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Heat dissipation becomes a critical problem because of the miniaturisation and the increase of power density in electronic devices and electric equipment, which calls for electrical insulating materials with high thermal management capability. Epoxy thermosets have been widely used as electrical insulating materials, but suffer from their low thermal conductivity. This study reviewed the research progress on the development of epoxy thermosets with high pristine thermal conductivity. First, the thermal conduction mechanism of polymers was briefly introduced. Second, the approaches used to enhance the thermal conductivity of epoxy thermosets were summarised, which mainly dealt with the formation of microscopically anisotropic but macroscopically isotropic structure in the epoxy thermosets. Third, the applications of high thermal conductivity epoxy thermoset resins were reviewed. Finally, the review provided the existing challenges and the future directions for the development of epoxy thermosets with high pristine thermal conductivity.

Investigating Epoxy/hardener ratio and adsorption rate in epoxy/graphene oxide nanocomposites is of great importance, since these values can affect on the mechanical properties of the nanocomposite. In this study, molecular dynamics simulation was used to investigate and compare the mechanical properties of epoxy/graphene and graphene oxide nanocomposites (EPON 828, EPON 862, Epoxy Novolac, and Cycloaliphatic Epoxy with GNs and GO). Also, the effect of different weight percentages of graphene oxide (0,1,3 and 5 wt %), different weight percentages of epoxy compared to hardener, adsorption rate, and different temperatures were studied. The results showed that increasing the weight percentage of graphene oxide in epoxy matrices improved the adsorption rate between Epoxy/GO and the strength of nanocomposites. In addition, the amount of Young's modulus slightly decreased with increasing the temperature. Besides, the highest amount of Young modulus was obtained by increasing the weight percentage of epoxy to hardener at 63:37 wt %. Moreover, by comparing the mechanical properties of epoxy nanocomposites at 5 wt % graphene oxide, the highest Young modulus were found to be related to Novolac/GO 4.27 Gpa and EPON 862/GO 4.24 Gpa. This study contributes to a more comprehensive understanding on the behavior of the mechanical properties of epoxy/graphene oxide nanocomposites. [Display omitted] • Relationship between matrix and reinforcement in nanocomposites. • Functionalized graphene improved adsorption and mechanical properties. • Effect of Epoxy/hardener ratio and crosslink on mechanical properties. • Novolac/GO and EPON862/GO are best candidates between nanocomposites. [ABSTRACT FROM AUTHOR]