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The dynamics of a homogeneous adiabatic autoignition of an ammonia/air mixture at constant volume was studied, using the algorithmic tools of Computational Singular Perturbation. Since ammonia combustion is characterized by both unrealistically long ignition delays and elevated NO x emissions, the time frame of action of the modes that are responsible for ignition was analyzed by calculating the developing time scales throughout the process and by studying their possible relation to NO x emissions. The reactions that support or oppose the explosive time scale were identified, along with the variables that are related the most to the dynamics that drive the system to an explosion. It is shown that reaction H 2 O 2 (+M) → OH + OH (+M) is the one contributing the most to the time scale that characterizes ignition and that its reactant H 2 O 2 is the species related the most to this time scale. These findings suggested that addition of H 2 O 2 in the initial mixture will influence strongly the evolution of the process. It was shown that ignition of pure ammonia advanced as a slow thermal explosion with very limited chemical runaway. The ignition delay could be reduced by more than two orders of magnitude through H 2 O 2 addition, which causes only a minor increase in NO x emissions.

Natural gas is well-suited as a fuel in the transport sector. Due to its excellent combustion characteristics, engines operating with compressed natural gas (CNG) reach high efficiency, especially if operated at lean conditions. However, CNG engine research mainly focusses on stoichiometric conditions in order to use a three-way catalytic converter for the exhaust gas after treatment system. With the objective to explore the potential of CNG engines operated at lean conditions, a turbo-charged CNG engine with high com-pression ratio is developed and optimized for lean operation. In order to increase the ignition energy, the CNG engine is equipped with scavenged pre-chambers. A specific control structure is developed, which allows to operate the engine at a pre-defined (lean) air-to-fuel ratio. Further functionalities such as the combustion placement control and algorithms to estimate the conditions inside of the pre-chamber are implemented. The first part of this paper describes this engine control structure, which is specifically developed for the lean-burn CNG engine. In the second part, the effects of pre-chamber scavenging on engine performance criteria such as the combustion stability, engine efficiency or engine emissions are analyzed. With the objective to use pre-chamber scavenging to improve engine performance, a scavenging feed-back control strategy is proposed. In order to control the ignition delay, this strategy adapts the amount of CNG injected into the pre-chamber with a linear controller or an extremum seeking algorithm depending on the air-to-fuel ratio of the main chamber.

Natural gas is well-suited as a fuel in the transport sector. Due to its excellent combustion characteristics, engines operating with compressed natural gas (CNG) reach high efficiency, especially if operated at lean conditions. However, CNG engine research mainly focusses on stoichiometric conditions in order to use a three-way catalytic converter for the exhaust gas after treatment system. With the objective to explore the potential of CNG engines operated at lean conditions, a turbo-charged CNG engine with high compression ratio is developed and optimized for lean operation. In order to increase the ignition energy, the CNG engine is equipped with scavenged pre-chambers. A specific control structure is developed, which allows to operate the engine at a pre-defined (lean) air-to-fuel ratio. Further functionalities such as the combustion placement control and algorithms to estimate the conditions inside of the prechamber are implemented. The first part of this paper describes this engine control structure, which is specifically developed for the lean-burn CNG engine. In the second part, the effects of pre-chamber scavenging on engine performance criteria such as the combustion stability, engine efficiency or engine emissions are analyzed. With the objective to use pre-chamber scavenging to improve engine performance, a scavenging feedback control strategy is proposed. In order to control the ignition delay, this strategy adapts the amount of CNG injected into the prechamber with a linear controller or an extremum seeking algorithm depending on the air-to-fuel ratio of the main chamber., Combustion Engines, 176 (1)