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Today, the South Atlantic Convergence Zone (SACZ), a convective band that extends across central Brazil to the western South Atlantic Ocean, modulates Southern Hemisphere summer rainfall in Southeastern Brazil. During the Holocene, however, the role of the SACZ over the rainfall regime in this part of South America is still under debate. This study aims to provide new insights into the SACZ Late-Holocene variability through analysis of the geochemical (XRF-based bulk sediment Metal/Metal ratios) and sedimentological (grain size and end-member modeling) variations along four cores retrieved in a coastal area (24–49 m water depth) located in the core of modern SACZ. Our records show an increase in Ti/Ca ratios, suggesting increased rainfall and that the terrigenous input to the Brazilian southeastern inner shelf changed in the Late-Holocene (last 4200 years). These changes are also followed by a decrease in the K/Ti ratio, indicative of an increase in chemical weathering in the sediment source, and an increase in the Mn/Ti, suggesting an increase in oxidation. Additionally, decadal-scale variability with periodicities of 25 and 55 years obtained by a time-series (Redfit) analysis highlights a potential role of the Pacific Decadal Oscillation and the Atlantic Multidecadal Oscillation, respectively, as drivers of the SACZ variability over the last 4200 years. [ABSTRACT FROM AUTHOR]

This study examines the impact of the constant sedimentation—CS premise on sedimentation rates, mass accumulation rates and age-depth results obtained from unsupported 210Pb models. The investigation is based on vertical profiles of 210Pb, 226Ra, 228Ra, 40K, and 137Cs measured through gamma spectrometry from seven sediment cores collected from the coastal region of southern Brazil. This region is known for harboring mud shelf depocenters. The mean sedimentation rate in the study area was estimated to be between 0.33 and 0.58 cm yr−1. The geographical disposition of the sampling sites allowed the identification of distinct sedimentological features, including a northernmost, middle shelf depocenter, a more coastal depocenter, and a region with sandy sediments deposited by wave-driven dynamics. The findings of this study have revealed that the decision to consider or exclude the CS premise can be made through a thorough examination of the vertical profiles of activities and the application of robust statistical analysis to identify outliers in the vertical profiles of mass accumulation rates. These important considerations play a crucial role in guiding researchers toward selecting the most appropriate approach to investigate sediment cores. [ABSTRACT FROM AUTHOR]

Activities related to the marine exploration of oil and gas reservoirs tend to cause a concentration of natural radionuclides in related materials. As such, knowledge regarding the distribution of radionuclides in sedimentary basins with current oil operations is essential for modeling radiological hazards and possible risks of site contamination. This study investigated the distribution of 226Ra and 228Ra, radioisotopes from the 232U and 232Th decay chains in bottom sediment of the Santos basin. Sediment samples were collected from sites in a sampling grid based on depth contours and were analyzed through high-resolution gamma spectrometry. A distribution model of the spatial variation of these isotopes, the first of its kind for the Basin, supported the interpretation of similar tendencies in their distribution. From studying the spatial trends of the mean levels of the isotopes with descriptive statistics and variance analysis, latitudinal and bathymetric differences in the content of radionuclides emerged. These differences are probably derived from the distinct sources of these elements, as 226Ra originates in the deep ocean from the decay of parent 230Th and from the patterns of sedimentation driven by open ocean circulation, while 228Ra is supplied by terrigenous materials transported by the northward-flowing Brazilian Coastal Current. [ABSTRACT FROM AUTHOR]

A combined analysis of sedimentological, molecular, and microfossil proxies was used to determine paleoclimatic and paleoceanographic variations and assess sediment transport pathways along the last c.a. 6300 years in a sedimentary record collected on the inner shelf of the southwestern Atlantic Ocean. The combined use of terrestrial and marine proxies enables a more complete environmental perspective of the La Plata River plume influence on the southwestern Atlantic shelf, regarding the relationship between climate, productivity, as well as hydrodynamic. Variations in marine productivity, lipid biomarkers of terrestrial plants, diagnostic geochemical indices, and sea-surface temperature point to three phases within the core. The first interval (6300–5200 cal yr BP) was characterized by low marine and terrigenous organic matter input, with pulses of phytodetritus indicated by benthic foraminifera. These features suggested dry climatic conditions over the southeastern portion of South America, with the influence of sediments from the adjacent continent and, on a smaller scale, transported from the Argentinian shelf due to the high relative sea level. The second interval (5200–2800 cal yr BP) was distinguished by a slight increase in marine productivity and terrigenous input, indicating a transition period with an increase of total rainfall influenced by an intensified South American Monsoon System (SAMS) and the modern El Niño-Southern Oscillation (ENSO) phenomenon. These features, associated with the changes in wind patterns and the lower relative sea level, suggest the onset of the influence of the La Plata River (LPR) plume over the southern regions of the Brazilian continental shelf for the last 6300 cal yr BP. The last interval (2800–890 cal yr BP) had the highest contents of marine and terrigenous proxies, suggesting less climatic variability, as the long-term intensification of the SAMS and a further increase in the amplitude of the ENSO resulted in the modern establishment and dominant influence of the LPR plume on the core site. Variations in sea-surface temperature up to 3.3°C were related to the influence of the LPR plume on the shelf off southern Brazil. [ABSTRACT FROM AUTHOR]