1. Calcium hydroxide, magnesium hydroxide, silicon dioxide nanoparticles and their combinations as consolidants for lime mortars and gypsum plasters.
- Author
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Martínez-Arredondo, Ana, García-Vera, Victoria E., Navarro-Moreno, David, Tenza-Abril, Antonio J., and Lanzón, Marcos
- Subjects
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MAGNESIUM hydroxide , *CALCIUM hydroxide , *SILICA , *WATER vapor , *X-ray diffraction - Abstract
• Single and dual nanoparticle-based treatments are used for preserving materials. • Hardness and erosion properties were improved using these nanoparticles (NPs). • A new C-S-H cementing gel is formed when Ca(OH)2/SiO2 NPs are combined. • The NPs did not significantly alter water vapour permeability. • ΔE was suitable in all cases (0.40–3.79), except for Ca-NPS (5.10). This paper studies the effectiveness of four consolidation treatments based on nanoparticles suspensions: calcium hydroxide (Ca-NP), magnesium hydroxide (Mg-NP), a treatment combining calcium hydroxide and magnesium hydroxide (Ca/Mg-NP), and a treatment consisting of calcium hydroxide and silicon dioxide (Ca/Si-NP) that were both applied separately. The suspensions were sprayed on gypsum plasters and lime renders which are common substrates in historical constructions and show a high degree of similarity with the treatments. The consolidation efficiency was evaluated using non-destructive techniques, such as peeling test, Shore-D hardness, water flow using Karsten tube and water vapour permeability tests. In addition, TEM images and XRD tests demonstrated the formation of a new C-S-H cementing phase when Ca/Si-NPs were combined due to a reaction between Ca(OH) 2 with SiO 2. Colour tests (CIE-L*a*b*) showed the consolidants did not produce major colour alterations, although the Ca-NP treatment caused a slight lightness increase. The strengthening effect was greater in lime mortars and water flow was moderately reduced in all treatments, except in mortars coated with Ca/Mg-NP. Finally, the chemical nature of the treatments is similar to the substrates, and they did not significantly alter the water vapour permeability of the studied materials. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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