1. Adsorptive removal of Cu2+ and Ca2+ from aqueous solution by microcrystalline cellulose extracted from post-harvest banana pseudo-stem.
- Author
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Nguyen Thi, Quynh Anh, Nguyen, Manh Hien, Huy, Nguyen Nhat, Padungthon, Surapol, and Nguyen, Trung Thanh
- Subjects
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FOURIER transform infrared spectroscopy , *POINTS of zero charge , *WATER hardness , *SCANNING electron microscopy , *METAL ions - Abstract
In this study, microcrystalline cellulose was prepared from the post-harvest banana stem by using a homogeneous Fenton system (MCC-F) and used as an adsorbent for removing Cu2+ and Ca2+. Simultaneously, the reference materials of MCC-H and MCC-N were also prepared by using H2O2 and NaIO4 solutions, respectively. Characteristics of the prepared materials were determined by scanning electron microscopy, Fourier transform infrared spectroscopy, X-ray diffraction, thermogravimetric analysis, the point of zero charge, and the content of aldehyde and carboxyl functional groups. In batch Cu2+ and Ca2+ adsorption tests, an optimal pH value of 7.0 was found for both target metal ions while 30 min and 75 min were chosen as the optimal contact time for Cu2+ and Ca2+ ions, respectively. The best fit was obtained with the pseudo-second-order kinetic model. Langmuir, Freundlich, and D–R isotherm models were applied to calculate adsorption data. Thermodynamic results suggest that the adsorption of metal ions by MCC-F is an exothermic and spontaneous process. Therefore, MCC-F is a high-potential and promising material for water and wastewater treatment. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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