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This work aims at conducting a numerical investigation of the effect of the inter-die distance on the probability of roping during meltblowing. The results are qualitatively compared with the experimental data obtained by the present group in studies of roping in a model situation of solution blowing. The effectiveness of nonwoven products as filter membranes and others depends on the fiber size and geometrical fiber distributions in fiber mats. Jet roping in meltblowing results in a distortion of the laydown structure, which is detrimental to the product's efficiency. A quasi one-dimensional model is utilized here to predict the probability of jet–jet intersection in flight leading to roping, which was observed experimentally in the prior works of this group. The results of the present work are expected to be helpful in optimizing operating parameters to minimize roping in meltblown products. [ABSTRACT FROM AUTHOR]

The work demonstrates, for the first time, thermo-responsive, water-insoluble, hydrogel-based, nano-fibrous filter media comprised of copolymers of N-isopropylacrylamide (NIPAM) and methyl methacrylate formed by electrospinning. Moreover, a comprehensive novel physical explanation of all aspects responsible for the physical mechanisms resulting in the thermo-responsive regulation of the water flow rate and an enhanced interception of nanoparticles by such filter membranes is given. They are the wettable-non-wettable transition, pore, and fiber-size changes, as well as a diminishing filter thickness at the lower critical solution temperature (LCST) of the copolymers developed here, which interplay with a significant reduction in the water viscosity with temperature. Poly(N-isopropylacrylamide) (PNIPAM) hydrogel is an attractive material because of its thermo-responsive properties. Its wettability changes with water temperature. This characteristic holds great promise for the development of advanced filter media and related responsive materials. In this study, PNIPAM hydrogels were designed and transformed into filter membranes for applications in water filtration in biomedical and other related systems. These thermo-responsive filter membranes offer the potential for enhanced filtration efficiency, selectivity, and the overall system performance. Here, two different procedures were adopted to form water-insoluble thermo-responsive filter media based on PNIPAM hydrogels. The PNIPAM-based hydrogels were electrospun, resulting in the formation of thermo-responsive water-insoluble nanofiber membranes. These membranes underwent a series of comprehensive experiments to assess their performance and characteristics, including mass loss, water droplets for the wettability assessment, filtration tests, shrinkage measurements, and microscopic observations. These diverse experiments yield a full understanding of the PNIPAM-based nanofiber membranes' properties and their potential applications. [ABSTRACT FROM AUTHOR]

[Objective] To establish a method for the determination of various additives in fruits such as waxberry and mulberry using ultra- high performance liquid chromatography triple quadrupole tandem mass spectrometry. [Method] The pre-treatment of the sample was carried out using acetonitrile methanol water solution (V: V: V, 1:1:1) as the extraction reagent. After shaking and ultrasonic extraction, the sample was diluted and made to volume with pure water. Using 0.22 µm filter membrane filters the samples. Ultra-high performance liquid chromatography-triple quadrupole tandem mass spectrometry was used for analysis and detection under multi-reaction monitoring (MRM). The separation and analysis were performed on a Waters Atlantis T3, C18 (2.1 mm×150 mm, 5 µm), quantitative with external standard method. [Result] Within the range of 10.59-3 260.67 ng/mL, the linear relationship of 10 additives was good (R²≥0.9938), the detection limit of the method was 0.02-1.50 mg/kg, and the quantitative limit was 0.25-4.00 mg/kg. The average recovery rates of 10 additives were 85.21%-108.92% between 2,5 and 10 times the LOQ concentration, and the RSD was 0.74%-9.63%. [Conclusion] The established method has the advantages of simple pretreatment, high sensitivity, good accuracy and strong repeatability, and can be applied to the analysis and detection of additives in fruits such as waxberry and mulberry. [ABSTRACT FROM AUTHOR]

Facemask materials have been under constant development to optimize filtration performance, wear comfort, and general resilience to chemical and mechanical stress. While single‐use polypropylene meltblown membranes are the established go‐to material for high‐performing mask filters, they are neither sustainable nor particularly resistant to sterilization methods. Herein an in‐depth analysis is provided of the sterilization efficiency, filtration efficiency, and breathing resistance of selected aerosol filters commonly implemented in facemasks, with a particular focus on the benefits of nanofibrous filters. After establishing a general overview over face mask filters and machine washing parameters required for successful decontamination, respective changes in filter performance and structure are presented. Sustainably manufactured, highly efficient, but also more fragile electrospun membranes not only offer competitive performance as well as a more environment‐friendly production and degradation process, but also support a subsequent sterilization and recharging approach via alcohol exposition and drying in an electric field. It is further elaborated on the prospective sustainability of each material to offer a clear outlook on electrospun membranes as the most promising filter membranes of the future. [ABSTRACT FROM AUTHOR]

ABSTRACT Background Methods Results Conclusion In cell‐free and concentrated ascites reinfusion therapy (CART), filtration membrane obstruction during the ascites processing step is an important clinical problem. A novel membrane designed polyether sulfone filter (n‐PES) was developed to reduce filter membrane obstruction. However, no clinical studies have compared the performance of n‐PES filters with that of conventional filters. Therefore, we aimed to assess whether n‐PES filters reduce membrane obstruction compared to conventional polyethylene (PE) filters during CART ascites processing.This was a single‐center, retrospective, observational, controlled cohort study. We compared ascites processing records from the drop‐type with adjustable concentrator CART (DC‐CART) sessions that used n‐PES filters with those that used conventional PE filters. The primary outcome was the occurrence rate of membrane obstruction. Propensity score matching was used to assemble DC‐CART sessions with comparable baseline ascites characteristics.Among the 173 DC‐CART sessions, 31 sessions using n‐PES filters and 31 using PE filters with similar propensity scores were included in the analysis. The rate of filter membrane obstruction was significantly lower in the n‐PES group than in the PE group (p = 0.049). Additionally, the total treatment time was significantly shorter for the n‐PES group (p = 0.006). No sessions experienced issues with the processing procedure.This is the first study to demonstrate that an n‐PES filter reduces the incidence of filter membrane obstruction in clinical CART sessions using human ascites. The n‐PES filter may reduce the burden on the medical staff performing CART. [ABSTRACT FROM AUTHOR]

A surface‐enhanced Raman scattering (SERS) filter membrane based on a Janus copper/poly(vinylidene fluoride)/zinc oxide/silver/zeolitic imidazolate framework‐8 (Cu/PVDF/ZnO/Ag/ZIF‐8, J‐CPZAZ) is designed in this work, which can extract and enrich methylmercury (MeHg) from real samples containing various sizes and types of interferents into the PVDF/ZnO/Ag/ZIF‐8 SERS enhancement unit directly within 2 min. Combined with the microcavity structure in PVDF/ZnO/Ag/ZIF‐8, J‐CPZAZ can also localize the incident light at the same position. This co‐confinement effect of “hotspot‐molecule” effectively lowers the limit of detection of MeHg to 10−10 m. Interestingly, a controllable wettability of J‐CPZAZ endows it with good oil‐water separation function for separating various kinds of MeHg extractant (>95%) from mixed aqueous solution. Based on these features, a dual‐layer J‐CPZAZ filter membrane is further successfully fabricated, enabling both‐in‐one detection and removal of MeHg from real water environments. In the experiments, real water samples are selected from six different water areas in Shandong Province, China, for relevant tests and compared the results with those obtained using traditional gas chromatography. The results demonstrate that the dual‐layer J‐CPZAZ filter membrane exhibits both high MeHg removal efficiency (≈100%) and detection accuracy (average error < 1.8%), showcasing great application potential. [ABSTRACT FROM AUTHOR]

Synthetic fibers are widely used in daily life due to their durability, elasticity, low cost, and ease of use. The textile industry is the primary source of synthetic microfibers, as these materials are mostly used in production processes. Globally, plastic pollution has been identified as a major environmental threat in this era, since plastics are not degradable but break down into smaller particles such as mesoplastics, microplastics, and microfibers. Synthetic microfiber pollution is a significant issue in aquatic ecosystems, including oceans and rivers, with laundry wastewater being a major source. This problem is particularly pressing in cities like Galle, Sri Lanka, where numerous tourist hotels are located. Despite the urgency, there has been a lack of scientific and systematic analysis to fully understand the extent of the issue. This study addresses this gap by analyzing the generation of microfibers from laundry activities at a selected hotel and evaluating the efficiency of a laundry wastewater filtration system. This study focused on a fully automatic front-loading washing machine (23 kg capacity) with a load of 12 kg of polyester–cotton blend serviettes (black and red). Samples (1 L each) were taken from both treated and untreated wastewater during four wash cycles, with a total of 100 L of water used for the process. The samples were filtered through a 100 μm sieve and catalytic wet oxidation along with density separation were employed to extract the microfibers, which were then collected on a membrane filter paper (0.45 μm). Microfibers were observed and analyzed for shapes, colors and sizes under a stereo microscope. Results revealed that untreated laundry wastewater contained 10,028.7 ± 1420.8 microfibers per liter (n = 4), while treated wastewater samples recorded 191.5 ± 109.4 microfibers per liter (n = 4). Most of the microfibers observed were black and white/transparent colors. Further analysis revealed that 1 kg of polyester–cotton blend fabric can generate 336,833 microfibers per wash, which was reduced to 6367 microfibers after treatment. The filtration unit recorded an impressive efficiency of 98.09%, indicating a remarkably high capacity for removing microfibers from wastewater. These findings highlight the potential of such filtration techniques to significantly reduce microfiber emissions from laundry wastewater, presenting a promising approach to mitigating environmental pollution from microfibers. [ABSTRACT FROM AUTHOR]

Objective To comprehensively analyze the influencing factors of the blood plate paper bridge method for H antigen induction and identification, and to investigate its mechanism in order to promote the application of this method in Salmonella serotyping. Methods The experimental conditions of the blood plate paper bridge method for Salmonella serotyping were optimized by comparing the effects of different paper bridge materials on the induction and identification of H antigen, scanning the surface of different paper bridge materials by scanning electron microscope to explore the mechanism of the effects, and combining the factors of environmental humidity and saline dosage. The optimized method was compared with the simple plate method of GB 4789.4 standard for serotyping 40 strains of Salmonella. Results The matte surface of CN110 and CN95 nitrocellulose membranes had similar bridging effect with ordinary filter paper, and the difference was not statistically significant (P>0.05), while the effect of filter membrane was significantly lower than that of ordinary filter paper (P< 0.05). Salmonella spread better at higher humidity, and there was a significant difference between the results at 80% humidity compared with those of the 50% and 20% groups (P<0.0167). The spreading effect was significantly improved with increasing amount of saline (P<0.001), and the optimal amount was 15 µL. Forty foodborne Salmonella strains were identified using the two methods, and the method in this study was able to accurately identify Salmonella serotypes in one go, whereas the simple plate method required one to three inductions. Conclusion The blood plate paper bridge method optimized in this study is easy to operate and has a significant induction effect, which is suitable for the identification of Salmonella serotypes. This method can be used as an effective complement to Salmonella serotyping methods to improve the efficiency and accuracy of foodborne disease traceability. [ABSTRACT FROM AUTHOR]

The compaction of hydrogel films under permeation flow can be measured, in-situ, by tracking the internal displacements of their structure, thereby revealing the internal deformation profile. Additionally, monitoring the permeation flow rate and applied pressure over time enables determination of variations in the hydrogel's permeability due to flow-induced compaction. Hydrogels are soft porous materials capable of containing high amounts of water within their polymeric matrix. Flow-induced internal deformation can modify the hydrogel's permeability and selectivity, which are important attributes in separation processes, both industrial (e.g., membrane-based water purification) and natural (mucous filters in suspension feeders and intestinal lining) systems. Measuring the flow-induced compaction in thin hydrogels films can reveal the interplay between flow and permeability. However, the micro-scale internal compaction remains uncharted for due to experimental challenges. A technique is demonstrated for analyzing the compaction and stratification of permeable soft materials, in-situ, created by a pressure-driven permeation flow. To this end, the internal deformations within a soft material layer are calculated, based on tracking the positions of fluorescent micro-tracers that are embedded within the soft material. We showcase the capabilities of this technique by examining a hundred-micron-thick calcium-alginate cake deposited on a nanofiltration membrane, emphasizing the achieved micro-scale resolution of the local compaction measurements. The results highlight the possibility to examine thin hydrogel films and their internal deformation produced by flow-induced stresses when varying the flow conditions. The method enables the simultaneous calculation of the soft material's permeance, as the pressure-driven flow conditions are continuously monitored. In summary, the proposed method provides a powerful tool for characterizing the behaviour of permeable soft materials under permeation conditions, with potential applications in engineering, biophysics and material science. [ABSTRACT FROM AUTHOR]

Acrylamide, a probable human carcinogen present in heat-processed foods and environmental contaminants, requires sample extraction and preconcentration before chromatographic analysis. The method developed in this study employed derivatization with xanthydrol and dispersive liquid–liquid microextraction utilizing low-density anisole. Durian or potato chips were combined with deionized water, defatted with hexane, and subjected to precipitation of soluble carbohydrates and proteins using clarification reagents. Water samples were filtered through a membrane filter. Acrylamide was derivatized by introducing an acidic methanolic solution of xanthydrol at 50 °C. The derivatized acrylamide was extracted with 70 µL of anisole and vortexed, with the methanol from the xanthydrol solution serving as the disperser solvent. The anisole layer was analyzed using gas chromatography with both flame ionization and mass spectrometric detection. Linear calibration plots exhibited coefficients of determination >0.9997. The precision was measured at <10% RSD, and recoveries ranged from 84% to 107%. The quantitation limit varied from 2 to 10 µg kg−1 for processed chips and from 0.05 to 0.10 µg L−1 for water samples. Acrylamide was detected in all processed chip samples, with some concentrations exceeding the benchmark value of 750 μg kg−1. However, no acrylamide was identified in any of the water samples. [ABSTRACT FROM AUTHOR]

Purpose: The purpose of this study is to prepare a state-of-the-art review on advanced ceramic materials including their fabrication techniques, characteristics, applications and wettability. Design/methodology/approach: This review paper presents the various types of advanced ceramic materials according to their compounding elements, fabrication techniques of advanced ceramic powders as well as their consolidation, their characteristics, applications and wetting properties. Hydrophobic/hydrophilic properties of advanced ceramic materials are described in the paper with their state-of-the-art application areas. Optical properties of fine ceramics with their intrinsic characteristics are also presented within. Special focus is given to the brief description of application-based manipulation of wetting properties of advanced ceramics in the paper. Findings: The study of wetting/hydrophobicity/hydrophilicity of ceramic materials is important by which it can be further modified to achieve the required applications. It also makes some sense that the material should be tested for its wetting properties when it is going to be used in some important applications like biomedical and dental. Also, these advanced ceramics are now often used in the fabrication of filters and membranes to purify liquid/water so the study of wetting characteristics of these materials becomes essential. The optical properties of advanced ceramics are equally making them suitable for many state-of-the-art applications. Dental, medical, imaging and electronics are the few sectors that use advanced ceramics for their optical properties. Originality/value: This review paper includes various advanced ceramic materials according to their compounding elements, different fabrication techniques of powders and their consolidation, their characteristics, various application area and hydrophobic/hydrophilic properties. [ABSTRACT FROM AUTHOR]

Surface collection efficiency (SCE) of a cellulose membrane filter (CMF) and a cellulose-glass fiber filter used in environmental monitoring for alpha-emitting radionuclides from nuclear facilities and natural radioactivity sources was evaluated for particles in the size range of 0.03–0.1 μm at different levels of face velocity. The SCE of the CMF was higher than that of the cellulose-glass fiber filter, and only the membrane filter showed the dependence of SCE on the particle size at higher face velocity. The use of the CMF at higher face velocity in environmental radioactivity monitoring leads to measurements of the background alpha spectrum with more degradation under the changing particle size condition in the atmosphere. Consequently, that fact needs to be taken into account, along with the expected particle size distribution and concentration of the airborne radioactivity being sampled, when selecting a face velocity to achieve the best possible detection limit. [ABSTRACT FROM AUTHOR]

Ceramic membrane filters fabricated from local raw materials are excellent for municipal wastewater treatment. This paper studied the fabrication of ceramic membranes using Response Surface Methodology (RSM). It also looked at the influence of clay, palm kernel shell ash, kaolin, and starch on the properties of ceramic membrane filters. Optimal test conditions and procedures were determined by selecting a fitting model based on experimental data. The Box–Behnken design (BBD) was chosen for its ability to reduce the number of experimental trials, thus making it cost-effective. The BBD design was executed using Design-Expert 13 software (Stat-Ease, Inc., Minneapolis, MN, USA), requiring 29 experimental runs. According to the study, responses such as porosity, flow rate, thickness, and density were used in the model. The fabrication of the 29 ceramic membranes includes formulation, shaping (slip casting method), drying, and sintering. Based on RSM, an optimum ceramic membrane design was proposed: Kaolin = 413 g, Clay = 180 g, Starch 147 g, Palm Kernel shell ash = 13 g. Compared with the test results, this combination possesses favorable and reliable accuracy. The addition of kaolin played a role in creating a porous framework within the ceramic membrane. Clay serves as a binding agent, aiding the consolidation of ceramic particles within the membrane matrix. Starch served as a pore-forming agent during the fabrication process. From the study, the palm kernel shell ash served as a binder and a reinforcing agent, bolstering mechanical strength and structural robustness. [ABSTRACT FROM AUTHOR]

ABSTRACT Objective Materials and Methods Results Conclusions To evaluate the efficacy of 3D‐printed scaffolds that were osteoinductively functionalized with a bone morphogenetic protein 2 (BMP‐2)‐incorporated biomimetic calcium phosphate particles (BMP‐2‐inc. BpNcCaP)/hyaluronic acid (HA) composite gel in vertical bone augmentation in beagle dogs.Four Beagle dogs were used in this study. Three months after the extraction of 1st, 2nd, 3rd, and 4th premolars at both sides of the lower jaws of Beagle dogs, one or two critical‐size vertical bone defects (4 mm vertical bone defect without buccal and lingual bone) on each side were surgically created. The defects were randomly subjected to the following groups: (1) Control (without bone‐defect‐filling materials); (2) 3D scaffold; (3) BMP2‐inc. BpNcCaP/HA‐functionalized 3D scaffold. Six weeks post‐surgery, samples were harvested and subjected to micro‐CT and histomorphometric analyses.The struts of the BMP2‐inc. BpNcCaP/HA‐func. 3D scaffold were covered by a thick layer of cemented irregular particles with an average pore size at 327 ± 27 μm. The BpNcCaP/HA‐func. 3D scaffold group bore significantly higher bone volume, bone volume fraction, trabecular number, trabecular thickness, bone mineral density, connectivity density, and bone volumes in three directions (mesiodistal, buccolingual, and apicocoronal) when compared with the groups of Control and 3D scaffold. Moreover, the BMP2‐inc. BpNcCaP/HA‐func. 3D scaffold group bore significantly lower trabecular separation and exhibited significantly higher bone‐to‐scaffold contact percentage and newly formed bone area percentage within pores in comparison with 3D scaffold.BMP2‐inc. BpNcCaP/HA‐func. 3D scaffold dramatically enhanced vertical alveolar bone augmentation, which suggests a promising application potential of BMP2‐inc. BpNcCaP/HA‐func. 3D scaffold in dental clinic. [ABSTRACT FROM AUTHOR]

Nanofiber membranes receive considerable interest recently because of their distinctive structural features, facile preparation, as well as high filtering efficiency. Due to ever‐increasing air pollution, membranes made from biodegradable materials can play a crucial part in providing purified air with minimum concerns of environmental issues after the membrane's end of service life. The purpose of this systematic review is to assess the performance of biodegradable electrospun nanofibrous membrane filters toward air sub‐micron particles. To identify relevant studies, a systematic search is carried out in major scientific search engines including PubMed, Scopus, and the Web of Science. Data extraction is used to collect the necessary information on the membranes' structural properties, as well as filtration performance metrics such as efficiency, pressure drop, and quality factor. Among the electrospun membranes derived from biodegradable polymers, the polyvinyl alcohol (PVA)‐based electrospun membranes are more effective in filtration efficiency in capturing sub‐micron particles. The results highlight that these types of membranes are effective in filtration with low energy consumption, making them more apt for air purification. The use of such membranes can supply both high filtering performance and protection of the environment. [ABSTRACT FROM AUTHOR]

Polar organic chemical integrative samplers (POCIS) are promising devices for measuring the time‐weighted average concentrations of hydrophilic compounds in aquatic environments. However, the mechanisms underlying compound uptake by POCIS remain unclear. We investigated the permeation kinetics of polyethersulfone and polytetrafluoroethylene membrane filters, and the sorption kinetics of Oasis HLB (Waters), Envi‐Carb (Supelco), and Oasis WAX (Waters) sorbents. The log octanol−water partition coefficient (KOW) values of the 19 targeted compounds ranged from −0.55 to 6.0. The overall mass‐transfer coefficients were negatively correlated with KOW, indicating that interactions between hydrophobic compounds and the membrane inhibit permeation. The sorption rate coefficient showed no correlation with KOW and depended on the type of sorbent used. These results imply that the uptake of highly hydrophilic compounds by POCIS is determined by both the membrane and the sorbent kinetics; however, membrane kinetics dominate the uptake of hydrophobic compounds. Environ Toxicol Chem 2024;43:2115–2121. © 2024 SETAC [ABSTRACT FROM AUTHOR]

The conventional approach to generate pores in ceramic membranes involves the incorporation of a pore-forming element. However, this method tends to diminish the mechanical properties of the membranes and poses challenges in effectively regulating both pore size and membrane porosity. In this work, low-cost ceramic filtering membranes with enhanced mechanical strength have been successfully prepared mainly from abundant clays and without the need for pore-forming agents. The Porosity and pore size were controlled by adding a finely-grained clay (d 90 = 22 μm) by-product to coarse clay (d 90 = 50 μm) within a specified range of 33–66 wt%. The microstructure evolution of prepared membranes was examined by XRF, FTIR, XRD, SEM, and DTA-TGA analysis, while the technological properties were evaluated by permeability, porosity, density, and mechanical measurements. The findings indicated that the increase in the amount of finely grained clay mixed with coarse clay and the sintering temperature had a synergistic effect on the porosity and pore size of the obtained membranes. The incorporation of finely-grained clays, accompanied by an elevation in sintering temperature, led to a reduction in porosity from 31.3 ± 0.7 % to 6.2 ± 0.5 % and pore size, along with the crystallization of the α-mullite (12 %) and anorthite (30 %) phase with a quartz phase and an improvement in mechanical strength reaching up to 251 ± 3 MPa. A formulation comprising 33 wt% of finely-grained clay by-products and 67 wt% of coarse clay, sintered at 1000 °C, emerged as a promising ultrafiltering membrane with enhanced mechanical strength reaching 120 ± 1 MPa, and a permeability of 1000 L/h.m2 at 1 bar. [ABSTRACT FROM AUTHOR]

Microplastic analysis is a crucial step for locating the environmental contamination sources and controlling plastic contamination. A popular tool like Fourier transform infrared (FTIR) spectroscopy is capable of identifying plastic types and can be carried out through a variety of containers. Unfortunately, sample collection from water sources like rivers usually involves filtration so the measurements inevitably include the membrane filter that also has its own FTIR characteristic bands. Furthermore, when plastic particles are small, the membrane filter's spectrum may overwhelm the desired plastics' spectrum. In this study, we proposed a novel preprocessing method based on the dictionary learning technique for decomposing the variations within the acquired FTIR spectra and capturing the membrane filter's characteristic bands for the effective removal of these unwanted signals. We break down the plastic analysis task into two subtasks — membrane filter removal and plastic classification — to increase the explainability of the method. In the experiments, our method demonstrates a 1.5-fold improvement compared with baseline, and yields comparable results compared to other state-of-the-art methods such as UNet when applied to noisy spectra with low signal-to-noise ratio (SNR), but offers explainability, a crucial quality that is missing in other state-of-the-art methods. The limitations of the method are studied by testing against generated spectra with different levels of noise, with SNR ranging from 0 to – 30dB, as well as samples collected from the lab. The components/atoms learned from the dictionary learning technique are also scrutinized to describe the explainability and demonstrate the effectiveness of our proposed method in practical applications. [ABSTRACT FROM AUTHOR]

An ultrasensitive photothermal assay was designed for point-of-care testing (POCT) of tumor markers based on a filter membrane. Firstly, Cu2-xSe was successfully encapsulated in liposome spheres with biotin on the surface and connected to carcinoembryonic antigen (CEA) aptamer with 3'end modified biotin by streptavidin. Secondly, the CEA antibody was successfully modified on the surface of the nitrocellulose membrane through simple incubation. Finally, the assay process was completed using a disposable syringe, and the temperature was recorded using a handheld infrared temperature detector. In the range 0–50 ng mL−1, the temperature change of the nitrocellulose membrane has a strong linear relationship with CEA concentration, and the detection limit is 0.097 ng mL−1. It is worth noting that the entire testing process can be easily performed in 10 min, much shorter than traditional clinical methods. In addition, this method was successfully applied to the quantitative determination of CEA levels in human serum samples with a recovery of 96.2–103.3%. This rapid assay can be performed by "one suction and one push" through a disposable syringe, which is simple to operate, and the excellent sensitivity reveals the great potential of the proposed strategy in the POCT of tumor biomarkers. [ABSTRACT FROM AUTHOR]

Filters with high throughput, minimal dead volume, and greater sensitivity to particle size are needed, which traditional benchtop filtration cannot provide. Leveraging microfabrication techniques developed by the electronics and optics industries, the filters presented here feature a unique serpentine "NanoRidge" structure, offering a continuous filtration gap spanning over three meters on a compact 4 × 14.5 mm2 footprint. This design provides more precise size filtration cut-offs and consistent flow paths compared to traditional membrane filtration systems. Despite challenges associated with glass substrate deformation impacting uniform filter gap sizes, the study provides valuable insights into the development of NanoRidge filters (NRFs) for enhancing filtration efficiency in preparatory techniques and sample analysis. This study describes the fabrication and testing of these new filter types and directly compares the performance to traditional membrane filters using the metrics of particle size cut-off (the smallest difference in particle size which can be filtered vs passed) and particle loss. The NanoRidge filters were characterized using imaging (during fabrication, post-fabrication and use, fluorescent particles captured and small molecule dye), pressure and flow measurements, and a series of particle sizes "filter or pass" studies. Particle capacity (100–250 nm) ranged from 5 × 108 to 7 × 109 in 1 ml samples at a flow rate of 100 μl/min with backpressure in the range of 1–3 Bar. The optimized fabrication procedure for the 150 nm NRF yielded a small particle recovery of 95% while also achieving a large particle filtration of 73%. High filtration efficiency was also proven in the final 60 and 80 nm NRF fabrication procedures at 96% and 91%, respectively. [ABSTRACT FROM AUTHOR]

The growing production and use of plastics significantly contribute to microplastics (MPs) contamination in the environment. Humans are exposed to MPs primarily through the gastrointestinal route, as these particles are present in beverages and food, e.g., sugar. Effective isolation and identification of MPs from food is essential for their elimination. This study aimed to evaluate factors influencing the isolation of MPs from sucrose solutions to determine optimal conditions for the process. Polyethylene particles were used to test separation methods involving chemical digestion with acids and filtration through membrane filters made of nylon, mixed cellulose ester, and cellulose acetate with pore sizes of 0.8 and 10 µm. The effects of temperature and acid type and its concentration on plastic particles were examined using scanning electron microscopy and µ-Raman spectroscopy. The results indicate that increased temperature reduces solution viscosity and sucrose adherence to MPs' particles, while higher acid concentrations accelerate sucrose hydrolysis. The optimal conditions for MPs' isolation were found to be 5% HCl at 70 °C for 5 min, followed by filtration using an efficient membrane system. These conditions ensure a high recovery and fast filtration without altering MPs' surface properties, providing a reliable basis for further analysis of MPs in food. [ABSTRACT FROM AUTHOR]

Isotope data of key pollutants are needed for source apportionment analysis in natural ecosystems. Isotope data for cadmium (Cd), a rare and dispersed but toxic element, are very limited mainly due to its low contents in the natural environment. In this study, for samples with low Cd content but high organic matter content, a dry ashing pre-treatment method was proposed to effectively enrich Cd to meet the requirements of its isotope analysis (Cd content > 20 ng). This method was applied to soils, sediments, biological tissues, and coal, with a maximum digestion weight of 1.67 g or more. With the assistance of quartz microfiber filter membranes during dry ashing, good Cd recovery (91.6--108.0%) and significant removal of organic matter were achieved. Mass bias was corrected by combining the silver external standard (Ag-doping) method with the sample-standard-bracketing (SSB) method, and Cd isotope measurements were performed under wet plasma conditions (with an accuracy of 0.060‰). Cd isotopic compositions obtained by the dry ashing method were compared with those obtained by the high-pressure bomb digestion method, and the differences ranged from -0.056 to 0.076‰, indicating that the dry ashing with wrapped membranes method did not cause any fractionation of Cd during the sample pre-treatment process. Meanwhile, the tolerance of tin (Sn) and zinc (Zn) elements provided a significant advantage under wet plasma conditions over dry plasma conditions without reducing the tolerance of molybdenum (Mo) and zirconium (Zr). The method developed in this study should enhance the application of Cd isotopes in investigating Cd cycling in primary ecosystems and organisms. [ABSTRACT FROM AUTHOR]

Filtration is a procedure for changing raw water into clean water using filtering media. Over time, the quality of the filtration media will decrease, therefore maintenance needs to be carried out. This research develops a decision support system for membrane filter maintenance in portable South Kalimantan peat water treatment solar-powered, using the Fuzzy Inference System (FIS) Takagi-Sugeno-Kang method, which is implemented in a microcontroller system using three input variables, namely turbidity, TDS, and filtration pressure. Based on the tests that have been carried out, the microcontroller system design has provided information on the filter's condition, and the pump actuator can work automatically to determine the appropriate condition of the filter based on changes in the set variable values. The sensors used were tested to determine the accuracy of their readings. Testing the system design compared with MATLAB calculations obtained an accuracy of 96.47%. [ABSTRACT FROM AUTHOR]

Pleated membrane filters are ubiquitous in many industrial filtration systems due to their high surface-area-to-volume ratio. However, their performance often falls short compared to flat non-pleated membrane filters of the same membrane surface area. This raises the question: What is the optimal initial internal pore structure of the membrane to achieve the most efficient filtration? To address this question, we first present a mathematical model describing the feed flow and particle transport within the complex geometry of a pleated filter based on our previous work [Fong and Sanaei, "Flow and transport in a pleated filter," Phys. Fluids 34, 097102 (2022)]. We then analyze the governing equations using asymptotic analysis by exploiting the small aspect ratios of the pleated membrane and filter cartridge. In the second part of the paper, we formulate a computationally efficient optimization problem aimed at determining the optimal initial pore shape to improve filtration performance. Depending on the initial average porosity, substantial differences in the computed optimal pore profile are observed. Furthermore, by varying a geometric parameter in our model, we investigate the influence of the pleat packing density on the optimal initial pore shape. [ABSTRACT FROM AUTHOR]

Water is vital for the sustainable growth of human communities. Due to the greatest population and significant economic development, demands on water and purification have significantly risen. Classical wastewater treatment procedures have made some progress over the years in purifying effluents for disposal, but they fall lacking in the way they deeply control emerging harmful substances. The potential to reuse treated wastewater for home, agricultural, and industrial needs depends on breakthroughs in purifying technologies. One of the most recent breakthroughs to be implemented effectively in reducing contaminants to desirable levels is membrane technology. Nanofiltration, microfiltration, reverse osmosis, ultrafiltration, and membrane bioreactors are examples of widely utilized membrane processes depending on features such as size or charge. Over traditional treatment, membrane technology offers various benefits. This review article discusses a number of membrane‐related topics, including membrane categorizing, application in various fields, benefits, and drawbacks. Furthermore, offers an outlook of the filtering membranes that will be used in the future. Smart membranes have gained interest because of their tunable permeability and selectivity characteristics. Technological advancements in the media that are utilized in activated growth membrane bioreactors. Modified interfacial polymerization approaches have been investigated in addition to adsorptive ultrafiltration mixed matrix membranes to enhance the performance of the polyamide thin‐film composite and thin‐film nanocomposite membranes. [ABSTRACT FROM AUTHOR]

The editorial in "Frontiers in Membrane Science & Technology" discusses the importance of membrane module design in enhancing the efficiency, scalability, and cost-effectiveness of membrane processes used in water treatment, resource recovery, and energy production. The design of membrane modules involves critical parameters such as membrane material, module configurations, surface area-to-volume ratio, and hydrodynamic design to ensure optimal performance and adaptability across various applications. The editorial also highlights the impact of module design on specific membrane processes like nanofiltration, membrane distillation, and membrane bioreactors, emphasizing the need for advances in module designs to achieve sustainable and cost-effective solutions. [Extracted from the article]

A functionalized ethylene–vinyl-alcohol (EVOH) nanofibrous membrane (NFM) was fabricated via co-electrospinning H4SiW12O40 (SiW12) and EVOH first, and then grafting citric acid (CCA) on the electrospun SiW12@EVOH NFM. Characterization with FT-IR, EDX, and XPS confirmed that CCA was introduced to the surface of SiW12@EVOH NFM and the Keggin structure of SiW12 was maintained well in the composite fibers. Due to a number of carboxyl groups introduced by CCA, the as-prepared SiW12@EVOH-CCA NFM can form a high number of hydrogen bonds with CR, and thus can be used to selectively absorb congo red (CR) in aqueous solutions. More importantly, the CR enriched in the NFM can be rapidly degraded via photocatalysis. SiW12 in the NFM acted as a photocatalyst, and the hydroxyl groups in the NFM acted as an electron donor to accelerate the photodegradation rate of CR. Meanwhile, the SiW12@EVOH-CCA NFM was regenerated and then exhibited a relatively stable adsorption capacity in five cycles of filtration–regeneration. The bifunctional nanofibrous membrane filter showed potential for use in the thorough purification of dye wastewater. [ABSTRACT FROM AUTHOR]

In this study, starch was obtained from rice wastes and the maximum extraction yield was 90.95 %. Chemical modification reactions were carried out by hydroxypropylation to obtain a modified starch extract, named 005A, soluble in synthetic injection brine. Extract 005A had a modified starch concentration of 1.24 %, with a pseudoplastic rheological profile and viscosities of 325.54 cP and 121.03 cP at temperatures of 25 and 60 °C, respectively. The application of extract 005A was evaluated by injectivity/filterability tests, which indicated a good filtration rate and viscosity loss of 3.81 % when passing the fluid through the filtering membrane. Stability tests indicated that the 005A extract had a viscosity loss of 21.35 %, at the temperature of 60 °C, after 60 days. The application of this extract enabled additional mineral oil recovery of 12.19 % in simulated core flooding tests. Therefore, the extract of hydroxypropyl starch is a promising viscosifying agent for Enhanced Oil Recovery (EOR) fluids. [ABSTRACT FROM AUTHOR]

The development of high‐performance artificial synaptic neuromorphic devices poses a significant challenge in the creation of biomimetic sensing neural systems that seamlessly integrate both sensory and computational functionalities. In pursuit of this objective, promising bionic opto‐olfactory co‐sensory artificial synapse devices are constructed utilizing the BP‐C/CNT (2D/1D) hybrid filter membrane as the resistive layer. Experimental results demonstrated that the devices seamlessly integrated the light modulation, gas detection, and biological synaptic functions into a single device while addressing the challenge with separating artificial synaptic devices from sensors. These devices offered the following advantages: 1) Simulating visual synapses, they can effectively replicate fundamental synaptic functions under both electrical and optical stimulation. 2) By emulating olfactory synapse responses to specific gases, they can achieve ultra‐low detection limits and rapid identification of ethanol and acetone gases. 3) They enable photo‐olfactory co‐sensing simulations that mimic synaptic function under light‐modulated pulse conditions in distinct gas environments, facilitating the study of synaptic learning rules and Pavlovian responses. This work provides a pioneering approach for exploring highly stable 2D BP‐based optoelectronics and advancing the development of biomimetic neural systems. [ABSTRACT FROM AUTHOR]

The SARS-CoV-2 pandemic resulted in a scale-up of viral genomic surveillance globally. However, the wet lab constraints (economic, infrastructural, and personnel) of translating novel virus variant sequence information to meaningful immunological and structural insights that are valuable for the development of broadly acting countermeasures (especially for emerging and re-emerging viruses) remain a challenge in many resource-limited settings. Here, we describe a workflow that couples wastewater surveillance, high-throughput sequencing, phylogenetics, immuno-informatics, and virus capsid structure modeling for the genotype-to-serotype characterization of uncultivated picornavirus sequences identified in wastewater. Specifically, we analyzed canine picornaviruses (CanPVs), which are uncultivated and yet-to-be-assigned members of the family Picornaviridae that cause systemic infections in canines. We analyzed 118 archived (stored at −20 °C) wastewater (WW) samples representing a population of ~700,000 persons in southwest USA between October 2019 to March 2020 and October 2020 to March 2021. Samples were pooled into 12 two-liter volumes by month, partitioned (into filter-trapped solids [FTSs] and filtrates) using 450 nm membrane filters, and subsequently concentrated to 2 mL (1000×) using 10,000 Da MW cutoff centrifugal filters. The 24 concentrates were subjected to RNA extraction, CanPV complete capsid single-contig RT-PCR, Illumina sequencing, phylogenetics, immuno-informatics, and structure prediction. We detected CanPVs in 58.3% (14/24) of the samples generated 13,824,046 trimmed Illumina reads and 27 CanPV contigs. Phylogenetic and pairwise identity analyses showed eight CanPV genotypes (intragenotype divergence <14%) belonging to four clusters, with intracluster divergence of <20%. Similarity analysis, immuno-informatics, and virus protomer and capsid structure prediction suggested that the four clusters were likely distinct serological types, with predicted cluster-distinguishing B-cell epitopes clustered in the northern and southern rims of the canyon surrounding the 5-fold axis of symmetry. Our approach allows forgenotype-to-serotype characterization of uncultivated picornavirus sequences by coupling phylogenetics, immuno-informatics, and virus capsid structure prediction. This consequently bypasses a major wet lab-associated bottleneck, thereby allowing resource-limited settings to leapfrog from wastewater-sourced genomic data to valuable immunological insights necessary for the development of prophylaxis and other mitigation measures. [ABSTRACT FROM AUTHOR]

Filter membranes are the core components of the solid–liquid separation equipment, and their control over particulate pollutants directly determines the effective operation of the system. The feeding of the balaenid whales, acting as an "oral filter," provides new technical ideas for the design of traditional filter membranes. This study proposes a 3-input, 9-output UNet deep learning framework and applies it to rapid flow field prediction in patterned baleen membranes of balaenid whales during filter feeding, named UNet-BaleenCFD. The datasets are obtained through computational fluid dynamics (CFD) simulations combined with linear interpolation, and the model is validated for the effectiveness against the revised theoretical model. To account for the differences in units and magnitudes of velocity and pressure, dimensionless velocity and pressure values are calculated in the loss function. Compared to the traditional CFD, UNet-BaleenCFD can accelerate by three orders of magnitude. Additionally, the predictions made by UNet-BaleenCFD are in good agreement with the results from CFD, indicating that UNet-BaleenCFD is a promising method for predicting flow fields in filter channels. This study can provide effective theoretical guidance for the development of new filter membranes. [ABSTRACT FROM AUTHOR]

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Electrochemical synthesis of ammonia (NH3) in aqueous electrolyte has long been suffered from poor nitrogen (N2) supply owing to its low solubility and sluggish diffusion kinetics. Therefore, creating a N2 rich microenvironment around catalyst surface may potentially improve the efficiency of nitrogen reduction reaction (NRR). Herein, a delicately designed N2 filtering membrane consisted of polydimethylsiloxane is covered on catalyst surface via superspreading. Because this membrane let the dissolved N2 molecules be accessible to the catalyst but block excess water, the designed N2 rich microenvironment over catalyst leads to an optimized Faradaic efficiency of 39.4% and an NH3 yield rate of 109.2 µg h−1 mg−1, which is superior to those of the most report metal‐based catalysts for electrochemical NRR. This study offers alternative strategy for enhancing NRR performance. [ABSTRACT FROM AUTHOR]

The adhesion of dust particles on the surface of the dust collector tends to cause great resistance to the dust collector and affects the operating efficiency. In order to visualize particles in the filtration process and to grasp the mechanism of particle viscosity and sphericity on filtration performance, a numerical simulation study was conducted to investigate the deposition behavior of particles during filtration, employing FLUENT-EDEM coupling technology. By examining the deposition process, the role of particle characteristics on dust behavior within the entire filtration system was elucidated. The effects of varying particle surface energy and particle sphericity on filtration pressure drop and cake porosity were analyzed. The findings reveal that under the force of the air, particles on the surface of the filter membrane experience compaction, leading to a reduction in the porosity of the formed cake layer. The diminution of porosity serves to impede the air, consequently augmenting the pressure drop across the filtration system and hindering the operational efficacy of the dust collector. As the surface energy of the particles increases, the adhesive forces between particles are intensified, leading to an elevation in the porosity of the cake layer and a subsequent decrease in the pressure drop. When the surface energy of the particles is increased from 0.01 J/m2 to 0.04 J/m2, the porosity experiences a modest increase of only 9.1%, yet the pressure drop is significantly reduced by half, amounting to a decrease of 1594 Pa. Under high particle surface energy, as filtration air velocity increases, particles are compressed, resulting in a decrease in cake porosity and an increase in pressure drop. Concurrently, our findings indicate that as the sphericity of particles increases, their surfaces become increasingly smooth which in turn results in a decreased porosity of the cake layer and, consequently, an elevation in the filtration pressure drop. [ABSTRACT FROM AUTHOR]

Chinese hamster ovary (CHO) cells are among the most common cell lines used for therapeutic protein production. Membrane fouling during bioreactor harvesting is a major limitation for the downstream purification of therapeutic proteins. Host cell proteins (HCP) are the most challenging impurities during downstream purification processes. The present work focuses on identification of HCP foulants during CHO bioreactor harvesting using reverse asymmetrical commercial membrane BioOptimal™ MF‐SL. In order to investigate foulants and fouling behavior during cell clarification, for the first time a novel backwash process was developed to effectively elute almost all the HCP and DNA from the fouled membrane filter. The isoelectric points (pIs) and molecular weights (MWs) of major HCP in the bioreactor harvest and fouled on the membrane were successfully characterized using two‐dimensional gel electrophoresis (2D SDS‐PAGE). In addition, a total of 8 HCP were identified using matrix‐assisted laser desorption/ionization‐mass spectroscopy (MALDI‐MS). The majority of these HCP are enzymes or associated with exosomes, both of which can form submicron‐sized particles which could lead to the plugging of the filters. [ABSTRACT FROM AUTHOR]

• Analyses of river microbiomes have major limitations;. • The method of water sample preparation is important;. • The search for microbiological indicators makes sense;. • Comparing results from different methods is problematic. A common method of preparing water samples for environmental DNA isolation is to vacuum filter the water sample through membrane filters. The aim of research was to test the performance of five methods of preparing river water samples for DNA isolation. DNA was isolated using a commercial kit and next-generation sequencing was performed on an Illumina Miseq platform. Pseudomonas spp. was the dominant bacterial genus in all samples. However, its relative abundance varied between samples. Depending on the volume of water filtered, the eluates yielded 62–63 % (V = 100 mL), 59–63.9 % (V = 50 mL), 17.8–19.4 % (V = 500 mL) of the relative abundance of Pseudomonas sp. In contrast, DNA isolation from the membrane filter (V = 100 mL) yielded 38 % and from the sediment after centrifugation 27 %. Differences were observed for all taxa obtained. The results indicate that even the sample volume used for filtration influences the results obtained from next-generation sequencing. [ABSTRACT FROM AUTHOR]

Proton Exchange Membrane Fuel Cells are a favorite technology for decarbonizing the transportation sector. However, their large-scale democratization is hampered by their high cost compounded by their unsatisfactory lifespan. To anticipate potential degradation while keeping improving performance, it is essential to maintain an acceptable humidity range inside the cells, especially at the membrane level. However, membrane humidity level is not directly measurable, alternative techniques must be considered to recover this key variable. Here, we develop a real-time software sensor of the membrane water content at the fuel cell's heart. We build a model describing the membrane water balance, electrochemical behavior, and species mass balance. We then reduce the model and perform an Adaptive Extended Kalman Filter. We perform sensitivity analyses in both steady-state and transient conditions. We validate the filter on a "Worldwide Harmonized Light Vehicles Test Cycles" test procedure. Finally, we obtain a fast and accurate model-based software sensor. • Real-time capable software sensor for PEMFC membrane water content. • Observer based on membrane model accounting for most of major transport phenomena. • Adaptive Extended Kalman filter applied to differential-algebraic equations. • Sensitivity analysis of membrane water content shows a 5% coefficient of variation.

As the demand for clean water sources increases, it is crucial to identify the best wastewater treatment technology that is cost-effective and energy efficient. Despite their separation performance and durability limitations due to the membrane materials and chemicals used in current production techniques, membranes are useful for recovering water from contaminated water sources. This review focuses on nanocellulose-based membranes that utilize various methods, as biodegradable and inexpensive nanocellulose has been used widely in membrane research in recent years. The research regarding nanocellulose-based membranes is growing widely as incorporating nanocellulose enhances the hydrophilic properties and mechanical strength and increases the membrane adsorption capacities, which is ideal for future commercialization. The material high aspect ratio explains this potential, large specific surface area, good capacity retention, and environmental inertness. In addition to the benefits already described, active sites include chemical moieties that might improve the efficacy of pollutants attaching to surfaces. Besides that, nanocellulose could be chemically modified to increase the surface affinity and reactivity of membranes to remove specific contaminants efficiently. Future research directions for lignocellulosic nanocellulose for wastewater treatment and the difficulties and possibilities of nanocellulose-based membranes in these fields are also discussed. Lastly, the application of nanocelluloses in water treatment with an emphasis on membranes and filters fabricated primarily of nanocellulose. Hence, nanocellulose for these membrane applications provides tremendous potential for the wastewater treatment industry. [ABSTRACT FROM AUTHOR]

Considering the high demand for air quality, the development of biomass-based air filtration membranes with high air filtration efficiency and good stability is an urgent task. In this work, polyvinyl alcohol (PVA), gelatin (GA), and cellulose nanocrystals (CNC) were mixed and prepared into a membrane through an electrospinning method for air filtration. After a hydrophobic modification, the modified PVA/GA/CNC composite membrane showed excellent filtration efficiency for PM2.5 (97.65%) through the internal three-dimensional structure barrier and the electrostatic capture effect of the CNC with a negative charge, as well as a low-pressure drop (only 50 Pa). In addition, the modified PVA/GA/CNC composite membrane had good mechanical properties (maximum tensile fracture rate of 78.3%) and high stability (air filtration efficiency of above 90% after five wash-filter cycles and a high-temperature treatment at 200 °C). It is worth noting that the whole preparation process is completed without organic solvents, putting forward a new strategy for the construction of green air filtration membranes. [ABSTRACT FROM AUTHOR]

Industrial evolution and agricultural expansion, explained by continuing population growth, have rendered enormous problems for the world throughout the past few decades, primarily because of waste generation. To reduce environmental impact and dependence on fossil fuels, scientists have explored replacing synthetic polymers with environmentally friendly and sustainable alternatives in many emergent applications. In this regard, microbial biopolymers have gained special attention. Many biopolymers originating from various strains of bacteria, fungi, and algae have been reported and their possible applications have increased rapidly. This review focuses on the wide range of microbial biopolymers, their characteristics, and factors influencing their production. The present study also describes the environmental applications of microbial biopolymers. The use of these biopolymers is very attractive as a value-added and sustainable approach to wastewater treatment. By acting as adsorbents, coagulants, and flocculants as well as filters in membrane processes, microbial biopolymers shine as promising solutions beyond conventional methods. They can be integrated into various stages of the treatment process, further enhancing the efficiency of wastewater treatment methods. Microbial biopolymer applications in bioremediation and soil stabilization are also reviewed. Several studies have demonstrated the strong potential of biopolymers in soil improvement due to their ability to minimize permeability, eliminate heavy metals, stabilize soil, and limit erosion. Challenges related to scaling up and the downstream processing of microbial biopolymers, as well as its future perspectives in environmental applications, are also discussed. [ABSTRACT FROM AUTHOR]

Membranes on palladium alloy basis with surface modified by nanoparticles with high catalytic activity are useful in deep hydrogen purification and single-stage process of high-purity hydrogen production. This paper reports the development and improvement of methods for synthesis of Pd-based pentatwinned nanoparticles of strictly specified morphology with certain shapes, facets and composition. The competing effect of surfactants and optimization of the halide ions ratio in solution make it possible to direct a particle growth towards formation of pentatwinned Pd-nanostars. Pd–23%Ag coatings synthesized on the surface showed uniquely high peak current density of up to 238 mA cm−2 in alkaline methanol oxidation reaction. This is due to both increased surface area and greater catalytic activity of nanostars' facets. A record increase in hydrogen permeability of up to 12.5 mmol s−1 m−2 at 100 °C has been achieved for palladium-silver membranes with modified surface. This indicates an acceleration of sorption/desorption stages. The developed method for controlling morphology of nanoscale coatings opens the way to the production of membrane hydrogen filters, which operate at room temperature. [Display omitted] • Surface-modified Pd membranes are an excellent tool for high-purity hydrogen production. • Approaches have been developed to manipulate the processes of morphology fine-tuning of Pd nanostars. • Modified Pd–Ag films exhibited high peak current density up to 238 mA cm−2 in methanol electrooxidation. • A record flux density up to 12.5 mmol s−1m−2 at 100 °C has been demonstrated in membrane hydrogen purification process. • Modified membranes open up the possibility of deep hydrogen purification at low temperatures. [ABSTRACT FROM AUTHOR]

DNA extraction yield from drinking water distribution systems and premise plumbing is a key metric for any downstream analysis such as 16S amplicon or metagenomics sequencing. This research aimed to optimize DNA yield from low-biomass (chlorinated) reverse osmosis-produced tap water by evaluating the impact of different factors during the DNA extraction procedure. The factors examined are (1) the impact of membrane materials and their pore sizes; (2) the impact of different cell densities; and (3) an alternative method for enhancing DNA yield via incubation (no nutrient spiking). DNA from a one-liter sampling volume of RO tap water with varying bacterial cell densities was extracted with five different filter membranes (mixed ester cellulose 0.2 µm, polycarbonate 0.2 µm, polyethersulfone 0.2 and 0.1 µm, polyvinylidene fluoride 0.1 µm) for biomass filtration. Our results show that (i) smaller membrane pore size solely did not increase the DNA yield of low-biomass RO tap water; (ii) the DNA yield was proportional to the cell density and substantially dependent on the filter membrane properties (i.e., the membrane materials and their pore sizes); (iii) by using our optimized DNA extraction protocol, we found that polycarbonate filter membrane with 0.2 µm pore size markedly outperformed in terms of quantity (DNA yield) and quality (background level of 16S gene copy number) of recovered microbial DNA; and finally, (iv) for one-liter sampling volume, incubation strategy enhanced the DNA yield and enabled accurate identification of the core members (i.e., Porphyrobacter and Blastomonas as the most abundant indicator taxa) of the bacterial community in low-biomass RO tap water. Importantly, incorporating multiple controls is crucial to distinguish between contaminant/artefactual and true taxa in amplicon sequencing studies of low-biomass RO tap water. [ABSTRACT FROM AUTHOR]

Parmotrema perlatum, a lichen belonging to the family Parmeliaceae, is well known for its culinary benefits and aroma used as a condiment in Indian homes is also known as the "black stone flower" or "kalpasi" in India. This research intends to analyze the antioxidant power of the crude extracts using four pH‐based buffers solubilized proteins/peptides and RP‐HPLC fractions of P. perlatum obtained by purification. The proteins that were extracted from the four different buffers were examined using LC‐MS/MS‐based peptide mass fingerprinting. When compared to the other buffers, the 0.1 M of Tris‐HCl buffer pH 8.0 solubilized proteins/peptides had the strongest antioxidant capacity. The sequential purification of the peptide was carried out by using a 3‐kDa cut‐off membrane filter and semipreparative RP‐HPLC. Additionally, the purified fractions of the peptide's antioxidant activity were assessed, and effects were compared with those of the crude and 3 kDa cut‐‐off membrane filtrates. The peptide fractions were sequenced by LC‐MS/MS, which reveals that fraction 2 from RP‐HPLC with the sequence LSWFMVVAP has shown the highest antioxidant potential in comparison with other fractions which can serve as the potential natural antioxidant drug. Further, fraction 2 also showed antibacterial activity against the selected microorganisms. [ABSTRACT FROM AUTHOR]

With the intensification of global climate problems, electric heating has recently attracted much attention as a clean and low-carbon heating method. Carbon nanotubes (CNTs) are an ideal medium for electric heating applications due to their excellent mechanical, electrical, and thermal properties. The preparation of electrothermal films based on an aqueous CNT dispersion as a raw material is environmentally friendly. However, in the traditional one-step filtration method, the residual excess dispersant and the small aspect ratio of the CNTs in the preparation process limit the performance of electrothermal CNT films. In this paper, we report a two-step filtration method that removes the free dispersant and small CNTs in the first filtration step and obtains denser CNT films by controlling the pores of the filter membrane in the second filtration step. The results suggest that, compared to the CNT1 film obtained from one-step filtration, the CNT1-0.22 film, obtained from two-step filtration using 1 and 0.22 μm membranes, has a smoother and flatter surface, and the surface resistance is 80.0 Ω sq−1, which is 29.4% lower. The convective radiation conversion efficiency of the CNT1-0.22 film is 3.36 mW/°C, which is 36.1% lower. We anticipate that such CNT films could be widely applied in building thermal insulation and underfloor heating. [ABSTRACT FROM AUTHOR]

The highest rate of embolization during carotid artery stenting occurs during post-dilation. We evaluated the ability of the Paladin system (Contego Medical, Raleigh, NC), a novel PTA balloon with an integrated 40-ɥm pore filter, to collect microemboli that may pass into the cerebral circulation when used during post-dilation. 25 symptomatic patients underwent transradial CAS using the Paladin system in conjunction with the Roadsaver (Terumo Corporation, Tokyo, Japan) micromesh stent. No additional embolic protection was used. The Paladin filters were collected following the procedure and preserved in formalin for histological analysis. The contents were evaluated for particle count and size. Subjects were followed for 30 days and evaluated for major cardiac adverse events (death, stroke and MI). Secondary endpoints included procedure success, device success, access site complications according to EASY score classification, major vascular or ischemic complications at follow up and in-stent restenosis rate evaluated with duplex ultrasound. Mean age of patients was 68,5 years. Type 2 aortic arch was present in 77 % of patients and type 1 and type 3 in 12 % and 11 % of patients respectively. Procedural and device success was obtained in all cases without complications. The 30-day MAE rate was 0 %. Twenty-three filters underwent histological analysis. Microscopic debris was present in 100 % of filters, and 75 % of particles were less than 100ɥm in size. The mean number of particles per filter was 3352 ± 1567 (IQR 4300–2343), and the mean number of particles between 40-100ɥm per filter was 2499 ± 1240 (IQR 3227–1575). CAS through radial approach can be safely and effectively performed using the IEP technology Paladin device and double-layer micromesh Roadsaver stent. This strategy can simplify the procedure and decrease peri-procedural complications and procedural time. • Highest rate of embolization during carotid artery stenting occurs during post-dilatation • TRA for CAS offers minimal contact with the aortic arch, reducing the risk of stroke • The Paladin System, further minimizes the risk of cerebral embolization during CAS [ABSTRACT FROM AUTHOR]

Aerosol microbiome studies have received increased attention as technological advancements have made it possible to dive deeper into the microbial diversity. To enhance biomass collection for metagenomic sequencing, long-term sampling is a common strategy. While the impact of prolonged sampling times on microorganisms' culturability and viability is well-established, its effect on nucleic acid stability remains less understood but is essential to ensure representative sample collection. This study evaluated four air samplers (SKC BioSampler, SASS3100, Coriolis μ, BioSpot-VIVAS 300-P) against a reference sampler (isopore membrane filters) to identify nucleic acid stability during long-term sampling. Physical sampling efficiencies determined with a fluorescent tracer for three particle sizes (0.8, 1, and 3 μm), revealed high efficiencies (> 80% relative to reference) for BioSampler, SASS3100, and BioSpot-VIVAS for all particle sizes, and for Coriolis with 3 μm particles. Coriolis exhibited lower efficiency for 0.8 μm (7%) and 1 μm (50%) particles. During 2-h sampling with MS2 and Pantoea agglomerans, liquid-based collection with Coriolis and BioSampler showed a decrease in nucleic acid yields for all test conditions. BioSpot-VIVAS displayed reduced sampling efficiency for P. agglomerans compared to MS2 and the other air samplers, while filter-based collection with SASS3100 and isopore membrane filters, showed indications of DNA degradation for 1 μm particles of P. agglomerans after long-term sampling. These findings show that long-term air sampling affects nucleic acid stability in both liquid- and filter-based collection methods. These results highlight bias produced by bioaerosol collection and should be considered when selecting an air sampler and interpreting aerosol microbiome data. [ABSTRACT FROM AUTHOR]

INTRODUCTION: The absence of a consistent downward G vector can make separation of gases from liquids challenging, such as in field medicine without stable upright equipment or during spaceflight. This limits the use of medical equipment and procedures like administration of intravenous (IV) fluids in microgravity and can make field medicine hazardous. Administering IV fluids and medications in microgravity requires a technique to separate air from the liquid phase. Current commercial filters for separation of gases are incompatible with high flow and blood. We present a novel filter designed to provide adequate air clearance without a consistent downward G vector. METHODS: I nline air-eliminating filters were designed for use with IV fluid tubing in microgravity using computer-aided design software and printed using nylon 12 on an EOS Selective Laser Sintering 3D printer. A 0.2-μm membrane filter was adhered around a central, hollow pillar with external spiral baffles allowing separation and venting of air from the fluid. Results were compared against commercially available inline air-eliminating filters. RESULTS: The 3D-printed filters outperformed the commercial filters in both percentage of air removed and flow rates. The centrifugal, baffled filter had flow rates that far exceeded the commercial filters during rapid transfusion. DISCUSSION: I V fluid administration is an often underappreciated and a necessary basic requirement for medical treatment. An air-eliminating filter compatible with blood and rapid transfusion was developed and validated with crystalloid solutions to allow the successful administration of IV fluid and medication without a consistent downward G vector. [ABSTRACT FROM AUTHOR]

A recent study published in the American Journal of Respiratory & Critical Care Medicine investigated the presence of nanoplastics in the human respiratory system. The study found that nanoplastics, specifically polyethylene (PE) and polypropylene (PP), were detected in the bronchoalveolar lavage fluid (BALF) of participants with respiratory diseases. The concentrations of PE and PP in the BALF samples were significantly higher than those in control samples. This study provides important insights into the presence of nanoplastics in the lower respiratory tract and highlights the need for further research on the potential adverse effects of nanoplastics on human health. [Extracted from the article]