ,Pollution ,Hydraulic calcium –hydrosilicate ,Calcium silicate ,Raman spectroscopy ,[PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci] ,CO2 ,Water to cement (binder) ratios ,Silicon ,Celitement ,Portland cement ,Materials science ,nachhaltiger Zement ,FOS: Physical sciences ,Lime ,Clinker (cement) ,Homogeneous distribution ,Degrees of freedom (mechanics) ,Mechanical characterizations ,Nano-indentation measurements ,Density (specific gravity) ,Geochemistry and Petrology ,Mesoscale and Nanoscale Physics (cond-mat.mes-hall) ,chemical composition ,Environmental Chemistry ,Calcium silicate hydrate ,[SPI.MECA.SOLID]Engineering Sciences [physics]/Mechanics [physics.med-ph]/Mechanics of the solides [physics.class-ph] ,0105 earth and related environmental sciences ,Cement ,Ordinary Portland cement ,calcium ,Condensed Matter - Mesoscale and Nanoscale Physics ,Silicates ,Materials Science (cond-mat.mtrl-sci) ,Aluminum compounds ,Mechano-chemical activation ,Silicate ,C-S-H ,Ramanspektroskopie ,chemistry ,Chemical engineering ,Hardening ,ddc:600 - Abstract
Celitement is a new type of cement that is based on hydraulic calcium-hydrosilicate (hCHS) that possesses a potential for minimizing the ratio C/S from above 3 in OPC down to 1, which significantly reduces the amount of CO$_2$ released during processing. The reaction kinetics of hCHS differs from that of classical clinker phases due to the presence of highly reactive silicate species, which involve silanol groups instead of pure calcium silicates and aluminates and aluminoferrites. In contrast to Portland cement, no calcium hydroxide is formed during hydration, which otherwise regulates the Ca concentration. Without the buffering role of Ca(OH)$_2$ the concentration of the dissolved species c(Ca$^{2+}$) and c(SiO$_4^{4-}$) and the corresponding pH must be controlled to ensure a reproducible reaction. Pure hCHS reacts isochemically with water, resulting in a C-S-H phase with the same chemical composition as a single hydration product, with a homogeneous distribution of the main elements Ca and Si throughout the sample. Here we study via nanoindentation the mechanical properties of two different types of hardened pastes made out of Celitement (C/S=1.28), with varying amounts of hCHS and variable water to cement ratio. We couple nanoindentation grids with Raman mappings to link the nanoscale mechanical properties to individual microstructural components, yielding in-depth insight into the mechanics of the mineralogical phases constituting the hardened cement paste. We show that we can identify in hardened Celitement paste both fresh C-S-H with varying density, and C-S-H from the raw material using their specific Raman spectra, while simultaneously measuring their mechanical properties. Albeit not suitable for phase identification, EDX measurements provide valuable information about the distribution of alkalis, thus further helping to understand the reaction pattern of hCHS., Comment: 32 pages, 8 figures
- Published
- 2020
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