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The efflorescence problem is always an intractable problem for geopolymer. Silica fume (SF), nano-silica (NS), 5A zeolite (ZL) and nano-silica treated with silane (NST), were used to mitigate the efflorescence of fly ash (FA) - granulated blast furnace slag (GBFS) - steel slag (SS) based geopolymer. The effect of their dosages on the efflorescence was evaluated through accelerated efflorescing, leaching and unconfined compressive strength (UCS) tests. The inhibition mechanisms were explored by XRD, SEM, FTIR and MIP characterization. It revealed that SF and NS presented the most effective mitigating effect on efflorescence, with 9 % of SF and 2 % of NS totally inhibiting efflorescence and improving the compressive strength, and ZL and NST also alleviated the efflorescence at appropriate contents. Optimizing pore network and stabilizing free alkali were found to be the most important aspects for inhibiting efflorescence. The SF and NS worked efficiently in both two ways, which contained a large amount of dissolvable silicate that reacted with the excessive alkali to form C(N)-A-S-H and C-S-H gels. This filled and reduced the pores from 26 nm to less than 10 nm, and stabilized alkali with reduce the free w (Na+) by more than 50.45 %. On the other hand, ZL can solidify free alkali through the ion exchange property and fill pores due to its microaggregate nature, and NST reduced the efflorescence through blocking free alkali migration paths by hydrophobicity of the pores. These findings would guide the selection of appropriate methods to solve the efflorescence problem of geopolymers. • Reactive silicates in SF and NS can consume free alkalis to improve efflorescence resistance. • The NS inhibited free alkalis migration through optimized pore structure. • The ZL and NST mitigated efflorescence by reducing alkali leaching. [ABSTRACT FROM AUTHOR]

The present research deals with the production and characterization of geopolymers prepared by mixing metakaolin with sodium silicate, sodium hydroxide solution and different amounts of electric arc furnace dust derived from the production of carbon steel, to be used by the construction industry. Specimens with compositions containing 90, 80, 70, 60 and 50 g of metakaolin and respectively 10, 20, 30, 40 and 50g of electric arc furnace dust powder were prepared. A blank composition containing metakaolin, sodium silicate, sodium hydroxide solution and free from electric arc furnace dust were also prepared for comparison. After production and hardening, all samples were characterized regarding compressive strength and water absorption. Hardened samples with compositions containing 10 and 30g of electric arc furnace dust were then submitted to a release test in order to evaluate the heavy metals elution. It has been observed that the addition of electric arc furnace dust worsens the pastes workability during their production in this way limiting the amount of electric arc furnace dust which may be added to the geopolymeric matrix. However, samples containing 90 g of metakaolin and 10 g of electric arc furnace dust still maintain fair compressive strength (about 27 MPa), low water absorption (about 28 %) and display limited elution of heavy metals. An additional thermal treatment of 1h at 700 °C, performed to induce sintering of the geopolymeric composites and therefore to reduce their porosity, did not lead to materials with improved performances. [ABSTRACT FROM AUTHOR]

In this work, we utilized an in-situ chemical synthesis method to fabricate a Fe 3 O 4 /K-geopolymer (KGP) composite to be applied in a microwave absorbent field. This material, as a type of ceramic precursor, is highly expected to be a 3D printing material to prepare microwave absorbing components with complex shapes. The investigation results demonstrate that the material possesses a large effective microwave absorbing bandwidth of 3.7 GHz with the minimum reflection loss reducing to −12.2 dB when the generated Fe 3 O 4 percent reaches 12 wt% in the KGP composite. This microwave absorbent performance can be attributed to a synergistic effect between the eddy current loss caused by the improved electrical conductivity of magnetic nanoparticles and the interfacial polarization effect from the geopolymer matrix and magnetic medium interface. Also, we used direct ink writing technology to print two-dimensional components with desirable patterns. Thickness-dependent wave absorption evaluation results confirmed a maximum reflection loss of −25.9 dB at 15.2 Hz was obtained from the printed sample containing 9.0 wt% Fe 3 O 4 for a layer thickness of 10 mm, indicating that wave consumption effectiveness was determined by porous microstructures, magnetic loss of Fe 3 O 4 nanoparticles as well as suitable impedance matching. The preparation method and synthesized material pave the way for integrated manufacturing of 3D printing components with microwave absorbing performance. • Fe 3 O 4 /KGP composite was fabricated using an in-situ chemical synthesis method. • The Fe 3 O 4 /KGP composite slurry could be printed into components with wave-absorbing properties. • The microwave dissipation capacity and intrinsic mechanism of the composite were investigated. [ABSTRACT FROM AUTHOR]

This study examines the use of rice husk ash (RHA) and incinerated sugarcane press mud (ISPM) as precursors in the lime/pozzolan geopolymer system and the effect of the bacterium Lysinibacillus sp. WH on the mechanical properties and microstructures. The RHA-to-ISPM ratio was varied, and the geopolymer pastes were cured at ambient temperature. The results show that an increase of ISPM content up to 5% improves strength and reduces water absorption and voids, while higher ISPM levels beyond 5% degrade the quality of geopolymer paste. An increase in ISPM content reduces setting times due to an increase amount of calcium in the pastes. Notably, the addition of bacteria resulting in a reduction of setting times has been proved for the first time in this work. Moreover, the addition of bacteria can enhance all mechanical properties and introduce self-healing abilities, with microcracks healing within < 20 days of treatment, regardless of mix proportions. Microstructural studies, using a scanning electron microscope (SEM), Fourier Transform Infrared Microscopy (FT-IR), X-ray diffraction (XRD), and Rietveld refinement analysis, reveal that bacteria increase cristobalite, and decrease quartz, thus resulting in strength enhancement of geopolymer pastes. Furthermore, this work is the first to provide evidence that bacteria tend to reduce the efflorescence formation as confirmed by a decrease in gaylussite. These findings pave ways to the production of more sustainable geopolymer systems via upcycling wastes and prolonging service life due to bacterial activity. [ABSTRACT FROM AUTHOR]

Geopolymer concretes have shown better resistance against alkali–silica reaction (ASR) than ordinary Portland cement concretes, which was attributed to the low pore solution alkalinity of the geopolymer. However, the alkalinity of the geopolymer pore solution depends on the concentration and volume of the activating solutions used and age of the geopolymer. The main objective of this study was to investigate the effects of pore solution alkalinity on the ASR expansion of the metakaolin‐based geopolymer concrete. The chemistry of the pore solution of metakaolin‐based geopolymer was studied, and its reaction with reactive and non‐reactive aggregates was investigated. The concrete prism expansion tests showed no ASR‐induced expansion in geopolymer despite sufficient pore solution alkalinity to attack the reactive aggregates. The SEM and XRD characterizations confirmed that no ASR‐related gel was formed during the reaction between reactive aggregates and extracted pore solution. The chemical structure of the reaction product between aggregates and pore solution was characterized using MAS NMR and revealed no difference in the reaction products with reactive and non‐reactive aggregates. The results suggest that the pore solution alkalinity is not the sole governing parameter for ASR expansion in the geopolymer. [ABSTRACT FROM AUTHOR]

Geopolymers represent a distinct class of materials characterised by their X-ray amorphous nature and nanoporous, nanoparticulate structure. Geopolymers can be conveniently mixed, poured, and cured under ambient conditions. This makes this class of materials an interesting alternative to ordinary Portland cement for structural processes. Additionally, the addition of alumina can improve mechanical properties, while the addition of glass can form an impermeable glaze which could be useful for molten salt containment. Therefore, in this investigation, potassium metakaolin-based geopolymer composites with varying proportions of glass particles and alumina platelets were fabricated, cured, heat-treated, and analyzed to study the effects of composition on material properties. Various attributes including rheological properties, densities, mass loss, shrinkage, and porosities were compared. It was observed that certain compositions exhibited high viscosities, making high shear mixing challenging, while also displaying significant permeability that would hinder their ability to contain liquids without leakage. Additionally, certain samples showed reduced densities, suggesting potentially weaker mechanical properties; however, the investigation did not include a direct assessment of mechanical properties. The most promising candidates for containing liquids at high temperature contained 50 wt% KGP, 25 or 35 wt% glass powder, and 25 or 15 wt% alumina platelets, respectively. ASH-G slurries required a minimum of 65 vol% KGP to produce a homogenous material compatible with additive manufacturing. The minimum amount of glass phase to form surface glazes was 16 vol%. Only samples containing more glass phase than alumina phase produced glazed composites. [ABSTRACT FROM AUTHOR]

As a by-product of the coal industry, the effective use of coal gangue presents significant implications for environmental protection and sustainable development upon effective utilization. Given the rich content of silicon and aluminum in coal gangue, this study converts it into a precursor for ceramic binders used in grinding wheels through the geopolymerization reaction process. Ceramic binders of the SiO2-B2O3-Al2O3-RO-R2O system were prepared at sintering temperatures ranging from 590 to 740°C, and the performance of each sample was tested. The research found that the flexural strength of the ceramic binder reached a peak of 31 MPa when sintered at 690°C. Additionally, the hardness was observed to be the highest at a sintering temperature of 640°C, reaching 211.8 hV. It was observed that as the sintering temperature rose, wettability tended to decrease. Using techniques including XRD, SEM, and EDS, the effect of sintering temperature on the microstructure and phase transformation of the material was analyzed, and these changes determined the properties of the material. This study not only confirmed the potential value of coal gangue in the abrasive tools industry but also opened up new strategies and technical solutions for the field of solid waste resource utilization. [ABSTRACT FROM AUTHOR]

Graphite/geopolymer composite is a promising smart material that can be used in various applications. This paper reports the design of strong self‐heating graphite/geopolymer composites with high graphite percentages up to 120 wt% of metakaolin. The physical, mechanical, electrical, and electrothermal performance of composites were investigated; the compressive strength was tested at various ages and the electrothermal performance was tested using AC and DC voltages. The results showed that a compromise between high compressive strength and high electrothermal conversion can be achieved when a specific balance between the percentage of the graphite and the water content is established. The current study specified the reason for the deterioration of the electrothermal performance of the graphite/geopolymer composites, that is, the formation of a barrier layer between the electrode and the sample surface; it has been found that this can be avoided by removing the free ions from the geopolymer via washing. A composite with 47 ± 1 MPa compressive strength and stable electrothermal performance of 98°C at 6 DC volts can be prepared using 90 wt% graphite and 57 mL water content. This work is a step in the future innovation of smart construction using self‐heating and antifreezing construction materials. [ABSTRACT FROM AUTHOR]

The widespread adoption of geopolymer concretes in the industry has been slow, mainly due to concerns over their long-term performance and durability. One of the main causes of concrete structures' deterioration is chloride-induced corrosion of the reinforcement. The reinforcement corrosion process in concrete is composed of two main stages: the initiation phase, which is the amount of time required for chloride ions to reach the reinforcement, and the propagation phase, which is the active phase of corrosion. The inherent complexities associated with the properties of precursors and type of activators, and with the multi-physics processes, in which different transfer mechanisms (moisture, chloride, oxygen, and charge transfer) are involved and interact with each other, have been a major obstacle to predicting the durability of reinforced alkali-activated concretes in chloride environments. Alternatively, the durability of alkali-activated concretes can be assessed through testing. However, the performance-based tests that are currently available, such as the rapid chloride permeability test, the migration test or the bulk diffusion test, are only focusing on the initiation phase of the corrosion process. As a result, existing testing protocols do not capture every aspect of the material performance, which could potentially lead to misleading conclusions, particularly when involving an electrical potential to reduce the testing time. In this paper, a new performance-based test is proposed for assessing the performance of alkali-activated concretes in chloride environments, accounting for both the initiation and propagation phases of the corrosion process. The test is designed to be simple and to be completed within a reasonable time without involving any electrical potential. [ABSTRACT FROM AUTHOR]

Cracks in concrete structures are generally initiated due to the shrinkage i.e. the volume change characteristics of the concrete structures. In this experimental study, effects of the mix parameters related to alkaline liquid (AL) and recycled fine aggregate (RFA) on the shrinkage behaviour of environment-friendly mortar mixes produced with fly ash (FA)-based geopolymer binder and RFA were investigated and reported. To find out the effects of AL, concentration of liquid sodium hydroxide (LSH) was varied from 6M to 16M, ratio of liquid sodium silicate (LSS) to LSH in AL was varied from 1.0 to 2.5 and AL/FA ratio was considered as 0.4 and 0.6. Different fly ash-based geopolymer mortar mix were produced depending on above-said combinations of mix parameters along with the RFA content (by weight) of 10%, 20%, 30%, 40% and 50% in lieu of natural fine aggregate. Prismatic specimens (25 mm × 25 mm × 285 mm) were cast and cured at ambient air temperature to determine the shrinkage behaviour. Higher RFA content in mix, higher LSS/LSH ratio in AL and higher AL/FA ratio resulted in higher shrinkage value. But, lesser shrinkage value was noticed for those specimens of mortar mix with the consideration of higher concentration of LSH in AL with varying RFA content. [ABSTRACT FROM AUTHOR]

In this study, geopolymers (GMs) were produced using basalt fiber, polyamide fiber, and polypropylene fiber-reinforced and ground blast furnace slag (GBFS) waste ceramic powder (WCP). In the initial phase of the study, the optimal ingredient proportions were identified, and an ideal geopolymer was selected based on its highest compressive strength. Subsequently, at the second stage of the study, various fibers with differing proportions were incorporated into the ideal geopolymer, and the resulting properties were evaluated through laboratory testing. In the third stage, the optimal GMs were determined through a holistic approach, employing a multi-criteria decision-making method. A total of ten mixtures, comprising 23 properties (230 parameters in total), were subjected to a multi-criteria decision support method (TOPSIS). The optimal GM mixture with the proportions and suitable components was identified. The findings indicated that a 20% substitution of WCP with GBFS resulted in an optimal and cost-effective mixture in a 10 M NaOH solution, serving as a reference point or ideal unreinforced mixture in this research. With regard to the addition of fibers, all three types of fibers were observed to enhance the compressive, flexural, and splitting tensile strength of the WCP–GBFS-based GM. Maximum compressive strength was observed to be 60.15 MPa, while the flexural strength was 12.98 MPa and the splitting tensile strength was 3.45 MPa for the polyamide fiber (PA)-reinforced GM. Furthermore, all reinforced GMs exhibited enhanced abrasion resistance, with the inclusion of polypropylene fibers yielding the best results. Additionally, these fiber-reinforced GMs demonstrated significant resistance to high temperatures, even as temperatures increased. The TOPSIS results indicated that PA0.8 was the optimal GM, and its components with suitable components were recommended as a sustainable net zero/low CO2 emission building material. [ABSTRACT FROM AUTHOR]

This study presents the development of a synthesis route for sodium aluminosilicate hydrate (N–A–S–H) gels with various Si/Al ratios carried out at ambient temperature. The synthesis is based on a simple "sol–gel" method, where commercial reactants are used to provide highly reactive Si and Al sources. Comprehensive characterization, including scanning electron microscope‐energy‐dispersive spectroscopy (SEM‐EDS), gas pycnometry, inductively coupled plasma (ICP), X‐ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), X‐ray diffraction (XRD), and magic angle spinning (MAS) nuclear magnetic resonance (NMR) (27Al, 23Na, 29Si, and 1H), is employed to verify the morphology, density, chemical composition, long‐range order, and local structure of the gels. Our results show that the synthesized gels are pure, amorphous, and homogeneous with Si/Al final ratio ranging from 1.22 to 2.23. Structural analysis of the gels indicates the synthesis of compounds with high degree of geopolymerization, which are representative of N–A–S–H gel formed in sodium‐based geopolymers. [ABSTRACT FROM AUTHOR]

In societies worldwide, there is significant pressure on the construction industry to employ waste/recycled materials instead of natural-sourced materials to develop infrastructures to mitigate negative environmental consequences. This study investigated the feasibility of using waste pumice powder as a binder in place of granular blast-furnace slag to manufacture geopolymer concrete. Three sets of GC mixes were developed with three ratios of alkaline activator/binder (A/B) of 0.45, 0.5, and 0.55. Eight GC mixes were prepared for each set, with eight replacement ratios of GGBFS with WPP (0%, 30%, 50%, 60%, 70%, 80%, 90%, and 100%). The influence of WPP addition as a substitute source of aluminosilicate precursors on the fresh (workability and setting time), mechanical (compressive strength and flexural strength), physical characteristics (density and water absorption), and microstructure morphology of WPP/slag-based geopolymers were studied. A linear correlation between UPV and compressive strength was found. The results revealed that setting times and workability are affected by the A/B ratio and content of WPP. WPP reduces the workability and increases setting time (both initial and final). There was a drop in compressive and flexural strengths as the percentage of WPP in the GC increased. The maximum compressive (60 MPa) and flexural strength (4.96 MPa) at an A/B ratio of 0.45 for a 100% slag content mix were obtained. However, a GC mix containing 50% WPP and 50% slag with a compressive strength of 28 MPa after 28 days of curing at ambient temperature was achieved, which is acceptable for structural applications. [ABSTRACT FROM AUTHOR]

The development of alternative environmentally friendly and sustainable materials in the construction industry has become a fundamental area of research. The current cementitious materials used in existing retrofitting techniques for masonry structures are unsustainable from an environmental point of view. The geopolymer, as a suitable alternative to ordinary Portland cement (OPC), has attracted interest in the last 20 years due to its environmental sustainability and improved properties compared to conventional concrete. To improve the ductile behavior of geopolymers, the adoption of fibers has been widely proposed in the scientific literature for a broad range of applications. The adoption of natural fibers can make geopolymers more advantageous based on their intrinsic environmental sustainability. The aim of this paper is to validate the performance of sisal fiber-reinforced geopolymer plaster as a strengthening material for masonry structures, which will be achieved by modeling the mechanical behavior of geopolymer samples in two different phases. The first phase accounts for the experimental results suitably obtained in the laboratory, while the second phase models the behavior of a masonry panel reinforced with geopolymer plaster using a suitable FEM model in Abaqus. [ABSTRACT FROM AUTHOR]

Heavy metals and dyes cause serious harm for water environment, geopolymer materials with the large pores and specific surface area, and easy modification of pore surface have received extensive attention in wastewater treatment. Herein, using loess‐clay (LC) as natural mineral materials, we developed an eco‐friendly geopolymer of loess‐clay (GpLC) with excellent adsorption properties and promotion plant growth was prepared by alkali excitement. Its morphology and structure were exhibited by scanning electron microscopy, Fourier transform infrared spectroscopy, XRD, and Brunauer–Emmett–Teller. Moreover, its adsorption property for removing metal ions and different dyes was measured, and the adsorption kinetics and thermodynamics were investigated. GpLC presented excellent adsorption ability for Pb2+, which the removal rate got to 98.7 %. It had the universality of removing organic pollutants, and the removal rate reached to 98.0 %. It was dominated chemisorption and single‐layer adsorption, which GpLC conformed to quasi‐second‐order adsorption kinetics, and being more consistent with Langmuir isothermal model. Furthermore, it was found that GpLC could promote growth of crops as it contain P and K element with essential element of plants. In summary, it provides insights and strategy for developing a kind of eco‐friendly functional materials with strong adsorption capacity and promoting plant growth, and it is an effective method for reusing loess resources. [ABSTRACT FROM AUTHOR]

This work created a fireproof sandwich structure in which the face sheets were made of expanded vermiculite and expanded perlite‐filled geopolymer composites and embedded basalt fiber mats and the core material was rock wool in designing the lightweight and cost‐effective fire‐resistant structure for steel bridges with excellent retardant and heat‐insulating performance. The effects of adding 5%, 10%, 15%, and 20% expanded vermiculite and expanded perlite to the geopolymer on mechanical properties and the thermal conductivity were investigated to obtain the optimized material mixtures for preparing the face‐sheets material of the sandwich panel. Then, the fireproof sandwich structures were fabricated and exposed to 800°C for 3 h to study the structural integrity, backfire side temperature, and mass loss ratio. The results indicated that adding 10 wt% expanded vermiculite and 10 wt% expanded perlite to the geopolymer achieved the retention of compressive strength of 66.5% after being exposed to 800°C, and the geopolymer mixtures showed a low thermal conductivity of 0.1942 W/(mK). The TOPSIS evaluation analysis reveals that the proposed fireproof sandwich panel had the highest integrated performance considering the structural weight, insulation properties, and cost. The findings of this work may provide some insights into fireproof and insulating applications in bridge engineering. [ABSTRACT FROM AUTHOR]

In this research, experimental studies and numerical analyses were carried out to investigate how the usage of geotextile and geopolymer coated geotextile as a hybrid method changes the uplift behavior of the screw piles in cohesionless soil. In this context, traditional pile behavior, the effect of different number of helixes and embedment depths on screw piles, the mechanism of geotextile and the effects of geopolymer coating process were investigated. In addition, experimental studies were modeled by using Plaxis 3D and parametric studies were carried out after verification between the results of experimental study and numerical analysis. In the numerical analysis, a segmented helix model consisting of four 90-degree slices was developed instead of the planar helixes commonly used in the literature. For further investigation of the effectiveness of hybrid method, parameters such as improvement ratios and breakout factors were calculated. When the results obtained within the scope of the study were evaluated, the geopolymer coating process increased the bearing capacity of the geotextile by 24 % at 27 % less elongation. It was also seen that uncoated and geopolymer coated geotextile increased the screw pile performance in terms of improvement ratios by 294 % and 364 %, respectively. [Display omitted] [ABSTRACT FROM AUTHOR]

The utilization of geopolymer as a grouting material has gained significant attention in research and construction applications. Geopolymer grout is a type of binding material that differs from traditional grouts, typically based on Portland cement. Researchers have explored its effectiveness and potential applications in grouting processes, considering its unique properties and characteristics. In this paper, various studies employing and utilizing geopolymer as a grouting material are reviewed. The emphasis is on mixture design of geopolymer grout, physical property, chemical composition of geopolymer grout, rheological behavior of geopolymer grout such as yield stress (in case of Bingham fluid) and viscosity, and engineering properties such as compressive strength, expansion, shrinkage, etc. [ABSTRACT FROM AUTHOR]

The paper deals with analyzes of Isothermal Conduction Calorimetry response obtained during the alkaline activation of four types of precursors (metakaolin, slag and two kinds of waste ceramic powders) to geopolymers. The first two precursors are traditionally used, while the latter two are emerging materials and knowledge of their alkaline activation might have high importance in the recycling of Construction and Demolition Waste. The studied precursors differ each to other not only in the chemical composition, but also in the phase composition—the waste ceramic precursors are highly crystalline. It was found that the total reaction heat evolved in the geopolymerization is directly proportional to the amorphous matter content as well as to the compressive strength of the activated product. This finding can be used as fast evaluation tool in searching of new potential geopolymer precursors. The dissolution and polycondensation steps were observed in all experiments and their kinetics was described by Jander's equation. While the rate of dissolution step is not dependent on temperature, the polycondensation has been accelerated by the higher temperature. The level of the rate acceleration was described by apparent activation energy; these findings can be useful in tuning of geopolymers curing procedure. [ABSTRACT FROM AUTHOR]

This study investigates the use of geopolymer technology as an alternative for the management of mine tailings, which is a serious environmental problem in mining areas, including the Arequipa region of Peru. In this study, the mixture of stabilized mine tailings with different percentages of binders (i.e., metakaolin and pumice) and their impact on the mechanical, microstructural, and toxicological properties of the synthesized geopolymers were analyzed. The ratios of mine tailings to binder material varied between 100/0 and 0/100. The activation was carried out with an alkaline solution of sodium hydroxide (10 M) and sodium silicate (modulus 2.5). Specimens were fabricated as 50 mm cubes, and the seven mix designs were evaluated in triplicate. The evaluations included compressive strength at 7, 14, 28, and 56 days of curing, chemical analysis by Fourier Transform Infrared Spectroscopy (FT-IR), microstructural characterization by X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM/EDS), thermal behavior by thermogravimetry and differential thermal analysis (TGA/DTA) between 40 °C and 1000 °C, and toxicological tests by the Toxicity Characteristic Leaching Procedure (TCLP, EPA 1311) to determine the efficiency of immobilization of toxic metals. The results demonstrate significant improvements in compressive strength for the F50 specimens compared to A0, with increases of approximately 300%, 270%, and 461% observed at 7, 28, and 56 days of curing, respectively, with microstructural stability with an average pore size of 7.21 μm, and efficiency in the immobilization of heavy metals in geopolymers with 30% or 40% binder (60%–70% mine tailings). The leachate concentrations of As, Cd, Pb, and Hg were below the established thresholds, indicating that the stabilized mine tailings can be classified as "non-hazardous materials". Geopolymers with 30% to 50% binder showed strength development with microstructural stability and efficiency in the immobilization of heavy metals, complying with current regulations. Therefore, these geopolymers are suitable for various applications and in different environmental conditions. [ABSTRACT FROM AUTHOR]

This study aimed to develop optimized alkali-activated concrete using ferronickel slag for high-temperature applications, focusing on minimizing environmental impact while maintaining high compressive strength and slump. A response surface methodology, specifically the mixture design of experiments, was employed to optimize five components: water, FNS-based alkali-activated binder, and three aggregate sizes. Twenty concrete mixes were tested for slump and compressive strength before and after exposure to 600 °C for two hours. The optimal mix achieved 88 MPa compressive strength before heat exposure and 34 MPa after, with a slump of 140 mm. An upscaled version with improved workability (210 mm slump) maintained similar unheated strength but showed reduced post-heating strength (23.5 MPa). Replacing limestone with olivine aggregates in the upscaled mix resulted in 65 MPa unheated and 32 MPa post-heating strengths. Life Cycle Analysis revealed that the optimized ferronickel slag alkali-activated concrete's CO2 emissions were 77% lower than those of ordinary Portland cement concrete of equivalent strength. This approach demonstrated the applicability of mixture design of experiments as an alternative design methodology for alkali activated concrete, providing a valuable performance-based design tool to advance the application of alkali-activated concrete in the construction industry, where no prescriptive standards for alkali-activated ferronickel concrete mix design exist. The study concluded that the developed ferronickel slag alkali-activated concrete, obtained through a performance-based mixture design methodology, offers a promising, environmentally friendly alternative for high-strength, high-temperature applications in construction. [ABSTRACT FROM AUTHOR]

This study aims to improve the fire resistance of geopolymers by adding thermal insulation materials. These additives help the material perform better at high temperatures. Previous research focused on using fly ash, metakaolin, and zeolite in geopolymer composites. This study looks at how porous additives affect compressive strength and whether non-destructive testing can measure damage after heat exposure. Four temperature tests were set: 400 °C for 60 min, 400 °C for 120 min, 800 °C for 60 min, and a maximum of 658 °C for 120 min. The results showed that the compressive strength and ultrasonic pulse velocity (UPV) dropped as the temperature increased, with a sharp decrease at 800 °C. Unmodified samples broke apart at high temperatures, while modified samples lost 40% to 70% of their strength. The study confirmed that a dense, amorphous matrix improves heat resistance, even with porous additives like fly ash. A link between UPV and compressive strength was found, suggesting non-destructive testing could be useful for checking structural integrity after a fire. [ABSTRACT FROM AUTHOR]

Geopolymer concrete (GC) is an innovative and sustainable type of composite resulting from the chemical reaction between waste materials containing and alkaline activators. The researchers have been focused to reduction of the greenhouse‐gas release, especially during the production of cement. Although numerous studies have been conducted on alkali‐activated cement or GC at the material level, there is limited research in the literature on the structural performance of reinforced GC members. The aim of this study is to investigate the effect of fiber combination on the shear and flexural performance of RC beams with maximum and minimum reinforcement ratio. To investigate the shear and flexural behavior of GC beam, four‐point and three‐point tests were performed on 12 GC with hybrid fibers, 4 GC with trio fibers, and 2 GC fiber‐free as references beams. The test parameters were the combination of fibers (steel, glass, carbon, and basalt), the longitudinal reinforcement ratio, and loading type. The key test results include the load‐deflection behavior, characteristics of the cracks, the effect of fiber type on the shear and flexural performance, ductility and stiffness properties, microstructure, the strain in the concrete, and the bars and code predictions. The test results showed that as expected, reducing the longitudinal reinforcement ratio decreased the strength, but the decrease in strength was tolerated by using different types of fibers. The use of trio fibers in beams under bending increased the strength capacity, considerably. Finally, the capacity prediction performance of current codes, that is, GB50010, EuroCode‐2, TS500, and ACI318, were also examined, and the calculations resulted that the current code equations had a percentage error of approximately 25% and 82% on average for flexural and shear, respectively, although EuroCode‐2 equations performed slightly better. [ABSTRACT FROM AUTHOR]

This study focused on the partial replacement of river sand in fly ash-based geopolymeric mortar with Basic Oxygen Furnace (BOF) steel slag fine aggregate. The research aimed to create eco-friendly geopolymeric mortar using fly ash, steel slag and an alkaline solution of sodium hydroxide and sodium silicate. Physical testing against flowability, bulk density and water absorption has been conducted, and mechanical behaviour against compressive and flexural strength has also been investigated. However, the raw material and developed mortar have been characterised using Scanning Electron Microscope (SEM) for morphological studies, Fourier Transform Infrared Spectroscopy (FTIR), and X-Ray Diffraction (XRD) for mineralogical studies. Geopolymer mortar with 30% steel slag replacing river sand (30SSM) showed the highest strength, reaching 35MPa in compression and 5.6MPa in flexure. This strength can be attributed to the strong and flexible (ductile) characteristics of steel slag when combined with the geopolymeric paste. Additionally, the angular and rough surface texture of steel slag enhances the physical bonding within the matrix. This high-volume fly ash (cement-free) based steel slag aggregate geopolymeric mortar offers a sustainable option for various building components like paver blocks, bricks etc. Article Highlights: Partial replacement of river sand with BOF steel slag reduces environmental impact and promotes resource utilisation. 30% steel slag replacement yields maximum compressive (35MPa) and flexural strength (5.6MPa). The angular and vesicular structure of steel slag provides better physical connections in the geopolymeric matrix. [ABSTRACT FROM AUTHOR]

In the present work, medical waste ash was used as an aluminosilicate precursor to produce a geopolymer binder with stabilised heavy metals. The ash was initially calcined at a temperature of 800 °C for two hours to reduce the organic content. Calcined kaolin and medical waste ash were used as precursors to produce the geopolymer binder and sodium silicate and calcium oxides were used as alkaline activators. The effect of curing temperature (23, 60, and 100 °C) and the calcium oxide addition (0, 5, and 10%) on the geopolymer properties were evaluated. Eighteen geopolymer samples were prepared and evaluated for immobilizing heavy metals through the Toxicity Characteristic Leaching Procedure (TCLP). When compared to raw materials, TCLP results indicated that geopolymerization can significantly reduce the concentration of heavy metals in the medical waste ash leachate. The metal fixation percentages of the geopolymers ranged from 70 to 100%. The sequential extraction test results showed that geopolymerization (stabilization/solidification) is very beneficial in reducing the bioavailable fraction in the solid waste and maximizing the difficulty of fraction extraction. [ABSTRACT FROM AUTHOR]

The aim of this research is to evaluate the possibilities of improving the properties of natural pozzolan-based geopolymers with microwave curing in a shorter time and with less energy consumption. Volcanic tuff was used as an aluminosilicate source, sand was used as a filler, and potassium hydroxide and sodium silicate were used as alkali activators. The specimens were cured by four various methods: (i) heat; (ii) microwave; (iii) heat+microwave; (iv) microwave+heat curing. It has been determined that it is possible to improve the properties of mortar with microwave curing in a shorter time and with less energy consumption compared to heat curing. Heat+microwave and microwave+heat curing provided higher properties than only heat or only microwave curing. The lowest porosity (13,03 %) and the highest degree of reaction (18,67 %), unit weight (2,3 g/cm³), ultrasound pulse velocity (3,1 km/s), flexural strength (4,22 MPa), and compressive strength (15,05 MPa) were obtained by 24 hours of heat curing at 90°C followed by 15 minutes of microwave curing. The application of the combined curing methods is important in terms of improving the mechanical properties of the material approximately two times, although it causes a little more energy consumption compared to other methods. [ABSTRACT FROM AUTHOR]

Chemical activation of geopolymer concrete is critical for improving its performance. The purpose of this research is to improve the chemical activation of self-compacted fly ash-based geopolymer concrete exposed to chlorides using magnetized water. A multicompound activator containing sodium hydroxide (SH) and sodium silicate (SS) was used to activate fly ash. Various SS/SH ratios (1.0–3.0), various molarities of SH (8–16 M), and MW of 1.2 tesla were considered. Slump flow, L-box, v-funnel, compressive strength, chloride profile, and X-ray diffraction approaches were performed. The results confirmed that the optimal concentration of SH increased from 14 M in nonmagnetized concrete to 16 M in magnetized concrete, indicating that MW has a positive impact on the chemical activation and consequently the geopolymerization reaction. Concrete workability decreased as the SH concentration and SS/SH ratio increased. Using an SS/SH ratio of 3.0 results in superior mechanical behavior and increased chloride penetration resistance. [ABSTRACT FROM AUTHOR]

The cold sintering process (CSP) was used to produce membranes and improve the densification of a geopolymer-zeolite matrix, fully recycling a waste geopolymer powder. The role of CSP parameters were studied varying temperature (25, 40 and 80°C), applied pressure (56 MPa and 168 MPa) and reactive solution (H 2 O, KOH or NaOH 2, 4, 6, 8 M). CSP applied on the waste geopolymer powder (molar ratio Si/Al = 2.0 and K/Al = 1.0) resulted in relative densities ranging from about 50–77%, while modal pores varied from 0.006 µm to 0.017 µm in the mesopore range. Compressive strength was up to 45 MPa. The addition of 10 wt% of the waste geopolymer powder to a geopolymer- zeolite powder containing 81% of in situ synthetized NaA phase allowed a densification approaching 70% with mechanical strength up to 7.4 MPa. • Membranes were produced by cold sintering process (CSP). • A waste geopolymer powder was recycled to produce membranes. • Relative densities were 50–77% and modal pores 0.006–0.017 µm. • CSP on a geopolymer-NaA zeolite powder allowed a densification approaching 70%. [ABSTRACT FROM AUTHOR]

The nonlinearity and heterogeneity of geopolymer mix design have urged the research community to supplement the existing experimental design approach with machine learning and empirical regression models to improve the practical strength performance of geopolymers. This systematic review aims to elaborate and consolidate the fundamental machine learning algorithms and statistical models applied in the strength prediction of geopolymers. This review specifically delves into the statistical linear/nonlinear optimization algorithms, supervised machine learning algorithms, and model performance statistical metrics. The PRISMA and Scopus databases were used for bibliometric data extraction. The search strings devised to carry out the review were “geopolymer” OR “alkali-activated materials” AND “machine learning” OR “statistical modeling”. This review observed that neural networks, random forest, support vector machines, and Gaussian process regression give better strength prediction performances with R2 values > 0.9 and RMSE values < 3. The choice of activation function influenced the training performance of the algorithm and defined the prediction output accuracy. Hyperparameter tuning and Shapley additive explanations showed that input features with a greater effect on compressive strength were curing conditions and silicate modulus. This review promotes the consolidation of conventional experimental mix design approaches with machine learning techniques in solving geopolymer mix design and strength-related problems to give greater confidence to engineers and researchers in the applicability and versatility of these models to real-life practical scenarios saving time and minimizing costs.Article Highlights: Mix design is the core determinant of the mechanical strength Raw data undergoes preprocessing to address outliers and missing data ANFIS and DNN are emerging technologies with advanced predictive power [ABSTRACT FROM AUTHOR]

Red mud is a by-product from alumina industry. Global production of red mud was around 369 million tons in 2023, and India contributed over 6% of total. Landfilling of red mud may leach out heavy metals to soil and water, which could have negative consequences for the ecosystem. Incorporating the red mud in a geopolymer matrix is a safe option. This paper aims to analyse the environmental impact of the 1.0 m3 red mud containing geopolymer paving blocks using GaBi (Indian extension database) software. The data used for the analysis was generated from the studies conducted in continuous geopolymer pilot plant (10 tons/day). The analysis shows the major contributions from alkali activators and electricity. Red mud paving blocks exhibit global warming potential (275 kg CO2 eq.), human toxicity (51.7 kg DCB eq.), and terrestrial ecotoxicity potential (0.441 kg DCB eq.). Red mud blocks have similar acidification (1.65 kg SO2 eq.) and abiotic depletion potential (fossil) (3080 MJ) on comparison with cement paving blocks. Red mud geopolymer paving blocks offer a sustainable alternative with the reduced environmental footprint compared to conventional methods.Highlights: Red mud paving blocks seems to be more sustainable than traditional cement paving blocks. Red mud paving blocks exhibit lower global warming (21.6%), human toxicity (50%) and terrestrial ecotoxicity (38.9%) potential compared to cement paver. Abiotic depletion (fossil) and acidification potential are nearly same for both paving blocks. [ABSTRACT FROM AUTHOR]

Cement is one of the building materials that is most frequently utilized in the construction field. However, the cement industry contributes significantly to the production of greenhouse gases. Therefore, many works have focused on improving sustainable construction materials that could contribute to decreasing greenhouse gas emissions. This study aimed to design a sustainable geopolymer mortar (GPM) made of fly ash (FA) and ground-granulated blast furnace slag (GGBS), which would be suitable for repairing damaged concrete structures. The work focused on investigating the effect of GGBS percentage, alkaline activator ratio, and superplasticizer dosage on the compressive strength, setting time, and workability of an ambient-cured GPM. The results of this research indicated that the compressive strength of GPM improved with the increase in GGBS percentage until a certain limit. However, the workability and setting time deteriorated with the increase in GGBS percentage. Increasing the alkaline activator ratio contributed to improving the compressive strength, workability, and setting time of GPM up to specific levels, but then they started to reduce. Superplasticizer dosage contributed to enhancing the compressive strength, workability, and setting time of GPM. This study found that the optimum FA/GGBS-based GPM that may be used in repair applications contains 50% GGBS, 50% FA, and 5% superplasticizer. The silica sand/binder ratio and alkaline activator ratio were 2.75 and 1.0, respectively. The compressive strength at 1 day, setting time, and workability of the optimum mix were about 12.70 MPa, 20 min, and 138.75 mm, respectively. The XRF, XRD, TGA, and SEM analyses were useful tools used to interpret the effects of the alkaline activator ratio on the fresh and mechanical properties of GPM. [ABSTRACT FROM AUTHOR]

The use of seawater in cement-based concrete is debateable because it may increase the hydration rate but significantly decreases the durability. Alternately, seawater can be used as an alkaline activator solution in geopolymer however, very little is currently known about its effects. This study investigated the effect of seawater as alkaline activator mix solution and curing media on the compressive strength of geopolymer paste. The mixtures varied based on the molarity of alkaline activator solution. Alkaline activators were prepared with two solutions: diluted water and seawater. A day after casting, steam curing method was conducted at 65 °C for 2 hours and then immersed in seawater or normal water for 28 days. This study revealed that seawater in alkaline activator reduced the compressive strength by up to 25%. Applying temperature resulted the early age strength nearly comparable to the later age strength. Immersion the paste in seawater increased the strength up to 15%. The X-Ray diffraction analysis shown the presence of chloride on the surface, consequently preserving the compressive strength without any reduction at 28 days of immersion. The Scanning Electron Microscopy analysis inside the geopolymer paste prepared with seawater shown the microstructure of quartz, mullite, hematite, and the presence of chloride spread around resulting the disruption of polymerization. The results indicated that seawater has the potential as an alkaline activator mix solution and curing media, compensated by requirement of higher molarity of NaOH. [ABSTRACT FROM AUTHOR]

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To solve the problem of high energy consumption in tailings pretreatment methods and explore a low energy consumption tailings activation method, alkaline hydrothermal activation pretreatment was carried out on part of sulfur tailings to enhance their activity and improve the mechanical properties of sulfur tailings-based geopolymers. The influences of activation temperature and activation time on alkaline hydrothermal activation effect have been studied. X-ray diffraction technology, Fourier transform infrared spectroscopy analysis, thermogravimetric analysis, nuclear magnetic resonance imaging analysis, and scanning electron microscopy test were used to characterize the performance of activated sulfur tailings and sulfur tailings-based geopolymers. The results show that when the sulfur tailings are activated at 200 °C for 2. 0 h, the prepared geopolymer obtains the highest 3 and 28 d compressive strength, which are 15. 5 and 22. 1 MPa, respectively. Alkaline hydrothermal activation can effectively destroy the crystalline phase in sulfur tailings, promote the release of active silica and aluminum. More hydration product gel is formed in the gel system to improve the pore structure of geopolymer, thus improving the compressive strength of sulfur tailings-based geopolymers. The above experimental results indicate that alkaline hydrothermal activation is a method that can effectively improve the activity of sulfur tailings. [ABSTRACT FROM AUTHOR]

In order to clarify the optimal liquid-solid ratio ( L/ S) values for the activation of metakaolin at different concentrations of phosphoric acid solution, five sets of phosphoric acid solution of 4, 5, 6, 7 and 8 mol•L-1 were set up, and four L/ S values of 0. 6, 0. 7, 0. 8 and 0. 9 were used for preparation of metakaolin-phosphoric acid based geopolymer (MPAG). The 7 and 28 d compressive and flexural strengths of MPAG were used as the evaluation indexes to investigate the effects of above preset variables on its mechanical properties. The compressive strength of samples corresponding to the optimal L/ S value concentration of each group after sulfate erosion were further investigated. Finally, the phase composition and microscopic morphology of MPAG were characterized and analyzed. The results show that MPAG is mainly composed of an amorphous aluminum phosphate phase. Greater compressive strength can be obtained by using L/ S value of 0. 6 when the concentration of phosphoric acid solution is 4 - 6 mol•L-1, and when the concentration increase to 7 - 8 mol•L-1, the recommended of L/ S value is 0. 7. MPAG exhibits good sulfate resistance, with a compressive strength retention rate of 84% to 93% after 28 d immersion. The samples prepared with 6 mol•L-1 phosphoric acid under any L/ S value achieved the maximum flexural strength for that L/ S value. The 28 d maximum flexural strength is 6. 80 MPa when L/ S value is 0. 6. The results of this study can provide references for the preparation and application of MPAG. [ABSTRACT FROM AUTHOR]

Geopolymers (GPs) are emerging, low‐density ceramic materials that are simple to manufacture, with high elastic modulus and strength, albeit with low toughness. Fiber reinforcements have been used to achieve varied ductile behaviors, but little is known about the GP addition to polymeric frame structures. Thus, drawing inspiration from the nanostructure of bones, this paper investigated an interpenetrating, co‐continuous composite consisting of a GP as the stiff but brittle phase, and a 3D‐printed polymer (PA12 White) as the soft and deformable phase. The composite mechanical properties and failure modes were studied experimentally using uniaxial compression and four‐point bending tests. The co‐continuous network constrained brittle cracking within the GP and reduced strain localization in the polymer. The results showed that the composite had higher strength (56.11 ± 2.12 MPa) and elastic modulus (6.08 ± 1.37 GPa) than the 3D‐printed polymer and had higher toughness (5.98 ± 0.24 MJ/mm3) than the GP for the specific geometries examined. The shape effect study demonstrated that cubic structures had higher elastic modulus and strength but at the expense of lower toughness when compared to rectangular prism structures. The study of scale effects indicated that increasing the number of periodic unit cells while maintaining consistent bulk dimensions led to augmented strength and toughness, albeit without statistically significant alterations in elastic modulus. Thus, this paper presents an experimental realization of a novel, bio‐inspired, interpenetrating, GP–polymer composite design, offering improved strength and toughness. It also provides valuable insights into the shape and size effects on the mechanical properties of this new composite. [ABSTRACT FROM AUTHOR]

Expansive soil is widely distributed and often needs to be improved for engineering and construction needs. Using blast furnace slag and fly ash as precursors and NaOH as an alkali activator, a geopolymer was prepared to solidify expansive soil, and the effect of nano-SiO2 on the compressive strength and water stability of the geopolymer-solidified expansive soil was further studied. The effects of alkali addition ratio, nano-SiO2 addition ratio, and curing agent addition ratio on the unconfined compressive strength and water stability of the cured soil were studied through unconfined compressive strength tests, and the curing mechanism was analyzed by electron microscopy scanning. The experimental results showed that the unconfined compressive strength and water stability of geopolymer-stabilized soil first increased and then decreased with an increase in alkali activator dosage. The optimal dosage of alkali activator was found to be 12.5%. Furthermore, it was found that adding nano-SiO2 can further enhance the strength and water stability of solidified soil. When the content of nano-SiO2 was 3%, the unconfined compressive strength was increased by 15%. With an increase in the content of nano-SiO2 doped polymer (GFNS), the unconfined compressive strength and water stability of the solidified soil showed a trend of first increasing and then decreasing, reaching a peak at a content of 20%. The cementitious materials, such as hydrated calcium silicate and hydrated calcium silicate aluminate, generated by the reaction between nano-SiO2 and geopolymer played a role in bonding and filling in the solidified soil. Under the joint action of the two, the structural arrangement between the solidified soil particles became more compact, which improved the strength of the solidified soil. [ABSTRACT FROM AUTHOR]

The potential substitution of Portland cement–based concrete with low- and high-calcium fly ash–based geopolymers was investigated. However, predicting the workability and compressive strength of geopolymers with the desired physical and mechanical properties is a complicated process because of the variety of chemical compositions found in aluminosilicate sources. Therefore, machine-learning techniques were used to predict the physical and mechanical properties of the geopolymers and eliminate the usual trial-and-error laboratory procedures. The experimental and predicted results of geopolymer properties using the multilayer perceptron regressor, voting regressor, and XGBoost techniques were compared. The XGBoost model outperformed the other models in terms of accuracy for predicting workability and compressive strength, producing the R2 of 0.96 and 0.89, respectively. Sensitivity analysis determined that the percentage of CaO had the largest effect on geopolymer workability of 27.13%. Fly ash content had the largest effect on compressive strength of 34.44%. Our approach offers a straightforward and dependable strategy for designing and optimizing fly ash–based geopolymers. [ABSTRACT FROM AUTHOR]

This study aimed to evaluate the potential of replacing fly ash (FA) with bauxite tailing (BT) slurry for geopolymer synthesis and investigate the long-term leaching behaviour of BT slurry/FA geopolymers (BFGs) for heavy metal immobilisation. The mechanical properties and heavy metal immobilisation efficiency of BFGs were tested, and numerical simulations were conducted to assess their environmental impact as a backfill material. The results showed that the incorporation of 5 Wt.% BT increased the early compressive strength of the geopolymer without any additional treatment. A small quantity of Cu2+ improved the mechanical strength, while excess heavy metals harmed the geopolymer. Heavy metal immobilisation efficiency decreased with increased heavy metal addition and exceeded 99.9% for Pb2+ and Cu2+ when simulating acid rain leachate. The modified Elovich equation described the leaching kinetics of Cu2+ well, and the leaching rate decreased with time. Numerical analysis indicated that Cu2+ leaching from landfill leachate occurred in three phases, with an initial increase followed by a gradual decrease, stabilisation, and diffusion into the surrounding soil layer. This study provides insight into the material's long-term stability and environmental performance, offering a scientific basis for relevant engineering applications. Highlights: Direct utilisation of unprocessed tailing slurry to synthesise geopolymer. The leaching pattern of Pb2+ and Cu2+ under acidic conditions was explored. The modified Elovich equation effectively describes the leaching kinetics of Cu2+. The environmental impact of bauxite tailings slurry-based geopolymers was evaluated. [ABSTRACT FROM AUTHOR]