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In order to further reveal the tectonic activity of the central and northern North China Craton (NCC) since late Paleozoic, the Datong coal-bearing basin was selected as the research object. The tectono-thermal events and uplifting cooling events of the basin were retrieved through zircon and apatite fission tracks and vitrinite reflectance measurements. The research shows that the Datong coal-bearing basin experienced three tectono-thermal events with ages of 245–207 Ma (middle–late Triassic), 179 ± 9 Ma (early Jurassic), and 140 Ma to 78 ± 11 Ma (middle–late Cretaceous), respectively. That just coincides with the lamprophyre activity, Kouquan fault activity, and Zuoyun basaltic andesite magmatic activity which surround the Datong coalfield. The basin also experienced three uplift events with the peak ages of 202 ± 18 Ma (late Triassic), 157 ± 7 Ma (late Jurassic), and 45 ± 3 Ma or 36 ± 3 Ma (middle Eocene), respectively. The Datong Permo-Carboniferous and Jurassic coal vitrinite reflectance proved that the average metamorphism temperature is 104–108 °C, even reaching 163–367 °C. The fission track results showed that the paleotemperature was even higher than 170–250 °C from 117 to 282 Ma and 80–120 °C from 20 to 68 Ma, in the Datong coal-bearing basin. The results show that the deep tectonic activities of the NCC were still active in the Mesozoic and even Cenozoic Paleogene. [ABSTRACT FROM AUTHOR]

Deep-seated structures can exhume deep crustal rocks (>20 km), transmitting the signal of geodynamic processes from the subduction zone to the interiors of the continents. The role of deep-seated structures can be analyzed with low-temperature thermochronological dating techniques. However, studies coupling low-temperature thermochronology with structural geological analyses of the deformational style are not common in the Northern Andes. In this contribution, we present new apatite (AFT) and zircon (ZFT) fission-track data coupled with meso- and microstructural analyses to reveal the deformational and exhumation history of the Santander Massif (SM; Northern Andes) and the related cortical Bucaramanga strike-slip fault (BF). Samples for thermochronological analyses were collected along an elevation profile with a significant elevation difference of 2.4 km across the western flank of the SM, crossing the BF. The time-temperature history modeling of ZFT data reveals phases of prolonged residence in the zircon partial annealing zone from ∼125 to 94 Ma and a cooling phase related to an exhumation episode at around 25 Ma based on samples collected near the BF. Inverse modeling of AFT data reveals structurally-controlled Pliocene exhumation rates of 0.6–0.7 km/Myr mediated by the action of secondary faults. A shift in the deformation style resulting from the oblique interaction of the SM and Mérida Andes domain is interpreted as the main driver of the Pliocene exhumation. This deformation phase is observed in the fault damage zone, where evidence of brittle-ductile deformation was exhumed. Finally, we discuss the geodynamic implications of our thermochronological and structural analyses, contrasting local and more regional competing hypotheses (Pamplona Indenter vs. slab break-off of the Caribbean plate), which may explain the tectonic evolution of the northern part of the Eastern Cordillera and the SM in the Colombian Northern Andes. • Oligocene Bucaramanga fault exhumation coincides with NW Panama block collision, influencing North Andes tectonic escape. • Active Miocene-Pliocene exhumation along the leading S–W edge of an indenting block linked to Caribbean slab break-off. • Meso- and microstructural data evidence crustal deformation and exhumation of different structural levels. [ABSTRACT FROM AUTHOR]

Keywords: Monazite; fission tracks; etching; FIB-SEM; etch-anneal-etch EN Monazite fission tracks etching FIB-SEM etch-anneal-etch 1065 1073 9 06/01/22 20220601 NES 220601 Introduction A series of experiments presented by [9] led to a first-order understanding of monazite fission track etching properties. [Extracted from the article]

This publication shows results of a comparison of three techniques for localising radioactive, and U-bearing particles in contrasted samples. Particles are localised by the means of three methods: (1) Fission Tracks (FT), (2) Imaging Plate (IP), and (3) real time autoradiography (BeaQuant®). These techniques were applied to various samples, including a sediment sampled in the vicinity of the Fukushima Dai-Ichi Nuclear Power Plant (FDNPP) and a sample made of pure U oxide particles. In addition, the efficiency of the combination of two methods (FT and IP) to localise specifically anthropogenic U-bearing particles was tested. [ABSTRACT FROM AUTHOR]

• Shrinkage of latent tracks during in situ ion irradiation is observed and quantified. • Rather than alpha-particles, alpha-recoils induce significant track-shrinkage. • Zircon is more sensitive than apatite to alpha-recoil-induced track-shrinkage. • The etchable lengths of latent fission tracks can be estimated as a function of α-dose. • Alpha-recoil-induced track shortening must be considered in natural zircon. The diffusion of defects (e.g., vacancies and interstitials) and elements used for dating (e.g., He and Pb) in a mineral structure is a thermal process: This is the primary assumption used to determine the age and thermal history of minerals. For instance, thermal history reconstruction, through the number and length distribution of tracks produced by spontaneous fission of 238U, is obtained by assuming a thermal event to be the only energy source for shortening of fission tracks. Here, we report a new, non-thermal energy source that induces additional shortening of fission tracks by the irradiation of alpha-recoils from the alpha-decay of 238U and 232Th. We simulate alpha-decay induced track-shortening by combining ion accelerator irradiations with transmission electron microscopy. This allows for the first observation of track-shrinkage during in situ ion irradiation. We show that rather than alpha-particles, alpha-recoils induce a significant shortening of fission tracks by nuclear-collisions. The shortening of track-length can be quantified as a function of alpha-decay event dose. However, apatite is less sensitive than zircon to this non-thermal process. The findings exemplify the interactions among different types of self-irradiation from alpha-particles, alpha-recoils and fission-fragment nuclei in single mineral grains and have important implications for the use of zircon and apatite for radiometric dating and thermochronology. [ABSTRACT FROM AUTHOR]

Application of the glass fission-track dating method to Chester Bluff tephra (CBt), exposed in loess deposits at Chester Bluff along the Yukon River in east-central Alaska, has clarified the age of the immediately underlying fossiliferous interglacial bed. Surprise Creek tephra (SZt), at site CRH47 in the northern Old Crow basin of the Yukon Territory, is a correlative of CBt so that the new age information on CBt can also be applied to the interglacial sediments below SZt. Two independent age determinations were obtained on CBt, 243 ±28 ka and 249 ±26 ka, giving a weighted mean age and error of 246 ±19 ka. Therefore, the closely associated interglacial bed belongs to the early part of Marine Oxygen Isotope Stage (MIS) 7. The stratigraphy and paleoenvironmental setting of SZt show that deposition of the tephra occurred soon after interglacial conditions, when the climate became colder, probably between MIS 7.5 and 7.4, that is, slightly younger than the mean fission-track age, but within the 1σ uncertainty. This result tightly constrains the age of the rich mammalian faunal assemblage found at and just below SZt at the CRH47 site. [ABSTRACT FROM AUTHOR]

Despite the conceptual elegance and simplicity of the External Detector Method (EDM) for fission track dating, an increasing number of laboratories are switching to LA-ICP-MS as a means of measuring the uranium content of apatite, zircon and sphene. LA-ICP-MS based fission track (LAFT) dating offers shorter turnaround times, removes the need to handle radioactive materials and hydrofluoric acid, and facilitates double-dating with the U-Pb method. This paper aims to bring the statistical treatment of LAFT data on an equal footing with the EDM by formulating four different analytical protocols, depending on the accuracy and reproducibility of the uranium measurements. Under the ‘absolute’ dating approach, the spontaneous track densities and uranium concentrations are directly plugged into the fundamental fission track age equation, assuming that both of these measured quantities have been determined accurately, and that the fission decay constant and equivalent isotopic track length are known. The ‘zeta calibration’ approach avoids making these assumptions by normalisation to a reference material of known age. Uranium zoning has a detrimental effect on the accuracy of LAFT ages. This effect can be removed by counting only those fission tracks located within the laser ablation pit. Alternatively, the uranium heterogeneity may be quantified by fitting multiple ablation spots in some or all the analysed grains, using a (lognormal) distributional assumption for the uranium concentration. LAFT dating is arguably less well suited than the EDM to young and U-poor samples that lack sufficient spontaneous fission tracks to reveal visual evidence for uranium zoning. Such samples occasionally contain no fission tracks at all, resulting in infinite analytical uncertainties. This paper introduces a pragmatic solution to this problem, in which the uranium measurement are converted to ‘virtual’ induced fission track counts to produce strictly positive ages with finite standard errors. With the age equation and zero-track strategy in place, LAFT ages can be subjected to more sophisticated statistical analysis. Using a logarithmic transformation, these ages can be visualised on radial plots and deconvolved into finite and continuous mixtures. The methods introduced in this paper have been implemented in a software package called IsoplotR that is available free of charge at http://isoplotr.london-geochron.com . [ABSTRACT FROM AUTHOR]

Synchrotron radiation techniques (μ-XRF and μ-XANES) were applied to the study of organic-rich phosphatized limestones of NW Greece (Epirus). The results revealed uranium accumulation in areas of the material containing, among others, carbonate apatite (francolite) and organic matter. The U L -edge of μ-XANES spectra showed that uranium was present in tetravalent form. U-bearing francolite crystals were separated from the rock and characterized by Raman spectroscopy and microprobe. The analysis of the crystals also indicated the presence of sodium and sulfur. The uranium presence in the crystals was also visualized, after neutron irradiation and etching, by the observation of the fission tracks. [ABSTRACT FROM AUTHOR]

HeFTy is a popular thermal history modelling program which is named after a brand of trash bags as a reminder of the ‘garbage in, garbage out’ principle. QTQt is an alternative program whose name refers to its ability to extract visually appealing (‘cute’) time–temperature paths from complex thermochronological datasets. This paper compares and contrasts the two programs and aims to explain the algorithmic underpinnings of these ‘black boxes’ with some simple examples. Both codes consist of ‘forward’ and ‘inverse’ modelling functionalities. The ‘forward model’ allows the user to predict the expected data distribution for any given thermal history. The ‘inverse model’ finds the thermal history that best matches some input data. HeFTy and QTQt are based on the same physical principles and their forward modelling functionalities are therefore nearly identical. In contrast, their inverse modelling algorithms are fundamentally different, with important consequences. HeFTy uses a ‘Frequentist’ approach, in which formalised statistical hypothesis tests assess the goodness-of-fit between the input data and the thermal model predictions. QTQt uses a Bayesian ‘Markov Chain Monte Carlo’ (MCMC) algorithm, in which a random walk through model space results in an assemblage of ‘most likely’ thermal histories. In principle, the main advantage of the Frequentist approach is that it contains a built-in quality control mechanism which detects bad data (‘garbage’) and protects the novice user against applying inappropriate models. In practice, however, this quality-control mechanism does not work for small or imprecise datasets due to an undesirable sensitivity of the Frequentist algorithm to sample size, which causes HeFTy to ‘break’ when datasets are sufficiently large or precise. QTQt does not suffer from this problem, as its performance improves with increasing sample size in the form of tighter credibility intervals. However, the robustness of the MCMC approach also carries a risk, as QTQt will accept physically impossible datasets and come up with ‘best fitting’ thermal histories for them. This can be dangerous in the hands of novice users. In conclusion, the name ‘HeFTy’ would have been more appropriate for QTQt, and vice versa. [ABSTRACT FROM AUTHOR]

Abstract: In this paper, we will describe and indicate the performance of a new method based on the use of femtosecond laser ablation (fs-LA) coupled to a quadrupole-based inductively coupled plasma mass spectrometer (ICP-QMS) for analyzing the isotopic composition of micrometer-size uranium particles. The fs-LA device was equipped with a high frequency source (till 10kHz). We applied this method to 1–2μm diameter-uranium particles of known isotopic composition and we compared this technique with the two techniques currently used for uranium particle analysis: Secondary Ionization Mass Spectrometry (SIMS) and Fission Track Thermal Ionization Mass Spectrometry (FT-TIMS). By optimizing the experimental conditions, we achieved typical accuracy and reproducibility below 4% on 235U/238U for short transient signals of only 15s related to 10 to 200pg of uranium. The detection limit (at the 3 sigma level) was ~350ag for the 235U isotope, meaning that 235U/238U isotope ratios in natural uranium particles of ~220nm diameter can be measured. We also showed that the local contamination resulting from the side deposition of ablation debris at ~100μm from the ablation crater represented only a small percentage of the initial uranium signal of the ablated particle. Despite the use of single collector ICP-MS, we were able to demonstrate that fs-LA-ICP-MS is a promising alternative technique for determining uranium isotopic composition in particle analysis. [Copyright &y& Elsevier]

In this paper we describe the application of laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) coupling to particle analysis, i.e., the determination of the isotopic composition of micrometric uranium particles. The performances of this analysis technique are compared with those of the two reference particle analysis techniques: secondary ion mass spectrometry (SIMS) and fission track-thermo-ionization mass spectrometry (FT-TIMS), based on the measurement of the isotopic ratios of U/U in particles present in an inter-comparison particulate sample. The agreement of the results obtained using LA-ICP-MS with target values and with the results obtained using FT-TIMS and SIMS was good. Accuracy was equivalent to that of the other two techniques (±3 % deviation). However, relative experimental uncertainties present with LA-ICP-MS (7 %) were higher than those present with FT-TIMS (4.5 %) and SIMS (3 %). Furthermore, measurement yield of LA-ICP-MS coupling was close to that obtained with the same quadrupole ICP-MS for the measurement of a liquid sample (~10), but lower than that obtained with FT-TIMS and SIMS, respectively, by a factor of 10 and 20, although the particles analyzed using LA-ICP-MS were most likely smaller (diameter ~0.6 μm, containing 4-7 fg of U). Nevertheless, thanks to the brevity of the signals obtained, the detection capacity for low isotopic concentrations by LA-ICP-MS coupling is equivalent to that of FT-TIMS, although it remains well below that of SIMS (×15). However, with more sensitive double focusing ICP-MS, performances equivalent to those achieved using SIMS could be obtained. [ABSTRACT FROM AUTHOR]

Using artificially created swift, heavy ions of 129I with a typical fission-fragment mass and specific energies which are common during the spontaneous fission of 238U, the response in minerals commonly used in geochronological dating such as muscovite, zircon and apatite, has been evaluated by the means of Atomic Force Microscopy (AFM). The surface impact structures form hillocks with greater diameters but smaller heights for low-energetic ions and smaller diameters but greater heights for high-energetic ions. The observed hillock widths range from 22 ± 2 nm for low-energetic ions to 17 ± 1 nm for the highest energy in mica. Furthermore, the dimensions formed in apatite for low and high-energy ions range from 53 ± 2 nm to 27 ± 2 nm and from 64 ± 3 nm to 28 ± 1 nm in zircon. With increasing 129I particle energy hillock heights increase, but diameters decrease regardless of mineral orientation. The crystallographic orientation of apatite and zircon also seems to have no effect on hillock dimensions, which are identical for perpendicular and parallel to the c-axis oriented mineral grains. The results support the “Compound Spike” track formation model of Chadderton (2003), which combines the Coulomb ion explosion model with a thermal spike model. [ABSTRACT FROM AUTHOR]

Abstract: One of the purposes of this study is to give further constraints on the temperature range of the zircon partial annealing zone over a geological time scale using data from borehole zircon samples, which have experienced stable temperatures for ∼1 Ma. In this way, the extrapolation problem is explicitly addressed by fitting the zircon annealing models with geological timescale data. Several empirical model formulations have been proposed to perform these calibrations and have been compared in this work. The basic form proposed for annealing models is the Arrhenius-type model. There are other annealing models, that are based on the same general formulation. These empirical model equations have been preferred due to the great number of phenomena from track formation to chemical etching that are not well understood. However, there are two other models, which try to establish a direct correlation between their parameters and the related phenomena. To compare the response of the different annealing models, thermal indexes, such as closure temperature, total annealing temperature and the partial annealing zone, have been calculated and compared with field evidence. After comparing the different models, it was concluded that the fanning curvilinear models yield the best agreement between predicted index temperatures and field evidence. [Copyright &y& Elsevier]

The thermal recovery (annealing) of mineral structure modified by the passage of fission fragments has long been studied by the etching technique. In minerals like apatite and zircon, the annealing kinetics are fairly well constrained from the hour to the million-year timescale and have been described by empirical and semi-empirical equations. On the other hand, laboratory experiments, in which ion beams interact with minerals and synthetic ceramics, have shown that there is a threshold temperature beyond which thermal recovery impedes ion-induced amorphization. In this work, it is assumed that this behavior can be extended to the annealing of fission tracks in minerals. It is proposed that there is a threshold temperature, T, beyond which fission tracks are erased within a time t, which is independent of the current state of lattice deformation. This implies that iso-annealing curves should converge to a fanning point in the Arrhenius pseudo-space (ln t vs. 1/ T). Based on the proposed hypothesis, and laboratory and geological data, annealing equations are reevaluated. The geological timescale estimations of a model arising from this study are discussed through the calculation of partial annealing zone and closure temperature, and comparison with geological sample constraints found in literature. It is shown that the predictions given by this model are closer to field data on closure temperature and partial annealing zone than predictions given by previous models. [ABSTRACT FROM AUTHOR]

Abstract: The Apennine Range is a young convergent orogen that formed over a retreating subduction zone. Syn-orogenic metamorphic rocks are exposed in the mid-Tuscan ridge, Tuscan coast and Tuscan Archipelago and provide information about processes of continental subduction and exhumation associated with accretion and retreat. Apatite and zircon fission-track analyses were applied to some of these syn-orogenic metamorphic rocks. The new low-temperature thermochronological data helped to constrain the timing of the metamorphic peak and the age and modality of exhumation of these rocks that were structurally buried at 20 to 40km depth during the main tectonogenic phase of the Northern Appenine belt. In the Giglio and Elba islands and in the Monti dell''Uccellina, along the coast, minimum ages of partially reset zircon samples yielded a first time constraint on the Late-Oligocene age of the metamorphic peak. The ca. 27Ma obtained at the Monti dell''Uccellina is coeval to that found in the Alpi Apuane (located at the northern termination of the mid-Tuscan ridge). The data from the Tuscan Archipelago point to a slightly older age. In the Monti Pisani, south of the Alpi Apuane, and in the Argentario Promontary along the coast, south of the Monti dell''Uccellina, completely reset zircon samples, but composed by different populations, were behaving as multiple thermochronometers and confirm the already proposed isothermal nature of the exhumation occurred after the metamorphic peak. Zircon P1 peak indicated that at 13–10Ma rocks were already at shallow crustal levels (<9km). Zircon minimum ages and apatite ages point to a sharp increase in the exhumation rate at ~6–4Ma. Data indicate a common thermal history for the whole mid-Tuscan ridge and coastal outcrops. The 6–4Ma increase in exhumation rate can be attributed either to unroofing due to the extensional tectonics or to a contractional “out-of-sequence” or “re-activation” event occurring in the internal sector of Tuscany already affected by a regional extensional regime. [Copyright &y& Elsevier]

Abstract: The fission track technique is a sensitive detection method for particles which contain radio-nuclides like 235U or 239Pu. However, when the sample is a mixture of plutonium and uranium, discrimination between uranium particles and plutonium particles is difficult using this technique. In this study, we developed a method for detecting plutonium particles in a sample mixture of plutonium and uranium particles using alpha track and fission track techniques. The specific radioactivity (Bq/g) for alpha decay of plutonium is several orders of magnitude higher than that of uranium, indicating that the formation of the alpha track due to alpha decay of uranium can be disregarded under suitable conditions. While alpha tracks in addition to fission tracks were detected in a plutonium particle, only fission tracks were detected in a uranium particle, thereby making the alpha tracks an indicator for detecting particles containing plutonium. In addition, it was confirmed that there is a linear relationship between the numbers of alpha tracks produced by plutonium particles made of plutonium certified standard material and the ion intensities of the various plutonium isotopes measured by thermo-ionization mass spectrometry. Using this correlation, the accuracy in isotope ratios, signal intensity and measurement errors is presumable from the number of alpha tracks prior to the isotope ratio measurements by thermal ionization mass spectrometry. It is expected that this method will become an effective tool for plutonium particle analysis. The particles used in this study had sizes between 0.3 and 2.0μm. [Copyright &y& Elsevier]

(U-Th)/He and fission-track analyses of apatite along deep-seated tunnels crossing high-relief mountain ranges offer the opportunity to investigate climate-tectonic forcing on topographic evolution. In this study, the thermochronologic analysis along the Simplon tunnel (western-central Alps; Italy and Switzerland) constrains in detail the mechanisms controlling the topographic evolution of the Simplon Massif. Cooling rates vary from about 10°C/Ma at about 10 Ma to about 35°C/Ma in the last 3 Ma. Such increase in cooling rates corresponds to the inception of glacial cycles in the northern hemisphere. Age patterns show correlation with faults distribution until 2 Ma, suggesting that tectonics-controlled rocks exhumed up to that age. After 2 Ma thermo-chronometric data show that the Simplon area has experienced primarily erosional exhumation. All age patterns provided are not affected by topographic effects, thus indicating that present-day topography has been carved in the last 2 Ma, most likely controlled by glacial erosion. [ABSTRACT FROM AUTHOR]

The present-day topography of the Tian Shan range is considered to result from crustal shortening related to the ongoing India-Asia collision that started in the early Tertiary. In this study we report evidence for several episodes of localized tectonic activity which occurred prior to that major orogenic event. Apatite fission track analysis and (U-Th)/He dating on apatite and zircon indicate that inherited Paleozoic structures were reactivated in the late Paleozoic-early Mesozoic during a Cimmerian orogenic episode and also in the Late Cretaceous-Paleogene (around 65-60 Ma). These reactivations could have resulted from the accretion of the Kohistan-Dras arc or lithospheric extension in the Siberia-Mongolia zone. Activity resumed in the late Mesozoic prior to the major Tertiary orogenic phase. Finally, the ongoing deformation, which again reactivates inherited tectonic structures, tends to propagate inside the endoreic basins that were preserved in the range, leading to their progressive closure. This study demonstrates the importance of inherited structures in localizing the first increments of the deformation before it propagates into yet undeformed areas. [ABSTRACT FROM AUTHOR]

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