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Soil degradation poses a significant challenge to Egypt's agriculture, making resource optimization essential. Nanobiochar presents a promising solution for pollutant removal; however, its low yields may hinder commercialization. This study investigates the production of biochar from sugarcane bagasse and olive mill waste, focusing on its composition, morphology, and effectiveness in soil immobilization. Advanced techniques like SEM, TEM, and FTIR were used to characterize the nanobiochar, highlighting its potential as a sustainable solution to soil contamination. The study revealed that ZnCl2 treatment significantly lowers pH, while KOH modification raises it. Surface morphology analysis showed that SCB biochar exhibited a highly porous structure, while OMW biochar had less porous edges and irregular oval-shaped pores. The effects of biochar activation on the availability of heavy metals like Ni, Pb, and Mo (in mg.Kg−1) were also examined. Ni concentrations decreased from 1.27 mg.Kg−1 in untreated biochar (NA) to 0.78 mg.Kg−1 in KOH-treated biochar (KA) and 0.67 mg.Kg−1 in ZnCl2-treated biochar (ZnA). Pb levels dropped from 7.7 mg.Kg−1 in NA to 5.2 mg.Kg−1 in KA and slightly to 4.74 mg.Kg−1 in ZnA. Mo showed a similar trend, with the highest concentration in NA at 1.21 mg.Kg−1, followed by 0.88 mg.Kg−1 in KA and 0.75 mg.Kg−1 in ZnA. Overall, OMW nanobiochar demonstrated a greener, more sustainable solution to soil contamination compared to SCB nanobiochar. [ABSTRACT FROM AUTHOR]

This paper presents the authentication analysis of a bronze bust of Napoleon I, attributed to the Italian artist Renzo Colombo (1856–1885) based on his signature and other casting and molding inscriptions. The bust was made using the lost wax technique and artificially patinated in the Pinédo variant workshop. This study combined historiographical research (using the specialized literature) with data from auction catalogs. These were compared with photographs of the entire bust and close-up images of key areas, including anthropomorphic features, clothing, inscriptions, and structural and ornamental details. The condition of the bust and its historical and chemical characteristics were assessed through direct analysis with magnifying tools and indirect analysis using scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDX). [ABSTRACT FROM AUTHOR]

Members of Asteraceae family have properties enabling their application for medical purposes. The major- and microelement content in 15 medicinal species of the Asteraceae family growing in the National Botanical Garden, Republic of Moldova was determined by instrumental neutron activation analysis. A total of 31 chemical elements, Na, Mg, Al, Cl, K, Ca, Sc, V, Cr, Mn, Fe, Co, Ni, Zn, As, Se, Br, Rb, Sr, Mo, Sb, Cs, Ba, La, Ce, Sm, Tb, Hf, Ta, Th and U, were identified in herbal samples. Potassium was found to be the most abundant major element; its content in plants ranged from 20,700 mg/kg in Artemisia lerchiana to 58,000 mg/kg in Matricaria recutita. The content of other major elements existed in the following ranges: Ca from 4700 to 14,200 mg/kg and Mg from 1710 to 3870 mg/kg. The maximum content of Mg, K and Ca in analyzed plants was higher compared to data presented in the literature. Among essential microelements the most abundant were Fe (83–910 mg/kg), Mn (23–150 mg/kg) and Zn (27–76 mg/kg). The daily intake of metal and the health risk index for selected elements (As, Ni, Sb, V, Mn, Cr, Co, U, Sr, Al, Fe, and Zn) were calculated. Health risk indexes were obtained for V and Co in Calendula officinalis, Tanacetum balsamita, Achillea clypeolata, Artemisia balchanorum, Artemisia lerchiana, Helichrysum arenarium, and Matricaria recutita. The principal component analysis showed three associations of elements, which can be defined as physiological, geological and anthropogenic sources of elements. [ABSTRACT FROM AUTHOR]

In metal additive manufacturing, reusing collected powder from previous builds is a standard practice driven by the substantial cost of metal powder. This approach not only reduces material expenses but also contributes to sustainability by minimizing waste. Despite its benefits, powder reuse introduces challenges related to maintaining the structural integrity of the components, making it a critical area of ongoing research and innovation. The reuse process can significantly alter powder characteristics, including flowability, size distribution, and chemical composition, subsequently affecting the microstructures and mechanical properties of the final components. Achieving repeatable and consistent printing outcomes requires powder particles to maintain specific and consistent physical and chemical properties. Variations in powder characteristics can lead to inconsistencies in the microstructural features of printed components and the formation of process-induced defects, compromising the quality and reliability of the final products. Thus, optimizing the powder recovery and reuse methodology is essential to ensure that cost reduction and sustainability benefits do not compromise product quality and reliability. This study investigated the impact of powder reuse and particle size distribution on the microstructural and mechanical properties of Ti-6Al-4V specimens fabricated using a laser beam directed energy deposition technique. Detailed evaluations were conducted on reused powders with two different size distributions, which were compared with their virgin counterparts. Microstructural features and process-induced defects were examined using scanning electron microscopy and X-ray computed tomography. The findings reveal significant alterations in the elemental composition of reused powder, with distinct trends observed for small and large particles. Additionally, powder reuse substantially influenced the formation of process-induced defects and, consequently, the fatigue performance of the components. [ABSTRACT FROM AUTHOR]

A study was conducted about the variation of levels of macro- and microelements in the soil and leaves of two species of the genus Nitraria L. in various habitats in Siberia. New data were obtained on the concentration variations of K, Na, Ca, Mg, Fe, Mn, Zn, Cu, Ni, Li, Sr, and Cd in leaves of N. schoberi L. and N. sibirica Pall. It was found that the salinity of habitats of N. sibirica (up to 3.23%) can exceed salinity of soils under N. schoberi (up to 0.5%) by more than sixfold. Soils of N. schoberi habitats are characterized by lower contents of carbonates (1.0–3.8%) and of physical clay (2–19%) as compared to soils of N. sibirica habitats: 1.2–18.2 and 9–40%, respectively. An increase in the physical-clay content of soil positively correlated with the accumulation of Mg, Cu (p ≤ 0.01), and Mn (p ≤ 0.001) in the plant leaves. The degree of soil salinity was positively associated with the accumulation of Ca, Zn, Sr (p ≤ 0.01), Mg (p ≤ 0.05), and Cd (p ≤ 0.001) in the leaves. An increase in concentration of mobile Na in soil positively correlated with concentrations of Ca, Cu (p ≤ 0.01), and Zn (p ≤ 0.001) in the leaves. In N. sibirica leaves, the concentration of K, Ca, Mg, Fe, Sr, Mn, Zn, and Cu was 1.5–3 times higher than that in N. schoberi leaves. Both species are capable of accumulating very high concentrations of Na (N. schoberi: up to 83.8 g/kg and N. sibirica: up to 77.2 g/kg). In the leaves of N. schoberi plants of immature age, K and Na levels were seven times higher than those in leaves of adult generative plants, whereas Mg and Ca levels were 3–5 times higher. This study should expand the understanding of mechanisms of Nitraria species' adaptation to high-salinity conditions. [ABSTRACT FROM AUTHOR]

Blueberries offer multiple health benefits, and their cultivation has expanded to warm tropical regions. However, references for foliar nutritional content are lacking in the literature. Proximal sensing may enhance nutritional characterization to optimize blueberry production. We aimed (i) to characterize the nutrient contents of healthy plants of three blueberry varieties adapted to warm climates (Emerald, Jewel, and Biloxi) using a reference method for foliar analysis (inductively coupled plasma (ICP)) and a portable X-ray fluorescence (pXRF) spectrometer on fresh and dry leaves and (ii) to differentiate blueberry varieties based on their nutrient composition. Nutrient content was statistically compared per leaf moisture condition (fresh or dry) with ICP results and used to differentiate the varieties via the random forest algorithm. P and Zn contents (ICP) in leaves were different among varieties. Dry leaf results (pXRF) were strongly correlated with ICP results. Most nutrients determined using ICP presented good correlation with pXRF data (R2 from 0.66 to 0.93). The three varieties were accurately differentiated by pXRF results (accuracy: 87%; kappa: 0.80). Predictions of nutrient contents based on dry leaves analyzed by pXRF outperformed those based on fresh leaves. This approach can also be applied to other crops to facilitate nutrient assessment in leaves. [ABSTRACT FROM AUTHOR]

Cigarette beetles Lasioderma serricorne (Fabricius, 1792) and saw-toothed grain beetles Oryzaephilus surinamensis (Linnaeus, 1758) are considered serious stored grain pests. Developing silica nanoparticles (SNs) coated with the most effective and persistent photosensitizer is a viable alternative to current synthetic chemical pesticides. Chemical characterization confirmed the conjugation process between SNs and rose bengal (RB) and formation of SNs photosensitizer rose bengal (SNP-RB). Additionally, bioassays were performed to determine the impact of the median-lethal concentration (LC50) of the three substances against pests. The corresponding LC50 values against L. serricorne and O. surinamensis were 5.14, 20.32, 50.60 and 9.79, 28.93, 106.29 for SNP-RB, SNs and RB respectively. Therefore, the toxicity of these tested compounds after three hours of sun light exposure could be descendingly arranged in order as follows: SNP-RB, SNs and RB. The relative percentages of mineral contents were detected in the whole body tissue of L. serricorne and revealed the existence of nine elements in untreated adults, 11 elements in adults treated with RB as well as nine elements in adults treated with SNP-RB. Silicon was the least abundant element in both controls as well as adults treated with SNP-RB, Sulphur was the least abundant element in adults treated with RB and carbon was detected as the most abundant element in all treatments. Considering O. surinamesis, ten elements existed in untreated adults, 11 elements in adults treated with RB, whereas ten elements were found in adults treated with SNP-RB. Carbon was the most abundant element in all treatments, whereas calcium appeared as the least abundant element in SNP-RB. [ABSTRACT FROM AUTHOR]

Bee pollen is a complex compound formed by the honey bee through a mixture pollen, nectar, and bee saliva. It contains many elements that have importance for the human biochemical process. However, when the content of minerals in the pollen exceeds the biological limit, it can be toxic to health. This study aimed to assess and identify the presence of 16 essential (potassium [K], phosphorus [P], calcium [Ca], magnesium [Mg], sodium [Na], iron [Fe], silicon [Si], manganese [Mn], zinc [Zn], boron [B], copper [Cu], molybdenum [Mo], nickel [Ni], chromium [Cr], selenium [Se], and cobalt [Co]) and 16 nonessential elements (aluminum [Al], beryllium [Be], barium [Ba], arsenic [As], cadmium [Cd], mercury [Hg], thallium [Tl], lithium [Li], antimony [Sb], vanadium [V], lead [Pb], rubidium [Rb], strontium [Sr], cesium [Cs], titanium [Ti], and uranium [U]) in bee pollen samples from different floral sources in Turkey, while also evaluating the noncarcinogenic risks associated with bee pollen. A melissopalynological investigation was conducted to identify the plant origins of the bee pollen samples. Thereafter, the levels of 32 elements in bee pollen samples were quantified using inductively coupled plasma‐mass spectrometry (ICP‐MS). Finally, calculations were performed to determine the recommended dietary allowance percentage (RDA%), estimated daily intake (EDI), target hazard quotient (THQ), and hazard index (HI). The bee pollen samples had varying levels of macro, trace, and ultratrace elements, with K, P, Ca, Mg, and Na being the most abundant macro elements and Ti, Ba, Ni, Cr, and V being the least abundant ultratrace elements. The RDA% values for essential elements in bee pollen were found to vary, with Cu, Zn, Fe, and Cr having the highest levels. The results of the THQ and HI calculations demonstrated that consuming bee pollen at recommended rates did not pose a risk to the health of adults or children. Integr Environ Assess Manag 2024;20:1575–1585. © 2023 SETAC Key Points: Bee pollen contains varying levels of macro, trace, and ultratrace elements.Bee pollen offers a natural source of essential nutrients for human health, including potassium (K), phosphorus (P), magnesium (Mg), calcium (Ca), copper (Cu), iron (Fe), zinc (Zn), chromium (Cr), manganese (Mn), nickel (Ni), selenium (Se), and molybdenum (Mo).Comparing estimated daily intake values for bee pollen elements with the reference dose (RfD) values suggested no health risk for both adults and children.A health risk assessment (target hazard quotient and hazard index) indicates bee pollen consumption is safe. [ABSTRACT FROM AUTHOR]

Sphagnum mosses play a significant role in peat formation and carbon sequestration in mire ecosystems. It is critical to investigate the productivity and chemical composition of different Sphagnum species in order to assess their role in the global carbon cycle and potential in light of climate change. The data on productivity and growth characteristics during the growing season, group chemical composition and elemental composition at the beginning and end of the growing season, as well as aspects of the pigment complex operation, were collected for four Sphagnum species: Sphagnum lindbergii Schimp., S. fuscum (Schimp.) Klinggr., S. divinum Flatberg & K. Hassel, and S. squarrosum Crome. High cover density and productivity, low ability to decompose, and constancy of the pigment complex of S. fuscum reflect a high degree of adaptation to the specific conditions of ridges. A constant chemical composition of S. lindbergii during the growing season can be explained by stable conditions of hollows that allow it to maintain its metabolic processes, but the light conditions in hollows bring the reaction of the pigment apparatus of this species closer to shaded S. divinum and S. squarrosum. S. lindbergii and S. squarrosum contain more nitrogen than other species and have a greater ability to decompose. [ABSTRACT FROM AUTHOR]

Biochar (BC) is often used as an additive in anaerobic digestion (AD) to increase yield and/or to stabilise the process when the manure content is increased. Unfortunately, BC is rarely described in detail in terms of its raw material sources, production processes, and structural, physical and chemical properties to allow correlation with its effects on AD. It is an open question whether microorganisms from AD can penetrate into different biochar pore types, depending on their wood origin. In this paper, we describe the preparation (temperatures, treatment times, yields) and characterisation shrinkage, density, pore sizes, pore size distribution, specific surface area, ash, volatiles, fixed carbon, elemental composition, polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), benzene, toluene, ethyl-toluene, xylene (BTEX) and volatile halogenated hydrocarbons (VHH) of BC cubes of Scots pine (Pinus sylvestris) and common beech (Fagus sylvatica) powder made from this BC in addition to commercial charcoal powder. The pore size distribution determined by mercury porosimetry differs from that determined by 3D-reflected light microscopy. After incubating BC cubes in AD, the cubes were mechanically cleaned and cut into two pieces. Microorganisms were detected inside the cubes by fluorescence microscopy. Particle size and wood source determine the influence of BC on AD. [ABSTRACT FROM AUTHOR]

Cigarette beetles Lasioderma serricorne (Fabricius, 1792) and saw-toothed grain beetles Oryzaephilus surinamensis (Linnaeus, 1758) are considered serious stored grain pests. Developing silica nanoparticles (SNs) coated with the most effective and persistent photosensitizer is a viable alternative to current synthetic chemical pesticides. Chemical characterization confirmed the conjugation process between SNs and rose bengal (RB) and formation of SNs photosensitizer rose bengal (SNP-RB). Additionally, bioassays were performed to determine the impact of the median-lethal concentration (LC50) of the three substances against pests. The corresponding LC50 values against L. serricorne and O. surinamensis were 5.14, 20.32, 50.60 and 9.79, 28.93, 106.29 for SNP-RB, SNs and RB respectively. Therefore, the toxicity of these tested compounds after three hours of sun light exposure could be descendingly arranged in order as follows: SNP-RB, SNs and RB. The relative percentages of mineral contents were detected in the whole body tissue of L. serricorne and revealed the existence of nine elements in untreated adults, 11 elements in adults treated with RB as well as nine elements in adults treated with SNP-RB. Silicon was the least abundant element in both controls as well as adults treated with SNP-RB, Sulphur was the least abundant element in adults treated with RB and carbon was detected as the most abundant element in all treatments. Considering O. surinamesis, ten elements existed in untreated adults, 11 elements in adults treated with RB, whereas ten elements were found in adults treated with SNP-RB. Carbon was the most abundant element in all treatments, whereas calcium appeared as the least abundant element in SNP-RB. [ABSTRACT FROM AUTHOR]

This paper presents the authentication analysis of a bronze bust of Napoleon I, attributed to the Italian artist Renzo Colombo (1856–1885) based on his signature and other casting and molding inscriptions. The bust was made using the lost wax technique and artificially patinated in the Pinédo variant workshop. This study combined historiographical research (using the specialized literature) with data from auction catalogs. These were compared with photographs of the entire bust and close-up images of key areas, including anthropomorphic features, clothing, inscriptions, and structural and ornamental details. The condition of the bust and its historical and chemical characteristics were assessed through direct analysis with magnifying tools and indirect analysis using scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDX).

A non-equiatomic high-entropy alloy (HEA) CoCrFeNiAl coating on the 5083 alloy substrate is produced by wire-arc additive manufacturing (WAAM). It is revealed that microhardness changes significantly at the contact zone of the "coating — substrate" system. The changes range from 7.6 GPa at the coating boundary and the contact zone up to 1.6 GPa at the substrate boundary and the contact zone. The coating and substrate have the microhardness values of 6.3 GPa and 1.1 GPa, respectively. The structural phase state, defective structure, and elemental composition of the “coating — substrate” system are analyzed using methods of modern physical material science. It is shown that they depend on the distance from the contact zone between the coating and substrate. Also, it is found out that application of the high-entropy coating on the 5083 alloy surface is accompanied by mutual alloying of the coating and substrate. Creation of two types of submicro- and nanosized particles is revealed in the study. Nanosize particles of Al2O3 and MgAlO oxides, Al and HEA subgrains form the first structure. The second structure consists of nanosized HEA subgrains, Al13Fe4 and (NiCo)3Al4 nanoparticles located along the grain boundaries.

Blueberries offer multiple health benefits, and their cultivation has expanded to warm tropical regions. However, references for foliar nutritional content are lacking in the literature. Proximal sensing may enhance nutritional characterization to optimize blueberry production. We aimed (i) to characterize the nutrient contents of healthy plants of three blueberry varieties adapted to warm climates (Emerald, Jewel, and Biloxi) using a reference method for foliar analysis (inductively coupled plasma (ICP)) and a portable X-ray fluorescence (pXRF) spectrometer on fresh and dry leaves and (ii) to differentiate blueberry varieties based on their nutrient composition. Nutrient content was statistically compared per leaf moisture condition (fresh or dry) with ICP results and used to differentiate the varieties via the random forest algorithm. P and Zn contents (ICP) in leaves were different among varieties. Dry leaf results (pXRF) were strongly correlated with ICP results. Most nutrients determined using ICP presented good correlation with pXRF data (R2 from 0.66 to 0.93). The three varieties were accurately differentiated by pXRF results (accuracy: 87%; kappa: 0.80). Predictions of nutrient contents based on dry leaves analyzed by pXRF outperformed those based on fresh leaves. This approach can also be applied to other crops to facilitate nutrient assessment in leaves.

This study aims to fill the knowledge gap regarding the physicochemical properties of combustible municipal solid waste (CMSW) from Lomé under its wet and dry seasons. Over both seasons, waste characterisation campaigns were conducted followed by the proximate and ultimate analyses of CMSW samples composed of putrescible, miscellaneous combustible (MC), plastic, textile, and paper & cardboard fractions. In addition, the energy and oxide contents from CMSW were measured with a calorimeter and X-Ray Fluorescence analyser respectively. The results showed that putrescible had the highest weight proportion with significant differences among waste fractions over wet and dry seasons (p-value 1.90E–07 putrescible (2.73 MJ/kg) > textile (0.86 MJ/kg) > MC (0.67 MJ/kg) > paper & cardboard (0.18 MJ/kg). The content of silicon dioxide (75.88 wt%) and manganese oxide (0.02 wt%) were the highest and lowest from plastic, respectively. Therefore, CMSW showed important energy value though highly contaminated by fines.

Particulate matter (PM) in the air has significant implications for human health and the environment, particularly in urban areas with high concentrations. This study focuses on the isotopic (δ13C and δ15N), elemental (CNS) as well as the total carbon to total nitrogen ratio (TC/TN) characterization of PM in Trombay, Mumbai. Monthly atmospheric dust samples were collected from 2016 to 2020 during the premonsoon and postmonsoon seasons. The average elemental concentrations for premonsoon samples were N (1.73% ± 0.25%), C (7.38% ± 0.72%), S (0.84% ± 0.13%), and TC/TN ratio (4.38 ± 0.86). For postmonsoon samples, the average elemental concentrations were N (1.47% ± 0.185%), C (6.95% ± 1.04%), S (0.84% ± 0.13%), and TC/TN ratio (4.80 ± 0.94). The average δ13C values for premonsoon and postmonsoon seasons were −24.31 ± 1.15‰ and −24.56 ± 1.20‰, respectively. The average δ15N values for premonsoon and postmonsoon seasons were 5.22 ± 1.92‰ and 4.57 ± 1.32‰, respectively. The results showed variations in elemental concentrations between the seasons, with higher values observed in premonsoon samples which can be attributed to increased dust generation from land and sea. Overall, this study provides insights into the local sources and characteristics of PM in the Trombay area and highlights the importance of long-term monitoring to understand the seasonal variations in PM composition.

Using the method of hot compaction (HC) of mechanically activated powder mixtures of titanium and carbon (carbon black) in an ethanol medium, titanium-matrix composites with a carbide strengthening phase were obtained. To obtain a composite with different content of titanium carbide, the amount of carbon was varied within the range of 0–1 wt.%. The mechanically activated carbon-doped titanium powder mixtures, as well as the mechanically activated titanium powder subjected to HC (temperature of 900°C and holding time of 15 min) and additional annealing at different temperatures and holding times are studied by optical metallography, scanning electron microscopy, and X-ray diffraction and chemical analysis. According to the metallography and X-ray diffraction results, the TiC content in the HC composite has been found to be significantly higher than the estimated value. The reason is a destruction of ethanol molecules during mechanical activation resulting in the release of carbon and hydrogen. To obtain the targeted (no more than 10 vol.%) TiC content in the titanium matrix composite, it is necessary to establish a specific technological mode for the mechanical activation of the titanium powder. [ABSTRACT FROM AUTHOR]

According to their nutritional value, their ability to adapt to the various environmental conditions, and their versatility, cereals are among the most cultivated plants in the world. However, the ongoing climate changes subject crops to important environmental stress that for some varieties leads to high production losses. Therefore, the selection of species and varieties that are more versatile and adaptable to different environmental conditions can be important. However, the characteristics of some cereals are not completely known; this is a priority before aiming to improve their cultivation. The aim of this study is to characterize select species that are potentially suitable for local environmental conditions and that possess nutritional value. The elemental composition was assessed in different cereal species grown following intensive and organic agriculture practices. Six species were grown for this study with techniques of intensive agriculture: Triticum monococcum L., Triticum dicoccum L., Triticum aestivum L., variety Verna, Triticum durum Desf., variety Senatore Cappelli, Triticum durum Desf., variety Claudio, and Avena strigosa Schreb.; four of these were also grown following organic procedures: Triticum monococcum L., Triticum dicoccum L., Triticum aestivum L., variety Verna, and Triticum durum Desf., variety Senatore Cappelli. The study considered twenty elements, including major nutrients (Ca, K, Mg, P, and S), seven micronutrients (B, Cu, Fe, Mn, Mo, Se, and Zn), and trace elements with toxic properties (Al, Ba, Cd, Cr, Na, Rb, Sc, and Sr) that can be accumulated at the seed level. The results highlight the differences in the element concentrations in the cereal seeds in relation to the genus and species; the highest concentrations of the major nutrients appeared in T. monococcum; the concentrations were 6.9, 2.09, 7.2, and 2.9 mg/g for K, Mg, P, and S, respectively. The highest concentrations of certain micronutrients, B, Ca, Mo, and Se (16, 785, 3.69, and 0.34 μg/g), were in A. strigosa. There is also evidence that the element content can be affected by the adopted cultivation procedure; however, the effects of the growing procedure can be significantly different when different species are considered. T. monococcum, grown by an organic procedure, presented lower concentrations of the major nutrients, while it demonstrated a modest increase in the micronutrients in the T. durum variety organic S. Cappelli, and the production procedure did not affect the elemental composition of the T. aestivum variety Verna. The survey also highlights that the studied species and the growing procedure affected the capacity to accumulate and translocate trace hazardous elements for human health at the seed level. [ABSTRACT FROM AUTHOR]

The 13C-NMR spectra and elemental composition of lipids of gray forest soils (Greyic Phaeozems), dispersed carbonate chernozems (Haplic Chernozem Hypocalcic), and chestnut soils (Kastanazems) of Western Transbaikalia were analyzed. The contribution of carbon in lipids to the total organic carbon was calculated. This is the first characterization of the lipid fraction of organic matter in cold soils of Western Transbaikalia. An analysis of the spectra, including the assignment of signals from ethoxy groups, phenol derivatives, and alkene fragments, as well as an indication of the ranges of chemical shifts characteristic of certain types of carbon nuclei, were carried out. The content of various types of structural elements in the studied lipids was compared. Based on the obtained results, the main part of lipids consisted of esters and fatty acids. Analysis of the composition of lipids showed that the content of carbon and hydrogen atoms was 65‒73 and 8‒10%, respectively. The high concentration of oxygen atoms in lipids indicated that functional groups containing oxygen were concentrated in the aliphatic part of the lipids. The share of lipid carbon in the total reserve of organic carbon was 6.5% for chestnut soils, 5.8% for gray forest soils, and 4.1% for dispersed carbonate chernozems. [ABSTRACT FROM AUTHOR]

In recent years, the reduction of fossil fuels leads in finding a revolutionary solution for meeting their necessary demands. Also burning of fossil fuels releases undesirable pollutants that release harmful greenhouse gases. In order to overcome this polluting means of fossil fuel usage, the utilization of locally available invasive plants such as Parthenium hysterophorus (PHP) and Lantana camara (LC) has been proposed as it leaves low carbon footprints in the environment. In this study, the proximate and ultimate analysis along with the morphological structure was examined to identify the elemental composition, heating values, and physical structures. The depicted characteristic results are feed into ASPEN Plus simulation for evaluating the domination of gasification temperature and steam to biomass ratio (S/B ratio) on producer gas composition with different quasi-steady-state models by varying the equivalence ratios (0.2 to 0.4) at diverse temperatures ranging from 300 to 1000 °C by supplying air and air–steam as gasifying agents. The obtained results are compared with the literature of experimental studies. The validation of the developed model is done by comparing the elemental percentage and heating value. From the evaluation, it is observed that the temperature increment during the steam gasification enhances hydrogen production. The effects of gasification with air and air–steam supply are investigated using essential operational factors such as gasification temperature, equivalence ratio, and S/B ratio. The S/B ratio drives a tremendous part in the elemental composition by increasing hydrogen (% by vol.) and carbon monoxide (% by vol.). [ABSTRACT FROM AUTHOR]

The simulations and predictions obtained from mathematical models of bioprocesses conducted by microorganisms are not overvalued. Mechanistic models are bringing a better process understanding and the possibility of simulating unmeasurable variables. The Dynamic Energy Budget (DEB) model is an energy balance that can be formulated for any living organism and can be classified as a structured model. In this study, the DEB model was used to describe E. coli growth in a batch reactor in carbon and nitrogen substrate limitation conditions. The DEB model provides a possibility to follow the changes in the microbes' cells including their elemental composition and content of some important cell ingredients in different growth phases in substrate limitation conditions which makes it more informative compared to Monod's model. The model can be used as an optimal choice between Monod-like models and flux-based approaches. Key points: • The DEB model can be used to catch changes in elemental composition of E. coli • Bacteria batch culture growth phases can be explained by the DEB model • The DEB model is more informative compared to Monod's based models [ABSTRACT FROM AUTHOR]

Progress in the field of ecological stoichiometry has demonstrated that the outcome of ecological interactions can often be predicted a priori based on the nutrient ratios (e.g., carbon: nitrogen: phosphorus, C:N:P) of interacting organisms. However, the challenges of accurately measuring the nutrient content of active parasites within hosts has limited our ability to rigorously apply ecological stoichiometry to host–parasite systems. Traditional nutrient analyses require high parasite biomasses, often preventing individual‐level analyses. This prevents researchers from estimating variation in the nutrient content of individual parasites within a single host infrapopulation, a critical factor that could define how the ecology of the parasite affects the host–parasite interaction. Here, we explain how energy dispersive technology, a technique currently used to measure the elemental content of free‐living microbes, can be adapted for parasitic microbial infrapopulations. We demonstrate the power of accurately quantifying the biomass stoichiometry of individual microbial parasites sampled directly from individual hosts. Using this approach, we show that the stoichiometric composition of two microbial parasites capable of infecting the same host are stoichiometrically distinct and respond to host diet quality differently. We also demonstrate that characteristics of the stoichiometric trait distributions of these infrapopulations were important predictors of host fecundity, a proxy for virulence in this system, and better predictors of parasite load than the mean parasite stoichiometry or our parasite and diet treatments alone. EDS provides a rigorous tool for applying ecological stoichiometry to host–parasite systems and enables researchers to explore the nutritional physiology of host–parasite interactions at a scale that is more relevant to the ecology and evolution of the system than traditional nutrient analyses. Here we demonstrate that this level of resolution provides useful insights into the diet‐dependent physiology of microbial parasites and their hosts. We anticipate that this improved level of resolution has the potential to elucidate a range of eco–evo interactions in host–parasite systems that were previously unobservable. [ABSTRACT FROM AUTHOR]

Elements such as As, Cd, Cr and Pb are classified as contaminants of major concern for public health, due to their high degree of toxicity. Saffron is an important medicinal herbal spice used in variety of food items, pharmaceutical medicines, and cosmetics. Presence of heavy metals in saffron will increase the health risk to consumers. Also, authentication of geographical origin of saffron is an issue of utmost importance for global trading. The present study is focused on investigation of elemental contaminants in saffron and elemental composition of saffron from India (Jammu and Kashmir); Iran and Afghanistan are also explored for geographical discrimination, using Chemometrics. In total, 29 elements including Ag, Al, As, B, Ba, Be, Ca, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, P, Pb, Sb, Se, Si, Sr, Ti, Tl, V and Zn were analyzed using ICP-OES. Toxic elemental contaminants including As, Cd, Pb were found below the maximum permissible limit. Using PCA, elements B, Ni, Ba, Fe, V, Si, Al, Ti, K, Na, Sr, and Zn were found as significant discriminators of geographical origin. Elemental composition of saffron may be utilized, to prevent cases of falsified geographical origin in trade. [ABSTRACT FROM AUTHOR]

Indiscriminate dumping of infectious and toxic medical wastes generated from the hospital as well as open burning of these wastes are becoming prevalent in recent times. This usually result in several health and environmental problems. The objective of this study was to determine the soil elemental compositions in hospital waste disposal sites in Uyo metropolis. The study areas, included Uniuyo Teaching Hospital, St. Luke's Hospital, Uniuyo Medical Centre and Children Hospital. Underlying soil samples in the waste disposal sites were collected in a cellophane bag and tied properly to prevent air ingress. Atomic absorption spectrophotometer was employed to determine trace metals present in the waste disposal sites which were compared to World Health Organization Standards. The results were analyzed using statistical analysis, ANOVA. Results obtained from the atomic absorption spectrophotometer revealed that each of the samples contained one of the following elements such Pb, Ni, Cr, As, Cd, Al. The ANOVA results showed that mean values of the heavy metals were within WHO permissible limit, like lead Pb (1.302) at the children hospital site, Nickel Ni (0.448) at Uniuyo Teaching Hospital site, Aluminum Ai (0.486333) at the Uniuyo Medical Centre site, Arsenic As (0.239333) at the control site. Except chromium Cr (0.343667) at the children hospital site that was above the WHO standard. From the result of the statistical analysis, it was observed that medical wastes had a significant effect on the environment of Uyo metropolis. Based on the findings, it is recommended that effective method of waste segregation and disposal should be implemented, and designated sites should be used as dump sites. [ABSTRACT FROM AUTHOR]

The year 2021 marked a decade of holopelagic sargassum (morphotypes Sargassum natans I and VIII, and Sargassum fluitans III) stranding on the Caribbean and West African coasts. Beaching of millions of tons of sargassum negatively impacts coastal ecosystems, economies, and human health. Additionally, the La Soufrière volcano erupted in St. Vincent in April 2021, at the start of the sargassum season. We investigated potential monthly variations in morphotype abundance and biomass composition of sargassum harvested in Jamaica and assessed the influence of processing methods (shade-drying vs. frozen samples) and of volcanic ash exposure on biochemical and elemental components. S. fluitans III was the most abundant morphotype across the year. Limited monthly variations were observed for key brown algal components (phlorotannins, fucoxanthin, and alginate). Shade-drying did not significantly alter the contents of proteins but affected levels of phlorotannins, fucoxanthin, mannitol, and alginate. Simulation of sargassum and volcanic ash drift combined with age statistics suggested that sargassum potentially shared the surface layer with ash for ~50 d, approximately 100 d before stranding in Jamaica. Integrated elemental analysis of volcanic ash, ambient seawater, and sargassum biomass showed that algae harvested from August had accumulated P, Al, Fe, Mn, Zn, and Ni, probably from the ash, and contained less As. This ash fingerprint confirmed the geographical origin and drift timescale of sargassum. Since environmental conditions and processing methods influence biomass composition, efforts should continue to improve understanding, forecasting, monitoring, and valorizing sargassum, particularly as strandings of sargassum show no sign of abating. [ABSTRACT FROM AUTHOR]

The composition, structure and mechanical properties of Ti–Al–Ta–N coatings obtained by high-power impulse magnetron sputtering and direct current magnetron sputtering have been studied using energy-dispersive X-ray spectroscopy, X-ray diffraction, scanning electron microscopy, and nanoindentation. It has been established that for high-power impulse sputtering, the current and power of the magnetron discharge increase exponentially during the pulse and reach peak values that are an order of magnitude higher than similar characteristics for magnetron sputtering at direct current. A high level of ionization of the sputtered particles caused a significant increase in the number of ions in the particle flux deposited on the substrate. The suppression of the growth of columnar grains and the formation of a denser and more homogeneous microstructure were ensured by an increase in the intensity of ion bombardment of the growing coating. This made it possible to improve its mechanical characteristics. [ABSTRACT FROM AUTHOR]

Approaches for in-situ monitoring elemental composition in the working zone during additive manufacturing (AM) with directed energy deposition are relatively underdeveloped and especially needed for processes with multiple powder delivery feeds, such as laser-based directed energy deposition. In this study, Laser-Induced Breakdown Spectroscopy (LIBS) was explored for monitoring elemental composition of an AM-sintered graded Fe-Ni alloy. Fe and Ni powder feeds were varied during Fe-Ni alloy sample building, and LIBS was used to determine gradient alloy composition, which was also verified by mapping Fe and Ni gradients along the sample build direction with an Energy-Dispersive X-ray Spectroscopy (EDS) technique. An integrated experimental and modeling approach presented in this work rapidly fits Fe and Ni peak LIBS emission data by using a physics-informed emission peak identification algorithm based on an atomic emission spectrum simulation to predict peak occurrences, locations, and significant intensities. The approach allows to considerably reduce the computational time needed for peak identification, labeling, and fitting in experimental recorded spectroscopic data. The performed LIBS experimental measurements using this approach demonstrated a 5-Hz composition analysis data rate. Changes in the Fe and Ni peak intensity areas of the compositionally graded sample were correlated to the externally measured composition using EDS, which yielded a good correlation between LIBS and EDS-measured data. The developed approaches indicate directions for obtaining elemental composition data at speeds comparable with AM process control parameter variations, striding towards in-situ non-invasive composition monitoring and closed-loop process control implementations. [ABSTRACT FROM AUTHOR]

Coal-waste dumps in the Upper Silesian Coal Basin are usually colonized by tall grass Calamagrostis epigejos and Solidago canadensis, which influence the direction of vegetation formation and the soil chemistry. The aim of this study is to analyze and determine the content of major elements (Fe, Ca, P, Mg, Al, Na, K, S) and trace elements (Mo, Cu, Pb, Zn, Ni, Co, Mn, Sr, Cd, Cr) in aboveground and underground parts of the plants and the soil at the thermally active coal-waste dump. Analysis of the heavy metal concentrations reveals that they are higher in plant materials than in soil materials within the root zone of the plants. Environmental indicator analysis (geoaccumulation index, enrichment factor, translocation factor) shows that the studied species exhibit varying degrees of pollution, with cadmium and zinc showing the highest accumulation rates. The content of elements in the analyzed species, both in washed and unwashed specimens, does not show significant differences, which is confirmed by the enrichment factor. Statistical analysis shows a positive correlation between the amount of microelements in plants (roots, aerial part) and soil samples in both thermally active and inactive zones. These findings broaden the scientific inquiry and hold practical significance for the reclamation of post-industrial areas. [ABSTRACT FROM AUTHOR]

Objectives: Marine algae are important sources of nutritionally and pharmacologically important products. Here in the study, nutritional composition and biological activities of a marine red algae Nitophyllum punctatum were assessed. The present study aimed to analyze the nutritional composition and biological effects of the N. punctatum. Methods: The marine algae N. punctatum was collected, shade dried and extracted using Soxhelet apparatus. The elemental composition was estimated using Atomic Absorption Spectroscopy; the anti-inflammatory effect was determined using Raw 264.7 macrophages. Genotoxicity was assessed by standard methods using Allium cepa root model. Results: The elemental composition analysis revealed the presence of essential minerals such as calcium, magnesium, potassium, and iron, indicating the potential nutritional value of the algae. The extract demonstrated significant inhibition of Nitric oxide (NO) production and downregulated the expression of pro-inflammatory cytokines such as TNF-α and IL-6, suggesting its potential as an anti-inflammatory agent. Furthermore, the anti-genotoxic potential of the methanol extract was evaluated using the Allium cepa model, a well-established system for assessing genotoxicity. Onion root tips were treated with various concentrations of the extract, and the chromosomal changes were performed as indicators of genotoxicity. Results indicated a protective effect against Ethyl methyl sulfonate (EMS) induced genotoxicity in onion roots. Conclusions: The findings suggest that the methanol extract of N. punctatum possesses potent anti-inflammatory and anti-genotoxic properties, which may be attributed to the presence of bioactive compounds. The study highlights the potential pharmacological importance of N. punctatum as a source of natural compounds with anti-inflammatory and anti-genotoxic activities.

Abstract Background Urolithiasis has emerged as a global affliction, recognized as one of the most excruciating medical issues. The elemental composition of stones provides crucial information, aiding in understanding the causes, mechanisms, and individual variations in stone formation. By understanding the interactions between elements in various types of stones and exploring the key role of elements in stone formation, insights are provided for the prevention and treatment of urinary stone disease. Methods This study collected urinary stone samples from 80 patients in Beijing. The chemical compositions of urinary stones were identified using an infrared spectrometer. The concentrations of major and trace elements in the urinary stones were determined using Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES) and Inductively Coupled Plasma Mass Spectrometry (ICP-MS), respectively. The data were processed using correlation analysis and Principal Component Analysis (PCA) methods. Results Urinary stones are categorized into five types: the calcium oxalate (CO) stone, carbonate apatite (CA) stone, uric acid (UA) stone, mixed CO and CA stone, and mixed CO and UA stone. Ca is the predominant element, with an average content ranging from 2.64 to 27.68% across the five stone groups. Based on geochemical analysis, the high-content elements follow this order: Ca > Mg > Na > K > Zn > Sr. Correlation analysis and PCA suggested significant variations in the interactions between elements for different types of urinary stones. Trace elements with charges and ionic structures similar to Ca may substitute for Ca during the process of stone formation, such as Sr and Pb affecting the Ca in most stone types except mixed stone types. Moreover, the Mg, Zn and Ba can substitute for Ca in the mixed stone types, showing element behavior dependents on the stone types. Conclusion This study primarily reveals distinct elemental features associated with five types of urinary stones. Additionally, the analysis of these elements indicates that substitutions of trace elements with charges and ion structures similar to Ca (such as Sr and Pb) impact most stone types. This suggests a dependence of stone composition on elemental behavior. The findings of this study will enhance our ability to address the challenges posed by urinary stones to global health and improve the precision of interventions for individuals with different stone compositions.

Сatagenetic transformations of asphaltenes of organic matter (OM) from recent sediments and fossil rocks were studied on rocks sampled from different sedimentary basins (Timan-Pechora, Mezen, West Siberian, Kuznetsk, Aldan-Maya and Middle Amur) of Russia. Changes in the elemental composition of asphaltenes were analyzed with the Veselovsky’s model of the formation of major groups of fossil fuels using cO parameter (cO = (O/8 – N)/(C/3)) as compared with the total carbon based on elemental analysis. Just as the Van-Krevelen diagram, the plot built in C–cO coordinates for OM of various genetic forms demonstrates a significant difference in the asphaltenes composition evolution during catagenesis. At the same time, the cO parameter has notably increased in asphaltenes of both types of OM. Structural transformations of asphaltenes during catagenesis were identified in the course of high-resolution NMR (nuclear magnetic resonance) spectroscopy. The research results comprise data on carbon distributions in the aromatic and aliphatic groups in the investigated asphaltenes of different type OM of sediments and rocks at different stages of lithogenesis. A correlation between the asphaltene composition and structural parameters depending on thermocatalytic transformations is revealed. The asphaltenes of terrestrial organic matter are distinguished by higher cO values and different carbon yields of aromatics (higher) and aliphatics (lower) throughout the catagenesis phase. The highly transformed marine OM is marked by surge condensation of aromatic rings in asphaltenes, which makes them similar to asphaltenes of the terrestrial type OM.

The evolution of the elemental composition of dispersed organic matter (DOM) heterocyclic components during catagenesis was traced via studying samples from the Tyumen (SG-6) and Srednevylyuy-27 (SV-27) super-deep wells of Siberia. During mesocatagenesis, the composition of terrigenous DOM asphaltenes and resins undergoes directed changes: a decrease in hydrogen and oxygen content, enrichment with carbon, and graphitization of the structure. During apocatagenesis, due to high-temperature destruction, on the one hand, there is a condensation of individual blocks of asphaltenes and their transition to an insoluble form (formation of epiasphaltenic kerogens – EPAK). On the other hand, the lighter part of the asphaltenes goes into the formation of hydrocarbons and gas formation – a relative increase in the concentration of the former in % by mass of residual bitumoids is noted, as well as structural redistributions within benzene and spirit-benzene resins. In all studied parameters of the elemental composition, a symmetrical (unidirectional) transformation of resinous and asphaltene components of bitumoids from the SG-6 and SV-27 wells under harsh thermobaric conditions is noted. The obtained results should be taken into account when predicting new oil and gas accumulation zones in deep-laid horizons.

Background: Urolithiasis has emerged as a global affliction, recognized as one of the most excruciating medical issues. The elemental composition of stones provides crucial information, aiding in understanding the causes, mechanisms, and individual variations in stone formation. By understanding the interactions between elements in various types of stones and exploring the key role of elements in stone formation, insights are provided for the prevention and treatment of urinary stone disease. Methods: This study collected urinary stone samples from 80 patients in Beijing. The chemical compositions of urinary stones were identified using an infrared spectrometer. The concentrations of major and trace elements in the urinary stones were determined using Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES) and Inductively Coupled Plasma Mass Spectrometry (ICP-MS), respectively. The data were processed using correlation analysis and Principal Component Analysis (PCA) methods. Results: Urinary stones are categorized into five types: the calcium oxalate (CO) stone, carbonate apatite (CA) stone, uric acid (UA) stone, mixed CO and CA stone, and mixed CO and UA stone. Ca is the predominant element, with an average content ranging from 2.64 to 27.68% across the five stone groups. Based on geochemical analysis, the high-content elements follow this order: Ca > Mg > Na > K > Zn > Sr. Correlation analysis and PCA suggested significant variations in the interactions between elements for different types of urinary stones. Trace elements with charges and ionic structures similar to Ca may substitute for Ca during the process of stone formation, such as Sr and Pb affecting the Ca in most stone types except mixed stone types. Moreover, the Mg, Zn and Ba can substitute for Ca in the mixed stone types, showing element behavior dependents on the stone types. Conclusion: This study primarily reveals distinct elemental features associated with five types of urinary stones. Additionally, the analysis of these elements indicates that substitutions of trace elements with charges and ion structures similar to Ca (such as Sr and Pb) impact most stone types. This suggests a dependence of stone composition on elemental behavior. The findings of this study will enhance our ability to address the challenges posed by urinary stones to global health and improve the precision of interventions for individuals with different stone compositions. [ABSTRACT FROM AUTHOR]

This study aims to investigate grain quality and nutritional values of rice (Pokkali, a salt-tolerant cultivar; RD73, a new cultivar improved from KDML105 introgressed with Saltol QTL from Pokkali, and KDML105, a moderately salt-susceptible cultivar) grown under non-saline (0.04–0.87 dS/m) and slightly saline (1.08–4.83 dS/m) field conditions. The results revealed that salinity caused significant reduction in grain size but significant increments in reducing sugar and total protein contents in the grains. Nevertheless, the amounts of starch in the grains of KDML105 and Pokkali rice genotypes were unaffected by the stress. The starch granule size distribution was also unaffected by salinity. Interestingly, only starch from Pokkali was significantly diminished in amylose content, from 19.18% to 16.99%. Accordingly, parameters relating to starch gelatinization, retrogradation, and pasting properties of KDML105 and RD73 were unaffected by salinity; only Pokkali showed a significant increase in percentage of retrogradation along with a significant reduction in gelatinization enthalpy. In the saline field, total phenolic content and antioxidant capacity in the grains of all rice cultivars tended to increase, particularly in Pokkali. On average, essential element contents in grains from the saline-treated plants showed a 33%, 32%, 32%, 22%, 20%, 11%, and 10% increase in total P, N, K, Mg, Zn, Fe, and Ca content, respectively. Interestingly, total Fe content exhibited the greatest percentage of increments in KDML105 (187%). Taken together, cultivation of rice in the slightly saline field did not alter its eating and cooking qualities, while enhanced some nutritional properties such as proteins, minerals, and secondary metabolites like phenolic compounds. [ABSTRACT FROM AUTHOR]

The study compares the elemental composition of asphaltenes with the parameters of hydrocarbon biomarkers and Precambrian insoluble organic matter (OM) of the Aldan–Maya depression. The elemental composition of the asphaltenes was found to depend on the pyrolytic characteristics of the OM. Using asphaltene compositions in combination with biomarker parameters, the genetic and catagenetic features of difficult-to-study objects such as Precambrian bitumens can be characterized more accurately and reliably. The elemental composition of the asphaltenes was shown to correlate with the aromatic parameters that reflect the OM maturity. In contrast, the parameters of the asphaltenes show essentially no correlation with biomarker data for the saturated components. [ABSTRACT FROM AUTHOR]

The multi-component Al–Si–Re–O coating with a thickness of 3.5 μm was deposited on the quartz glass surface by the method of pulsed magnetron sputtering. Its structural phase state and optical and mechanical properties have been investigated. According to X-ray diffractometry and transmission electron microscopy, the structure of the coating is amorphous and has the following elemental composition: Al – 9.29 at.%, Si – 23 at.%, Re – 2.35 at.%, and O – 65.7 at.%. The present work studies the problem of crater formation under the bombardment of the quartz glass surface with Al–Si–Re–O coating by iron particles having a speed of 5–8 m/s. The study discovers protective properties of the Al–Si–Re–O coating manifested as an appreciable decrease of the surface density of the craters formed after impacts of iron microparticles as compared to the uncoated quartz glass. This effect is due to changes in the structure, phase composition, and mechanical properties of the glass surface layer coated by the reinforcing coating. The results show that the quartz glass with the Al–Si– Re–O coating remains transparent in the visible (T ≥ 77%) and UV ranges (T ≥ 23.8%). [ABSTRACT FROM AUTHOR]

Gelatinous zooplankton (GZ) biomass is an important, yet often overlooked, vector of the particulate organic matter downward export and a nutritional prey source for the mesopelagic and benthic communities. To better quantify the potential impact of their blooms on biogeochemistry and food webs, we performed decomposition and sinking experiments under two different temperature regimes, 6 and 12 °C using 260 Salpa aspera, sampled in the Northeast Pacific (48.39°–50.40°N, 126.40°–145.00°W) during May 2021. Salps sank 1312 and 1424 m day−1 on average in 6 and 12 °C, respectively. The fast sinking is common among other salp species. Salp decay was exponential and occurred ~ 1.5 times faster under warmer conditions. Comparison of the published GZ decay rates supported their strong temperature dependence (Q10 = 3.46) and revealed that S. aspera decayed slower than most GZ taxa. Carcass sinking rates were higher than previously reported for this species and slowed after a prolonged decay. Biochemical (proteins, carbohydrates, lipids) and elemental (C: carbon, N: nitrogen) compositions were determined for salps at various decomposition stages. The high water content (~ 97%) and low organic content (27.8 ± 7.1% dry weight) were typical of other thaliaceans. The high C:N ratio (6.61 ± 1.14) of S. aspera, compared to many thaliaceans, suggested that their carcasses are valuable sources of carbon beyond the euphotic zone. [ABSTRACT FROM AUTHOR]

Nickel hydroxide (Ni(OH)2) is a valuable compound derived from nickel, widely utilized across various fields because of its versatile properties. This study aimed to characterize as-prepared β-Ni(OH)2 via chemical precipitation using various analytical techniques. X-ray diffraction (XRD) analysis confirmed the formation of a β-Ni(OH)2 hexagonal crystalline structure, validating the successful precipitation. Fourier-transform infrared spectroscopy (FTIR) spectra exhibited main characteristic peaks of (υOH) and υ(NiO), corresponding to the formation of nickel hydroxide (Ni(OH)2). Subsequently, X-ray photoelectron spectroscopy (XPS) revealed a prominent peak for Ni2+ oxidation, confirming the successful precipitation of nickel hydroxide at pH 6.5, which identifies the existence of impurities, such as chlorine and calcium, from the waste matrix. Scanning electron microscopy (SEM) micrographs demonstrated stratified granules with a nearly pure brucite crystalline phase, typical of β-Ni(OH)2. Furthermore, the surface morphology revealed a coarse texture and uneven clustering, suggesting possible elevated oxide levels on the Ni surface. Energy-dispersive X-ray spectroscopy (EDX) confirmed the presence of nickel (Ni) and oxygen (O), with Ca impurities attributed to the chemical precipitation process. Particle size distribution analysis estimated an average particle size of 2.0 µm. Additionally, the precipitation of nickel was investigated using inductively coupled plasma optical emission spectroscopy (ICP-OES). Ni was observed in decreasing order, 62.7 g/L, 0.8 g/L, and 0.501 g/L in the pregnant leach, precursor solution, and solid precipitate (cake), respectively. The separation of Ni(OH)2 through the precipitation process from the waste (acidic chloride media) enabled efficient recycling and re-use of nickel, which provides a cost-effective and environmentally friendly method for the highly efficient utilization of waste (acidic chloride media). [ABSTRACT FROM AUTHOR]

The coconut crab, Birgus latro, has black protrusions on the tops of its walking legs and claw fingers. In addition, there are regularly aligned small black protrusions on parts of the exoskeleton surface of the claws and leg. In this study, the elemental composition, crystal structure, tissue structure, and mechanical properties of these protrusions were studied using a materials science approach, and the results were compared with those of mineralized cuticle. These leg tips were found to be a non-calcified fibrous tissue of α-chitin connected to the mineralized cuticle. The tip of the second walking leg was elongated and had a pointed shape with an oval cavity at its center that was more than 1000 times larger than the pore tubes (100–350 nm) of the mineralized cuticle. It was very soft, with a hardness of 0.4 GPa, corresponding to 11–12% of the hardness of the hard exocuticle and 55–57% of the hardness of the soft endocuticle. The elastic modulus of 8.0 GPa obtained by means of nanoindentation testing was consistent with that of α-chitin fibers of shrimp shells obtained by means of tensile testing. These soft protrusions provide a secure grip on the surfaces of trees or rocks and protect the claw fingertips. It was concluded that the black protrusions are related to a unique ecological (engaging in vertical movements, entering and exiting limestone caves, and escape behavior) aspect of the coconut crab, the largest terrestrial crustacean. [ABSTRACT FROM AUTHOR]

The features of the surface treatment of potassium-gadolinium-tungstate single crystals doped with neodymium ions by low- and high-energy argon cluster ions are considered. Two radically different treatment modes are employed: the low-energy mode for more efficient smoothing of the surface and high-energy for more effective etching of the target. The topography of the target surface is analyzed before and after cluster-ion treatment using atomic force microscopy. It is shown that treatment in the low-energy mode smoothes out irregularities on the target surface formed by chemical and mechanical polishing at an etching depth of less than 100 nm. A comparison is made of the root-mean-square roughness and total roughness of the initial and treated surfaces of potassium-gadolinium tungstate doped with neodymium ions. Survey X-ray photoelectron spectra of the initial surface of a KGd(WO4)2:Nd single crystal and after cluster-ion treatment in various modes are presented. It is demonstrated that the intensities of the potassium and gadolinium peaks decrease after cluster-ion treatment in both modes. A significant decrease in the concentration of potassium atoms in the surface layer of the target is explained by the preferential sputtering of potassium as a lighter chemical element. The mutual decrease in the concentrations of gadolinium and potassium atoms can be explained by the weak bonds of these atoms in the lattice of the KGd(WO4)2:Nd single crystal. [ABSTRACT FROM AUTHOR]

The density of energetic materials plays a vital role in determining their performance. A novel method is proposed for reliable prediction of the density of energetic metal–organic frameworks (EMOFs). The experimental data of density for 142 EMOFs, with different metal nodes and ligands, are used to construct and examine the model. This model is based on the molecular weight, elemental composition, and some of the specific structural parameters, which can be obtained from the chemical structures of EMOFs. The presented model is simply applicable for EMOFs with complex compositions and structures, without using complicated computer codes. The statistical parameters and cross-validation (CV) technique were used for evaluating the accuracy, precision, goodness of fit, and goodness of prediction of the new model. The values of statistical parameters, such as mean absolute deviation (MAD), maximum of errors, root-mean-square error (RMSE), and the coefficient of determination (R2), are 0.09, 0.33, 0.12, and 0.94, respectively. The absolute percent error (APE) values are less than 5% in 93 data points and greater than 10% only in 7 cases. Finally, coefficients of determination in CV, i.e., Q2LOO and Q25-fold, are 0.93 and 0.91, respectively. [ABSTRACT FROM AUTHOR]

Microalgae biofilm emerged as a solid alternative to conventional suspended cultures which present high operative costs and complex harvesting processes. Among several designs, rotating biofilm‐based systems stand out for their scalability, although their primary applications have been in wastewater treatment and aquaculture. In this work, a rotating system was utilized to produce a high‐value compound (astaxanthin) using Haematococcus pluvialis biofilms. The effect of nitrogen regime, light intensity, and light history on biofilm traits was assessed to better understand how to efficiently operate the system. Our results show that H. pluvialis biofilms follow the classical growth stages described for bacterial biofilms (from adhesion to maturation) and that a two‐stage (green and red stages) allowed to reach astaxanthin productivities of 204 mg m−2 d−1. The higher light intensity applied during the red stage (400 and 800 µmol m−2 s−1) combined with nitrogen depletion stimulated similar astaxanthin productivities. However, by training the biofilms during the green stage, using mild‐light intensity (200 µmol m−2 s−1), a process known as priming, the final astaxanthin productivity was enhanced by 40% with respect to biofilms pre‐exposed to 50 µmol m−2 s−1. Overall, this study shows the possibility of utilizing rotating microalgae biofilms to produce high‐value compounds laying the foundation for further biotechnological applications of these emerging systems. [ABSTRACT FROM AUTHOR]

Abstract Progress in the field of ecological stoichiometry has demonstrated that the outcome of ecological interactions can often be predicted a priori based on the nutrient ratios (e.g., carbon: nitrogen: phosphorus, C:N:P) of interacting organisms. However, the challenges of accurately measuring the nutrient content of active parasites within hosts has limited our ability to rigorously apply ecological stoichiometry to host–parasite systems. Traditional nutrient analyses require high parasite biomasses, often preventing individual‐level analyses. This prevents researchers from estimating variation in the nutrient content of individual parasites within a single host infrapopulation, a critical factor that could define how the ecology of the parasite affects the host–parasite interaction. Here, we explain how energy dispersive technology, a technique currently used to measure the elemental content of free‐living microbes, can be adapted for parasitic microbial infrapopulations. We demonstrate the power of accurately quantifying the biomass stoichiometry of individual microbial parasites sampled directly from individual hosts. Using this approach, we show that the stoichiometric composition of two microbial parasites capable of infecting the same host are stoichiometrically distinct and respond to host diet quality differently. We also demonstrate that characteristics of the stoichiometric trait distributions of these infrapopulations were important predictors of host fecundity, a proxy for virulence in this system, and better predictors of parasite load than the mean parasite stoichiometry or our parasite and diet treatments alone. EDS provides a rigorous tool for applying ecological stoichiometry to host–parasite systems and enables researchers to explore the nutritional physiology of host–parasite interactions at a scale that is more relevant to the ecology and evolution of the system than traditional nutrient analyses. Here we demonstrate that this level of resolution provides useful insights into the diet‐dependent physiology of microbial parasites and their hosts. We anticipate that this improved level of resolution has the potential to elucidate a range of eco–evo interactions in host–parasite systems that were previously unobservable.