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A series of aryl-diazinyl-cyanoacetamide (2a–l) were prepared by coupling the appropriate diazotized arylamines with dioxoisoindoline cyanaoacetamide (1). Also, the cyclization of azo derivatives (2f, 2h, and 2j) with chloroacetonitrile to yield the pyrazole derivatives (5f, 5h, and 5j) was studied. Moreover, compound 2d reacts with malononitrile to afford compound (6e). In a similar manner compound, 2d reacts with hydroxylamine to afford the sole product tetrazine derivative 8d. All the newly synthesized compounds were fully characterized by both analytical and spectral analyses. The geometries of the azo and hydrazo tautomeric forms were optimized at the B3LYP/6-311G level of theory. The dyeing performance of the synthesized dyes on polyester fibers has been assessed. Most of the dyes showed a good affinity to polyester fibers. No details regarding the synthesis and dyeing performance of such dyes are reported before in the literature. [ABSTRACT FROM AUTHOR]

Polyetherimide (PEI) fibers are classified as high-performance fibers due to their notable characteristics, including chemical resistance, heat resistance, and flame resistance. However, the amorphous structure and intrinsic dyeability of polyetherimide (PEI) fibers set them apart from other high-performance fibers. The fibers possess considerable potential due to their remarkable performance features and are utilized in a wide range of industries, containing fashion and technical textiles, for varied purposes. The present work utilized the Orthogonal Array Taguchi method to systematically improve the dyeing process parameters for fabric samples made of polyetherimide (PEI). The use of a systematic methodology enabled effective experimentation and enabled the determination of the most favorable values of factors, while simultaneously reducing the utilization of resources. The study involved conducting rigorous experiments to evaluate the influence of several parameters on the color strength, tensile qualities, and washing fastness properties of the fabric samples. Furthermore, the utilization of the Taguchi approach facilitated the anticipation of these pivotal fabric properties by considering certain parameters. The objectives of this research encompass not only the progression of textile industry, but also the provision of beneficial perspectives for augmenting the caliber and efficacy of PEI fabrics in various applications. [ABSTRACT FROM AUTHOR]

Ixora coccinea is a highly branched shrub having dense floral biomass that blooms throughout the year. The present study emphasizes the extraction, optimization, application, biomass yield, and cost of pigment from Ixora coccinea flowers. Pigment extraction from Ixora coccinea flowers was done by using isopropanol. Response surface methodology (RSM), a statistical tool, revealed that the optimized conditions were the solvent-to-sample ratio of 10:1 (mL/g), stirring speed of 200 rpm, and time of 40 min for high-yield production of pigments from Ixora coccinea using Design Expert software. The pigment was purified by using thin layer chromatography (TLC) followed by column chromatography. Furthermore, the purified pigment was analyzed by Fourier transform infrared spectroscopy (FTIR) and gas chromatography-mass spectrophotometer (GC–MS) which confirmed bis (2-ethylhexyl) phthalate, octacosane, and (+ -)-4-amino-4,5-dihydro-2 (3H)-furanone as the abundant compounds. At a high concentration (400 mg/mL), the pigment possessed significant antimicrobial activity against Escherichia coli and Bacillus subtilis. The retaining of pigment on the cotton cloth with 40% absorption of the color indicates its prospective application in textile industries as a natural colorant. The total biomass of fresh flowers from fifty Ixora coccinea plants was 35,671.2 g in the summer season from which a pigment yield of 1783.56 g can be obtained and the estimated cost for pigment production was around $0.2 per gram. [ABSTRACT FROM AUTHOR]

To date, clothing has been produced and disposed of in large quantities. It is also known that each process, from the procurement of raw materials to production, transportation, sales, laundry, and disposal, has a significant environmental impact. According to the Global Fashion Agenda, greenhouse gas (GHG) emissions from the fashion industry account for 4% of the global total. Therefore, apparel makers are shifting from a linear economy to a circular economy. For example, the Japanese start-up Curelabo Co., Ltd. (Okinawa, Japan) developed jeans (bagasse washi jeans) made from bagasse, which is a residual material derived from sugarcane after the extraction of cane juice. Furthermore, the use of improved dyeing reduces boiler fuel consumption and eliminates the need for detergents and acid. For disposal, the used jeans and their production waste are processed into biochar for carbon sequestration. In this study, we attempted to calculate GHG emissions using life cycle assessment (LCA) for the circular economy model developed by Curelabo Co., Ltd. GHG emissions from the production of bagasse washi jeans were 1.09 × 101 kg-CO2e. Dyeing, bleaching, and fabric finishing, known as the wet processes, were found to contribute a large proportion of GHG emissions due to their high energy consumption. Furthermore, the entire lifecycle of GHG emissions from bagasse washi jeans, including transport, sales, laundry, and disposal, were 1.53 × 101 kg-CO2e. First, the use of bagasse washi yarn for the weft reduced by 2.99 × 10−1 kg-CO2e compared with the use of conventional 100% bleached cotton yarn. Second, compared with conventional dyeing, GHG emissions from the improved dyeing process were reduced by 2.78 kg-CO2e. Third, the disposal of the used jeans and their production waste into biochar reduced GHG emissions by 9.01 × 10−1 kg-CO2e. Additionally, GHG emissions can be reduced by re-inputting waste in the paper-making process and by using liquefied natural gas as boiler fuel in the dyeing process. [ABSTRACT FROM AUTHOR]

The fiber derived from the pseudo-stem of the banana plant is the subject of this investigation. It describes the processes involved in creating pseudo-stem fiber from bananas, such as fiber extraction, retting, and degumming. Banana fiber has been separated using per-acetic acid. To evaluate the efficacy of the process, the fiber's appearance and form have been altered. A homogeneous, spotless surface was observed under Scanning Electron Microscopy. Weight loss is the outcome of the treatment and absorbency increases. 3.66% of the weight loss is attributed to the per-acetic acid treatment. The fiber's average diameter was reduced 81.9% compared to the raw fiber. Fourier transform infrared spectroscopy analysis was utilized to assess the chemical changes brought about by the treatment, which verified the presence of cellulose in the fiber. The separated fibers were colored using natural dyes, which were then assessed based on how well they characterized the color. The results demonstrated the use of natural colors derived from extracts of madder and myrobalan. The standard test indicates that ferrous sulfate (FeSO4) exhibits strong resistance to light, washing, and rubbing fastness, making it a viable mordant for achieving brown to black color. [ABSTRACT FROM AUTHOR]

Novel azo compounds were synthesized by diazotization of aniline and of 3-aminopyridine in the presence of NaNO2 and HCl, followed by coupling with 2-methylresorcinol in alkaline media. The structures were characterized using FT-IR, 1H NMR, and 13C NMR analysis. The main purpose of the present study is to investigate coloration applications, and antibacterial and fastness properties of the new azo structures in textile industry. Exhaust dyeing processes were applied on cotton fabric. Color strength (K / S values), L, a *, and b * values were measured. The color fastness values (to rubbing, light, perspiration, washing) of azo compounds on cotton fabric were presented according to ISO standards for comparison. Antibacterial activity assessment of the colored fabrics was performed according to AATCC 147-2016 test method against two types of bacteria: Staphylococcus aureus and Klebsiella pneumoniae. The fabric dyed with 2-methyl-4-[pyridin-3-yldiazenyl]benzene-1,3-diol demonstrated acceptable antibacterial activity against S. aureus. [ABSTRACT FROM AUTHOR]

This paper explores the intersection of colorimetry and biomimetics in textile design, focusing on mimicking natural plant colors in dyed textiles via instrumental colorant formulation. The experimental work was conducted with two polyester substrates dyed with disperse dyes using the exhaustion process. Textiles dyed with different dye colors and concentrations were measured in a spectrophotometer and a database was created in Datacolor Match Textile software version 2.4.1 (0) with the samples' colorimetric properties. Colorant recipe formulation encompassed the definition and measurement of the pattern colors (along four defined natural plants), the selection of the colorants, and the software calculation of the recipes. After textile dyeing with the lowest expected CIELAB color difference (ΔE*) value recipe for each pattern color, a comparative analysis was conducted by spectral reflectance and visual assessment. Scanning electron microscopy and white light interferometry were also used to characterize the surface of the natural elements. Samples dyed with the formulated recipe attained good chromatic similarity with the respective natural plants' colors, and the majority of the samples presented ΔE* between 1.5 and 4.0. Additionally, recipe optimization can also be conducted based on the colorimetric evaluation. This research contributes a design framework for biomimicking colors in textile design, establishing a systematic method based on colorimetry and color theory that enables the reproduction of nature's color palette through the effective use of colorants. [ABSTRACT FROM AUTHOR]

This work aims to present the results of evaluating the coloristic properties of polylactic acid (PLA) fibers. PLA is common nowadays in much research, as it is a biodegradable plastic from renewable sources. However, little research is devoted to PLA fibers, and even less to applied research of colored fibers. The prepared color masterbatches, created using inorganic pigments, such as titanium dioxide and carbon black, were subsequently used to prepare dyed PLA fibers in mass. The fibers were drawn to the maximum drawn ratio. The properties of the pure and dyed fibers were investigated before and after accelerated light aging using Q-SUN equipment. The changes were recorded by Fourier Transform Infrared (FTIR) spectroscopy and colorimetric properties were recorded using a device spectrometer from TECHKON SpectroDens. We also evaluated thermal properties from the first heating via differential scanning calorimetry (DSC). The measurements were taken before and after the aging of the PLA fibers, in order to see the effect of aging on the supermolecular structure, excluding the influence of the preparation process and the influence of the kind of PLA. Using inorganic pigments showed sufficient color stability even after accelerated light aging, which is beneficial for using colored fibers in practice. [ABSTRACT FROM AUTHOR]

This study presents the application of three commercial non-ionic surfactants, namely nonylphenol polyethylene glycol ether (Kenon), sorbitan ester polyethylene glycol ether (Tween), and oleic acid polyethylene glycol ester (Keol), to improve the extraction process of weld, madder, and walnut green husk natural dyes. The critical micelle concentration (CMC) values of Keol, Kenon, and Tween were 0.15, 0.19, and 0.25 g/L, respectively. The introduction of non-ionic surfactants into the solution markedly improved colorant extraction from plant sources, leading to a significant increase in the percentage of dye extracted in water. The wool dyeing with extracted dyes was also found to benefit from the presence of Tween, resulting in up to 11, 29 and 28 % increase in the color strength for weld, madder and walnut green husk extracts, respectively. Moreover, non-ionic surfactants improved dyeing and levelling properties of wool samples, and did not negatively impact on the general fastness ratings of dyed samples. Overall, this study suggests that the use of non-ionic surfactants provides a favorable manner for improving the extraction process of natural dyes and enhancing their dyeing properties. [ABSTRACT FROM AUTHOR]

In order to improve the fixational rate of reactive dyes, response surface methodology was used to optimize the dyeing process of cotbon fabric in systatin non-Rueous and less water medium. The interaction among sodium carbonate concentration, Fixation time and fixation temperature was studied, and the optimum process parameters were optimized^ sodium carbonate concentration 48 g/L, fixation time lOmin and fixation temperature 89 °C . According to the optimum process conditions, the predicted fixation rate is 75. 67%. The fixation rate calculated by experiment is 76. 73%, which is consistent with the predicted value [ABSTRACT FROM AUTHOR]

To explore the dyeing process problem of hemp fiber with trapa acornis nakano shell pigment, cationic modifiers KR, chitosan, gelatin, and BS modifiers were used to modify hemp, and unmodified and modified hemp were dyed with the dye. The influence of modifiers on the direct dyeing effect of trapa acornis nakano shell dye was discussed. The effects of mordant tannic acid, alum, plant ash acid on the dyeing of unmodified hemp and modified hemp fabric with trapa acornis nakano shell dye studied. The results show that the fabric dyed with trapa acornis nakano shell dye has a certain UV absolution function and the maximum wavelength in visible light is 380 nm, corresponding to an absorbance of 0. 067 K/S value of BS modified direct dyeing method, unmodified Hanma alum post mordant method, water-soluble chitosan modified Hanma alum post mordant dyeing method, gelatin modified Hanma alum post mordant dyeing method, BS modified Hanma grass and wood ash one bath mordant dyeing method and BS modified Hanma alum post mordant methods are all above 3. 990, their dyeing fastnesses are all at level 3 or above. Except for the BS modified direct dyeing process, which has a wet friction fastness of level 3, all other processes have a color fastness of level 3-4 or above, with the highest light fastness reaching level 5. [ABSTRACT FROM AUTHOR]

Abstract The fiber derived from the pseudo-stem of the banana plant is the subject of this investigation. It describes the processes involved in creating pseudo-stem fiber from bananas, such as fiber extraction, retting, and degumming. Banana fiber has been separated using per-acetic acid. To evaluate the efficacy of the process, the fiber's appearance and form have been altered. A homogeneous, spotless surface was observed under Scanning Electron Microscopy. Weight loss is the outcome of the treatment and absorbency increases. 3.66% of the weight loss is attributed to the per-acetic acid treatment. The fiber’s average diameter was reduced 81.9% compared to the raw fiber. Fourier transform infrared spectroscopy analysis was utilized to assess the chemical changes brought about by the treatment, which verified the presence of cellulose in the fiber. The separated fibers were colored using natural dyes, which were then assessed based on how well they characterized the color. The results demonstrated the use of natural colors derived from extracts of madder and myrobalan. The standard test indicates that ferrous sulfate (FeSO4) exhibits strong resistance to light, washing, and rubbing fastness, making it a viable mordant for achieving brown to black color. Graphical Abstract

The research and development of green techniques for the synthesis of silver nanoparticles (AgNPs) with bioactive plants has gained more attention against toxic chemicals. In this research, the aqueous solution of safflower extract was utilized for the simple, green, and commercial synthesis of AgNPs from AgNO3 solution on the wool yarn. The effect of the amount of extract and AgNO3 on the properties of produced nanoparticles was studied. The analysis of AgNPs by Dynamic Light Scattering (DLS) system and Ultravioletvisible (UV-Vis) spectroscopy exhibited that the particle size of produced NPs was <57 nm. In addition, the colorimetric data of wool yarn dyed with safflower extract in the presence of different concentrations of AgNO3 solution were also studied. The results showed that the presence of nanoparticles changed the color hue (hᵒ: 86→58), and the absorption of safflower extract on the wool samples increased from 5 to 29. Also, the ratings of washing and rubbing fastness of dyed samples were satisfactory (4-5). [ABSTRACT FROM AUTHOR]

Medicinal plant-based dyeing introduces vibrant colours alongside antibacterial and anti-odor properties, fostering sustainability. Innovations include mass sampling for consistent pigment production. Furthermore, lotus seedpods, rich in bioactive compounds, exhibit potential in diverse fields. Chitosan, a biopolymer derived from chitin, boasts versatility in drug delivery systems, wound healing, and antimicrobial applications. This experimental inquiry delves into the dyeability and antimicrobial efficacy of cotton fabric subjected to treatment with chitosan and dyed using Lotus seeds. The investigation encompasses varied parameters such as dye concentration, duration, and temperature for fabric dyeing. The study elucidates the aqueous extraction methodology for dye from Lotus seeds, the chitosan-based mordanting techniques. Standardized assessments are utilized to gauge colour fastness characteristics, encompassing washing, rubbing, and perspiration fastness, along with assessing the antimicrobial attributes of the treated cotton fabric. The study indicates that the application of chitosan-treated cotton fabric enhances dye intensity and overall dyeing quality, consequently improving the colour fastness property of washing, rubbing, and perspiration. Additionally, the treated cotton fabric exhibits significant antimicrobial activity against common bacteria, highlighting the potential of Lotus seed-derived colourants and chitosan mordant in the development of sustainable and antimicrobial textiles. The future scope lies in optimizing the integration of Lotus seed-derived colourants and chitosan mordant for enhanced sustainability and antimicrobial efficacy in textile applications, leveraging advancements in dyeing technology and antimicrobial formulation techniques.

Abstract In recent years, a great interest has focused on the use of bicomponent filaments in several high-performance textile articles such as swimwear, sportswear and even high-quality denim. To dye fabrics containing these filaments, it is necessary to establish appropriate dye recipes allowing to obtain desired shades. In this article, we developed a genetic algorithm to optimize the color matching step of these bicomponent filaments, especially (PET/PTT) filaments. Three disperse dyes with different molecular weights were used for dyeing. The objective is to reproduce the reference color by choosing the appropriate disperse dyes among the available dyestuffs and their corresponding quantities to use on the mixture. For modeling, two sets of parameters (lied to the color formulation problem and the genetic algorithm), the objective function as well as the different stages of the algorithm were defined and described. In addition, different techniques of selection and mutation were applied and evaluated. The optimization criterion is to reduce the CMC color difference between the desired reference colors and the colors proposed by the algorithm. The developed algorithm showed good performances with very small color differences. The results indicate that the roulette wheel selection technique outperforms both rank and uniform selection methods. Moreover, employing a simple mutation strategy yields favorable outcomes with CMC color differences all lower than 1.

Natural dyes offer a bio-based opportunity to support the attractive coloration of textile fabrics made from natural fibers like cotton, wool, hemp, and many other textile materials. They can be part of a strategy to realize fully bio-based textiles and clothing materials. In line with this statement, the following study investigates the use of wood extracts for dyeing cotton fabrics. Specifically, extract powders of logwood (Haematoxylon campechianum L.), brazilwood (Caesalpinia spp.), and quebracho wood (Schinopsis lorentzii) are used. The aim of the study is to evaluate which colorations can be obtained by the application of those wood extracts and what fastness properties are reached. For this, different modified process parameters and mordants are evaluated. The dyeing process is modified using different mordants based on iron and aluminum salts. These mordants are applied in pre-, meta-, or post-mordant procedures. The color and fastness properties of prepared textile samples are determined by spectroscopic measurements, color measurements, washing procedures, and a Xenotest for measuring the light fastness. Ultimately, it is shown that a broad range of colorations can be realized through different combinations of wood extracts and mordanting procedures. Notably, stronger color depths are reached with pre- and meta-mordanting compared to post-mordanting. Good wash fastness is obtained for some color shades. However, with post-mordanting, better wash fastness can be achieved. The light fastness of the realized samples is only moderate to low. In conclusion, it can be stated that dyes from wood extracts are excellent materials to dye natural fibers if they are combined with the right mordanting agent in pre- or meta-mordanting procedures. The present study is therefore a good proof-of-concept for the realization of fully bio-based colored textile materials.

Waterless dyeing of polyamide 6.6 using scCO2 (supercritical carbon dioxide) was investigated. PA (polyamide) fibers can be dyed with various dyes, including disperse dyes. The conventional aqueous dyeing process uses large amounts of water and produces polluted water. Considering these environmental issues, waterless dyeing of fibers is a forefront issue, and utilization of supercritical carbon dioxide (scCO2) is a commercially viable technology for waterless dyeing. This study tested PA6.6 (polyamide 6.6) dyeing in scCO2 at 100 °C 220 bar pressure for 45 min. Color measurements and color fastness tests were performed, as well as tensile strength, scanning electron microscope (SEM) analysis, and Fourier transform infrared spectroscopy (FTIR) analysis. PA6.6 fabrics yielded higher K/S (color strength, the Kubelka–Munk equation) values with larger molecular weight dye and almost the same color strength with medium and small-sized dyes, demonstrating the ability of dyeing in a supercritical environment without water as a more environmentally friendly dyeing option compared to conventional dyeing. [ABSTRACT FROM AUTHOR]

This study has been carried out to dye double-sided cotton/polyester fabric by single bath method, with disperse and reactive dyes, without draining out the liquor after polyester side dyeing and with no extra chemicals. Three different dyeing procedures (two-bath two-step, one-bath two-step and one-bath one-step) have been used. The findings were evaluated in terms of dyebath exhaustion (E) and color strength (K/S) parameters. The experimental dyebath exhaustion values are found acceptable and fit well with the exponential model. Color strength for the one-bath dyeing procedures is found comparable with those of the two-bath method. The performed one-bath dyeing method is found more productive and environment friendly as compared to two-bath technique, because it saves the consumption of water, energy, time and chemicals. [ABSTRACT FROM AUTHOR]

Natural dyes offer a bio-based opportunity to support the attractive coloration of textile fabrics made from natural fibers like cotton, wool, hemp, and many other textile materials. They can be part of a strategy to realize fully bio-based textiles and clothing materials. In line with this statement, the following study investigates the use of wood extracts for dyeing cotton fabrics. Specifically, extract powders of logwood (Haematoxylon campechianum L.), brazilwood (Caesalpinia spp.), and quebracho wood (Schinopsis lorentzii) are used. The aim of the study is to evaluate which colorations can be obtained by the application of those wood extracts and what fastness properties are reached. For this, different modified process parameters and mordants are evaluated. The dyeing process is modified using different mordants based on iron and aluminum salts. These mordants are applied in pre-, meta-, or post-mordant procedures. The color and fastness properties of prepared textile samples are determined by spectroscopic measurements, color measurements, washing procedures, and a Xenotest for measuring the light fastness. Ultimately, it is shown that a broad range of colorations can be realized through different combinations of wood extracts and mordanting procedures. Notably, stronger color depths are reached with pre- and meta-mordanting compared to post-mordanting. Good wash fastness is obtained for some color shades. However, with post-mordanting, better wash fastness can be achieved. The light fastness of the realized samples is only moderate to low. In conclusion, it can be stated that dyes from wood extracts are excellent materials to dye natural fibers if they are combined with the right mordanting agent in pre- or meta-mordanting procedures. The present study is therefore a good proof-of-concept for the realization of fully bio-based colored textile materials. [ABSTRACT FROM AUTHOR]

In order to reduce the hazards caused by molten drops of PET during combustion, a flame retardant HBCP was synthesized from hexachlorocyclotriphosphazene nitrile and p-hydroxybenzaldehyde, and HBCP was blended with PET and then melt spun to produce flame retardant anti-dripping PET fibers. The effects of three disperse dyes (disperse yellow 3G; disperse blue 2BLN and disperse red 3B) on the dyeing process of pure PET fibers and flame flame-retardant and anti-dripping PET fibers were investigated, including the effects of dyeing mass fraction, dyeing temperature, dyeing time and pH value on the dyeing performance of the fiber. The experimental results show that the dyeing rate of both disperse yellow 3G and disperse red 3B is the highest and the dyeing effect is better when the dye mass fraction is 1.0%, dyeing temperature is 130 °C, dyeing time is 60 min, and the pH value of dye solution is 5; the disperse blue 2BLN achieves the highest dyeing effect when the dye mass fraction is 2.0%, the dyeing temperature is 120 °C, the dyeing time is 60 min, and the pH value of dye solution is 5. Under the same dyeing process conditions, the dyeing rate of all three disperse dyes is improved to some extent for the flame-retardant and anti-dripping PET fibers compared to the pure PET fibers. [ABSTRACT FROM AUTHOR]

PEI fibers are considered a high-performance type of fiber, known for their exceptional heat resistance and mechanical strength. These fibers, made of polyetherimide (PEI) polymer, have a completely amorphous structure, and can be dyed with disperse dyes, similar to how polyester fibers are dyed. This study focused on the reduction clearing process after dyeing PEI fibers with disperse dyes and examined various clearing agents used in both alkaline and acidic conditions, assessing how different concentrations, temperatures, and durations of reduction clearing processes affected the PEI samples. The main goal was to find the best reduction clearing parameters for disperse-dyed PEI samples, taking into account environmental impact, fabric durability, and color fastness. Analytical techniques like chemical oxygen demand (COD), biological oxygen demand (BOD5), total organic carbon (TOC), and carbon footprint analysis were used for evaluation. The study revealed that most disperse-dyed PEI fibers require a reduction clearing process, with few exceptions. It is important to note that clearing with sulfuric acid-based agents or in acidic conditions may slightly reduce the fiber's strength. On the other hand, the study identified that utilizing a solution containing 2 g/l sodium dithionite and 4 g/l NaOH for 30 min at 70 °C resulted in the least strength loss. Similarly, when considering the environmental impact, this same reduction clearing process was found to have the least detrimental effects based on COD, BOD5, TOC, and carbon footprint analyses. The data collection process was thoroughly documented throughout the study. [ABSTRACT FROM AUTHOR]

Most traditional synthetic dyes and functional reagents used in silk fabrics are not biodegradable and lack green environmental protection. Natural dyes have attracted more and more attention because of their coloring, functionalization effects, and environmental benefits. In this study, natural dyes were extracted from lac and used for coloring and functionalization in silk fabrics without any other harmful dyes. The extraction conditions were studied and analyzed by the univariate method. The optimal extraction process was that the volume ratio of ethanol to water was 60:40 with a solid–liquid ratio of 1:10, and reacting under the neutrality condition for 1 h at 70 °C. Silk fabric can be dyed dark owing to the certain lifting property of lac. After being dyed by Al3+ post-medium, the levels of the washing fastness, light fastness, and friction fastness of silk fabric are all above four with excellent fastness. The results show that the dyed silk fabrics have good UV protection, antioxidation, and antibacterial properties. The UV protection coefficient UPF is 42.68, the antioxidant property is 98.57%, and the antibacterial property can reach more than 80%. Therefore, the dyeing and functionalization of silk fabrics by utilizing naturally lac dyes show broad prospects in terms of the application of green sustainable dyeing and functionalization. [ABSTRACT FROM AUTHOR]

The traditional textile use of wool as a valuable renewable material needs alternative applications in order to, besides sheep milk and meat, valorize currently unnecessary wool. Each type of product containing sheep wool requires wool with customized properties. Finding suitable physical and chemical modifications needed to develop new products while minimizing harmful side effects is a challenge for scientists. The presented review provides a brief overview of works published over the last decade associated with innovative wool scouring, dyeing, antifelting, and modification of its structure without the ambition to present complete, detailed data. [ABSTRACT FROM AUTHOR]

In recent years, a great interest has focused on the use of bicomponent filaments in several high-performance textile articles such as swimwear, sportswear and even high-quality denim. To dye fabrics containing these filaments, it is necessary to establish appropriate dye recipes allowing to obtain desired shades. In this article, we developed a genetic algorithm to optimize the color matching step of these bicomponent filaments, especially (PET/PTT) filaments. Three disperse dyes with different molecular weights were used for dyeing. The objective is to reproduce the reference color by choosing the appropriate disperse dyes among the available dyestuffs and their corresponding quantities to use on the mixture. For modeling, two sets of parameters (lied to the color formulation problem and the genetic algorithm), the objective function as well as the different stages of the algorithm were defined and described. In addition, different techniques of selection and mutation were applied and evaluated. The optimization criterion is to reduce the CMC color difference between the desired reference colors and the colors proposed by the algorithm. The developed algorithm showed good performances with very small color differences. The results indicate that the roulette wheel selection technique outperforms both rank and uniform selection methods. Moreover, employing a simple mutation strategy yields favorable outcomes with CMC color differences all lower than 1. [ABSTRACT FROM AUTHOR]

Archaeological research into industrial heritage is a relatively recent field of study in the Czech Republic. During the past six years, several historical textile production facilities (including five dyeing workshops) have been uncovered as part of preparatory work for construction projects in areas traditionally associated with the textile industry. Following excavations, these facilities have been the subject of interdisciplinary research. This article presents a comprehensive account of its findings. The introductory part traces the historical development of the textile industry in what is now the Czech Republic. The article then presents the results of research carried out at sites in Brno, Úštěk and Krnov, documenting the possibilities of rescue archaeology and non-destructive surveys as well as tracing this type of workshop's heating units evolution, providing a comprehensive overview of industrial dyeing in the territory of the present-day Czech Republic during the 18th and 19th centuries. [ABSTRACT FROM AUTHOR]

Polypropylene (PP) has unique competitiveness with other synthetic fibers due to its suitable spinnability, availability of raw materials, and low processing cost. PP fabric exhibits excellent chemical, physical, and mechanical properties, such as a light texture, adequate tensile strength, and resistance to most chemicals. However, the absence of reactive functional groups in PP fiber, besides its high crystallinity, results in hydrophobic surface, low affinity to dyestuffs, and poor antistatic properties, which restrict its use in the clothing field. Herein, a water- and energy-saving, eco-friendly finish is proposed to render PP desired properties suitable for textile applications. The surface of PP fabric was activated using oxygen and nitrogen plasma radiations. The plasmairradiated PP fabric was post-treated with two renewable eco-friendly proteinic biopolymers, namely gelatin and sericin, in the presence and absence of a crosslinking agent. The effects of different process conditions on the properties of the modified PP, including the duration of plasma exposure, the concentration of biopolymer, and treatment temperature were monitored. The affinity of the treated PP fabric towards anionic and cationic dyes was evaluated. The findings of this study demonstrated that the comfort attributes of the plasma/biopolymer-finished fabrics, such as the induced antistatic properties, wettability, and ultraviolet protection, were remarkably improved. The plasma-mediated biopolymer-finished PP fabrics were found dyeable with cationic and anionic dyes. The change in the chemical and morphological structures of PP fabrics was monitored using Fourier transform infrared spectroscopy, scanning electron microscopy, and energy dispersive X-ray spectroscopy. [ABSTRACT FROM AUTHOR]

Complex extraction, which has the characteristics of high efficiency and selectivity of chemicals, has unique advantages in dye wastewater treatment. In the paper, a green closed‐loop dye wastewater treatment route for dyeing industry is re‐evaluated by studying the complex extraction and stripping of Telon yellow 4B, and dyeing test of regenerated dye. FT‐IR characteristic peaks of the initial organic phase and the regenerated organic phase are consistent, and the dye can be migrated from the loaded organic phase to the aqueous phase after stripping. The concentration of dye in the aqueous phase and extraction conditions have a significant effect on extraction rate, especially the aqueous‐organic phase ratio and the pH value of the aqueous phase. Meanwhile, the stripping conditions have a marked impact on stripping rate, among which NaOH dosage is an important factor. The regenerated dye solution and the freshly prepared dye solution at same concentration have the same color shade and K/S value, and the color fastness of dyed fabrics is all above Grade 4. High extraction rate, high stripping rate, excellent reusability of regenerated organic phase, and the dyeing performance of the regenerated dye prove that complex extraction is a green dye wastewater treatment process with the practical feasibility. [ABSTRACT FROM AUTHOR]

With the progress of society, people pay more and more attention to their health and the surrounding living environment. Consequently, there is a growing demand for ecological and environmentally friendly functional dyed textiles among consumers. However, conventional textile dyeing often involves the use of synthetic dyes that contain harmful chemicals to the human body. These dyes are not easy to degrade and are prone to causing a series of health hazards and environmental pollution. Therefore, the concept of sustainable development has led to renewed interest in non-toxic, harmless, and naturally degradable natural plant dyes. Roselle-red (MGH) is a kind of natural pigment extracted from the calyx of solanum roseum. It is green, safe, and has antibacterial and antioxidant effects. It has found extensive application in food preservation and medical healthcare. Because of its bright color and inherent functionality, it is often used for dyeing silk fabrics, but due to the lack of affinity between silk fibers, the dyeing rate is not high. In order to promote its dyeing effect, some heavy metal ionic mordants are commonly used for mordant dyeing. Although this method can effectively improve the dyeing and fixation of natural pigments on silk fabrics, these mordants are usually toxic, and there are potential environmental pollution problems. Moreover, after dyeing the fabric, the color fastness is not high, especially the washing fastness is poor. Therefore, it is necessary to develop a new method to improve color fastness. To solve the problems such as low color fastness and poor washing resistance of the silk fabric after dyeing, the rigid and flexible properties of acrylic monomer copolymerization can be used to improve the molecular aggregation structure and the enrichment degree of hydrophobic elements on the fiber surface, so as to achieve the purpose of film coating. A kind of polyacrylate polymer was synthesized from methyl methacrylate, butyl acrylate, 2-hydroxyethyl methacrylate and methyl acryloxypropyl tri (trimethylsiloxanyl) silane. Then, the treated fabric was immersed in glutaraldehyde solution to achieve the purpose of chemical cross-linking. Subsequently, the polymer was used as a fiber coating material for natural roselle-red dyed silk fabrics. Finally, the double effect of color fastness and waterproofing was significantly improved by using the three functions of fast coating, water penetration resistance and chemical bonding. The results of IR spectra show that the pigment and finishing agent have been successfully introduced into the structure of silk fibers by the coating crosslinking of PAMES and GA. SEM results show that there is a coating layer on the surface of the fiber after waterproofing and crosslinking, and the presence of silicon in EDS analysis results further proves that PAMES has been successfully coated on the fiber surface. In the thermal stability test, the maximum thermal degradation temperature of the finished silk fabric and the original silk fabric moves to 327.77 ℃, while the peak value of thermal degradation decreases significantly, indicating that the deposition coating of PAMES has a certain effect of hindering heat transfer. The result of water contact angle test shows that the finished silk fabric has obvious hydrophobic property. The mechanical properties of finished silk fabrics are significantly improved, and the color fastness of the silk fabric is obviously improved after treating and dyeing. The wet fastness is increased from grade 2-3 to grade 4, and the soap fastness is increased from grade 1-2 to grade 3-4. The treated fabric exhibits good waterproof effect, and the water contact angle increases from being close to zero to 125°. The mechanical properties are significantly improved, with breaking strength increasing from 8.73 MPa to 26.37 MPa. By using the coating cross-linking method, the polymer (PAMES) as the fiber coating material is applied to the silk fabric dyed with roselle-red pigment, which enhances the stability of natural roselle-red pigment, and effectively improves the color depth and color fastness of silk fabrics. Thus, the polymer has a broad application prospect, and also provides a technical route for other natural vegetable dyes dyed silk fabrics. [ABSTRACT FROM AUTHOR]

A series of five novel monoazo dyes designed from 4-amino antipyrine diazo coupling with five different cyclic ketones is successfully reported and characterized by possible spectroscopic methods to confirm their structural appearance. Based on FTIR and 1H-NMR spectral interpretation, dyes A and E are stable in their tautomer-like hydrazone and enol forms. In this endeavor, dyes were also subjected to an assessment of dyeing performance using high-temperature and high-pressure methods at 130 °C, and the synthesized dyes were found to have good dyeing abilities. Electron withdrawing group carbonyls in the heterocyclic moiety, adjacent to the diazo linkage, influence the shades of the dye on the fabric. The dyed fabric exhibits moderate to favorably good color fastness properties of washing, sublimation, heat, and perspiration. Antimicrobial screening was also performed against two fungal strains and four bacterial strains including Gram-positive and Gram-negative bacteria. The results are negligible for dyes A–D, but dye E possesses moderate to excellent inhibitory actions toward bacterial strain B. subtilis as well as the fungi C. albicans. These pathogens are found to exist on cotton fabrics for a month and induce health issues. Dyed cotton fabrics with dye E is found to be resistant to the fungus C. albicans which bears 14 days of lifespan on cotton fabric and causes nosocomial infections including vaginal yeast sepsis, diaper rashes, and thrush. [ABSTRACT FROM AUTHOR]

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The functionality and excellent low temperature dyeability of wool fabrics play a crucial role in expanding their potential applications in the fields of healthcare and technical textiles. The study proposes a highly effective modification method to impart coloration enhancement and functionality for wool fibers using lipoic acid (LA) as a coupling agent to bind hydroxypropyl-β-cyclodextrin (HP-β-CD) capped magnetic nanoparticles (Fe3O4). The structure and morphology of the modified wool fabrics (MWF) were characterized by various measure techniques including FT-ATR, FE-SEM/EDS, XRD, X-ray photoelectron spectroscopy (XPS) and thermogravimetric analysis (TG). The results demonstrated the successful immobilization of HP-β-CD capped Fe3O4 nanoparticles on the surface of wool fibers through LA. The MWF exhibited enhanced wettability, anti-wrinkle performance, improved UV resistance, effective antioxidation, and good antibacterial effect against Gram-positive (Staphylococcus aureus). These properties were found to be dosage-dependent on LA. In addition, the dyed MWF with Curcumin and Acid red 1 demonstrated higher color strength compared to untreated wool, and the color strength (K/S value) reached to 17.1 and 23.4 respectively when using 4% (o.w.f) dye concentration at 80℃ without any pH adjustment. Furthermore, the dyed MWF with both dyes exhibited the improved rubbing and washing colorfastness. This study presents a potential effective approach for enhancement in the bio-functionality and dyeability of wool fabrics.

Antimicrobial resistance presents a substantial global health challenge, prompting the exploration of innovative strategies to combat pathogenic bacteria. Within this context, considerable attention has been directed towards textile materials treated with antimicrobial agents for their potential to mitigate the spread of infectious diseases. This research sought to investigate the influence of Neem dyeing and Lemon mordanting on enhancing the innate antimicrobial properties of Silk and Lyocell fabric. Textile materials underwent mordanting exclusively with natural agents, such as citrus lemon extract, to enhance dye adherence. The dyeing process involved the use of Azadirachta indica dye obtained through aqueous boiling, applied to lyocell and silk fabrics under various parameters. The key findings revealed a significant augmentation in the antimicrobial effectiveness of lyocell and silk fabrics following Neem dyeing and Lemon mordanting. Optimized conditions, including prolonged dyeing time, elevated temperatures, and constant dye concentrations, notably improved inhibition percentages against common pathogens like Staphylococcus aureus and Klebsiella pneumoniae. Furthermore, the study assessed the washing and perspiration fastness properties of silk and lyocell fabrics in accordance with established standards. In conclusion, the integration of Neem dyeing and Lemon mordanting emerges as a promising method to significantly enhance the antimicrobial efficacy of Lyocell and silk fabrics. This approach opens avenues for the development of textiles with heightened infection control properties, particularly in sectors focused on public health and hygiene. The evaluation of fastness properties also yielded excellent results, further supporting the viability of this method in academic and practical contexts. Considering the global challenge of antimicrobial resistance, adopting such innovative strategies in textile treatment can contribute significantly to the development of effective and sustainable solutions. Future research endeavours may explore additional applications and variations of this method, ensuring its adaptability and widespread implementation in diverse settings.

The leather industry generates a significant amount of various wastes, and their utilisation is a serious task for researchers. Ways to reuse or decontaminate such waste are being developed intensively. Unfortunately, the reuse of finished leather, which eventually becomes waste, is almost unexplored. The present research is designed to evaluate the potential of finished leather hydrolysis to obtain protein hydrolysates suitable for reuse in leather processing and to establish factors that influence leather quality during such an application. Enzyme preparation Vilzim PRO Conc was characterised as a potential agent for such hydrolysis. The addition of 3â4% Vilzim PRO Conc is appropriate for the enzymatic stage of the hydrolysis process. It was established that after alkaline­enzymatic hydrolysis of used leather powder the obtained hydrolysates are complicated systems containing proteins, chromium compounds, dyes, fatliquoring materials, etc. Hydrolysates could be used for the dyeing of chromed leather. The method of preparation for dyeing and dyeing of wet­blue leather with the use of hydrolysate influences the depth of dye penetration and the quality of finished leather. It was established that the neutralisation process is not necessary before such dyeing. Also, an increased amount of formic acid is necessary to improve the bonding of fatliquors with dermal tissue after treatment with hydrolysate.

Abstract Numerous natural dyes were used to dye mediaeval Islamic paper from the tenth to the nineteenth century, using a variety of techniques. The objective of this research is to develop an analytical method using high performance liquid chromatography with diode array detection (HPLC–DAD) to identify natural dyes in forty historical Islamic paper manuscripts from two collections. In addition, novel information was obtained from original treatises containing recipes for dyeing paper and the chronological use of dyes in dyeing mediaeval Islamic paper between the tenth and seventeenth centuries. The results show that thirty-four of the forty manuscripts examined contained dyes. Six natural dyes were detected, including henna, madder, lac, safflower, turmeric, and weld. This is the first study aimed at developing a method for determining various natural dyes in Islamic paper from a wide historical and geographical range in the mediaeval time and to fill significant gaps in the technical and historical knowledge of papermaking.

ABSTRACTPineapple leaf fiber is an environment-friendly natural fiber that does not harm any natural substance. To produce commercially available and attractive textile materials, pineapple leaf fibers were bleached with hydrogen peroxide and colored with natural dyes. Four natural dyes (turmeric powder, ebony fruit, lac, and sappan wood) were selected as natural sources for the extraction of natural colorants with and without salt, alum, and lime as mordants. The hydrogen peroxide concentration of 10 %owf, liquor ratio of 1:100, contact time of 30 min, and bleaching temperature of 70 °C were found to be the optimum bleaching parameters. The uses of different types of mordant on natural dyes give a variety of shades. The positive value of color axes (a* and b*) was an affirmation of mixture of red and yellow colors of mordanted-dyed PALF. PALF displayed a satisfactory dyeing performance for ebony fruit extracted dye with adequate fastness properties (from good to excellent) for light, wash, and perspiration, whether unmordanted or mordanted. Meta-mordanting increased the colorfastness properties of the samples. Results show excellent coloring ability for pineapple fiber dyeing, which can be a potential substitute for synthetic fiber as a sustainable approach to clean production.

Based on the trend of low-carbon emissions and environmentally friendly development, this paper extracted natural dye from gardenia for cellulose fiber dyeing and endowed them with UV resistance and antibacterial properties. And more attention was paid to the dye structure of the gardenia yellow dye and its alkali-hydrolyzed gardenia yellow dye on dye uptake, UV–visible absorption characteristic peak as well as functional finishing. The main dye components of gardenia yellow dye and its alkali-hydrolyzed gardenia yellow dye were measured by the UV–visible and LC–MS spectrum. The crocin, which was the main dye components in the gardenia yellow dye, presented higher maximum absorption wavelength and darker colors compared with alkali-hydrolyzed gardenia yellow dye, which the main dye components was croceic acid. The cotton fabrics dyed with gardenia yellow dye or alkali-hydrolyzed gardenia yellow dye all indicated well dyeing performacne and functional characteristics such as antioxidant activity, UPF values and antibacterial property against Staphylococcus aureus and Escherichia coli. The main reason for different in the dyeing and functional performance of cotton fabrics dyed with gardenia yellow dye or its alkali-hydrolyzed dye were the removing gentiobiose molecules under alkali treatment, which changed the conjugate systems, ionization capacity, and polyphenols and flavonoids content. And the study examines the dyeing kinetics, adsorption isotherm, and thermodynamics of gardenia yellow dye and its alkali-hydrolyzed gardenia yellow dye on the cationic cotton. It is expected that achievement of this research provide guide to the value adding utilization of agricultural by-products from crop industries and view to investigate the effect of dye composition on the dyeing and functional performance. [ABSTRACT FROM AUTHOR]

Tussah silk is one of the most widely used wild silks. It is usually dyed with acid dyes, despite the shortcoming of poor wet fastness. Reactive dyeing is a good solution to this problem. In our work, sulfatoethylsulfone (SES), sulfatoethylsulfone/monochlorotriazine (SES/MCT), monochlorotriazine (MCT), and bis(monochlorotriazine) (Bis(MCT)) dyes were used to dye tussah silk. All of these dyes showed lower exhaustion and fixation on tussah silk than on mulberry silk under alkaline conditions. Among them, SES dyes were more applicable, with a fixation of 70–85% (at 4%owf dye) at 90 °C when using sodium bicarbonate as an alkali. SES dyes also showed a rapid fixation speed. The dyeing of tussah silk required lower sodium bicarbonate dosage, the use of more neutral electrolytes, and a higher dye quantity to achieve deep effects compared to mulberry silk. Dyed tussah silk displayed lower apparent color depth and brilliance than dyed mulberry silk. The neutral boiling dyeing of tussah silk with SES dyes exhibited higher exhaustion, higher fixation (82–92% at 4%owf dye), and a slower fixation speed compared with alkaline dyeing. Furthermore, in this dyeing method, SES dyes showed higher and more efficient fixation on tussah silk than on mulberry silk. All dyed tussah silk had excellent color fastness to soaping. [ABSTRACT FROM AUTHOR]

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Copyright of Advanced Textile Technology is the property of Zhejiang Sci-Tech University Magazines and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Inorder to improve the biological functionality and dyeability of silk fabrics, chitosan/alpha-lipoic acid (CS/LA) conjugates were used to modify silk fabrics via dip-padding and hot-pressing methods. Structural and morphological characterization of the as-prepared silk fabrics was performed by various testing techniques. The results showed that the incorporation of CS/LA conjugates with silk fiber significantly improved the antioxidant properties, crease resistance, ultraviolet protection, and dyeability of silk fiber. The effect of different dyeing parameters on dyeing properties was investigated. When dyed with curcumin and weak acid red B at low temperatures without any additional agent, the modified silk fabric could achieve a higher color depth (K/S) and dye exhaustion than unmodified ones. The adsorption behaviors of the modified silk fabrics on curcumin and weak acid red B followed the Langmuir isotherm model and the quasi-second-order kinetic model at dyeing temperature of 40 °C without pH adjustment. In addition, the dyed modified silk fabric with curcumin still maintained excellent antioxidation activity even after 15 times of washing circles and high color fastness. This study presents a viable approach to achieve healthcare function and low-temperature dyeing of silk textile products, which is also in line with the development goal of the sustainable process for textile dyeing and finishing. [ABSTRACT FROM AUTHOR]