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Kinetic theory has long predicted that temperature inversion may happen in the vapor-phase for evaporation and condensation between two parallel plates, i.e., the vapor temperature at the condensation interface is higher than that at the evaporation interface. However, past studies have neglected transport in the liquid phases, which usually determine the evaporation and condensation rates. This disconnect has limited the acceptance of the kinetic theory in practical heat transfer models. In this paper, we combine interfacial conditions for mass and heat fluxes with continuum descriptions in the bulk regions of the vapor and the liquid phases to obtain a complete picture for the classical problem of evaporation and condensation between two parallel plates. The criterion for temperature inversion is rederived analytically. We also prove that the temperature jump at each interface is in the same direction as externally applied temperature difference, i.e., liquid surface is at a higher temperature than its adjacent vapor on the evaporating interface and at a lower temperature than its adjacent vapor on the condensing interface. We explain the interfacial temperature jump and temperature inversion using the interfacial cooling and heating processes, and we predict that this process can lead to a vapor phase temperature much lower than the lowest wall temperatures and much higher than the highest wall temperature imposed. When the latent heat of evaporation is small, we found that evaporation can happen at the low temperature side while condensation occurs at the high temperature side, opposing the temperature gradient. [ABSTRACT FROM AUTHOR]

We prove near-optimal tradeoffs for quantifier depth (also called quantifier rank) versus number of variables in first-order logic by exhibiting pairs of n-element structures that can be distinguished by a k-variable firstorder sentence but where every such sentence requires quantifier depth at least nΩ(k/logk). Our tradeoffs also apply to first-order counting logic and, by the known connection to the k-dimensional Weisfeiler--Leman algorithm, imply near-optimal lower bounds on the number of refinement iterations. A key component in our proof is the hardness condensation technique introduced by Razborov in the context of proof complexity. We apply this method to reduce the domain size of relational structures while maintaining the minimal quantifier depth needed to distinguish them in finite variable logics. [ABSTRACT FROM AUTHOR]

Micromagnetic simulations require the numerically challenging preservation of the Euclidean norm during the whole simulation. This can be accomplished by applying a priori length preserving methods, renormalization algorithms, or penalization strategies. The latter one includes both the penalty method and the Lagrangian multiplier. The penalty method requires the definition of a penalty parameter during the initiation of the simulation which, depending on its size, can lead to an unsatisfied constraint or stiff and difficult to solve systems of equations. The Lagrange multiplier always penalizes in problem-dependent intensity, hence, an additional degree of freedom is added to the system of equations to the drawback of higher computational costs. This paper proposes a method that utilizes a perturbed Lagrangian multiplier and an element level static condensation to condensate the additional degree of freedom. This guarantees fast simulations, and no parameter fitting in advance. Suitable numerical examples are conducted to prove the workability of the outlined scheme and to highlight the efficiency compared to the non-condensed formulation. [ABSTRACT FROM AUTHOR]

The reaction of different acyl hydrazines with hexafluoro‐1,4‐napthoquinone was studied for the first time. It was demonstrated that this interaction stops at the substitution of one fluorine atom in the quinone moiety. Based on the observed reaction, a general approach to the synthesis of different pentafluoro‐1,4‐dioxo‐1,4‐dihydronaphthalen‐2‐yl hydrazides was developed. It was revealed that optimal conditions for the condensation of hexafluoro‐1,4‐napthoquinone with hydrazides are reflux in MeOH for 0.25 h; note, the protocol does not require any chromatographic purification of the target products. The method is versatile and makes it possible to prepare products containing various substituents in the aryl part of the molecule. In addition, alkyl and heteroaryl hydrazides can be employed as starting compounds too, and the presence of hydroxy and cyano groups in the applied acyl hydrazines does not interfere with the condensation. The structure of one of the obtained products, namely 4‐chloro‐N□‐(3,5,6,7,8‐pentafluoro‐1,4‐dioxo‐1,4‐dihydronaphthalen‐2‐yl)benzohydrazide, was confirmed by X‐ray diffraction. In crystals of this hydrazide, both NH groups form intermolecular hydrogen bonds that give rise to layers lying in the [001] plane. Prepared N'‐(3,5,6,7,8‐pentafluoro‐1,4‐dioxo‐1,4‐dihydronaphthalen‐2‐yl)hydrazides are of interest as redox‐active ligands and precursors for obtaining a wide range of functionalized 1,4‐napthoquinones for medicine chemistry. [ABSTRACT FROM AUTHOR]

Tandem processes are valuable tools that allow to build molecular complexity while reducing waste production and the number of steps of synthetic routes. In this work, the in situ photooxidation of benzyl alcohols to the corresponding benzaldehydes is coupled with a Knoevenagel condensation for the preparation of benzylidenemalononitrile derivatives. In this rapid one‐pot tandem process, sodium anthraquinone‐1,5‐disulfonate (SAS) and β‐alanine are employed as safe and inexpensive catalysts, while air is used as a terminal oxidant. Moreover, using water as reaction medium results in most cases in the precipitation of the target products, thus facilitating their isolation. [ABSTRACT FROM AUTHOR]

The employment of the [1+1] condensation approach for the preparation of new macrocyclic scaffolds (LN6 and LN3O3) towards high-performance Dy(III) single-molecule magnets (SMMs) with pseudo-D6h symmetry is described. Engineering of the macrocycles denticity from LN6 to LN3O3 leads to a mononuclear SMM with a large Ueff value of 1300 K. The experimental results are supported by ab initio calculations, which indicate relaxation of the magnetization via the second-excited state. [ABSTRACT FROM AUTHOR]

The present work addresses the systematic accurate fabrication and design of biphilic surfaces having superhydrophobic circular islands surrounded by a hydrophilic background by investigating their condensation frosting and defrosting behavior. A significant delay in frost formation is observed on samples with higher superhydrophobicity ratio A*, defined as superhydrophobic area to total area ratio. As the superhydrophobic island diameter D increases from D = 500 µm to D = 700 µm (A* from 19.62% to 38.46%), a 50% improvement/delay is observed in terms of frost formation or densification. Besides delaying icing/frosting, the presence of superhydrophobic areas empowers the formation of porous and nonuniform frost structure, which facilitates ice removal during the defrosting process. To this end, as the surface is recovered the ambient temperature, almost complete passive cleaning performance within only 23 s is observed on the biphilic design having superhydrophobic islands with the diameter of D = 500 µm, that is, a superhydrophobicity ratio A* of 19.62%. This work concludes on the optimum biphilic ratio, which is not only effective as a passive method by hindering frosting but also leads to a slush/water free surface after defrosting eased by the Laplace pressure gradient which is imposed by the different biphilic wettability patterns. [ABSTRACT FROM AUTHOR]

Proteins with intrinsically disordered regions (IDRs) often undergo phase separation to control their functions spatiotemporally. Changing the pH alters the protonation levels of charged sidechains, which in turn affects the attractive or repulsive force for phase separation. In a cell, the rupture of membrane‐bound compartments, such as lysosomes, creates an abrupt change in pH. However, how proteins' phase separation reacts to different pH environments remains largely unexplored. Here, using extensive mutagenesis, NMR spectroscopy, and biophysical techniques, it is shown that the assembly of galectin‐3, a widely studied lysosomal damage marker, is driven by cation‐π interactions between positively charged residues in its folded domain with aromatic residues in the IDR in addition to π–π interaction between IDRs. It is also found that the sole two negatively charged residues in its IDR sense pH changes for tuning the condensation tendency. Also, these two residues may prevent this prion‐like IDR domain from forming rapid and extensive aggregates. These results demonstrate how cation‐π, π–π, and electrostatic interactions can regulate protein condensation between disordered and structured domains and highlight the importance of sparse negatively charged residues in prion‐like IDRs. [ABSTRACT FROM AUTHOR]

Exploration of high‐temperature bosonic condensation is of significant importance for the fundamental many‐body physics and applications in nanodevices, which, however, remains a huge challenge. Here, in combination of many‐body perturbation theory and first‐principles calculations, a new‐type spatially indirect exciton can be optically generated in two‐dimensional (2D) Bi2S2Te because of its unique structure feature. In particular, the spin‐singlet spatially indirect excitons in Bi2S2Te monolayer are dipole/parity allowed and reveal befitting characteristics for excitonic condensation, such as small effective mass and satisfied dilute limitation. Based on the layered Bi2S2Te, the possibility of the high‐temperature excitonic Bose–Einstein condensation (BEC) and superfluid state in two dimensions, which goes beyond the current paradigms in both experiment and theory, are proved. It should be highlighted that record‐high phase transition temperatures of 289.7 and 72.4 K can be theoretically predicted for the excitonic BEC and superfluidity in the atomic thin Bi2S2Te, respectively. It therefore can be confirmed that Bi2S2Te featuring bound bosonic states is a fascinating 2D platform for exploring the high‐temperature excitonic condensation and applications in such as quantum computing and dissipationless nanodevices. [ABSTRACT FROM AUTHOR]

A process combining aldol condensation and hydrogenation of bio‐based cyclopentanone (CPO) in a one‐pot reaction is proposed. Cu‐based bifunctional catalysts obtained from hydrotalcite‐type precursors were found highly active in mild reaction conditions (i.e., 130–170 °C), producing valuable bicyclic (C10) and tricyclic (C15) aliphatic alcohols/ketones with interesting application as sustainable aviation fuel (SAF) precursors with enhanced properties. The presence of surficial strong basic sites active in aldol condensation, together with the formation of highly dispersed copper nanoparticles able to catalyze C═C and C═O hydrogenation (TOF of 0.06–0.16 s−1), assured high catalytic efficiency and fine control of the products nature and distribution. From the optimization of both catalysts formulation and reaction conditions it was found that, properly tuning the Cu content, it is possible to drive products distribution towards the production of bicyclic (C10) aliphatic alcohol with high selectivity (75% at total CPO conversion, when Cu = 10 wt %, at 170 °C, 1.0 MPa of H2) and short reaction time (4 h). The optimized catalyst formulation showed impressive stability over multiple reaction/regeneration cycles, demonstrating the high potential of the proposed catalytic process for future applications in sustainable biofuels production. [ABSTRACT FROM AUTHOR]

Theoretical analysis of the kinetic scheme describing formation and randomization of a binary copolymer due to end‐group interchange reactions is presented. Compact analytical expressions are obtained for the transient and equilibrium values of the copolymer degree of blockiness and fractions of active end‐groups of different types. The resulting copolymer is described by the first‐order Markov statistics, which can be rather far from the Bernoullian one. Its structure is determined by the composition of the system and a single combination of the rate constants of four elementary reactions. The kinetics includes fast and slow stages with characteristic time periods independent of and proportional to the average polymerization degree, respectively. During the fast stage, the initial polymers disappear, whereas the copolymer degree of blockiness is still very low. The distribution of units in the copolymer is Markovian, only if the initial polymers possess the most probable molar mass distributions. At the slow stage copolymer randomization gradually progresses, whereas the distribution of end groups may change in the opposite direction compared to the fast stage. The results can be used to analyze the experimental data on the chain structure of condensation, metathesis, and dynamic covalent polymers, where interchange reactions play a significant role. [ABSTRACT FROM AUTHOR]

Glistening is the condensation of water that forms within the intraocular lens (IOL) materials. In this study, a new approach was attempted to reduce the glistening of IOL materials by introducing hydrophobic acrylic monomers with different alkyl side chain lengths into the IOL materials. Various hydrophobic acrylic monomers such as butyl acrylate (BA), 2‐ethylhexyl acrylate (EHA), and dodecyl acrylate (DA) were copolymerized with a hydrophobic acrylic monomer, 2‐phenoxyethyl acrylate, respectively. In this process, we investigated the effect of the alkyl side chain lengths of hydrophobic acrylic monomers on the glistening of hydrophobic acrylic IOL materials. As the content of hydrophobic acrylic monomers (BA, EHA, and DA) increased, the glistening of IOL materials decreased significantly for all hydrophobic acrylic monomers. At the same content of hydrophobic acrylic monomers, the IOL material showed the least content of glistening when copolymerized with DA. However, the IOL material obtained using BA exhibited the largest content of glistening, indicating that the glistening reduction effect was large in the order of DA>EHA>BA. These findings show that the glistening of IOL materials decreases with increasing alkyl side chain lengths of hydrophobic acrylic monomers. [ABSTRACT FROM AUTHOR]

Zeolites are microporous crystalline materials that find a very wide range of applications, which, however, are limited by the size and dimensionality of their pores. Stable silica zeolites with a three‐dimensional (3D) system of extra‐large pores (ELP, i.e. pores with minimum windows along the diffusion path consisting of more than 12 SiO4/2 tetrahedra, 12R) are in demand for processing larger molecules than zeolites can currently handle. However, they have challenged worldwide synthetic capabilities for more than eight decades. In this review we first present a brief history of the discovery of ELP zeolites. Next, we show that earlier successes of zeolites with 3D ELP were not actually zeolites, but rather interrupted structures with, in addition, a composition that severely detracted from their stability. Finally, we present three new fully connected stable silica‐based 3D ELP zeolites ZEO‐1, ZEO‐3 and ZEO‐5, discuss their preparation methods and stability as well as the clear advantage of their increased porosity in catalysis and adsorption processes involving large molecules. We will discuss peculiar characteristics of their preparation and present two new reaction types giving rise to zeolites (1D‐to‐3D topotactic condensation and interchain expansion), highlighting how new synthesis methods can provide materials that would otherwise be unfeasible. [ABSTRACT FROM AUTHOR]

Purpose: Ascorbic acid, a water-soluble antioxidant, is an essential component of the human diet and is known for its potent antioxidant properties against several diseases. In recent years, there has been increasing interest in the development of nonenzymatic sensors due to their simplicity, efficiency and excellent selectivity. The aim of this study is to present a selective and sensitive method for the detection of ascorbic acid in aqueous system using a new electrochemical non-enzymatic sensor based on a gold nanoparticles Au-NPs-1,3-di(4-bromophényl)-5-tert-butyl-1,3,5-triazinane (DBTTA) composite. Design/methodology/approach: Using the square wave voltammetry (SWV) technique, a series of Au-NPs-DBTTA composites were successfully developed and investigated. First, DBTTA was synthesized via the condensation of tert-butylamine and a4-bromoaniline. The structure obtained was identified by IR, 1H NMR and 13C NMR analysis. A glassy carbon electrode (GCE) was modified with 10–1 M DBTTA dissolved in an aqueous solution by cyclic voltammetry in the potential range of 1–1.4 V. Au-NPs were then deposited on the DBTTA/GCE by a chronoamperometric technique. SWV was used to study the electrochemical behavior of the modified electrode (DBTTA/Au-NPs/GCEs). To observe the effect of nanoparticles, ascorbic acid in a buffer solution was analyzed by SWV at the modified electrode with and without gold nanoparticles (Au-NPs). Findings: The DBTTA/Au-NPs/GCE showed better electroanalytical results. The detection limit of 10–5 M was obtained and the electrode was proportional to the logarithm of the AA concentration in the range of 5 × 10−3 M to 1 × 10−1 with very good correlation parameters. Originality/value: It was also found that the elaborated sensor exhibited reproducibility and excellent selectivity against interfering molecules such as uric acid, aspartic acid and glucose. The proposed sensor was tested for the recognition of AA in orange, and satisfactory results were obtained. [ABSTRACT FROM AUTHOR]

Our novel binuclear complex-anchored Ru(III) catalyst, designed and assembled by sonicating 2,2′-(4,6-dihydroxy-1,3-phenylene)bis(1H-benzo[d]imidazole-4-carboxylic acid), Ru(DMSO)4Cl2 and 4-methylpyridine, demonstrates remarkable efficiency and selectivity. It promotes one-pot reactions, including active methylenes and benzyl alcohols in water, via a tandem aerobic oxidation/Knoevenagel condensation process, yielding benzylidene malononitrile in excellent yields. The catalyst's ability to oxidize benzyl alcohols to aldehydes, which then undergo Knoevenagel condensation with active methylenes, makes it a multifunctional catalyst. Notably, the catalyst can be successfully retrieved and recycled for five successive rounds with no significant decrease in catalytic efficiency. The ICP study showed that no catalyst leaching was observed, indicating that the designed catalyst is indeed heterogeneous. The Ru catalyst outperformed other documented catalysts in terms of lower dose, shorter duration, decreased working temperature, and the absence of dangerous additives. This demonstrates the catalyst's robustness and sustainability, making it a promising candidate for future organic conversions and industrial uses. [ABSTRACT FROM AUTHOR]

The nonribosomal peptide synthetase (NRPS) is a highly precise molecular assembly machinery for synthesizing structurally diverse peptides, which have broad medicinal applications. Withinthe NRPS, the condensation (C) domain is a core catalytic domain responsible for the formation of amide bonds between individual monomer residues during peptide elongation. This review summarizes various aspects of the C domain, including its structural characteristics, catalytic mechanisms, substrate specificity, substrate gating function, and auxiliary functions. Moreover, through case analyses of the NRPS engineering targeting the C domains, the vast potential of the C domain in the combinatorial biosynthesis of peptide natural product derivatives is demonstrated. [ABSTRACT FROM AUTHOR]

Atmospheric air, being also a moist gas, is present as a working medium in various areas of technology, including the areas of airframe aerodynamics and turbomachinery. Issues related to the condensation of water vapor contained in atmospheric air have been intensively studied analytically, experimentally and numerically since the 1950s. An effort is made in this paper to present new, unique and complementary results of the experimental testing of moist air expansion in the de Laval nozzle. The results of the measurements, apart from the static pressure distribution on the nozzle wall and the images obtained using the Schlieren technique, additionally contain information regarding the quantity and quality of the condensate formed due to spontaneous condensation at the transition from the subsonic to the supersonic flow in the nozzle. The liquid phase was identified using the light extinction method (LEM). The experiments were performed for three geometries of convergent–divergent nozzles with different expansion rates of 3000, 2500 and 2000 s−1. It is shown that as the expansion rate increases, the phenomenon of water vapor spontaneous condensation appears closer to the critical cross-section of the nozzle. A study was performed of the impact of the air relative humidity and pollution on the process of condensation of the water vapor contained in the air. As indicated by the results, both these parameters have a significant effect on the flow field and the pressure distribution in the nozzle. The results of the experimental analyses show that in the case of the atmospheric air flow, in addition to the pressure, temperature and velocity, other parameters must also be taken into account as boundary parameters for possible numerical analyses. Omitting information about the air humidity and pollution can lead to incorrect results in numerical simulations of transonic flows of atmospheric air. The presented results of the measurements of the moist air transonic flow field are original and fill the research gap in the field of experimental studies on the phenomenon of water vapor spontaneous condensation. [ABSTRACT FROM AUTHOR]

We introduce a simple zero-range process with constant rates and one fast rate for a particular occupation number, which diverges with the system size. Surprisingly, this minor modification induces a condensation transition in the thermodynamic limit, where the structure of the condensed phase depends on the scaling of the fast rate. We study this transition and its dependence on system parameters in detail on a rigorous level using size-biased sampling. This approach generalizes to any particle system with stationary product measures, and the techniques used in this paper provide a foundation for a more systematic understanding of condensing models with a non-trivial condensed phase. [ABSTRACT FROM AUTHOR]

The one-pot four-component condensation of benzoic acid (R1), aniline (R2), benzaldehyde (R3), and 2-isocyano-2-methylpropane was investigated at the B3LYP/6-311G** level to explore the reaction mechanism as a theoretical study. All routes were studied and structure of intermediates (IM) was optimized and all of the respective transition states (TS) were found. The calculation results proved that the proposed mechanism consists of eight steps that rate determining the state is nucleophilic attack of isocyanide to benzaldehyde. [ABSTRACT FROM AUTHOR]

The processes responsible for the isotopic compositions and abundances of volatile elements in the early solar system remain highly debated. Orders of magnitude variation of (highly) volatile elements exist between different magmatic iron meteorite groups, but it is unclear to what extent their depletions can be explained by evaporation from metal melts during parent body accretion and/or subsequent break up. To this end, we present 86 new evaporation experiments with the aim of constraining the volatility of most volatile metals from metallic melts. The results confirm the previously proposed important effects of S in metal melt on the volatility of the elements of interest governed by their S-loving or S-phobic behavior. Nominally S-loving elements In, Sn, Te, Pb and Bi are significantly more volatile in Fe melt relative to FeS liquid, whereas nominally S-avoiding elements Ga and Sb are more volatile in FeS liquid relative to Fe melt, at a given pressure and temperature. The newly derived volatility sequences for S-free/poor and S-rich metallic melts were also compared with commonly used volatility models based on condensation temperatures. The results indicate significant differences between the latter, including the much more volatile behavior of Te, relative to Se, in both explored bulk compositions, which are traditionally assumed to be equally volatile. The (minimum) degree of volatile element depletion due to evaporation was quantified using the new experimental results and models. A comparison between the volatile element depletions in magmatic iron meteorites and the predicted depletions appropriate for evaporation from Fe melts shows that the latter depletions can be easily reconciled with (an) evaporation event(s). Altogether, the new data and models will provide an important framework when more accurate and precise estimates of magmatic iron meteorite bulk volatile element contents are available. [ABSTRACT FROM AUTHOR]

Adsorption and capillarity, in the order of high free energy to low, are the two soil–water interaction mechanisms controlling the hydro-mechanical behaviour of soils. Yet most of the poroelasticity theories of soil are based on capillarity only, leading to misrepresentations of hydro-mechanical behaviour in the low free energy regime beyond vaporisation. This inability is reasoned to be caused by two major limitations in the existing theories: missing interparticle attraction energy and incomplete definition of adsorption-induced pore-water pressure. A poroelasticity theory is formulated to incorporate the two soil–water interaction mechanisms, and the transition between them – that is, condensation/vaporisation, by expanding the classical three-phase mixture system to a four-phase mixture system with adsorptive water as an additional phase. An interparticle attractive stress is identified as one of the key sources for deformation and strength of soils induced by adsorption and is implemented in the poroelasticity theory. A recent breakthrough concept of soil sorptive potential is utilised to establish the physical link between adsorption-induced pore-water pressure and matric suction. The proposed poroelasticity theory can be reduced to several previous theories when interparticle attractive stress is ignored. The new theory is used to derive the effective stress equation for variably saturated soil by identifying energy-conjugated pairs. The derived effective stress equation leads to Zhang and Lu's unified effective stress equation, and can be reduced to Bishop's effective stress equation when only the capillary mechanism is considered and to Terzaghi's effective stress equation when a saturated condition is imposed. The derived effective stress equation is experimentally validated for a variety of soil in the full matric suction range, substantiating the validity and accuracy of the poroelasticity theory for soil under variably saturated conditions. [ABSTRACT FROM AUTHOR]

This paper reports the synthesis of a new potential anticonvulsant, N-(2,2,2-trichloro-1- hydroxyethyl)-5H-dibenzo[b,f]azepine-5-carboxamide. Its synthesis is based on condensing the anticonvulsant drug carbamazepine with chloral hydrate used in medical practice. The reaction was carried out in a melt or by boiling in dry benzene with the removal of the resulting water from the reaction medium. The product was obtained with yields of 88 and 79%, respectively. Replacing the hydroxyl group in the resulting condensation product with an amino group led to the formation of N-(1-amino-2,2,2-trichloroethyl)- 5H-dibenzo[b,f]azepine-5-carboxamide. This synthesis was carried out in two stages. Initially, the hydroxy derivative was chlorinated with thionyl chloride. Then, by treating the resulting chlorine derivative with an aqueous solution of ammonia (25%) in MTBE medium, the target product was obtained. The structure of the obtained compounds was proven by ¹H NMR and IR spectroscopy data. The SwissADME online platform showed that the synthesized compounds should have high bioavailability as well as moderate solubility in water and be able to penetrate the blood-brain barrier. [ABSTRACT FROM AUTHOR]

AbstractSteam condensation in the presence of a noncondensable gas is of vital importance for passive cooling containment systems. The noncondensable gas causes a significant reduction in the condensation rate and heat transfer across the containment, which is important for postulated loss-of-coolant accidents in a nuclear reactor.In this work, computational fluid dynamics models of condensation and the adjacent single-phase steam-air mixture flow are developed for laminar and turbulent flow in vertical channels by two distinct wall condensation modeling approaches using the commercial code STAR-CCM+. The first is the fluid film model available in STAR-CCM+, which solves liquid layer governing equations with connections to the adjacent gas mixture flow. The second is a user-defined wall condensation model that neglects the fluid film and instead accounts for mass, momentum, and heat transfer via user-defined volumetric sink terms adjacent to the cold wall.The condensation models are assessed by first comparing the calculated results with the numerical solution of laminar flow, solved using a complete two-phase model that solves parabolic equations based on conservation of mass, momentum, energy, and species for each phase. Next, the results of a two-dimensional analysis are compared with COPAIN experiments and existing numerical solutions from three-dimensional analyses. The comparisons include new, detailed results that have not been reported in previous analyses of a COPAIN case. These new results include local field profiles of velocity, temperature, and air mass fraction, and local mass flux. [ABSTRACT FROM AUTHOR]

Dewdrops, the droplets of water naturally occurring on leaves and carapaces of insects, are a fascinating phenomenon in nature. Here, a man‐made array of dewdrops with arbitrary shapes and arrangements, which can function as an electromagnetic metasurface, is demonstrated. The realization of the dewdrop array is enabled by a surface covered by a tailored pattern of hydrophilic and hydrophobic coatings, where tiny droplets of water can aggregate and form dewdrops on the former. Interestingly, this metasurface made of dewdrops can be modulated by the condensation and evaporation process. By increasing relative humidity and decreasing temperature, the dewdrop metasurface is gradually formed with increasing amounts of water. While the reverse operation can make it completely disappear. This idea is demonstrated through two examples with different functions of dynamically controllable microwave absorption and scattering. The work shows a principle to construct functional electromagnetic devices with dewdrops, as well as a mechanism of dynamic control based on condensation and evaporation, promising unprecedented applications. [ABSTRACT FROM AUTHOR]

Development of new organic synthetic methods fascinating the researchers which facilitating the increasing demands of the modern society, environmental friendly with high efficiency and low cost. The introduction of chromophores in an organic molecules facilitating intersystem crossing (ISC) to harvest both singlet and triplet excitons is also currently demanding field. We report a facile synthesis of symmetrical azines from carbonyl compounds and hydrazine hydrate with carboxylic acid esters as catalyst in methanol. This reaction presents a condensation of primary amino groups in hydrazine hydrate and carbonyl compounds took place simultaneously in a very short refluxing time. The prepared azines 1–10 were structurally analysed by various analytical techniques such as LC-MS1, H NMR13, C NMR, UV-Vis, FTIR and single crystal X-ray diffraction. Photoluminescence properties of prepared azines were recorded in CCl4 at 1 × 10−3 M and excitation range from 329 to 362 nm. The photoluminescence analysis results revealed that compounds 1–10 (except 8) were showed delayed fluorescence and 8 was showed fluorescence property. The photophysical properties of compounds 1–10 such as electron density and band gap energies was calculated by density function theory. This results revealed that the intra-molecular charge transfer occurs within the azines. The azine function in the azines enabling intersystem crossing hence, it is showing phosphorescence. [ABSTRACT FROM AUTHOR]

CI chondrites have been a proxy for the solar system since the mid‐20th century. The photospheric and CI chondrite abundances (P and CI, respectively) show a strong correlation. CI as a proxy is also justified by the (i) smoothness of their abundances plotted as a function of odd mass number and (ii) agreement within the error of P as determined spectroscopically. But our statistical assessment of spectroscopic studies and solar wind from the Genesis mission indicates that the small, ~10%–30%, differences (residuals) between CI and P depend on the 50% condensation temperature (Tc50). So, if CI is to be used as a proxy for P, Cosmochemists may want to add a correction to individual elements. Our work is consistent with two published hypotheses: that (i) residuals are linear with Tc50 and (ii) that elements having Tc50 > 1343 K are depleted relative to those with 495 K < Tc50 < 1343 K in CI. We discuss other interpretations which are also feasible. Understanding these small differences of the CI and P for different elements and their variation with Tc50 can help constrain future models of solar system formation and the history of CI chondrites. [ABSTRACT FROM AUTHOR]

Mild and inexpensive copper‐catalyzed aromatization‐driven ring‐opening amination and oxygenation of spiro dihydroquinazolinones are presented, respectively. These protocols provide facile and atom‐economical access to the aminated and the carbonyl‐containing quinazolin‐4(3H)‐ones in good yields with good functional group compatibility, which are difficult to obtain by conventional methods. Remarkably, a telescoped procedure involving the condensation and the ring‐opening/functionalization for simple cycloalkanone was found to be accessible. Mechanistic studies suggest a radical pathway for this transformation. [ABSTRACT FROM AUTHOR]

In this study, the flow condensation of R-410A within 18 square microchannels arranged horizontally in parallel was experimentally investigated. All components of pressure drop, including expansion, contraction, deceleration, and friction, were quantified specifically for microchannels. The test conditions included saturation temperature, vapor quality, and mass flux, ranging from 18.86 to 24.22 bar, 0.09 to 0.92, and 200 to 445 kg/m2·s, respectively. The frictional pressure loss made up approximately 92.89% of the overall pressure reduction. The findings demonstrate that the pressure drop rises with higher mass flux and a lower saturation temperature. By comparing with correlations and semi-empirical models outlined in the literature across various scales, specimen types, and refrigerant media, correlations developed for two-phase adiabatic flows in multi-channel configurations can effectively predict the pressure drop in microchannel condensation processes. The model introduced by Sakamatapan and Wongwises demonstrated the highest predictive accuracy, with a mean absolute deviation of 8.4%. [ABSTRACT FROM AUTHOR]

Thousands of particle number (PN) counters have been introduced to the European market, following the implementation of PN tests during the periodic technical inspection (PTI) of diesel vehicles equipped with particulate filters. Expanding the PN-PTI test to gasoline vehicles may face several challenges due to the different exhaust aerosol characteristics. In this study, two PN-PTI instruments, type-examined for diesel vehicles, measured fifteen petrol passenger cars with different test protocols: low and high idling, with or without additional load, and sharp accelerations. The instruments, one based on diffusion charging and the other on condensation particle counting, demonstrated good linearity compared to the reference instrumentation with R-squared values of 0.93 and 0.92, respectively. However, in a considerable number of tests, they registered higher particle concentrations due to the presence of high concentrations below their theoretical 23 nm cut-off size. The evaluation of the different test protocols showed that gasoline direct injection engine vehicles without particulate filters (GPFs) generally emitted an order of magnitude or higher PN compared to those with GPFs. However, high variations in concentration levels were observed for each vehicle. Port-fuel injection vehicles without GPFs mostly emitted PN concentrations near the lower detection limit of the PN-PTI instruments. [ABSTRACT FROM AUTHOR]

An operationally simple, cost-effective, and environmentally benign method has been described for the synthesis of various polysubstituted benzoxanthenes via L-proline-catalyzed three-component condensation of β-naphthol, aromatic aldehydes, dimedone, or 2-hydroxy-1,4-naphthoquinone in aqueous medium. This process has additional benefits such as simple product isolation and purification techniques, good to higher yields, and above all, efficient catalyst reusability. The addition of sodium dodecyl sulfate is an extra benefit to speed up this reaction. [ABSTRACT FROM AUTHOR]

Sulfonium, selenonium, telluronium triflates, as well as chloronium, bromonium, and iodonium triflates have been examined in the model Schiff condensation as chalcogen‐ and halogen bond donating organocatalysts, respectively. The kinetic data indicated that the catalytic effect of the telluronium salt is provided via the decrease of enthalpy of activation of the reaction, whereas the catalytic effect of the iodonium salt – unexpectedly – is caused by the decrease of the value of the entropy of activation. In addition, it was experimentally shown that the catalytic activity of sulfonium and selenonium salts is significantly lower than that of chloronium and bromonium salts, but the latter pair of species is significantly less stable under the reaction conditions than the former pair. [ABSTRACT FROM AUTHOR]

Condensation reactions of 2-thioxo-2,3-dihydro-1H-spiro[benzo[h]quinazoline-5,1′-cycloheptan]-4(6H)-one with 2-aminoethanol and 3-aminopropanol were used to synthesize 2-[(2-hydroxyethyl)amino]-3Hspiro[benzo[h]quinazoline-5,1′-cycloheptan]-4(6H)-one and 2-[(3-hydroxypropyl)amino]-3H-spiro[benzo-[h]quinazoline-5,1′-cycloheptan]-4(6H)-one respectively. Interaction of this thioxoquinazoline with 2-chloromethylbenzoquinazolines with different structures yielded dibenzoquinazoline systems connected at position 2 by an -SCH2- linker. Reactions using methylene iodide produced 2,2'-[methylenebis(sulfanediyl)]-bis(3H-spiro[benzo[h]quinazoline-5,1′-cycloheptan]-4(6H)-one, while use of 1,2-dibromoethane, 2,3-dibromoacetic acid ethyl ester, and 1,3-dibromopropane led to the production of 9,10-dihydrospiro[benzo-[h]thiazolo[2, 3-b]quinazoline-6,1′-cycloheptan]-7(5H)-one, ethyl-7-oxo-5,7,9,10-tetrahydrospiro[benzo[h]-thiazolo[2,3-b]quinazoline-6,1′-cycloheptan]-9-carboxylate, and 10,11-dihydro-5H-spiro[benzo[h][1,3]-thiazino[2,3-b]quinazoline-6,1′-cycloheptan]-7(9H)-one respectively. The study compounds were found to have activity which was significantly inferior to that of reference antimicrobial drug furazolidone. Study compounds at doses of 150–185 mg/kg exhibited antitumor activity, inhibiting tumor growth in mice by 20–40%. [ABSTRACT FROM AUTHOR]

Condensation induces both heat addition and mass consumption effects on the carrier flow field, leading to complex wave patterns. In this study, we aim to elucidate the structures of flow field under the influence of condensation. To achieve this, we present a mathematical model, which is formulated using Euler equations with a singular source term. Given the difficulties posed by both weak solution theory and the Dal Maso–LeFloch–Murat (DLM) theory (J. Math. Pures Appl. 483‐548 (1995)) in defining solutions to the Riemann problem, we propose a novel approach. This involves the coupling of weak solutions within two subregions, taking into consideration the discontinuity of source term. Firstly, we identify two stationary discontinuities originating from the singular source term—namely, stationary waves and composite waves. Admissibility criterions are developed for these discontinuities to facilitate the selection of physically meaningful solutions. Secondly, we employ a double classical Riemann problems (CRPs) framework to analyze the structures of Riemann solution. Our analysis reveals that the Riemann solution may exhibit seven structures with stationary wave and four structures with composite wave. Finally, the proposed model and its theoritical results are applied to validate the structure of the flow field with condensation discontinuities. For the pure heat addition problem, we successfully demonstrate all wave patterns of the flow field, perfectly matching the outcomes of numerical experiments. [ABSTRACT FROM AUTHOR]

In this work, we explore the intricacies of the potential‐temperature variance budget in coastal fog. We propose an improvement to the theoretical framework of the budget, whereby we include the heat exchange due to water‐phase changes. We then show this framework's consistency with a real‐world case study from the Coastal Fog (C‐FOG) Research Program. Results show that the presence of intermittent energy bursts is driven by the sudden turbulent injection of heat into the environment caused by the condensation of water vapour, and the improved theoretical framework proves satisfactory in detailing the observed process. The heat excess is transported vertically, creating a two‐term balance of high‐order moments. A bulk parametrization of this balance is also proposed to provide a simplified representation of the phase‐change process and suggest that it could be used for operational purposes. Finally, the length‐scales of the processes are evaluated from the parametrizations. The analysis indicates that the scales of the phase change of water vapour are consistent with the buoyancy production and Taylor scales. [ABSTRACT FROM AUTHOR]

This study uses idealized simulations to investigate the impact of cloud condensation nuclei (CCN) on a cumulus congestus. Thirteen cases with the initial CCN_C, which is the CCN concentration at 1% supersaturation with respect to water, from 10 to 10,000 cm−3 are simulated. The analysis focuses on the liquid phase due to the negligible ice phase in this study. A non-monotonic response of cloud properties and precipitation to CCN concentration is observed. When CCN_C is increased from 10 to 50 cm−3, the enhanced condensation due to the more numerous droplets invigorates the cumulus congestus. The delayed precipitation formation due to the smaller droplets also facilitates the cloud development. The two processes together lead to a higher liquid water path (LWP), higher cloud top, and heavier precipitation. The cumulus congestus has the highest cloud top, the strongest updraft, and the most accumulated precipitation and at CCN_C = 50 cm−3. When CCN_C is increased from 50 to 500 cm−3, the condensation near the cloud base is further enhanced and the precipitation is further delayed, both of which lead to more liquid water remaining in the cloud, and thus an even higher LWP and heavier precipitation rate in the later stage. However, the significantly enhanced evaporation near the cloud top limits the vertical development of the cumulus congestus, leading to a lower cloud top. When CCN_C is further increased to be higher than 1000 cm−3, the cumulus congestus is strongly suppressed, and no precipitation forms. The ratio of the precipitation production rate to vertical cloud water flux in the updraft is not a constant, as is generally assumed in cumulus parameterization schemes, but decreases significantly with increasing CCN concentration. It is also found that the CCN effect on the cumulus congestus relies on which parameters are used to describe the cloud strength. In this study, as CCN_C increases, the LWP and the maximum precipitation rate peak at CCN_C = 500 cm−3, while the cloud top height, maximum updraft, and accumulated precipitation amount peak at CCN_C = 50 cm−3. [ABSTRACT FROM AUTHOR]

Liquid–liquid phase separation (LLPS) is responsible for the emergence of intracellular membrane‐less organelles and the development of coacervate protocells. Benefitting from the advantages of simplicity, precision, programmability, and noninvasiveness, light has become an effective tool to regulate the assembly dynamics of LLPS, and mediate various biochemical processes associated with LLPS. In this review, recent advances in optically controlling membrane‐less organelles within living organisms are summarized, thereby modulating a series of biological processes including irreversible protein aggregation pathologies, transcription activation, metabolic flux, genomic rearrangements, and enzymatic reactions. Among these, the intracellular systems (i.e., optoDroplet, Corelet, PixELL, CasDrop, and other optogenetic systems) that enable the photo‐mediated control over biomolecular condensation are highlighted. The design of photoactive complex coacervate protocells in laboratory settings by utilizing photochromic molecules such as azobenzene and diarylethene is further discussed. This review is expected to provide in‐depth insights into phase separation‐associated biochemical processes, bio‐metabolism, and diseases. [ABSTRACT FROM AUTHOR]

Ammonia has been used as a refrigerant since the beginning of the refrigeration industry and it continues to be an important industrial refrigerant. However, there is no well-verified method for predicting heat transfer during condensation in tubes and annuli. Available information is often contradictory, especially about the effect of oil. In this paper, available test data and predictive methods are reviewed. Reliable test data are identified and compared to well-known general correlations. The effect of oil on heat transfer is investigated. The results of this research are presented, and recommendations are made for design calculations. [ABSTRACT FROM AUTHOR]

This work presents the study results on the acid‐catalyzed cascade condensation of p‐toluenesulfonamide with glyoxal in H2SO4 in order to synthesize aza‐ and oxaazaisowurtzitanes—a platform for promising high‐energy‐density compounds—and explore their formation processes. The effects of the ratio of starting reactants, acidity, reaction medium concentration, and temperature on this process were studied in detail. Five novel compounds were derived, including four oxaazaisowurtzitanes comprising one to three aza groups, and one condensation intermediate. The most favorable conditions for the formation of the resultant caged compounds were established and some new regularities of the process were revealed. For instance, the reaction medium concentration was discovered for the first time to influence the generation process of oxaazaisowurtzitanes via direct condensation. The limiting stage of the cage formation process of oxaazaisowurtzitanes was identified. The formation rate of the oxaazaisowurtzitanes was shown to be dependent on their structure. The factor dramatically reducing the yield of the oxaazaisowurtzitanes at elevated synthesis temperature was also revealed. [ABSTRACT FROM AUTHOR]

Condensation of α‐arylaminoketones bearing 3‐hydroxypyran‐4‐one fragment with thiourea was studied. Based on considered investigation, the method for the synthesis of terarylenes with 2‐aminothiazole bridge was elaborated. The presented process is the first example of construction of thiazole core starting from α‐aminoketone precursor. The advantages of developed approach are easily available starting materials and convenient isolation of target products avoiding chromatographic purification. The structure of one of prepared products was confirmed by x‐ray analysis. The synthetic utility of obtained 2‐aminothiazoles with allomaltol substituent was demonstrated by reaction at amino and hydroxyl groups. [ABSTRACT FROM AUTHOR]

A computational homogenization framework is presented to study the dynamics of locally resonant acoustic metamaterial structures. Modelling the resonant units at the microscale as representative volume elements and building on well-established scale transition relations, the framework brings as a main novelty a reduced-order macroscopic homogenized continuum whose governing equations involve no additional variables to describe the microscale dynamics unlike micromorphic homogenized continua obtained by alternative computational homogenization approaches. This model-order reduction is obtained by formulating the governing equations of the micro- and macroscale problems in the frequency domain, introducing a finite-element discretization of the two problems and performing an exact dynamic condensation of all the degrees of freedom at the microscale. An appropriate inverse Fourier transform approach is implemented on the frequency-domain equations to capture transient dynamics as well; notably, the implementation involves the Exponential Window Method, here applied for the first time to calculate the time-domain response of undamped locally resonant acoustic metamaterial structures. The framework may handle arbitrary geometries of micro- and macro-structures, any transient excitations and any boundary conditions on the macroscopic domain. [ABSTRACT FROM AUTHOR]

ABSTRACT A method for efficient synthesis of quinolines via acceptorless dehydrogenative condensation is presented. A series of quinolines are obtained by the coupling reaction of 2‐aminobenzyl alcohols with secondary alcohols in the presence of bidentate terpyridine Mn(I) complex in good to excellent yields. Pleasantly, various substituted secondary alcohols and substituted aminobenzyl alcohols all provide quinolines with good functional group tolerance. Importantly, this investigation also provides a green and environmentally friendly protocol for constructing heterocyclic compounds. [ABSTRACT FROM AUTHOR]

Most studies regarding heat transfer on low‐finned tubes address the condensation of refrigerants and water on copper tubes. Existing models are mainly validated for this use case since studies regarding different substances or tube materials are scarce in the literature. This paper presents measurement data on the condensation of n‐propanol, isopropanol, isobutanol, and acetone on low‐finned stainless‐steel tubes. Together with experimental data from the literature, the measurements are used to test the performance of models from the literature. As the investigated models fail to describe all measurement data, a new model based on a set of dimensionless numbers is derived and fitted to the experimental data. [ABSTRACT FROM AUTHOR]

Due to the stability issue, It is difficult to prepare a silver nanocluster bearing functional sites, especially at a large scale. We report the synthesis and structure of a stable silver nanocluster bearing multiple surface aldehyde groups [Ag21(Ph2PO2)10(p‐CHOPhC≡C)6]SbF6, which allows for postsynthesis modification such as surface functionalization through aldimine condensation to give homochiral clusters. Remarkably, the preparation of this cluster can be done in ~90 % high yield at gram scale, which facilitates further studies and potential applications. Through DFT calculations and geometric structure analysis, the high stability of this cluster is attributed to the geometric closure and electronic structure. This is the first time that an effective one‐pot method has been developed to synthesize functional silver nanoclusters in high yield. The title cluster will be useful in the development of a variety of cluster‐based materials. [ABSTRACT FROM AUTHOR]

The stiffness matrix of a structural Sierpiński triangle under conditions of transversal bending is presented. The derivation is based exclusively on considerations of symmetry, equilibrium, and self-similarity. As a result, the stiffness matrix is shown to depend on a single material parameter. An illustrative numerical example is presented on the basis of an ad hoc computer code for the assembled stiffness of an overall structure consisting of a grid of fractal elements. [ABSTRACT FROM AUTHOR]

• Heat transfer coefficient of three component zeotropic mixture was measured. • A specially designed test section was used for local heat transfer measurement. • An asymmetrical distribution of heat transfer coefficient was observed. • A prediction correlation utilizing the mixture resistance was developed. Plate heat exchangers are gaining popularity as condensers for their compact design and high efficiency. However, the uneven fluid distribution in channels poses a challenge to effective heat transfer. Existing literature lacks experimental analysis of local heat transfer coefficients for pure and zeotropic mixture refrigerants in plate heat exchangers. This study experimentally analyzed the local heat transfer of the three-component zeotropic mixture R455A at various conditions (mass flux 20, 30, and 50 kg m−2 s−1 and saturation temperatures 30 and 35 °C). Results show that the heat transfer coefficient increases with flow rates and decreases with saturation temperature. However, results indicated lower heat transfer coefficients compared to pure refrigerants due to mixture effects. In addition, the local distribution of the heat transfer coefficient revealed that the heat transfer coefficient is highest at the center compared to the edges of the channel due uneven distribution of refrigerants within the channel. This HTC pattern confirms an asymmetrical flow within the plate. A new correlation is being developed to predict the heat transfer coefficient of the ternary mixture, showing improved accuracy than previously proposed correlations. [ABSTRACT FROM AUTHOR]

• Condensation of zeotropic mixtures in horizontal tube were experimentally studied. • The processes of temperature glide and composition shift were demonstrated quantitatively. • The heat and mass transfer resistances were discussed. • Effects of vapor quality, mass flux and saturation temperature on heat transfer were presented. Zeotropic refrigerant blends have attracted wide interest due to their promises to reduce global warming potential as well as their potential ability to improve the performance of heat pumps and air conditioners. The complex phenomenon of non-isothermal phase change complicates condensation of zeotropic refrigerant mixtures and merits extensive investigation to better understand their performance profiles. The present work experimentally studied condensation heat transfer of R407C and R448A – two R134a-based zeotropic refrigerant mixtures – in a horizontal smooth tube, condensed by counter-current water cooling. Measurements for mass flux were in the range of 120 to 320 kg m −2 s −1 and saturation temperature in the range of 42 to 64 °C. Variation in refrigerant temperature and composition shift during condensation were quantitatively presented. The experimental data showed the effects of mass flux and saturation temperature on the heat transfer coefficients of R407C and R448A in different vapor quality regions. The analysis of heat and mass transfer resistances related to the flow regimes and refrigerant thermophysical properties provides a deep understanding of the condensation heat transfer of zeotropic refrigerant mixtures. The experimental data presented in this work are of value for the design of condensers. [ABSTRACT FROM AUTHOR]

Measuring the mass concentration (PM0.1) of ultrafine particles (UFPs; diameter less than 100 nm) continuously, automatically, and accurately poses a considerable challenge because of the typically low PM0.1 concentration levels and susceptibility to interference from larger particles during the measurement processes. Previous work has shown that PM0.1 has a strong and stable correlation with the number concentration of particles with diameter above 50 nm (N50). This suggests that the indirect measurement of PM0.1 might be possible by measuring N50. In this work, the feasibility of using a Condensation Particle Counter (CPC) that measures PM0.1 by measuring N50 is examined. A water-based CPC was modified to measure N50 (CPC50). The CPC50's ability to measure PM0.1 was then evaluated by comparing its measurements with the PM0.1 measurements of a Scanning Mobility Particle Sizer (SMPS) in a suburban area. PM0.1 measured by the CPC50 was in good agreement with PM0.1 measured by the SMPS with a fractional bias (FBIAS) of 4% and a fractional error (FERROR) of 21% for hourly measurements. These findings indicate that a CPC50 could serve as a cheaper alternative to the SMPS, allowing for continuous and real-time measurement of PM0.1. Copyright © 2024 American Association for Aerosol Research [ABSTRACT FROM AUTHOR]

Previously unpublished Lower Jurassic sections of the East Midlands Shelf, along with reassessment of museum collections and previously published successions, indicate that seafloor sedimentation was dominated by complex erosional and depositional processes driven by dynamic and complex shelfal seafloor energy regimes during the Davoei and Margaritatus Zones of the Pliensbachian. The possible influence of tectonically driven relative sea level fluctuations is uncertain. Distinct condensation events, marked by authigenic mineralisation and clast reworking, can be identified at the Davoei–Margaritatus zonal boundary at the base of the Stokesi Subzone ('Lower Authigenic Mineral Bed'), and at the boundary between the Stokesi and Subnodosus Subzones ('Upper Authigenic Mineral Bed'). These correspond to a recognised candidate sequence boundary and candidate maximum flooding surface respectively. The Stokesi Subzone is well defined in all the studied sections by the ammonites between the two marker beds, whilst the Subnodosus Subzone can only be proven at Middleton Cheney. Nutrient supply for mineralisation observed in the 'Authigenic Mineral Beds' was derived from the erosion of uppermost Davoei Zone and lowermost Stokesi Subzone sediments. The high concentrations of authigenic mineralisation ions in the Davoei sediments were generated by large amounts of organic material derived from continental run-off. [ABSTRACT FROM AUTHOR]