1. Influence of Base Oil Polarity on the Transient Shear Flow of Biodegradable Lubricating Greases
- Author
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Martin Fiedler, Rubén Sánchez, Concepción Valencia, Claudia S. Leopold, Erik Kuhn, and José M. Franco
- Subjects
biodegradable lubricating greases ,AFM ,oil polarity ,rheology ,transient flow ,Science - Abstract
The scope of this study is to elucidate the physical mechanisms influencing the transient flow behavior of lubricating greases based on biogenic oleochemicals from a polarity point of view. This includes the mutually interacting influence of base oil polarity and thickening agents on the rheologically-measured mechanical structural degradation in transient shear flow. Due to the high temperature dependence of Keesom forces in the background of polar-active bond mechanisms, the analysis of the transient flow response as a function of temperature allows to attribute the observed influences to differences in base oil polarity. In general, clay-thickened greases show a greater tendency to be rheologically influenced by base oil polarities than soap-thickened lubricating greases.
- Published
- 2015
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