1. Influence of processing method on the conductive properties of nanocomposite films based on nanocellulose and graphene nanoplatelets.
- Author
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Beltrami, Mateus, Beltrami, Lílian V. R., Zattera, Ademir J., and Santana, Ruth M. C.
- Abstract
The need for improvements in electronic devices has been generating important demands in the technical-scientific area. Thus, including in these devices natural materials, which present desirable performance and are sustainably obtained from renewable sources, becomes an interesting option. Nanocellulose and graphene-based films have been researched for some years seeking to achieve special electrical properties. However, the production method of these films directly influences their electrical properties. In this context, this work proposes to explore the conductive and morphological properties of nanocellulose films combined with graphene nanoplatelets (GNP), produced by two different methods (casting and dip coating). For this, the nanocelluloses were obtained through the milling process in a defibrillator stone mill of eucalyptus cellulose bleached in distilled water. The casting films were produced from the incorporation of GNP directly into the nanocellulose suspension; while the dip coating films were produced from the immersion (5–10 layers) of dry nanocellulose films in a solution containing GNP. In this way, it was sought to compare the nanoplatelets embedded (casting method) within the film to those applied on the external surface of the film (dip coating method). The volumetric conductivity was measured (ASTM D257-07 standard) and the surface conductivity (4-point device) of the films produced. The results showed that all films containing GNP had higher conductivities than pure nanocellulose films. However, casting films, despite having a higher GNP concentration, presented lower volumetric and surface conductivity values when compared to dip coating films. In addition, reassess after 1 year, the dip coating films showed an insignificant decrease in conductivity values, indicating a longer useful life. However, the casting films show about 50% decrease in conductivity. Thus, it was concluded that the presence of GNP only in the outer layer of nanocellulose films is more efficient for potential application in electronic systems. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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