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This scientific paper discusses the importance of reducing greenhouse gas emissions to mitigate the effects of climate change. The proposed strategy is to reach net-zero emissions by transitioning to electric systems powered by low-carbon sources such as wind, solar, hydroelectric power, and nuclear energy. However, the paper also highlights the challenges of this transition, including high costs and lack of infrastructure. The paper emphasizes the need for continued research and investment in renewable energy technology and infrastructure to overcome these challenges and achieve a sustainable energy system. Additionally, the use of nuclear energy raises concerns, such as nuclear waste and proliferation, and should be considered with its benefits and drawbacks. The study assesses the feasibility of nuclear energy development in Latvia, a country in Northern Europe, and finds that Latvia is a suitable location for nuclear power facilities due to potential energy independence, low-carbon energy production, reliability, and economic benefits. The study also discusses methods of calculating electricity generation and consumption, such as measuring MWh produced by power plants, and balancing supply and demand within the country. Furthermore, the study assesses the safety of nuclear reactors, generated waste, and options for nuclear waste recycling. The transition to a carbon-free energy system is ongoing and complex, requiring multiple strategies to accelerate the transition. While the paper proposes that nuclear energy could be a practical means of supporting and backing up electricity generated by renewables, it should be noted that there are still challenges to be addressed. Some of the results presented in the paper are still based on studies, and the post-treatment of waste needs to be further clarified. [ABSTRACT FROM AUTHOR]

This scientific paper discusses the importance of reducing greenhouse gas emissions to mitigate the effects of climate change. The proposed strategy is to reach net-zero emissions by transitioning to electric systems powered by low-carbon sources such as wind, solar, hydroelectric power, and nuclear energy. However, the paper also highlights the challenges of this transition, including high costs and lack of infrastructure. The paper emphasizes the need for continued research and investment in renewable energy technology and infrastructure to overcome these challenges and achieve a sustainable energy system. Additionally, the use of nuclear energy raises concerns, such as nuclear waste and proliferation, and should be considered with its benefits and drawbacks. The study assesses the feasibility of nuclear energy development in Latvia, a country in Northern Europe, and finds that Latvia is a suitable location for nuclear power facilities due to potential energy independence, low-carbon energy production, reliability, and economic benefits. The study also discusses methods of calculating electricity generation and consumption, such as measuring MWh produced by power plants, and balancing supply and demand within the country. Furthermore, the study assesses the safety of nuclear reactors, generated waste, and options for nuclear waste recycling. The transition to a carbon-free energy system is ongoing and complex, requiring multiple strategies to accelerate the transition. While the paper proposes that nuclear energy could be a practical means of supporting and backing up electricity generated by renewables, it should be noted that there are still challenges to be addressed. Some of the results presented in the paper are still based on studies, and the post-treatment of waste needs to be further clarified.

High-pressure torsion (HPT) is widely used as a severe plastic deformation technique to create ultrafine-grained structures with promising mechanical and functional properties. Since 2007, the method has been employed to enhance the hydrogenation kinetics in different Mg-based hydrogen storage materials. Recent studies showed that the method is effective not only for increasing the hydrogenation kinetics but also for improving the hydrogenation activity, for enhancing the air resistivity and more importantly for synthesizing new nanostructured hydrogen storage materials with high densities of lattice defects. This manuscript reviews some major findings on the impact of HPT process on the hydrogen storage performance of different titanium-based and magnesium-based materials.

High-pressure torsion (HPT) is widely used as a severe plastic deformation technique to create ultrafine-grained structures with promising mechanical and functional properties. Since 2007, the method has been employed to enhance the hydrogenation kinetics in different Mg-based hydrogen storage materials. Recent studies showed that the method is effective not only for increasing the hydrogenation kinetics but also for improving the hydrogenation activity, for enhancing the air resistivity and more importantly for synthesizing new nanostructured hydrogen storage materials with high densities of lattice defects. This manuscript reviews some major findings on the impact of HPT process on the hydrogen storage performance of different titanium-based and magnesium-based materials. [ABSTRACT FROM AUTHOR]

The effect of thickness in multilayer thin-film composite membranes on gas permeation has received little attention to date, and the gas permeances of the organic polymer membranes are believed to increase by membrane thinning. Moreover, the performance of defect-free layers with known gas permeability can be effectively described using the classical resistance in series models to predict both permeance and selectivity of the composite membrane. In this work, we have investigated the Pebax®-MH1657/PDMS double layer membrane as a selective/gutter layer combination that has the potential to achieve sufficient CO2/N2 selectivity and permeance for efficient CO2 and N2 separation. CO2 and N2 transport through membranes with different thicknesses of two layers has been investigated both experimentally and with the utilization of resistance in series models. Model prediction for permeance/selectivity corresponded perfectly with experimental data for the thicker membranes. Surprisingly, a significant decrease from model predictions was observed when the thickness of the polydimethylsiloxane (PDMS) (gutter layer) became relatively small (below 2 µm thickness). Material properties changed at low thicknesses—surface treatments and influence of porous support are discussed as possible reasons for observed deviations.

Sulfonated poly(ether sulfone)s (SPESs) are developed which have different sulfonation level as a polymer electrolyte membrane for high-temperature operation. The sulfonation level of SPESs is calculated by 1H NMR, and the molecular structure and crystalline structure of SPESs are evaluated by Fourier transform infrared and X-ray diffraction. SPES membranes are thermally stable up to 250 °C. SPES membranes can keep their shapes at 120 °C and 23%RH. Water uptake at 120 °C and 23%RH is 5.7-6.4 wt%, while Nafion 212 shows 2.4 wt%. Proton conductivity measurements of SPESs are carried out from 30 to 120 °C at different relative humidity. With increasing sulfonation level of SPES, proton conductivity increases in all humidity. The proton conductivity obtained from all SPESs is more than 100 mS cm-1 at 120 °C in high humidity (>90%RH), and high-sulfonation SPES shows higher conductivities than Nafion 212 at 120 °C, 20%RH. [ABSTRACT FROM AUTHOR]

Novel charge-transfer (CT) complex hybrid films for high temperature polymer electrolyte fuel cell (PEFC) application based on sulfonated polyimide (SPI) with hydrophobic unit (4,4 (sulfonylbis(4,1-phenylene)bis(oxy)dianyline (BAPPS)) are synthesized and characterized. In this study, property changes of the polymer electrolytes prepared by a unique CT complex postmodification process are evaluated. The effect of the CT complex formation in the obtained films on the properties of the polymer films is evaluated, because the CT complex can work as a binder between SPIs. Water uptake of the CT complex hybrid films shows a lower value than that of the original SPI film. The CT complex hybrid films also exhibit comparable proton conductivity to Nafion 115 under high-temperature operational conditions (100-120 °C). These results suggest that the CT complex hybrid films developed are promising alternatives for high temperature PEFC application. [ABSTRACT FROM AUTHOR]

Electroreduction of CO 2 has potential for storing otherwise wasted intermittent renewable energy, while reducing emission of CO 2 into the atmosphere. Identifying robust and efficient electrocatalysts and associated optimum operating conditions to produce hydrocarbons at high energetic efficiency (low overpotential) remains a challenge. In this study, four Cu nanoparticle catalysts of different morphology and composition (amount of surface oxide) are synthesized and their activities towards CO 2 reduction are characterized in an alkaline electrolyzer. Use of catalysts with large surface roughness results in a combined Faradaic efficiency (46%) for the electroreduction of CO 2 to ethylene and ethanol in combination with current densities of ∼200 mA cm −2 , a 10-fold increase in performance achieved at much lower overpotential (only < 0.7 V) compared to prior work. Compared to prior work, the high production levels of ethylene and ethanol can be attributed mainly to the use of alkaline electrolyte to improve kinetics and the suppressed evolution of H 2 , as well as the application of gas diffusion electrodes covered with active and rough Cu nanoparticles in the electrolyzer. These high performance levels and the gained fundamental understanding on Cu-based catalysts bring electrochemical reduction processes such as presented here closer to practical application. [ABSTRACT FROM AUTHOR]

Microbial fuel cells (MFCs) are energy transducers that convert organic matter directly into electricity, via the anaerobic respiration of electro-active microorganisms. An avenue of research in this field is to employ algae as the organic carbon fuel source for the MFCs. However, in all studies demonstrating the feasibility of this principle, the algal biomass has always been pre-treated prior to being fed to MFCs, e.g. centrifuged, dried, ground into powder, and/or treated by acid-thermal processes. The alternative presented here, is a flow-through system whereby the MFCs were continuously fed by fresh algal biomass. The system consisted of i) a culture of Synechococcus leopoliensis grown continuously in a photo-chemostat, ii) a pre-digester initiating the digestion of the phototrophs and producing a fuel devoid of oxygen, and iii) a cascade of 9 MFCs, hydraulically and electrically independent. This compartmental system could in theory produce 42 W of electrical power per cubic metre of fresh culture (6 · 10 5 cells mL − 1 ). [ABSTRACT FROM AUTHOR]

Mg 2 Ni intermetallics are processed using three different routes to produce three different microstructural features: annealing at high temperature for coarse grain formation, severe plastic deformation through high-pressure torsion (HPT) for nanograin formation, and HPT processing followed by annealing for the introduction of stacking faults. It is found that both grain boundaries and stacking faults are significantly effective to activate the Mg 2 Ni intermetallics for hydrogen storage at 423 K (150 °C). The hydrogenation kinetics is also considerably enhanced by the introduction of large fractions of grain boundaries and stacking faults while the hydrogenation thermodynamics remains unchanged. This study shows that, similar to grain boundaries and cracks, stacking faults can act as quick pathways for the transportation of hydrogen in the hydrogen storage materials. [ABSTRACT FROM AUTHOR]

Enabling the production of solar fuels on a global scale through artificial photosynthesis requires the development of water oxidation catalysts with significantly improved stability. The stability of photosystems is often reduced owing to attack by singlet oxygen, which is produced during light harvesting. Here, we report photochemical water oxidation by CoFPS, a fluorinated Co-porphyrin designed to resist attack by singlet oxygen. CoFPS exhibits significantly improved stability relative to its non-fluorinated analogue, as shown by a large increase in turnover numbers. This increased stability results from resistance of CoFPS to attack by singlet oxygen, the formation of which was monitored in situ by using 9,10-diphenylanthracene as a chemical probe. Dynamic light scattering (DLS) confirms that CoFPS remains homogeneous, proving its stability during water oxidation catalysis. [ABSTRACT FROM AUTHOR]

The effect of thickness in multilayer thin-film composite membranes on gas permeation has received little attention to date, and the gas permeances of the organic polymer membranes are believed to increase by membrane thinning. Moreover, the performance of defect-free layers with known gas permeability can be effectively described using the classical resistance in series models to predict both permeance and selectivity of the composite membrane. In this work, we have investigated the Pebax ® -MH1657/PDMS double layer membrane as a selective/gutter layer combination that has the potential to achieve sufficient CO₂/N₂ selectivity and permeance for efficient CO₂ and N₂ separation. CO₂ and N₂ transport through membranes with different thicknesses of two layers has been investigated both experimentally and with the utilization of resistance in series models. Model prediction for permeance/selectivity corresponded perfectly with experimental data for the thicker membranes. Surprisingly, a significant decrease from model predictions was observed when the thickness of the polydimethylsiloxane (PDMS) (gutter layer) became relatively small (below 2 µm thickness). Material properties changed at low thicknesses-surface treatments and influence of porous support are discussed as possible reasons for observed deviations.