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Sustainable Development Goals (SDGs) target 11.a is a good vision for the coordinated development of the economy, society and environment in urban agglomerations. However, there was an extreme lack of indicators, data or case studies for SDG target 11.a, since it is a vague "process target", which is not conducive to the implementation of SDG target 11.a. It is important to propose a quantitative, convenient, and local policies relevant method to promote the realization or to test the implementation effects of SDG target 11.a. Combined with socio-economic data and land use data, this study uses the methods of comprehensive evaluation model, coupling and coordination degree, and comparative advantage degree methods to study the pattern evolution, coordination characteristics and advantageous areas of production–living–ecological (PLE) functions in the Guangxi Beibu Gulf Urban Agglomeration (GBG_UA) from 1995 to 2019. The results showed that, (1) considering the spatiotemporal distribution of PLE functions, the study area has a relatively stable ecological function as well as fluctuating production and living functions. Considering the coordination characteristics of PLE functions, high–high and low–low clustering effects were observed, and primary coordination maintained the highest proportion, accounting from 55.26% in 1995 to 71.05% in 2019, indicating the SDG target 11.a level in the GBG_UA was poor. Considering the advantageous areas for PLE functions, the region mostly comprises single-function advantageous areas and a few multifunction advantageous areas, including 20 single-function advantage counties (accounting for 52%), 15 dual-function advantage counties (accounting for 39%), and three multi-function advantage counties (accounting for 7.8%), which indicates the lack of diversified land use structures in this region. (2) Optimization suggestions for the coordinated development and realization of SDG target 11.a for the GBG_UA were provided. Suggestions were made based on the radiation and driving role of Nanning city to guide the coordinated development of surrounding counties (districts). Suggestions were also made to improve the design of the integrated transportation network as well as to optimize allocation according to the resource endowment of land and to realize an upgraded ecology as well as agricultural products and services. (3) The evaluation of PLE functions is a quantitative and convenient method that can optimize national and regional development planning and test the implementation effects of SDG target 11.a. This study offers foundational knowledge for the realization of SDG target 11.a in the GBG_UA and provides a reference for the research and implementation of SDG target 11.a in other regions around the world. [ABSTRACT FROM AUTHOR]

Sustainable Development Goals (SDGs) target 11.a is a good vision for the coordinated development of the economy, society and environment in urban agglomerations. However, there was an extreme lack of indicators, data or case studies for SDG target 11.a, since it is a vague “process target”, which is not conducive to the implementation of SDG target 11.a. It is important to propose a quantitative, convenient, and local policies relevant method to promote the realization or to test the implementation effects of SDG target 11.a. Combined with socio-economic data and land use data, this study uses the methods of comprehensive evaluation model, coupling and coordination degree, and comparative advantage degree methods to study the pattern evolution, coordination characteristics and advantageous areas of production–living–ecological (PLE) functions in the Guangxi Beibu Gulf Urban Agglomeration (GBG_UA) from 1995 to 2019. The results showed that, (1) considering the spatiotemporal distribution of PLE functions, the study area has a relatively stable ecological function as well as fluctuating production and living functions. Considering the coordination characteristics of PLE functions, high–high and low–low clustering effects were observed, and primary coordination maintained the highest proportion, accounting from 55.26% in 1995 to 71.05% in 2019, indicating the SDG target 11.a level in the GBG_UA was poor. Considering the advantageous areas for PLE functions, the region mostly comprises single-function advantageous areas and a few multifunction advantageous areas, including 20 single-function advantage counties (accounting for 52%), 15 dual-function advantage counties (accounting for 39%), and three multi-function advantage counties (accounting for 7.8%), which indicates the lack of diversified land use structures in this region. (2) Optimization suggestions for the coordinated development and realization of SDG target 11.a for the GBG_UA were provided. Suggestions were made based on the radiation and driving role of Nanning city to guide the coordinated development of surrounding counties (districts). Suggestions were also made to improve the design of the integrated transportation network as well as to optimize allocation according to the resource endowment of land and to realize an upgraded ecology as well as agricultural products and services. (3) The evaluation of PLE functions is a quantitative and convenient method that can optimize national and regional development planning and test the implementation effects of SDG target 11.a. This study offers foundational knowledge for the realization of SDG target 11.a in the GBG_UA and provides a reference for the research and implementation of SDG target 11.a in other regions around the world.

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The coordination and energetics of low-lying structures of [Li(EC)n]+ have been analyzed by density functional theory (DFT) and polarizable continuum model (PCM) at the B3LYP/6- 3111G (d, p) level. The results show that the first shell around the lithium ion is fully occupied with four ethylene carbonate (EC) molecules in both gas phase and solvent. The examination on the contribution of vibration entropy to free energy of isomers of [Li(EC)n]+ reveals that the stability of the best candidates at zero-temperature cannot be maintained at finite temperatures due to the effects of their vibration entropy. In addition, structural transitions between the most stable fourcoordinated and the metastable three-coordinated structure demand a very low energy barrier, suggesting that at a finite temperature the four-coordinated and three-coordinated isomers of [Li(EC)n]+ can coexist in the EC organic solvent lithium salt electrolyte. [ABSTRACT FROM AUTHOR]

The interaction of VO with the muchopolysaccharide chondroitin sulfate A (CSA) has been investigated by electron absorption spectroscopy and infrared measurements in aqueous solutions at different pH-values and ligand to metal ratios up to 6:1. The generation of a VO(CSA) species could be demonstrated. Coordination of the oxocation through the carboxylate group and the glycosidic oxygen of the d-glucuronate moieties is suggested. Infrared spectra of some poorly characterized solid VO/CSA complexes point to the same bonding characteristics. Preliminary results obtained at higher ligand to metal ratios suggest a different coordination behavior. [ABSTRACT FROM AUTHOR]