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2-aminopiridin-3-ol je organska heterociklična molekula z molekulsko formulo C5H6N2O. V molekuli sta dva dušikova in en kisikov atom, zato se molekula, njen anion ali kation, lahko koordinirajo na centralni atom ali ion v kompleksnih spojinah. Pregledali smo strukture v bazi podatkov CSD in ugotovili, da ni podatkov za komplekse prehodnih kovin z 2-aminopiridin-3-olom. Našli smo le strukturo renijevega kompleksa z deprotonirano obliko 2-aminopiridin-3-ola, 2-amino-3-oksipiridinom. V ostalih spojinah je 2-aminopiridin-3-ol protoniran in 2-amino-3-hidroksipiridinijev ion tvori soli s kompleksnimi anioni prehodnih kovin. Za primerjavo so prikazane še strukture kompleksov kobaltovega klorida s hidroksipiridini: 3-hidroksipiridin-2-onom, 3-hidroksipiridinom in 2-hidroksipiridinom. Našteti hidroksipiridini se lahko vežejo na centralni ion v kompleksih na podoben način kot pričakujemo za 2-aminopiridin-3-ol. Podobno kot 2-aminopiridin-3-ol tudi ti ligandi tvorijo vodikove vezi, ki stabilizirajo strukture spojin. 2-aminopyridin-3-ol is an organic heterocyclic compound with molecular formula C5H6N2O. In molecule there are two N- and one O-donor atoms, therefore molecule, its anion or cation could coordinate to a central atom or ion in complexes. We examined the structures in the CSD database and found that there are no data of transition metal complexes with 2-aminopyridin3-ol. We found only the structure of a rhenium complex with the deprotonated form of 2-aminopyridin-3-ol, 2-amino-3-oxypyridine. In other compounds 2-aminopyridin-3-ol is protonated and 2-amino-3-hydroxypyridinium ion forms salts with complex anions of transition metals. For comparison, other structures of cobalt chloride with hydroxypyridines: 3-hydroxypyridine, 3-hxydroxypyridin-2-one and 2-hydroxypyridine are shown. The listed hydroxypyridines can bind to a central atom or ion in the complexes in a similar way as expected for 2-aminopyridin-3-ol. Similar to 2-aminopyridin-3-ol, these ligands form hydrogen bonds, which stabilise the structures of the compounds.

Svoje magistrsko delo sem razdelila na eksperimentalni in pedagoški del. V eksperimentalnem delu sem pripravila različne koordinacijske spojine bakra(II) s kinaldinatom. Moj cilj je bil, da bi spojine poleg kinaldinata vsebovale še sekundarni piridinski ligand: 4-hidroksipiridin, 3-hidroksipiridin ali 3-hidroksimetilpiridin. V pedagoškem delu sem predstavila učno uro z eksperimentalnim delom, vzgojo kristalov bakrovega(II) acetata hidrata. Na začetku učne ure so učenci ponovili učno snov o kristalih. Učno uro sem umestila v učni načrt kemije za osnovno šolo. Priložen je tudi delovni list za učitelja in učenca. I divided my master's thesis into experimental and pedagogical work. In the experimental work, I prepared various coordination compounds of copper(II) with quinaldinate. Main goal was that the complexes contained in addition to quinaldinate also a secondary pyiridine ligand:4-hydroxypyridine, 3-hydroxypyridine or 3-hydroxymethylpyridine. In the pedagogical work, I introduced a teaching lesson which included experimental work on the preparation of large crystals of copper(II) acetate hydrate. At the beginning of the lesson, the pupils reiterated the learning material about the crystals. The lesson is incorporated into a chemistry curriculum for elementary school. A worksheet for the teacher, as well as for the student is attached.