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Geologic features (e.g., fractures and alluvial fans) can play an important role in the locations and volumes of groundwater discharge and degree of groundwater-surface water (GW-SW) interactions. However, the role of these features in controlling GW-SW dynamics and streamflow generation processes are not well constrained. GW-SW interactions and streamflow generation processes are further complicated by variability in precipitation inputs from summer and fall monsoon rains, as well as declines in snowpack and changing melt dynamics driven by warming temperatures. Using high spatial and temporal resolution radon and water stable isotope sampling and a 1D groundwater flux model, we evaluated how groundwater contributions and GW-SW interactions varied along a stream reach impacted by fractures (fractured-zone) and downstream of the fractured hillslope (non-fractured zone) in Coal Creek, a Colorado River headwater stream affected by summer monsoons. During early summer, groundwater contributions from the fractured zone were high, but declined throughout the summer. Groundwater contributions from the non-fractured zone were constant throughout the summer and became proportionally more important later in the summer. We hypothesize that groundwater in the non-fractured zone is dominantly sourced from a high-storage alluvial fan at the base of a tributary that is connected to Coal Creek throughout the summer and provides consistent groundwater influx. Water isotope data revealed that Coal Creek responds quickly to incoming precipitation early in the summer, and summer precipitation becomes more important for streamflow generation later in the summer. We quantified the change in catchment dynamic storage and found it negatively related to stream water isotope values, and positively related to modeled groundwater discharge and the ratio of fractured zone to non-fractured zone groundwater. We interpret these relationships as declining hydrologic connectivity throughout the summer leading to late summer streamflow supported predominantly by shallow flow paths, with variable response to drying from geologic features based on their storage. As groundwater becomes more important for sustaining summer flows, quantifying local geologic controls on groundwater inputs and their response to variable moisture conditions may become critical for accurate predictions of streamflow.

Groundwater sustains human well-being and ecosystems functioning. Many regions in Europe have experienced declining groundwater levels caused by decreasing groundwater recharge (GWR) or increasing groundwater abstractions (GWAs). These changes can lead to groundwater-related stress, threatening ecosystems and water supplies. Existing groundwater stress indicators estimate stress during a given period but do not address how stress changes or show the uncertainty of future stress. We propose a novel indicator of future groundwater stress (GWSI) due to changes in GWR and GWA and, thus, the alteration of long-term mean annual groundwater discharge (GWD). Groundwater stress is defined as any alteration in GWD since ecosystems are adapted to an equilibrium state. Focusing on decreasing GWD, which is generally more harmful than increasing GWD, we quantified the future GWSI in Europe by integrating scenarios of GWR and GWA in 2070–2099. GWR was evaluated using an ISIMIP2b multi-model ensemble of eight global hydrological models driven by the output of four global climate models under two greenhouse gas emission scenarios. GWA scenarios for irrigation, domestic and manufacturing sectors were combined with the GWR projections to generate an ensemble of GWSIs, simplified into three groundwater stress scenarios (high, intermediate, low). Projected GWSIs vary significantly among the scenarios. For the high-stress scenario, 58% of Europe's land area is projected to experience a GWD decrease of at least 25% under RCP8.5 compared to 38% under RCP2.6, while the respective values are 26 and 1% for the intermediate-stress scenario. Groundwater demand management alone might not prevent GWD declines under the high-stress and intermediate scenarios, particularly under RCP8.5. Therefore, climate change mitigation might imperative for reducing the decline of GWD, especially in Eastern and Southeastern Europe, where changes in GWR are projected to be the primary cause of declining GWD (in the high abstraction scenario under RCP8.5). Under RCP2.6, reductions in GWAs by 25–75% might balance a GWD decline in parts of Spain and Italy where GWAs are high, even in the high-stress scenario. In line with the precautionary principle, we recommend adapting to the high-stress scenario to minimize harm to the beneficiaries of groundwater. [ABSTRACT FROM AUTHOR]

Here, we explore the dynamic interplay of climate, tectonic forces and human impacts, that have shaped the current hydrology of the 27 main endorheic continental playa-lakes in southern Spain, most of them protected as Natural Reserves. This research offers a thorough examination of the hydro-geomorphic, geochemical, and tectonic characteristics that influenced the development of these wetlands. We introduce and apply several hydro-morphological indices that effectively characterize the hydrological functioning of these wetlands. Importantly, the examination of the geological setting and analysis of recent tectonics has been found to be effective in reconstructing the evolution of some of the major playa-lakes, including Fuente de Piedra playa-lake and El Gosque playa-lake. Lastly, the analysis of satellite information using the online tool water occurrence change intensity (WOCI) of Surface Water Explorer in the studied playa-lakes was found to be inconsistent in the long-term analysis. Enhanced attention is required to refine the WOCI tool, thereby ensuring a more precise depiction of wetland dynamics in the Mediterranean. Fine-tuning will better represent complex behaviors, thus improving its utility for monitoring and managing wetlands in the region. [ABSTRACT FROM AUTHOR]

Since the mid-1970s, groundwater resources in Bermuda have been explored to supplement growing potable water demand on the island. Much of this work has focused on modeling the shape and size of freshwater lenses beneath the island's surface, mainly the Devonshire Lens. Less attention has been paid to how these freshwater lenses interact with surrounding coastal seawater, a process that may grow in importance as sea levels rise. Due to isotopic differences between aquifer water and seawater, these interactions can be tracked using the oxygen isotopic composition of water (δ18Ow) samples collected from coastal and subterranean areas. A pilot study found more temporal variation in coastal seawater δ18Ow along Bermuda's South Shore (the section of the coast closest to the Devonshire Lens) compared to elsewhere around the island and suggested that freshwater was discharging into coastal seawater fromthe Devonshire Lens in significant quantities. However, this study was limited by its small dataset so could not quantify the full spatial and temporal variability of δ18Ow in this area. Here, we present salinity and δ18Ow measurements from seawater samples collected around Bermuda and in wells tapping the Devonshire Lens on timescales ranging from hourly to monthly to better visualize the dynamic interaction between coastal seawater and aquifersourced freshwater. We find tight correlation between salinity and δ18Ow in well waters, indicating a simple linear mixing relationship between seawater and aquifer water in the subsurface. We confirm previous findings of larger variability in δ18Ow along the South Shore compared to elsewhere and relate observed changes to tidal height on hourly to monthly timescales. Surprisingly, South Shore seawater salinity does not vary in accordance with δ18Ow, implying additional mechanisms, such as the addition of salt spray, must be acting to mute salinity changes. These findings also demonstrate the potential in using δ18Ow to study submarine groundwater discharge, as salinity measurements alone did not detect as much variability. As sea levels rise and interactions between ocean and aquifer waters change, coastal and well water δ18Ow measurements may be helpful in tracking these processes, and in particular, changes in aquifer size. [ABSTRACT FROM AUTHOR]

Objective To assess contribution and seasonal variation in groundwater discharge (LGD) to lake water and nutrient budgets, Methods this study investigated Changhu Lake in the middle reaches of the Yangtze River. Field sampling was conducted during both the wet and dry seasons using multiple tracing techniques, including electrical conductivity (EC), stable isotope (2H and 18O), hydrochemical element (Ca2+ and Mg2+), and 222Rn isotope data. The 222Rn mass balance model was employed to quantify the LGD and associated nutrient fluxes in different seasons. Results Results show that LGD rates during the wet and dry seasons were 64.52 mm/d and 14.95 mm/d, respectively, with significant differences between these seasons. Furthermore, during the wet and dry seasons, groundwater carried TN inputs of approximately 25.68×106 g/d and 5.58×106 g/d, respectively. The TP inputs were approximately 8.14×106 g/d and 0.17×106 g/d in the wet and dry seasons, respectively. The differences in the LGD rates between the wet and dry seasons lead to differences in groundwater carrying TN and TP inputs, and inputs of TP during the wet season is also influenced by agricultural activities during that period. Sronger precipitation and evaporation during the wet season drive greater LGD intensity and their carrying TN and TP fluxes. Conclusion The research can provide scientific reference for water resource management and aquatic ecosystem preservation efforts in the Changhu area.

The deep transboundary aquifer of regional scale along the Czech Republic–Austria border in Central Europe serves as a thermal-mineral water resource for balneotherapy and plays an important role in the region's development. The aquifer is composed mostly of Jurassic carbonates at depths from 160 to − 3000 masl. Despite more than two decades of exploitation, no complex analysis of groundwater flow directions and groundwater fluxes ever took place. Now, cross-border cooperation enabled the research team to gather crucial information on the Jurassic aquifer. For a better understanding of the groundwater flow system, a numerical model was developed. To simulate the effect of variable density and viscosity occurring in such a deep aquifer, the SEAWAT numerical model was used. The simulation shows that there is an inflow of low mineralised groundwater from the crystalline outcrops in the northwest and inflow of saline groundwater from southeast. Aquifer discharge was identified along the zone partly corresponding to the course of the Dyje River. To check the model's accuracy, the river water was sampled together with streamflow measurements. Detected sections of increasing chloride concentration indicate zones of the Jurassic aquifer discharge into the Dyje River. The discharge rate of 85 L/s derived from streamflow and chloride concentrations matches the value computed by the model. The relatively high discharge of the Jurassic aquifer contributes significantly to the high chloride loading observed in the Dyje River. [ABSTRACT FROM AUTHOR]

Seasonally frozen ground (SFG) is a significant component of the cryosphere, and its extent is gradually increasing due to climate change. The hydrological influence of SFG is complex and varies under different climatic and physiographic conditions. The summer rainfall dominant climate pattern in Qinghai Lake Basin (QLB) leads to a significantly different seasonal freeze–thaw process and groundwater flow compared to regions with winter snowfall dominated precipitation. The seasonal hydrological processes in QLB are not fully understood due to the lack of soil temperature and groundwater observation data. A coupled surface and subsurface thermal hydrology model was applied to simulate the freeze–thaw process of SFG and groundwater flow in the QLB. The results indicate that SFG begins to freeze in early November, reaches a maximum freezing depth of approximately 2 meters in late March, and thaws completely by June. This freeze–thaw process is primarily governed by the daily air temperature variations. During the early rainy season from April to June, the remaining SFG in deep soil hinders the majority of rainwater infiltration, resulting in a two-month delay in the peak of groundwater discharge compared to scenario with no SFG present. Colder conditions intensify this effect, delaying peak discharge by 3 months, whereas warmer conditions reduce the lag to 1 month. The ice saturation distribution along the hillslope is affected by topography, with a 10 cm deeper ice saturation distribution and 3 days delay of groundwater discharge in the steep case compared to the flat case. These findings highlight the importance of the freeze–thaw process of SFG on hydrological processes in regions dominated by summer rainfall, providing valuable insights into the hydro-ecological response. Enhanced understanding of these dynamics may improve water resource management strategies and support future research into climate-hydrology interactions in SFG-dominated landscapes.

Groundwater sustains human well-being and ecosystems functioning. Many regions in Europe have experienced declining groundwater levels caused by decreasing groundwater recharge (GWR) or increasing groundwater abstractions (GWAs). These changes can lead to groundwater-related stress, threatening ecosystems and water supplies. Existing groundwater stress indicators estimate stress during a given period but do not address how stress changes or show the uncertainty of future stress. We propose a novel indicator of future groundwater stress (GWSI) due to changes in GWR and GWA and, thus, the alteration of long-term mean annual groundwater discharge (GWD). Groundwater stress is defined as any alteration in GWD since ecosystems are adapted to an equilibrium state. Focusing on decreasing GWD, which is generally more harmful than increasing GWD, we quantified the future GWSI in Europe by integrating scenarios of GWR and GWA in 2070–2099. GWR was evaluated using an ISIMIP2b multi-model ensemble of eight global hydrological models driven by the output of four global climate models under two greenhouse gas emission scenarios. GWA scenarios for irrigation, domestic and manufacturing sectors were combined with the GWR projections to generate an ensemble of GWSIs, simplified into three groundwater stress scenarios (high, intermediate, low). Projected GWSIs vary significantly among the scenarios. For the high-stress scenario, 58% of Europe’s land area is projected to experience a GWD decrease of at least 25% under RCP8.5 compared to 38% under RCP2.6, while the respective values are 26 and 1% for the intermediate-stress scenario. Groundwater demand management alone might not prevent GWD declines under the high-stress and intermediate scenarios, particularly under RCP8.5. Therefore, climate change mitigation might imperative for reducing the decline of GWD, especially in Eastern and Southeastern Europe, where changes in GWR are projected to be the primary cause of declining GWD (in the high abstraction scenario under RCP8.5). Under RCP2.6, reductions in GWAs by 25–75% might balance a GWD decline in parts of Spain and Italy where GWAs are high, even in the high-stress scenario. In line with the precautionary principle, we recommend adapting to the high-stress scenario to minimize harm to the beneficiaries of groundwater.

Since the mid-1970s, groundwater resources in Bermuda have been explored to supplement growing potable water demand on the island. Much of this work has focused on modeling the shape and size of freshwater lenses beneath the island’s surface, mainly the Devonshire Lens. Less attention has been paid to how these freshwater lenses interact with surrounding coastal seawater, a process that may grow in importance as sea levels rise. Due to isotopic differences between aquifer water and seawater, these interactions can be tracked using the oxygen isotopic composition of water (δ18Ow) samples collected from coastal and subterranean areas. A pilot study found more temporal variation in coastal seawater δ18Ow along Bermuda’s South Shore (the section of the coast closest to the Devonshire Lens) compared to elsewhere around the island and suggested that freshwater was discharging into coastal seawater from the Devonshire Lens in significant quantities. However, this study was limited by its small dataset so could not quantify the full spatial and temporal variability of δ18Ow in this area. Here, we present salinity and δ18Ow measurements from seawater samples collected around Bermuda and in wells tapping the Devonshire Lens on timescales ranging from hourly to monthly to better visualize the dynamic interaction between coastal seawater and aquifer-sourced freshwater. We find tight correlation between salinity and δ18Ow in well waters, indicating a simple linear mixing relationship between seawater and aquifer water in the subsurface. We confirm previous findings of larger variability in δ18Ow along the South Shore compared to elsewhere and relate observed changes to tidal height on hourly to monthly timescales. Surprisingly, South Shore seawater salinity does not vary in accordance with δ18Ow, implying additional mechanisms, such as the addition of salt spray, must be acting to mute salinity changes. These findings also demonstrate the potential in using δ18Ow to study submarine groundwater discharge, as salinity measurements alone did not detect as much variability. As sea levels rise and interactions between ocean and aquifer waters change, coastal and well water δ18Ow measurements may be helpful in tracking these processes, and in particular, changes in aquifer size.

Study region: Dongting Lake (DTL), the second largest freshwater lake in China, plays a crucial role in regulating and storing water within the Yangtze River Basin.Study focus: The study utilized the water balance method to extensively investigate the exchange volume of groundwater and DTL from 2003 to 2020. Furthermore, we analyzed the impact of climate change and human activities on the interaction between groundwater and DTL.New hydrological insights for the region: Unlike previous studies, our study further included the ungauged runoff, providing a more comprehensive assessment of the water balance of DTL. From May to July, groundwater recharge from DTL, with an average monthly recharge of 0.71 km³. Conversely, groundwater discharges into DTL from August to April of the following year, with an average monthly discharge of 1.12 km³. The net groundwater discharge into the lake from 2003 to 2020 amounts to 7.98 km³/yr. Intriguingly, precipitation over the lake contributes a mere 0.6% to the total inflow, while lake evapotranspiration constitutes only 0.4% of the total outflow. Inflow runoff and outflow runoff play a leading role in the water balance of DTL, significantly influencing the exchange capacity between the lake and groundwater. Groundwater discharge into the lake serves as compensation for diminished runoff stemming from extreme climate occurrences, like droughts, and anthropogenic actions such as dam construction.

The study of groundwater–surface water interaction has attracted growing interest among researchers in recent years due to its wide range of implications from the perspectives of water management, ecology and contamination. Many of the studies shed light on conditions on a local scale only, without exploring a regional angle. To provide a broad and historical overview of groundwater–surface water interaction, a review of research carried out in Denmark was undertaken due to the high density of studies conducted in the country. The extent to which this topic has been investigated is related to Denmark's physiography and climate, the presence of numerous streams and lakes combined with shallow groundwater, and historical, funding, and administrative decisions. Study topics comprise groundwater detection techniques, numerical modeling, and contaminant issues including nutrients, ranging from point studies all the way to studies at national scale. The increase in studies in recent decades corresponds with the need to maintain the good status of groundwater‐dependent ecosystems and protect groundwater resources. This review of three decades of research revealed that problems such as the difference in scales between numerical models and field observations, interdisciplinary research integrating hydrological and biological methods, and the effect of local processes in regional systems remain persistent challenges. Technical progress in the use of unmanned aerial vehicles, distributed temperature sensing, and new cost‐effective methods for detecting groundwater discharge as well as the increasing computing capacity of numerical models emerge as opportunities for dealing with complex natural systems that are subject to modifications in future triggered by climate change. This article is categorized under:Science of Water > Hydrological ProcessesScience of Water > Water and Environmental ChangeWater and Life > Nature of Freshwater Ecosystems [ABSTRACT FROM AUTHOR]

This study reviews the available and published knowledge of the interactions between permafrost and groundwater. In its content, the paper focuses mainly on groundwater recharge and discharge in the Arctic and the Qinghai-Tibet Plateau. The study revealed that the geochemical composition of groundwater is site-specific and varies significantly within the depth of the aquifers reflecting the water-rock interactions and related geological history. All reviewed studies clearly indicated that the permafrost thaw causes an increase in groundwater discharge on land. Furthermore, progressing climate warming is likely to accelerate permafrost degradation and thus enhance hydrological connectivity due to increased subpermafrost groundwater flow through talik channels and higher suprapermafrost groundwater flow. In the case of submarine groundwater discharge (SGD), permafrost thaw can either reinforce or reduce SGD, depending on how much pressure changes affecting the aquifers will be caused by the loss of permafrost. Finally, this comprehensive assessment allowed also for identifying the lack of long-term and interdisciplinary in situ measurements that could be used in sophisticated computational simulations characterizing the current status and predicting groundwater flow and permafrost dynamics in the future warmer climate.

While it is recognized that groundwater contaminant plumes can impact surface waters, there remains little information on the magnitude, spatial extent, and especially temporal variability of the resulting exposure to the variety of aquatic organisms, particularly for stagnant surface waters (e.g., ponds). The present study of a historic landfill plume discharging to a pond investigated contaminant exposure to multiple aquatic zones (endobenthic, epibenthic, pelagic) over approximately 1 year within a temperate climate. Landfill tracers included the artificial sweetener saccharin, ammonium, chloride, and specific conductance. Sampling of pond sediment porewater (upwelling groundwater) and continuous geophysical imaging of the subsurface showed a relatively stable plume footprint covering approximately 26% of the pond, although with spatially varying leachate composition, revealing year‐round exposure to endobenthic (within sediments) organisms. Substantial and variable contaminant exposure to epibenthic organisms within the plume footprint was shown by elevated specific conductance measured directly above the sediment interface. Exposure varied daily at times and increased through winter to values representing undiluted plume groundwater. Exposure to pelagic organisms (overlying water) covered a larger area (~50%) due to in‐pond circulation. The stream outlet concentrations were stable at approximately 10 times dilution for chloride and saccharin, but were substantially less in summer for ammonium due to in‐pond processes. Whereas groundwater contaminants are typically assumed elevated at base flows, the outlet stream contaminant mass discharges to downstream receptors were notably higher in winter than summer, following stream flow patterns. Insights from the present study into the timings and locations of contaminant plume exposure to multiple ecological zones of a pond can provide guidance to contaminated site and aquatic ecosystem managers on improved monitoring, assessment, and remediation protocols. Environ Toxicol Chem 2023;42:1667–1684. © 2023 His Majesty the King in Right of Canada and The Authors. Environmental Toxicology and Chemistry published by Wiley Periodicals LLC on behalf of SETAC. Reproduced with the permission of the Minister of Environment and Climate Change Canada. [ABSTRACT FROM AUTHOR]

Riverbank groundwater discharge faces are spatially extensive areas of preferential seepage that are exposed to air at low river flow. Some conceptual hydrologic models indicate discharge faces represent the spatial convergence of highly variable age and length groundwater flowpaths, while others indicate greater consistency in source groundwater characteristics. Our detailed field investigation of preferential discharge points nested across mainstem riverbank discharge faces was accomplished by: (1) leveraging new temperature‐based recursive estimation (extended Kalman Filter) modelling methodology to evaluate seasonal, diurnal, and event‐driven groundwater flux patterns, (2) developing a multi‐parameter toolkit based on readily measured attributes to classify the general source groundwater flowpath depth and flowpath length scale, and, (3) assessing whether preferential flow points across discharge faces tend to represent common or convergent groundwater sources. Five major groundwater discharge faces were mapped along the Farmington River, CT, United States using thermal infrared imagery. We then installed vertical temperature profilers directly into 39 preferential discharge points for 4.5 months to track vertical discharge flux patterns. Monthly water chemistry was also collected at the discharge points along with one spatial synoptic of stable isotopes of water and dissolved radon gas. We found pervasive evidence of shallow groundwater sources at the upstream discharge faces along a wide valley section with deep bedrock, as primarily evidenced by pronounced diurnal discharge flux patterns. Discharge flux seasonal trends and bank storage transitions during large river flow events provided further indication of shallow, local sources. In contrast, downstream discharge faces associated with near surface cross cutting bedrock exhibited deep and regional source flowpath characteristics such as more stable discharge patterns and temperatures. However, many neighbouring points across discharge faces had similar discharge flux patterns that differed in chloride and radon concentrations, indicating the additional effects of localized flowpath heterogeneity overprinting on larger scale flowpath characteristics. [ABSTRACT FROM AUTHOR]

Qazvin plain is one of the areas in the country facing a severe shortage of water. In recent years, after the reduction of water allocation to this plain from Taleghan Dam, farmers have been digging illegal wells or over-harvesting existing wells in order to maintain their livelihoods. This has adverse effects, including severe depletion of wells, drying of aqueducts, salinity and degradation of groundwater quality, reduced yield of agricultural products, loss of soil quality, imposition of high costs on well owners, creating a major supply problem. Drinking water in cities and villages and eventually land subsidence (Qazvin Regional Water Authority, 2014). Studies show that the cultivation pattern in the last ten years has been almost constant and included wheat products, forage corn, canola, tomato, alfalfa, barley, sugar beet, peas, beans, potatoes, corn and lentils (Simiari and Mazandaranizadeh, 2017).Studies have shown that previous studies have either optimized water distribution or optimized cultivation patterns, but this study compared the differences between the two approaches to farmers' livelihoods in order to conserve groundwater resources.

Groundwater is critical for maintaining stream baseflow and thermal stability; however, the influence of groundwater on streamflow has been difficult to evaluate at broad spatial scales. Techniques such as baseflow separation necessitate streamflow records and do not directly indicate whether groundwater inflow may be sourced from more dynamic shallow flowpaths. We present a web tool application PASTA (Paired Air and Stream Temperature Analysis; https://cuahsi.shinyapps.io/pasta/) that capitalizes on increased public stream temperature data availability and large‐scale, gridded climate observations to provide new and efficient insights regarding relative groundwater influence on streams. PASTA analyzes paired air and stream water temperature signals to evaluate spatiotemporal patterns in stream thermal sensitivity and relative groundwater influence, including inference regarding the dominant source groundwater depth (shallow or deep (i.e., approximately >6 m depth)). The tool is linked to publicly available stream temperature datasets and accepts user‐uploaded datasets. As local air temperature is not often monitored, PASTA pulls daily air temperature data from the comprehensive Daymet products when directly measured data are unavailable, allowing the repurposing of existing stream temperature data. After data are selected or uploaded, the tool (a) fits sinusoidal curves of daily stream and air temperatures by year (water or calendar) to indicate groundwater influence characteristics and (b) performs linear regressions for stream versus air temperatures to indicate stream thermal sensitivity. Results are exported in ASCII file format, creating an efficient and approachable analysis tool for the adoption of newly developed heat tracing analysis from stream reach to landscape scales. Plain Language Summary: Comparing stream temperature to air temperature records can identify streamflow sources, or examine stream vulnerability to land use (e.g., impervious cover), climate change, or river use practices (e.g., dams). We have created a website that allows users to conduct two methods of stream and air temperature comparison using their stream temperature data or use publicly available stream temperature resources in a consistent and accessible format. These analyses generate metrics that indicate similarities and differences in air and stream temperature records over time that can provide insight into hydrologic connectivity for a single site or can be compared across time or space to inform changes in stream process within an area or period of interest. Key Points: PASTA is a web application for analyzing paired stream water and air temperature from public and user‐owned datasets, even without air dataThe output metrics can evaluate stream thermal sensitivity, relative groundwater contributions, and effective source depthApplication design allows method consistency and accessibility for various flowing water communties [ABSTRACT FROM AUTHOR]

Wetlands play an important role in the global carbon cycle as they can be sources or sinks for greenhouse gases. Groundwater discharge into wetlands can affect the water chemistry and act as a source of dissolved greenhouse gases, including CO2 and CH4. In this study, surface water quality parameters and CO2 and CH4 concentrations were evaluated in a tidal wetland (Hunter Wetlands National Park, Australia) using time series measurements. Radon (222Rn), a natural groundwater tracer, was used to investigate the role of groundwater as a pathway for transporting dissolved CO2 and CH4 into the wetland. In addition, water-to-air CO2 and CH4 fluxes from the wetland were also estimated. The results showed a high concentration of radon in wetland surface water, indicating the occurrence of groundwater discharge. Radon concentration had a strong negative relationship with water depth with a determination coefficient (R2) of 0.7, indicating that tidal pumping was the main driver of groundwater discharge to the wetland. Radon concentration also showed a positive relationship with CO2 and CH4 concentrations (R2 = 0.4 and 0.5, respectively), while the time series data revealed that radon, CO2, and CH4 concentrations peaked concurrently during low tides. This implied that groundwater discharge was a source of CO2 and CH4 to the wetland. The wetland had an average water-to-air CO2 flux of 99.1 mmol/(m2·d), twice higher than the global average CO2 flux from wetlands. The average CH4 flux from the wetland was estimated to be 0.3 mmol/(m2·d), which is at the higher end of the global CH4 flux range for wetlands. The results showed that groundwater discharge could be an important, yet unaccounted source of CO2 and CH4 to tidal wetlands. This work has implications for tidal wetland carbon budgets and emphasizes the role of groundwater as a subsurface pathway for carbon transport.

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Groundwater discharge flux into rivers (riverine groundwater discharge or RGD) is essential information for the conservation and management of aquatic ecosystems and resources. One way to estimate area‐integrated groundwater discharge into surface water bodies is to measure the concentration of a groundwater tracer within the water body. We assessed groundwater discharge using 222Rn, a tracer common in many surface water studies, through field measurements, surface water 222Rn mass balance model, and groundwater flow simulation, for the seldom studied but ubiquitous setting of a flooding river corridor. The investigation was conducted at the dam‐regulated Lower Colorado River (LCR) in Austin, Texas, USA. We found that 222Rn in both the river water and groundwater in the river bank changed synchronously over a 12‐hour flood cycle. A 222Rn mass balance model allowed for estimation of groundwater discharge into a 500‐m long reach of the LCR over the flood. The groundwater discharge ranged between negative values (indicating recharge) to 1570 m3/h; groundwater discharge from groundwater flow simulations corroborated these estimates. However, for the dynamic groundwater discharge estimated by the 222Rn box model, assuming whether the groundwater 222Rn endmember was constant or dynamic led to notably different results. The resultant groundwater discharge estimates are also highly sensitive to river 222Rn values. We thus recommend that when using this approach to accurately characterize dynamic groundwater discharge, the 222Rn in near‐stream groundwater should be monitored at the same frequency as river 222Rn. If this is not possible, the 222Rn method can still provide reasonable but approximate groundwater discharge given background information on surface water‐groundwater exchange time scales. [ABSTRACT FROM AUTHOR]

• Hydrological drought reduced surface runoff and decreased NH 4 -N concentration all year round. • Evaporative demand drought reduced fresh groundwater discharge and decreased NO 3 -N concentration during spring and summer. • N 2 O emission was highly correlated to the decline of NO 3 -N, DIN, and DTN. Severe droughts are increasingly prevalent under global climate change, disrupting watershed hydrology and coastal nitrogen cycling. However, the specific effects of drought on nitrogen transport from land to sea and subsequent nitrogen dynamics remain inadequately understood. In this study, we evaluated the consequences of the 2020–2022 drought on nitrogen supply and N 2 O emissions in Xiamen Bay, Southeast China. The results showed that drought significantly reduced annual NH 4 N, NO 2 N, and NO 3 N concentrations in Xiamen Bay by 49.4 %, 32.1 %, and 40.3 %, respectively, compared with the pre-drought year of 2019. The decline in NH 4 N concentration was mainly attributed to reduced surface runoff across all seasons. NO 3 N and NO 2 N concentrations declined only during spring and summer, primarily due to increased potential evapotranspiration (PET) hindering nitrogen supply via groundwater and concurrently enhancing land denitrification. Annual N 2 O emission from Xiamen Bay decreased by 40.0∼72.7 % during the drought, highly correlated with the decline in the concentrations of NO 3 N, DIN, and DTN (p < 0.001). Comparative analysis revealed that NO 3 N concentration exhibited consistent negative linear regressions with PET and declined as evaporative demand drought conditions worsened across Xiamen Bay, Sansha Bay, and Chesapeake Bay throughout 2010–2022. NH 4 N concentration showed a positive regression with river discharge in Xiamen Bay, but negative regressions in the other two bays. Our results indicates that drought reduces N 2 O emission primarily driven by nitrate substrate reduction in the bay. This study provides new insights for predicting coastal nitrogen dynamics and greenhouse gas emissions under global environmental change. [Display omitted] [ABSTRACT FROM AUTHOR]

Lake eutrophication is one of the most typical and serious water environmental problems in the world, and input of both point-source and non-point source nutrients into lake has been the focus of previous studies.However, the role of surface water-groundwater interactions in the occurrence and evolution of lake eutrophication has been often neglected.In this paper, the patterns of groundwater-lake water interactions were summarized, the research progress on the influence of groundwater discharge on the hydrology and water quality of lake were reviewed, and the advantages and applicability of different quantifying methods such as seepage meter measurement, water balance, radon mass balance, temperature tracing, and numerical simulation) were compared.The state-of-art of the studies and major challenges in understanding the spatial-temporal variability of groundwater discharge to lakes, and the transport and transformation of nitrogen and phosphorus at the groundwater-lake interface were reviewed.And three directions for the future study in this field were proposed: 1) characterizing the spatial-temporal variability of lacustrine groundwater discharge using multiple methods; 2) accurately quantifying the loads of nitrogen and phosphorus with groundwater discharge into lakes, on the basis of revealing hydrobiogeochemical processes at the interface; and 3) unraveling the effect of strong anthropogenic activities on groundwater-lake interactions.

Groundwater discharge can be a major source of nutrients to river systems. Although quantification of groundwater nitrate loading to streams is common, the dependence of surface water silicon (Si) and phosphorus (P) concentrations on groundwater sources has rarely been determined. Additionally, the ability of groundwater discharge to drive surface water Si:P ratios has not been contextualized relative to riverine inputs or in-stream transformations. In this study, we quantify the seasonal dynamics of Si and P cycles in the Grand River (GR) watershed, the largest Canadian watershed draining into Lake Erie, to test our hypothesis that regions of Si-rich groundwater discharge increase surface water Si:P ratios. Historically, both the GR and Lake Erie have been considered stoichiometrically P-limited, where the molar Si:P ratio is greater than the ~16:1 phytoplankton uptake ratio. However, recent trends suggest that eastern Lake Erie may be approaching Si-limitation. We sampled groundwater and surface water for dissolved and reactive particulate Si as well as total dissolved P for 12months within and downstream of a 50-km reach of high groundwater discharge. Our results indicate that groundwater Si:P ratios are lower than the corresponding surface water and that groundwater is a significant source of bioavailable P to surface water. Despite these observations, the watershed remains P-limited for the majority of the year, with localized periods of Si-limitation. We further find that groundwater Si:P ratios are a relatively minor driver of surface water Si:P, but that the magnitude of Si and P loads from groundwater represent a large proportion of the overall fluxes to Lake Erie.

With its important geographical location and status as the largest saltwater body in China, Qinghai Lake plays a vital role in the ecological environment of the northeastern part of the Qinghai-Tibet Plateau. Due to climate change and the subsequent adjustment of Qinghai Lake's tourism policy, it is necessary to understand groundwater discharges in southeast of Qinghai lake both for ecological protection and risk prevention. This study used radium isotopes 223Ra and 224Ra to trace groundwater discharges and nutrients carried into the lake. The spatial characteristics of Ra isotopes with greater activity in the upper and bottom layers in the lake indicated that they were influenced by inputs of shallow groundwater and diffusion from sediments. The average 224Ra diffusion flux of the sediments in the Lake was 33.54 dpm m−2 d−1. Based on the 224Ra mass balance model, the discharge flux of shallow groundwater in this region was estimated to be 3.49 × 106 ∼ 3.68 × 106 m3 d−1. The PO 4 3− and SiO 2 fluxes carried into the southeastern of the lake by groundwater were 1.78 × 1011 ∼ 1.88 × 1011 mg/y and 2.22 × 1012 ∼ 2.34 × 1012 mg/y, respectively. It is thus essential to monitor shallow groundwater discharge into Qinghai Lake for the protection of the water environment and prevention of potential ecological risks. [ABSTRACT FROM AUTHOR]

The pronounced topographical differences, giving rise to numerous water bodies, also endow these formations with substantial hydraulic gradients, leading to pronounced groundwater discharge within their low-lying, natural reservoir settings. However, the dynamics of groundwater discharge in reservoirs and their impact on greenhouse gas (GHG) production and emission under different conditions remain unclear. This study focuses on a reservoir in southeastern China, where we conducted seasonal field observations alongside microcosm incubation experiments to elucidate the relationship between greenhouse gas emissions and groundwater discharge. Based on the radon ( 222 Rn) mass balance model, groundwater discharge rates were estimated to be 2.14 ± 0.49 cm d -1 in autumn, 4.04 ± 2.09 cm d -1 in winter, 2.55 ± 1.32 cm d -1 in spring, and 2.61 ± 1.93 cm d -1 in summer. Groundwater discharge contributes on average to 31.23 % of CH 4 , 35.65 % of CO 2 , and 11.26 % of N 2 O emissions across all seasons in the reservoir. Groundwater primarily influences GHG emissions by directly inputting carbon and nitrogen, as well as by altering aquatic chemical conditions and the environment of dissolved organic matter (DOM), exerting significant effects particularly during spring and autumn seasons. Especially, in winter, higher groundwater discharge rates influence microbial activity and environmental conditions in the water body, including the C/N ratio, which somewhat reduces its enhancement of greenhouse gas emissions. This study provides an in-depth exploration of greenhouse gas emissions from reservoirs and examines the impact of groundwater on these emissions, aiming to reduce uncertainties in understanding greenhouse gas emission mechanisms and carbon and nitrogen cycling., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Methane (CH 4 ) inputs to lakes through lacustrine groundwater discharge (LGD-derived CH 4 ) represent a potentially important but often overlooked source of lake methane emissions. Although great efforts have been made to quantify LGD-derived CH 4 fluxes and their spatial variablity, the underlying mechanisms controlling seasonal LGD-derived CH 4 fluxes and their influence on lake CH 4 emissions remain poorly understood, particularly in humid inland areas. To address this gap, we applied the 222 Rn mass balance model, as well as hydrological, isotopic and microbial methods to assess seasonal LGD-derived CH 4 fluxes and their influence on the seasonal variability of lake methane emissions in a typical oxbow lake, central Yangtze River. The results revealed wide seasonal differences in LGD-derived CH 4 fluxes, which were controlled by hydrological and biogeochemical processes. During the dry season, although more intense methane oxidation and weaker methanogenesis occurred in groundwater, the much higher LGD rate (51.71 mm/d) produced a higher LGD-derived CH 4 flux (16.41 mmol/m 2 /d). During the wet season, methanogenesis was more active and methane oxidation was weaker, but a lower LGD rate (12.16 mm/d) led to a lower LGD-derived CH 4 flux (5.33 mmol/m 2 /d). Furthermore, higher LGD-derived CH 4 flux in the dry season resulted in higher CH 4 emissions from the lake and diminished the extent of methane oxidation in the lake. In comparison to other regions, the differences in LGD-derived CH 4 fluxes and their seasonal variations were found to be controlled by climatic conditions and lake types in different global regions. Higher LGD-derived CH 4 fluxes and more pronounced seasonal variations could be associated with higher temperature, larger water depth and more intense water level fluctuations. This study provides a novel perspective and broader implications for the comprehension and evaluation of seasonal methane emissions and understanding the carbon cycle in global lake ecosystems in humid areas with intense water level fluctuations., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

[Display omitted] • First survey of groundwater and GHGs for the large shallow eutrophic lake cross a year. • Groundwater contributes 12.1% to CO 2 emissions, with lesser contributions to CH 4 and N 2 O. • Groundwater was identified as a source of CO 2. • CH 4 and N 2 O are mainly influenced by ecological factors. Lakes are recognized as important sources of greenhouse gases (GHGs) emissions to the atmosphere, influenced by various ecological processes. Groundwater discharge into lakes, despite its small volume, has high concentrations of dissolved carbon and nitrogen that significantly affect the production and emission of GHGs from lakes. Therefore, a comprehensive investigation of the mechanisms behind lake GHGs emissions under the influence of groundwater discharge and ecological processes, holds substantial scientific importance. However, due to uncertainties and quantification challenges associated with groundwater discharge, related research is currently limited. Here, we conducted year-round field observations on Honghu Lake, a large shallow eutrophic lake in Hubei Province, China. We analyzed the seasonal variation of GHGs emissions and quantified the groundwater discharge flux using radon (222Rn). The fluxes of methane (CH 4), carbon dioxide (CO 2), and nitrous oxide (N 2 O) at the water–air interface were estimated to be 31.1 ± 4.88 mg m−2 d−1, 386 ± 90.7 mg m−2 d−1, and 0.327 ± 0.072 mg m−2 d−1, respectively. CH 4 is the primary greenhouse gas in Honghu Lake, contributing to 82.2 % and 62.2 % of the lake's total emissions over 20-year and 100-year frames. The average rate of groundwater discharge was 8.19 ± 0.471 mm d−1, with the highest discharge rate in winter and the lowest in spring. The daily groundwater discharge volume accounts for 0.649 % of the lake's total water volume. The daily contributions of groundwater discharge to the lake's total emissions of CH 4 , CO 2 , and N 2 O were 0.318 %, 12.1 %, and 2.59 %, respectively. The facilitative role of groundwater discharge in CO 2 emissions primarily manifests through the transport of dissolved organic carbon (DOC) and high concentrations of CO 2 into the lake. Meanwhile, CH 4 emissions depend on the activity of methanogenic bacteria, substrate availability, and anaerobic conditions, whereas N 2 O emissions are influenced by temperature and nutrient levels. Our study reveals that in the short term, the effect of groundwater on lakes is relatively minimal. Yet, its long-term role as a steady supplier of carbon and nutrients to lakes should not be overlooked. This study reveals the ways in which groundwater discharge and internal lake dynamics collectively fuel GHGs emissions. Our findings offer a new perspective and critical theoretical support for the assessment of lake greenhouse gas emissions. [ABSTRACT FROM AUTHOR]

Groundwater runoff is an important component of river runoff and is sensitive to climate change. However, it is difficult to differentiate groundwater runoff from total river runoff by current base flow separation methods. Here, we propose a physically based model with a two‐pass digital filter for separating groundwater runoff from streamflow time series. The proposed method is based on the fundamental theory of surface–groundwater interactions under a variable groundwater recharge process that is highly associated with river stages. Our results show that the groundwater flow recession constant and the base flow recession constant can be determined separately by performing variogram analysis on long‐term streamflow time series data. For watersheds with areas of 103–104 km2, the groundwater flow recession constant differs from the typical values of the base flow recession constant by an order of magnitude or more. Therefore, the developed method can be used to quantify groundwater runoff dynamics on a temporal scale spanning tens of years. Unlike other approaches to base flow separation, our proposed method can reveal the effects of climate change on groundwater runoff. Key Points: A physically based model with a two‐pass digital filter for groundwater runoff separation from streamflow time series was proposedGroundwater flow recession constant and the base flow recession constant can be determined separately using variogram analysisThe proposed method is able to reveal the effects of climate change on groundwater runoff [ABSTRACT FROM AUTHOR]

Study region: Northern Finland. Study focus: This study examined long-term (decade-scale) hydrological and ecological consequences of dam construction and subsequent river regulation on the environmentally protected Viiankiaapa mire. Pre-regulation floods affected the hydrology of the riverbanks and the Viiankiaapa mire, which contain habitats of flood-dependent or groundwater-influenced ecosystems. Groundwater discharge and flow patterns and pre-regulation flood coverage were simulated to investigate the impact of river regulation on the mire area. New hydrological insights for the region: The flood models indicate that regular flooding covered the westernmost part of the mire before the regulation. Groundwater modelling suggests that the regulation has raised the locations of springs in the river shore, reduced the hydraulic gradient towards the river, raised the groundwater table in the river banks and the western part of the Viiankiaapa mire, and increased groundwater discharge in the mire. The groundwater flow models and the stable isotopic composition of water indicate that the constructed dam changed the groundwater flow directions close to dam. The ecological effects of regulation were mixed: the studied flood-dependent plant species declined due to the reduction in floods after regulation. Conversely, the occurrence of Hamatocaulis vernicosus and Hamatocaulis lapponicus appears to be related to the high water table and groundwater discharge areas in the mire, suggesting suitable habitat for these species may have expanded after the regulation.

Synoptic sampling of three rivers for a suite of environmental tracers is shown to be an efficient way to gain an understanding of groundwater flow paths for a previously unstudied large area in Alberta, Canada. For regional‐scale characterization, classical hydrogeological techniques are limited by the location and number of groundwater wells. This study demonstrates that rivers can become an easily accessible location to sample the distribution of groundwater flow paths discharging to surface water. Modelling of groundwater discharge to the rivers and groundwater mean age helps generate knowledge of groundwater circulation for a large area, which is useful for conceptual model development and focusing future characterization efforts. Results indicate that the benchland areas in this region, with higher topographic relief, had hydrogeological conditions that favoured deeper groundwater circulation with a modelled mean age greater than 100 years from recharge to discharge. Lower relief areas, which coincide with a transition in bedrock formations in this region, appeared to have much shorter and shallower groundwater circulation. The approach required a field program completed in 5 days and financial budget approximately equivalent to drilling a single borehole and installing a monitoring well. It is concluded that under the right conditions, where few classical observation points exist and knowledge is limited, synoptic sampling of rivers can be used to develop scientifically defensible conceptual models at a comparable scale to regional planning and resource management. [ABSTRACT FROM AUTHOR]

Starting with a log-linear relationship between groundwater discharge per unit drainage area (Q/Ab), hydraulic turnover time (t) and aquifer mobile storage (z), this study builds a groundwater security method at catchment scale. The method embeds previously published approaches to calculate Q/Ab, t and z, and relies solely on stream flow discharges and watershed areas. The ability to build a method on a couple of variables is remarkable. The method recasts the calculated variables as aquifer security indicators (SQ, St and Sz), relating SQ with yield capacity, St with self-depuration capacity and Sz with resilience. Groundwater security is the weighted product of SQ, St and Sz. The method is validated with stream flow discharges and drainage areas concerning 294 hydrometric stations and their watersheds, located in continental Portugal. The results revealed a majority of moderately to highly secure watersheds, especially as regards St (> 62%), while 7–10% were classified as very highly secured in general (SQ-St-Sz). The least secured basins are located in the more arid regions of continental Portugal (Northeast and south regions), as expected. The method can be easily transposed to any other region worldwide, with the necessary adaptions to regional climate, geological and topographic settings.• Compile stream flow discharge data and organize them as natural logarithms and logarithmic variations as function of time, to estimate Q, t and z;• Recast the Q, t and z values as SQ, St and Sz ratings, respectively, using the appropriate reclassification scales, and estimate watershed security levels, namely average security or customized (weighted) securities that highlight the contributions of Q/Ab (watershed yield), t (aquifer's self-depuration capacity) or z (aquifer's resilience);• Use the results to draw illustrative diagrams and spatial distribution maps.

Groundwater discharge to streams is a nonpoint source of nitrogen (N) that confounds N mitigation efforts and represents a significant portion of the annual N loading to watersheds. However, we lack an understanding of where and how much groundwater N enters streams and watersheds. Nitrogen concentrations at the end of groundwater flowpaths are the culmination of biogeochemical and physical processes from the contributing land area where groundwater recharges, within the aquifer system, and in the near-stream riparian area where groundwater discharges to streams. Our research objectives were to quantify the spatial distribution of N concentrations at groundwater discharges throughout a mixed land-use watershed and to evaluate how relationships among contributing and riparian land cover, modeled aquifer characteristics, and groundwater discharge biogeochemistry explain the spatial variation in groundwater discharge N concentrations. We accomplished this by integrating high-resolution thermal infrared surveys to locate groundwater discharge, biogeochemical sampling of groundwater, and a particle tracking model that links groundwater discharge locations to their contributing area land cover. Groundwater N loading from groundwater discharges within the watershed varied substantially between and within streambank groundwater discharge features. Groundwater nitrate concentrations were spatially heterogeneous ranging from below 0.03–11.45 mg-N/L, varying up to 20-fold within meters. When combined with the particle tracking model results and land cover metrics, we found that groundwater discharge nitrate concentrations were best predicted by a linear mixed-effect model that explained over 60% of the variation in nitrate concentrations, including aquifer chemistry (dissolved oxygen, Cl ^− , SO _4 ^2− ), riparian area forested land cover, and modeled physical aquifer characteristics (discharge, Euclidean distance). Our work highlights the significant spatial variability in groundwater discharge nitrate concentrations within mixed land-use watersheds and the need to understand groundwater N processing across the many spatiotemporal scales within groundwater cycling.

The Las Vegas Formation (LVF) is a well-characterized sequence of groundwater discharge (GWD) deposits exposed in and around the Las Vegas Valley in southern Nevada. Nearly monolithologic bedrock surrounds the valley, which provides an excellent opportunity to test the hypothesis that GWD deposits include an aeolian component. Mineralogical data indicate that the LVF sediments are dominated by carbonate minerals, similar to the local bedrock, but silicate minerals are also present. The median particle size is ~35 μm, consistent with modern dust in the region, and magnetic properties contrast strongly with local bedrock, implying an extralocal origin. By combining geochemical data from the LVF sediments and modern dust, we found that an average of ~25% of the LVF deposits were introduced by aeolian processes. The remainder consists primarily of authigenic groundwater carbonate as well as minor amounts of alluvial material and soil carbonate. Our data also show that the aeolian sediments accumulated in spring ecosystems in the Las Vegas Valley in a manner that was independent of both time and the specific hydrologic environment. These results have broad implications for investigations of GWD deposits located elsewhere in the southwestern U.S. and worldwide. [ABSTRACT FROM AUTHOR]

In this study, we considered 41 fens located in northern and central Poland. In our main hypothesis, we assumed that the base chemical composition of fen waters primarily depends on the hydrological regime, indicating a relationship to morphogenetic type of fen. We analyzed 40 physicochemical parameters of peatland porewater samples and discussed the relation of water chemistry with the hydrological and morphogenetic conditions of the individual fens. Further, we considered the additional factors that could significantly modify water chemistry. Physicochemical and hydrological parameters indicated a large diversity in habitat conditions among the investigated fens. Parameters significantly differentiating the examined objects were the concentrations of basic anions and cations and the associated electrolytic conductivity. Higher ion concentrations indicated a greater share of groundwater in the recharge of the investigated wetlands. Fens having a greater inflow of groundwater were characterized primarily by higher concentrations of calcium, bicarbonates and electrolytic conductivity, and were usually associated with tunnel and melt-out valleys. However, in some cases, the higher electrolytic conductivity resulted from anthropogenic pollution. Therefore, the use of indicators to separate such anthropogenically influenced sites from those naturally enriched in basic ions is crucial. Moreover, human-related disturbance of fen ecosystems were also demonstrated by elevated concentrations of certain metals and nutrients. We found that the processes responsible for the mobilization and inflow of metals played a secondary role in the diversification of the chemical composition of the waters of the investigated fens.

An environmental isotope study was conducted to assess the cause for the freshening of seawater observed in the Mahim Bay, Mumbai, India after a storm event during the southwest monsoon period. Water samples were collected from the various locations of the coastal water and the suspected inland water sources such as rain, river and groundwater and analysed for major ion species and stable isotopes (δ18O and δ2H). Dissolved radon (222Rn) in the coastal water was monitored in-situ. Field monitoring survey in the coastal water indicated lower electrical conductivity (1,730 μS/cm) near Mahim Mosque compared to the surrounding shelf waters. Relatively high excess 222Rn activities (up to 55 Bq/m3) were observed in the Mahim Bay, even after 13 days of seawater freshening event. Based on the hydrochemical and isotope results, various prevailing hypotheses on the occurrence of low salinity water in the Mahim Bay were tested. It is inferred that the low salinity coastal water was associated with groundwater discharge occurring in the Mahim Bay and in the Mithi River and were unlikely due to the overflow of Vihar and Powai Lakes in the catchment of Mithi River and surface runoff because of the rain/storm events. Temporal variations of electrical conductivity and stable isotopic composition of coastal water in the Mahim Bay showed that the groundwater inputs were decreasing after the storm event. 222Rn was found to be a useful tracer for distinguishing the subsurface flow of water to the coastal system. [ABSTRACT FROM AUTHOR]

Physical barriers are widely used to control seawater intrusion (SWI). Amongst different kinds of physical barriers, mixed physical barriers (MPBs) are shown to be an effective approach to prevent SWI. However, the system may hinder the discharge of fresh groundwater and the removal of residual saltwater trapped in the inland aquifers of MPBs. Herein, using the validated numerical model, for the first time, we investigated the dynamics of residual saltwater and groundwater discharge after the installation of MPBs. For examining the applicability of MPB and its response to structural variations and hydraulic gradient, the comparison with traditional physical barriers and sensitivity analysis was also carried out. The MPB increased the mixing area of freshwater and saltwater at the beginning of the removal process, resulting in the reduction of the saltwater wedge length (RL) by 74.6% and the removal of total salt mass (RM) by 62.6% within the 4% of the total removal time. Meanwhile, the groundwater discharge (Q') rose rapidly after a sharp decline from 100% to 40% in the first stage. As the residual saltwater wedge was retreated, the mixing intensity and removal efficiency decreased substantially in the second stage. Similarly, Q' raised with a declining rate at this stage. The removal efficiency was positively correlated with wall depth and hydraulic gradient and there were optimal distance of the middle spacing and height of lower dam to reach the highest efficiency. The groundwater discharge reduced monotonously with the increase of dam height and wall depth as well as the decrease of barrier spacing and hydraulic gradient. Under certain conditions, the efficiency of MPB in removing residual saltwater could be 40%–100% and 0%–56% higher than that of traditional subsurface dam and cutoff wall, respectively. The laboratory scale conclusions provide valuable physical insight for the real field applications regarding dynamic mechanism and regularity. These findings will always help decision makers choose proper engineering measures and protect groundwater resources in coastal areas. [ABSTRACT FROM AUTHOR]

In February 2020, geochemical tracers along with hydrochemical and hydrological characteristics were used to reveal a discharge site of salt groundwaters in the head of the Razdol'naya R. estuary at a distance of 22 km from its mouth bar. The elevated activity of 224Ra isotopes from 11.1 ± 0.1 to 2.2 ± 0.05 Bq/m3 in the bottom water layer over a distance of 15 km indicates to the propagation of slightly saline waters from a pool 8 m in depth toward the receiving basin. The distribution of stable water isotopes (δ18O and δD) and ions of basic salt composition showed that water of the top aquifer at the site of discharge area can suffer the effect of seawater. The major cause of the observed phenomenon is supposed to be the penetration of seawater into the top aquifer within the estuary during winter low-water season and the seepage of this water in the region with largest depth. The contrast of the temperature of ground and surface water was accompanied by a positive temperature anomaly in the zone of their interaction and a decrease in ice thickness along the mixing zone. [ABSTRACT FROM AUTHOR]

Lacustrine groundwater discharge (LGD) can play an important role in water and contaminant mass balance of lakes. Dongting Lake is the second largest fresh lake in China which is connected to Yangtze River and has quite prominent ecological status and function within Yangtze River basin. However, the effect of groundwater discharge on the balance of water and contaminant in Dongting Lake has long been overlooked. This study estimated the groundwater discharge and associated contaminants input into Dongting Lake during the dry season using multiple tracers (222Rn, 18O, Cl−). After sensitivity analysis of different models, it is found that the result of 222Rn mass balance model is the most reliable. Based on the 222Rn mass balance model, the groundwater discharge rate is estimated to be 73.94 mm/d and the contribution of LGD to water balance is 10.94%. As the main nutrient components, NH3-N, P and Si from groundwater input account for 23.65%, 5.12% and 30.15% % of the total input, respectively. As the main heavy metal components, Fe, Mn and As from groundwater input all account for more than 50% of the total input. Although the LGD rate is relatively small, the contaminant input from LGD is significant enough, which may be a potential threat to the ecological stability of Dongting Lake. In this study, the mass balance models of multiple tracers were integrated to understand the role of groundwater in maintaining the water balance and pollution status of Dongting Lake, which has certain reference significance for the LGD study in plain lakes or reservoirs with complex water systems in humid regions. [ABSTRACT FROM AUTHOR]

Subterranean estuaries (STEs), where continental groundwaters and saltwaters meet, are zones of intense biogeochemical reactivity. As such, STEs significantly modify groundwater-borne nutrient fluxes to the coastal zone. Thus, evaluating their reactive role is crucial to anticipate impacts of submarine groundwater discharge (SGD) over coastal ecosystems. Here, we studied the nitrogen biogeochemistry of two STEs with contrasting wave-exposure and redox conditions in Panxón and Ladeira beaches (Ría de Vigo, NW Iberian Peninsula). Seasonal surveys were performed at the permanently saturated zone of both beaches during low tide in February, May, July, and October 2019. Sediment was sampled and porewater samples collected using push-pull piezometers. Salinity, 222Rn and 226Ra activities were used to trace water circulation inside each beach. Porewater nitrate, ammonium, nitrite and dissolved oxygen were used to evaluate the role of these STEs as reactive sinks or sources of inorganic nitrogen. Our results showed a marked seasonal variability of water circulation inside both beaches, with strong salinity gradients in February and May and weakened circulation in July and October. The presence of a gravel layer in Panxón beach completely altered the typical structure of STEs by increasing porewater transport and mixing through the beach interior. As a result, Panxón beach profiles were highly enriched in nitrate and oxygen. Conversely, suboxic, and anoxic conditions were prevalent in Ladeira beach during the study period, with ammonium being the prevailing inorganic nitrogen form. High nitrate concentrations occurred associated to the tidal circulation cell during February and May, being the only effective mechanism of sediment oxygenation in Ladeira beach. Although nitrate reduction and production were observed in both STEs, comparison with averaged conservative mixing porewater profiles showed that Ladeira beach acted as a net nitrogen sink whereas Panxón beach acted as a net nitrogen source. The presence of a gravel layer oxygenates the interior of Panxón beach, thus limiting nitrate reduction and promoting the amplification of groundwater-borne nitrogen fluxes to the coast.

A Bayesian chemistry-assisted hydrograph separation (BACH) approach was previously demonstrated using 15 years of monthly total phosphorus (TP) and total nitrogen (TN) data from eight mesoscale catchments in New Zealand's North Island. Calibration was done separately for three 5-year data periods, and in each period, concentrations of the two tracers (TP and TN) discharged from each of the three separated flow paths—fast (event-response near-surface flow), medium (seasonal shallow local groundwater flow), and slow (persistent deeper regional groundwater flow)—were assumed to be constant. This approach has now been extended to reveal non-linear trends in the tracer concentrations in each flow path, each represented using a four-parameter curve (initial and final values of a linear trend plus two harmonics). The extended method (called BACH2) identified clear TP and TN concentration trends in the medium and slow flow paths in most of the eight catchments. TP and TN concentration trends in the fast flow path were generally uncertain, however, due to the infrequency and inherent variability of concentrations sampled during high flow conditions. Concentrations closely matched previously published results from the constant-concentration BACH model calibrated to shorter data series. The BACH2 approach is a powerful tool for revealing concentration trends in the different pathways that sustain stream flow using commonly available water quality and flow data. This type of analysis has not previously been available outside of complex distributed simulation models. [ABSTRACT FROM AUTHOR]

Groundwater discharge is today recognized as an important pathway for freshwater, nutrients and other dissolved chemical substances to coastal systems. While its effect on supporting primary production in coastal ecosystems is increasingly recognized, its impact on growth of animals at higher trophic level (primary and secondary consumers) is less well documented. Here, we investigate the impact of groundwater discharge on the growth of the Mediterranean mussel (Mytilus galloprovincialis) in a coastal lagoon. Growth rates and condition index (tissue weight/shell weight) of mussels growing at groundwater-exposed sites and at a control site in Salses-Leucate lagoon (France) were measured. The mussels in this lagoon produce circadian (daily rhythm) growth increments in their shell, as opposed to semi-diurnal increments in tidally influenced systems. Mussels from groundwater-influenced sites have higher growth rate and condition index compared to those from a control site. Importantly, growth rates from groundwater-influenced sites are amongst the highest rates reported for the Mediterranean region (41 ± 9 μm d–1). The higher growth rates at groundwater-influenced sites are likely a consequence of both the higher winter temperatures of lagoon water as a result of groundwater discharging with relatively constant temperatures, and the groundwater-driven nutrient supply that increase the food availability to support mussel growth. Overall, this study demonstrates that groundwater discharge to Mediterranean lagoons provides favorable environmental conditions for fast growth of mussels of high commercial-quality.

To evaluate the seasonal water circulation of Tonle Sap Lake and its tributary rivers in Cambodia, the spatial distribution patterns of major and trace elements in surface water were investigated. Based on the similarity of the dissolved elemental concentrations, the water samples were mainly divided into the three groups: samples with relatively high percentages of Ca, Mo, and Sb (Subcluster B1); samples with high Si, Al, and Fe (B2); and samples with high Na, K, and Mg (B3). During the rainy season, the elemental composition of lake water (B1) appeared to be greatly influenced by the intrusion of water from the Mekong River (B1) through the Tonle Sap River (B1). During the dry season, the type of lake water shifted to B3, suggesting that the lake water stored during the rainy season was replaced by inflow from other tributaries and groundwater in its vicinity. Thus, the seasonal changes in the elemental composition of the lake water were largely controlled by surface water and groundwater circulation. The dissolved As concentration was higher in the lake water and during the dry season than that in the river water and during the rainy season, indicating the discharge of As from the lake's bottom sediment during the dry season. Although the redox cycling of Fe and Mn appeared to be less important due to the shallow water depth in the lake, there are potential risks of As poisoning induced by the formation of an anoxic water mass and increment in the concentration of phosphorus if eutrophication continues to progress. [ABSTRACT FROM AUTHOR]