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In this study, we explore the substrate-mediated control of self-assembly behavior in diboron molecules (C12H8B2O4, B2Cat2) using scanning tunneling microscopy (STM). The structural transformation of B2Cat2 molecules from one-dimensional (1D) molecular chains to two-dimensional (2D) molecular arrays was achieved by changing the substrate from Au(111) to bilayer graphene (BLG), highlighting the key role of substrate interactions in determining the assembly structure. Notably, the B-B bond in the molecular arrays on BLG is distinctly pronounced, reflecting a more refined molecular resolution with distinct electronic states than that on Au(111). Density functional theory (DFT) calculations confirm the weak interaction between B2Cat2 molecules and the BLG substrate, which facilitates the formation of 2D molecular arrays on BLG. This work demonstrates how controlling substrate properties enables the formation of 1D chains and 2D arrays, providing valuable insights for the design of next-generation molecular electronics and catalysis systems. [ABSTRACT FROM AUTHOR]

In this study, we explore the substrate-mediated control of self-assembly behavior in diboron molecules (C12H8B2O4, B2Cat2) using scanning tunneling microscopy (STM). The structural transformation of B2Cat2 molecules from one-dimensional (1D) molecular chains to two-dimensional (2D) molecular arrays was achieved by changing the substrate from Au(111) to bilayer graphene (BLG), highlighting the key role of substrate interactions in determining the assembly structure. Notably, the B-B bond in the molecular arrays on BLG is distinctly pronounced, reflecting a more refined molecular resolution with distinct electronic states than that on Au(111). Density functional theory (DFT) calculations confirm the weak interaction between B2Cat2 molecules and the BLG substrate, which facilitates the formation of 2D molecular arrays on BLG. This work demonstrates how controlling substrate properties enables the formation of 1D chains and 2D arrays, providing valuable insights for the design of next-generation molecular electronics and catalysis systems.

Arrays of phthalocyanine molecules on Pb(100) are investigated with scanning tunneling microscopy. Maps of the differential conductance exhibit drastic changes as the sample voltage is being varied. Maximal conductances are observed at positions between the molecules mimicking bonding states. However, the maxima are shown to result from a superposition of non-interacting states. We expect that this effect may be observed from many other molecules.

In this paper, we consider the problem of characterizing the minimum energy configurations of a finite system of particles interacting between them due to attractive or repulsive forces given by a certain intermolecular potential. We limit ourselves to the cases of three particles arranged in a triangular array and that of four particles in a tetrahedral array. The minimization is constrained to a fixed area in the case of the triangular array, and to a fixed volume in the tetrahedral case. For a general class of intermolecular potentials we give conditions for the homogeneous configuration (either an equilateral triangle or a regular tetrahedron) of the array to be stable that is, a minimizer of the potential energy of the system. To determine whether or not there exist other stable states, the system of first-order necessary conditions for a minimum is treated as a bifurcation problem with the area or volume variable as the bifurcation parameter. Because of the symmetries present in our problem, we can apply the techniques of equivariant bifurcation theory to show that there exist branches of non-homogeneous solutions bifurcating from the trivial branch of homogeneous solutions at precisely the values of the parameter of area or volume for which the homogeneous configuration changes stability. For the triangular array, we construct numerically the bifurcation diagrams for both a Lennard⁻Jones and Buckingham potentials. The numerics show that there exist non-homogeneous stable states, multiple stable states for intervals of values of the area parameter, and secondary bifurcations as well.

Molecular communication is a promising nanoscale communication paradigm that enables nanomachines to exchange information by using molecules as communication carrier. Up to now, the molecular communication channel between a transmitter nanomachine (TN) and a receiver nanomachine (RN) has been modeled as either concentration channel or timing channel. However, these channel models necessitate exact time synchronization of the nanomachines and provide a relatively low communication bandwidth. In this paper, the Molecular ARray-based COmmunication (MARCO) scheme is proposed, in which the transmission order of different molecules is used to convey molecular information without any need for time synchronization. The MARCO channel model is first theoretically derived, and the intersymbol interference and error probabilities are obtained. Based on the error probability, achievable communication rates are analytically obtained. Numerical results and performance comparisons reveal that MARCO provides significantly higher communication rate, i.e., on the scale of 100 Kbps, than the previously proposed molecular communication models without any need for synchronization. More specifically, MARCO can provide more than 250 Kbps of molecular communication rate if intersymbol time and internode distance are set to 2 \mus and 2 nm, respectively. [ABSTRACT FROM PUBLISHER]

The diagnosis of ventilator-associated pneumonia, VAP, is problematic because of a lack of objective tools that are utilized to make an assessment of bacterial-induced lung injury in a heterogeneous group of hosts. Clinical symptoms and signs are used to identify patients that may have a “lung infection”. However, the symptoms and signs can be produced by a myriad of other conditions. Recent clinical data also suggests bacterial-induced pathologic processes occur prior to the onset of the symptoms and signs. Utilizing bacterial culture alone, health care practitioners are forced to wait for days for results and will have to order days of empiric antibiotic therapy. Exploratory molecular studies utilizing clone libraries and molecular arrays for microbial identification document the inability of culture-based techniques to even identify all the microbes involved in VAP. These molecular studies also offer evidence that oral flora present in the lungs of patients with VAP, suggesting aspiration of oral secretions and/or biofilms on endotracheal tubes, supply the bacteria for VAP. Much more investigation is needed to determine the optimal timing of antibiotic treatment and which diagnostic molecular methods can be utilized in the ICU. [Copyright &y& Elsevier]

In this paper, we consider the problem of characterizing the minimum energy configurations of a finite system of particles interacting between them due to attractive or repulsive forces given by a certain intermolecular potential. We limit ourselves to the cases of three particles arranged in a triangular array and that of four particles in a tetrahedral array. The minimization is constrained to a fixed area in the case of the triangular array, and to a fixed volume in the tetrahedral case. For a general class of intermolecular potentials we give conditions for the homogeneous configuration (either an equilateral triangle or a regular tetrahedron) of the array to be stable that is, a minimizer of the potential energy of the system. To determine whether or not there exist other stable states, the system of first-order necessary conditions for a minimum is treated as a bifurcation problem with the area or volume variable as the bifurcation parameter. Because of the symmetries present in our problem, we can apply the techniques of equivariant bifurcation theory to show that there exist branches of non-homogeneous solutions bifurcating from the trivial branch of homogeneous solutions at precisely the values of the parameter of area or volume for which the homogeneous configuration changes stability. For the triangular array, we construct numerically the bifurcation diagrams for both a Lennard–Jones and Buckingham potentials. The numerics show that there exist non-homogeneous stable states, multiple stable states for intervals of values of the area parameter, and secondary bifurcations as well. [ABSTRACT FROM AUTHOR]