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Understanding orogenic collapse is key to comprehending the evolution of continental collision orogens. The Dabie orogen is a collapsed continental collision orogen that provides an ideal window for revealing orogenic collapse. Here, we conduct fieldwork, whole-rock geochemistry, and zircon U-Pb dating of the Daoshichong pluton in the North Dabie terrane to elucidate the collapse mechanism of the Dabie orogen. The Daoshichong pluton is composed of quartz monzodiorite and mafic microgranular enclaves (MMEs) with an Early Cretaceous (~130 Ma) crystallization age. The Daoshichong pluton is strongly deformed and ductile, displaying a gneissic structure. The quartz monzodiorites are K-rich and high-Mg adakitic rocks. They contain 60.2–63.3 wt.% SiO2 and have high K2O (2.88–3.42 wt.%) and MgO (2.08–3.04 wt.%) contents with relatively high Mg# values (44.4–49.3). They exhibit high Sr (673–819 ppm) and low Y (11.4–20.9 ppm) and heavy rare earth elements (e.g. Yb: 0.94–1.87 ppm) contents, resulting in high Sr/Y (35.1–72.0) and (La/Yb)N (15.7–36.1) ratios. The MMEs exhibit geochemical characteristics similar to those of the Early Cretaceous mafic – ultramafic rocks of the Dabie orogen. They have low SiO2 contents (48.1–51.9 wt.%) and high MgO contents (3.27–5.62 wt.%) with high Mg# values (47.3–51.2). They also exhibit relatively high Ni (16.6–63.6 ppm), Cr (30.5–164.6 ppm), Y (18.2–25.8 ppm) and Yb (1.50–1.94 ppm) contents and high Sr/Y ratios (53.7–109.5). Evidence from fieldwork and geochemistry distinctly indicates magma mixing during magma evolution between the MMEs and the quartz monzodioritic host. Thus, the Daoshichong quartz monzodioritic host and the MMEs can be interpreted as a mixture of mantle-derived magma and over-thickened lower continental crust-derived adakitic melt. Previous studies suggest that the Early Cretaceous (~130 Ma) high-Mg adakite-like rocks are distributed only along the eastern margin of the Dabie orogen (i.e. along the Tan – Lu Fault). This study is the first to report a homochronous (~130 Ma) K-rich and high-Mg adakite-like pluton in the core of the Dabie orogen. Our results suggest that a whole delamination of the over-thickened orogenic root caused the orogenic collapse, subsequently triggering crust – mantle interactions, dome structure, and magmatism in the Dabie orogen. SUMMARY HIGHLIGHTS: Early Cretaceous high-Mg adakitic rocks have been recognized in the North Dabie terrane. Generation of the Daoshichong adakitic host and MMEs is related to both delamination of the lower continental crust and magma mixing. It was a whole delamination of the over-thickened orogenic root which caused orogenic collapse. [ABSTRACT FROM AUTHOR]

ABSTRACT Knowledge of the early Palaeozoic tectonic evolution of the Indochina Block is critical for reconstructions of the Gondwana supercontinent in relation with other microcontinents. In the central Indochina Block, the Early Palaeozoic Tam Ky–Phuoc Son Suture Zone (TPSZ) and Po Ko Suture Zone (PKSZ) demarcate the boundary between the Truong Son Belt in the north and Kon Tum Massif in the south. In the southern parts of Truong Son Belt, we have identified meta‐mafic and meta‐intermediate rocks associated with plagiogranite, metapelitic and meta‐siliceous rocks. Here we present integrated field, geochemical and geochronological results of the meta‐gabbroic and amphibolitic samples in the southern Truong Son Belt to unravel the tectonic evolution of the Indochina Block during the Early Palaeozoic. The MC–LA–ICP–MS zircon U–Pb ages indicate magmatism at ca. 504–460 Ma. Based on geochemical composition, the samples range from gabbro to gabbro‐diorite. The gabbroic samples have slightly higher Mg# (58.9–62.8) than those of the gabbro‐dioritic samples (Mg# = 56.3–61.5), and both types of rock show low TiO2 contents (0.68–0.98 wt%), displaying enriched LREE ((La/Sm)N = 1.66–3.23) and LILE (e.g., Rb, Ba, Th and U), and pronounced negative HFSE (e.g., Nb, Ta and Ti anomalies) with low εHf(t) zircon values (from −6.34 to +0.71). These geochemical characteristics suggest that the metabasic rocks are of subduction‐related arc magmatic processes, and also indicate infiltration of sediment melt from subducting slab to mantle‐wedge prior to its partial melting. The new data suggests that northward subduction under the Truong Son Belt might have initiated during the Early Cambrian, and lasted until around the Middle Ordovician. On a regional scale, the ages of the Early Palaeozoic arc magmatism in the Truong Son Belt are comparable with the ages of tectonic events that occurred in Himalaya, West Qiangtang and East Tibet at the northern margin of the Gondwana supercontinent. [ABSTRACT FROM AUTHOR]

ABSTRACT The North Qilian Accretionary Belt, situated at the northernmost extent of the Proto‐Tethys tectonic domain, preserves key tectonic events such as Proto‐Tethys Ocean subduction and accretion. Despite ongoing debates about the closure mechanisms and timing of the North Qilian Ocean, our study presents novel findings on granitoids from the Changma region in the western segment of the North Qilian Accretionary Belt. Zircon U–Pb dating indicates an emplacement age of 436 Ma for the Qingshixia pluton and 425 Ma for the Heixialao pluton. The εHf(t) values of the Qingshixia granodiorite range from +8.25 to +10.89, with TDM2 model ages estimated between 614 and 716 Ma. In contrast, the εHf(t) values of the Heixialao monzogranite range from +1.79 to +4.48, with TDM2 model ages spanning from 1127 to 1291 Ma. The Qingshixia granodiorite displays adakitic traits, characterised by high Sr, low Y, low Yb, and a low K2O/Na2O ratio, whilst the Heixialao monzogranite exhibits peraluminous, high‐potassium calc‐alkaline features. The low concentrations of Ni and Cr, along with moderate Mg# values, suggest that the Qingshixia granodiorite likely originated from the partial melting of a subducting slab. By comparison with experimental melts, the relatively low Rb/Ba and Rb/Sr ratios and higher zircon saturation temperatures of Heixialao monzogranite suggest that it may have formed from partial melting of the mafic middle and lower crust. Integrating these findings with regional geological features and differences between east and west segments, we propose that the western segment of the North Qilian Ocean basin may have closed during the Late Silurian, contributing to a diachronic closure process from east to west and offering insights into the tectonic evolution of the Proto‐Tethys Ocean. [ABSTRACT FROM AUTHOR]

A combined investigation of geochemistry and geochronology was carried out for Early Cretaceous magmatic rocks in Tongling, centre of the Middle and Lower Yangtze River. The magmatic activity can be divided into two stages, peaking at ~140 Ma and ~127 Ma. The previous show high Sr and Sr/Y, low Y, and the later have low Sr, Sr/Y and La/Yb. There are correlation patterns between Sr-Nd isotopes and SiO2, and samples show little variation of V and Cr with large variation of Rb, which suggest the effects of partial melting of the diverse source and magma mixing/crustal assimilation were more important than fractional crystallization. The broad variation of εNd(t) and εHf(t) values can be attributed to binary mixing of YC lower crust with slab-derived or enriched mantle melts. The TDM2 of Nd and Hf, Zr saturation temperature, and magma oxygen fugacity display increased trend from ~140 Ma to ~127 Ma. Based on these signatures, origin model of the Early Cretaceous intrusions in Tongling was proposed. Affected by Pacific Plate subduction, following metasomatism by slab-derived fluid/melts, basaltic magma derived from lithospheric mantle underplated the lower crust. Meanwhile, partial melting of the lower crust formed the intermediate-felsic rocks of the first stage. As subduction continued, roll-back of the subducted slab resulted in extension, causing lithospheric thinning and the upwelling of hot asthenosphere. The second stage intrusions were the result of the reworking of the Meso-Neoproterozoic crust in the extension tectonic setting. [ABSTRACT FROM AUTHOR]

The NW Iran is located at the western termination of the Alborz Mountain range and continuation of the Sanandaj-Sirjan magmatic-metamorphic zone at the NW. The volcanic rocks in the Varzaghan area are distributed over different compositional ranges from high-K basalt, andesite, dacite, and trachyandesite, dacite, to rhyolite with adakitic signatures. Chondrite-normalized REE diagrams show flat MREE and HREE patterns for calc-alkaline volcanic rocks and enrichment in LREE, indicating a garnet-free source. Adakitic rock sample chondrite-normalized REE patterns are relatively steep with significant enrichment in LREE and depletion in HREE, indicating a garnet-bearing source or garnet fractionation process. The arc trace element signatures, narrow range of initial87Sr/86Sr(i) = 0.70425–0.70487, different initial143Nd/144Nd(i) = 0.51264–0.51286 and the presence of adakitic rocks reveal that the volcanic rock sources were not the same and can be related to the partial melting of metasomatized mantle and lower continental crust sources. Slab break-off and upwelling of hot asthenosphere in a post-collisional tectonic regime resulted in the melting of the subcontinental lithosphere and lower continental crust which produced calc-alkaline-adakitic volcanic rocks in the Varzaghan area. The main petrological processes involved in the volcanic rocks petrogenesis were fractional crystallization and crustal assimilation. [ABSTRACT FROM AUTHOR]

Adakitic rocks provide important data on Early Cretaceous magmatism and the tectonic setting of the eastern North China Craton. This study reports new data on adakitic alkali rhyolites in the offshore Bohai Bay Basin, eastern China. The eruption age of the rhyolites is represented by a weighted mean206Pb/238U age of 114.4 Ma. The geochemical characteristics of the samples are similar to those of adakitic rocks, with high Sr (307–1686 ppm) and low Y (3.18–11.3 ppm) and Yb (0.30–1.39 ppm) contents, as well as high Sr/Y (40–70) ratios. Moreover, the samples show relatively uniform εNd(t) values (−15.48 to −16.51) and older TDM2 values (2253–2170 Ma). These geochemical features indicate that they were mainly derived from partial melting of the lower continental crust. Amphibole rather than garnet is the main residual phase in the source, indicating that the magma originated from the normal lower crust (<40 km) rather than from the thickened lower crust. Our data, along with regional geology, lead us to suggest that the lithosphere was being stretched and thinned before ca. 114 Ma in the eastern North China Craton, and the region was already under an intraplate tectonic setting associated with a large mantle wedge at ca. 114 Ma. The tectonic regime was triggered by the rollback of the Paleo-Pacific Plate during the late Early Cretaceous. [ABSTRACT FROM AUTHOR]

The Deki Amhare complex is located in central Eritrea, within the Arabian–Nubian Shield (ANS). It consists of an inner core of monzogranite porphyry and diorite enclaves (MMEs), surrounded outwardly by granodiorite and quartz diorite. The zircon U–Pb ages, whole-rock geochemistry, and Sr–Nd–Hf isotopic compositions of the Deki Amhare complex granitoids were used to discuss the Neoproterozoic tectonics of the ANS. The Late Tonian granodiorite and quartz diorite are metaluminous and calc-alkaline to slightly high-K calc-alkaline I-type plutons, with ages of 811.2 ± 4.8 Ma and 811.6 ± 5.7 Ma, respectively. They exhibit positive εHf(t) (7.6–9.5) and εNd(t) (3.9–4.7) values and relatively low (87Sr/86Sr)i ratios (0.70374–0.70463), indicating that they derived from the partial melting of a metasomatized mantle wedge during intra-oceanic subduction. The Ediacaran monzogranite porphyry and MMEs are subalkaline to alkaline A2-type granitoids with ages of 620.0 ± 4.3 Ma and 614.8 ± 3.9 Ma. These display positive εHf(t) (5.3–8.7) and εNd(t) (4.2–4.7) values, as well as low (87Sr/86Sr)i ratios (0.70310–0.70480), implying that they formed through crust–mantle magma mixing related to post-collisional slab break-off. Based on these data, three stages of regional tectonic evolution can be described: (1) from ~1200 Ma to ~875 Ma, the mafic oceanic crust was derived from depleted mantle during the opening of the Mozambique Ocean; (2) from ~875 Ma to ~630 Ma, intra-oceanic subduction and arc formation occurred with the development of I-type batholiths; and (3) from ~630 Ma to ~600 Ma, crustal and lithospheric reworking took place post-collision, leading to the formation of A2-type granitoids. [ABSTRACT FROM AUTHOR]

The composition of Archean granitoid rocks changed from predominantly tonalite-trondhjemite-granodiorite (TTG) gneisses in the early Archean (4-3 Ga) to diversified granitoid rock assemblages in the late Archean (3.0-2.5 Ga), marking a crucial transformation in the geodynamic processes of early Earth. However, the reason for this major transition remains enigmatic because the petrogenetic features of different granitoid assemblages and their crust-mantle interactions during different periods are poorly understood. We use variations in the spatial-temporal distribution, lithological association, chemical composition, and petrogenesis of Neoarchean (2.7-2.5 Ga) granitoids and inferred correlative crust-mantle interactions in the Eastern Liaoning Range (ELR) of the northeastern North China craton to explore this geodynamic transition. The early Neoarchean (ca. 2.7 Ga) ELR granitoids were dominated by TTG gneisses, and the late Neoarchean (2.6-2.5 Ga) ELR granitoid typology and compositions became more complex, changing into TTGs and more K2O-rich granitoid rocks. The TTGs can be subdivided into a high-Ca group and a low-Ca group: The 2.71-2.68 Ga high-Ca group TTG magma originated from partial melting of subducted juvenile oceanic crust, and the low-Ca group TTG magma was derived from fractionation crystallization of the high-Ca group TTG magma. The chemical composition of the magmatic sources played a dominant role on the 2.60-2.50 Ga TTG magmatism: the high-Ca and low-Ca group TTG magmas came from low-K mafic rocks and tonalites, respectively. The 2.58-2.49 Ga K2O-rich granitoids can be divided into three petrogenetic series: (1) The high-Ca-Mg group K2O-rich granitoid magma originated from partial melting of high-K mafic rocks, (2) the low-Ca-Mg group K2O-rich granitoid magma was derived from partial melting of sedimentary rocks, and (3) the transition group K2O-rich granitoid magma was sourced from metagreywackes. The 2.71-2.68 Ga TTGs were generated in an island arc belt, and subducted slab melting and subsequent magmatic differentiation were the dominant mechanisms of the TTG magmatism. The 2.60-2.50 Ga diversified granitoids were formed in the oceanic-continental subduction process under the active continental margin; the complicated oceanic slab subduction and arc-arc and arc-continent collisions contributed to the diversity of late Neoarchean granitoid magmatism. [ABSTRACT FROM AUTHOR]

Alkaline basalts produced in continental arcs should contain information different from the arc tholeiite-calc-alkaline-series magmas, and their origin could provide unique constraints on deep mantle composition and material cycling. However, due to their sparse occurrence, alkaline basalts in continental arcs have not been studied thoroughly, which hinders our understanding of the mantle diversity and subduction dynamics under continental arcs. In this study, we present new 40Ar/39Ar ages, major and trace elements, and Sr-Nd-Hf isotopic data for the International Ocean Discovery Program Site U1504 alkaline basalts in the continental arc developed on the South China Block (SCB). These alkaline basalts were generated at ca. 121 Ma and display typical oceanic-island basalt geochemical characteristics. Their relatively high eNd(t) (3.5-3.7) and low (87Sr/86Sr)i (0.7034-0.7040) and La/Nb (0.5-1.0) values suggest that they were mainly derived from an asthenosphere mantle source. Compared to alkaline basalts in the SCB inland, U1504 alkaline basalts exhibit lower K2O/Na2O, Zr/Sm, Zr/Y, eNd(t), and eHf(t) values, indicating the addition of minor sub-continental lithospheric mantle. The enrichment of Nb, Ta, light rare earth elements, and slight depletion of Zr, Hf, and Ti, as well as elevated Fe/Mn and Sm/Yb and low CaO, indicate that their mantle lithology was mainly garnet pyroxenite. Based upon these findings and previous studies, the garnet pyroxenite was probably formed by the interaction of upwelling asthenosphere with slab edges in the scenario of break-off of the Paleo-Pacific Plate, and such interaction diversified the mantle chemistry beneath continental arcs. In conjunction with other reported alkaline basalt data, it is proposed that the enriched asthenosphere mantle beneath the SCB had formed sequentially from inland to coastal since the late Mesozoic, and this may be related to lateral and vertical flow in the deep asthenosphere controlled by the break-off of subducted plates. [ABSTRACT FROM AUTHOR]

Nb and Ta are geochemical twins, yet their ratio varies considerably in igneous rocks. It is generally supposed that felsic melts coexisting with residual rutile will have elevated Nb/Ta ratios relative to their basalt precursors, which is pivotal to our understanding of deep crustal melting and continent formation throughout Earth's history. This study reports petrological, bulk-rock and mineral geochemical, and Sr-Nd-Mo-Hf isotopic data on Eocene adakitic rocks in central Tibet. These rocks can be petrologically and geochemically divided into an amphibole-bearing high-Nb/Ta and an orthopyroxene-bearing low-Nb/Ta group, which were formed by partially molten eclogitized lower crust based on the geochemistry of their early-crystallized minerals. The two groups have similar Sr–Nd–Hf isotope compositions and abundances of strong incompatible elements, suggesting that their source protoliths share identical compositions. Besides, the values of TiO 2 , Ba, Zr/Sm, and La/Yb are comparable between the two groups of rocks, eliminating the possibility of variations in Nb/Ta-sensitive minerals (e.g., rutile, amphibole, biotite, and titanite) in the source as the cause of their Nb/Ta variation. The contrasting mineral assemblages of the two group rocks, along with the higher Ce/Mo ratios and lower δ98/95Mo values in the low-Nb/Ta group, indicate the source of the low-Nb/Ta contains less water than that of the high-Nb/Ta group. These findings, combined with experimental results and trace element partial melting modeling, lead us to propose that the D rutile Nb/Ta responsible formation of the low-Nb/Ta group is higher than that of the high-Nb/Ta group, due to the decreased water content in the source. Thus, the central Tibetan adakitic rocks provide the first natural example demonstrating that the Nb/Ta ratios in felsic rocks derived from rutile-bearing eclogite depend on the physical conditions of source melting, which are not always higher than the protolith. Our study also highlights the potential of employing Mo isotopes in adakitic rocks to test this hypothesis for those that are not petrologically distinguishable. [ABSTRACT FROM AUTHOR]

The relationships between metallogenic capacity and geochemical features of adakitic rocks along the South Tan-Lu Fault (STLF) remain unclear. In this study, the ore-barren adakitic rocks (Tuncang, Guandian and Wawuliu) exhibit higher K2O/Na2O ratios and lower Sr/Y ratios than the ore-bearing adakitic rocks (Chuzhou and Shangyaopu). These differences strongly suggest that the ore-barren adakitic rocks originated from the thickened lower continental crust (LCC), whereas the ore-bearing adakitic rocks were derived from oceanic slabs. Notably, the Tuncang granite exhibits higher Y/Yb and (Ho/Yb)N ratios than the Guandian granodiorite and Wawuliu intrusion. Accordingly, we suggest that the Tuncang granite likely originated from a delaminated eclogitic LCC, whereas the Guandian and Wawuliu intrusions were derived from a thickened basaltic LCC sources. The occurrence of diorite and gabbro mafic microgranular enclaves (MMEs) within the Tuncang granite strongly suggests a magma-mixing process. Considering their MgO contents and εNd(t) and (87Sr/86Sr)i values, we suggest that the gabbro MMEs were likely derived from an enriched mantle source previously metasomatized by subduction-related components and that the diorite MMEs were subsequently formed by magma mixing. Due to the slightly younger ages of the ore-bearing adakitic rocks, we propose a model in which the ore-barren adakitic rocks formed through LCC delamination at 130 Ma and the ore-bearing adakitic rocks formed through oceanic slab remelting at 125 Ma. Consequently, the exploration of Cu–Au mineralization along the STLF should focus on younger oceanic slab-derived adakitic rocks. [ABSTRACT FROM AUTHOR]

The widespread Cenozoic alkaline magmatism within and around the Tibetan Plateau offers a prime opportunity to probe the nature of the mantle at the depths where basalt magmas originate. The close temporal and spatial relationship between volcanism and regional strike‐slip fault systems also helps better understand the geodynamics of outward growth of the plateau in response to the continued India‐Asia convergence. We present a comprehensive study of the deeply sourced alkaline basalts formed along the Kunlun strike‐slip fault with the aim of understanding their petrogenesis and the composition of mantle sources beneath the northeastern Tibetan Plateau. High Nb/U and Ce/Pb ratios and relatively depleted bulk‐rock Sr‐Nd‐Pb isotope compositions corroborate the mantle origin of these alkaline basalts. Homogeneous and low 87Sr/86Sr of clinopyroxene indicates negligible crustal contamination during magmatic evolution. Low δ26Mg in the alkaline basalts and positive correlations with Hf/Sm and Ti/Ti* indicate that the basalts were derived from mantle that was metasomatized by melts derived from sedimentary carbonates during the Paleo‐Tethyan seafloor subduction. Based on 40Ar/39Ar dating results, it appears that the alkaline basaltic magmatism in the northeastern Tibetan Plateau occurred simultaneously with Kunlun strike‐slip faulting. These observations suggest that the India‐Asia convergence must have reactivated ancient subduction plate boundaries and resulted in strike‐slip faulting along these suture zones within and around the Tibetan Plateau. The eruption of low‐volume and deeply rooted alkaline basalts may have been controlled by fractures associated with the strike‐slip fault systems. Plain Language Summary: Small volcanoes that erupted basalt lava with alkaline compositions about 11.5 million years old occur along the northeast margin of the Tibetan Plateau and are close to a major fault system, the Kunlun Fault. Based on their chemical compositions, these basalts were melted from the upper mantle and provide information on the composition of the mantle beneath the plateau. Our chemical, geochronological, and isotopic analyses of the lava indicate that the sub‐plateau mantle was indeed affected by ancient oceanic slab subduction, including subduction of seafloor sediments that resulted in the addition of carbonate‐rich melts to the sub‐plateau mantle, making the mantle more susceptible to melting and more likely to produce alkaline basalt when it did melt. The age of the basalt lava overlaps the age of movement along the Kunlun fault, which suggests that the magma may have been produced from the same tectonic movements that produced the fault and risen through the crust along fractures associated with the fault. Key Points: The light Mg isotopes of the studied alkaline basalts highlight the occurrence of mantle carbonatite metasomatism via Paleo‐Tethyan oceanic slab subductionAlkaline basalts in northeastern Tibetan Plateau erupted coevally with Kunlun strike‐slip faulting that gave rise to mantle upwelling and decompression meltingLithospheric extrusion induced by India‐Asia collision reactivated pre‐existing lithospheric weakness and triggered mantle melting beneath the NE and SE plateau [ABSTRACT FROM AUTHOR]

High-silica adakites exhibit specific compositions, as follows: SiO2 ≥ 56 wt.%, Al2O3 ≥ 15 wt.%, Y ≤ 18 ppm, Yb ≤ 1.9 ppm, K2O/Na2O ≥ 1, MgO < 3 wt.%, high Sr/Y (≥10), and La/Yb (>10). Devonian I-type adakitic granitoids in the northern Appalachians of New Brunswick (NB, Canada) share geochemical signatures of adakites elsewhere, i.e., SiO2 ≥ 66.46 wt.%, Al2O3 > 15.47 wt.%, Y ≤ 22 ppm, Yb ≤ 2 ppm, K2O/Na2O > 1, MgO < 3 wt.%, Sr/Y ≥ 33 to 50, and La/Yb > 10. Remarkably, adakitic intrusions in NB, including the Blue Mountain Granodiorite Suite, Nicholas Denys, Sugar Loaf, Squaw Cap, North Dungarvan River, Magaguadavic Granite, Hampstead Granite, Tower Hill, Watson Brook Granodiorite, Rivière-Verte Porphyry, Eagle Lake Granite, Evandale Granodiorite, North Pole Stream Suite, and the McKenzie Gulch porphyry dykes all have associated Cu mineralization, similar to the Middle Devonian Cu porphyry intrusions in Mines Gaspé, Québec. Trace element data support the connection between adakite formation and slab break-off, a mechanism influencing fertility and generation of porphyry Cu systems. These adakitic rocks in NB are oxidized, and are relatively enriched in large ion lithophile elements, like Cs, Rb, Ba, and Pb, and depleted in some high field strength elements, like Y, Nb, Ta, P, and Ti; they also have Sr/Y ≥ 33 to 50, Nb/Y > 0.4, Ta/Yb > 0.3, La/Yb > 10, Ta/Yb > 0.3, Sm/Yb > 2.5, Gd/Yb > 2.0, Nb + Y < 60 ppm, and Ta + Yb < 6 ppm. These geochemical indicators point to failure of a subducting oceanic slab (slab rollback to slab break-off) in the terminal stages of subduction, as the generator of post-collisional granitoid magmatism. The break-off and separation of a dense subducted oceanic plate segment leads to upwelling asthenosphere, heat advection, and selective partial melting of the descending oceanic slab (adakite) and (or) suprasubduction zone lithospheric mantle. The resulting silica-rich adakitic magmas ascend through thickened mantle lithosphere, with minimal affect from the asthenosphere. The critical roles of transpression and transtension are highlighted in facilitating the ascent and emplacement of these fertile adakitic magmas in postsubduction zone settings. [ABSTRACT FROM AUTHOR]

Mesozoic granitoid formations offer crucial insights into the tectonic history of the North China Craton. New zircon U-Pb ages of two Mesozoic granitoids in the Huai'an terrane yield ages of 226.4 ± 1.1 Ma for the Yihe (YH) granite and 156.3 ± 2.9 Ma for the Zhujiagou (ZJG) granodiorite. The negative Nb, Ta, and Ti anomalies; high Nb/Ta ratios (20.4 to 24.1); high (La/Yb)N (30–84); low initial 87Sr/86Sr ratios (0.707725–0.708188); and negative ƐNd(t) values of the Yihe complex suggest that it originated from the partial melting of the lower crust and lithospheric mantle. However, the geochemical and Sr-Nd isotopic results of the ZJG granodiorite are characterized by I-type granites: Na2O + K2O values of 7.27 to 7.94 wt%, negative Nb anomalies, positive Pb anomalies, higher initial 87Sr/86Sr ratios (0.710979–0.714841), and much lower ƐNd(t) values (−27.1 to −30.1). The Late Jurassic Zhujiagou complex was derived from partial melting of a thickened low crust, and during the Late Triassic, magmatic rocks were formed under a post-collisional extensional regime. Multiple upwellings of the asthenosphere facilitated the mixing of magmas derived from partial melting of the lithospheric mantle and lower crust. These mixed magmas then ascended to the upper crust after undergoing fractional crystallization, leading to the formation of the YH complex. In the Late Jurassic, the tectonic regime of the NCC shifted from compression to extension. The Late Jurassic intrusion identified in this study developed within a compressional setting linked to the subduction of the Paleo-Pacific Ocean. [ABSTRACT FROM AUTHOR]

The Neoarchean Qingyuan greenstone belt (QGB) is located at the northeastern margin of the North China Craton (NCC) and has experienced amphibolite- to granulite-facies metamorphism. The supracrustal rock assemblage is composed of biotite-hornblende (Bt-Hb) monzonitic gneiss, garnet-biotite-hornblende (Grt-Bt-Hb) monzonitic gneiss, Grt-Bt-Hb plagioclase gneiss, amphibolite and orthopyroxene-biotite-hornblende (Opx-Bt-Hb) plagioclase gneiss. This study involves thorough field and petrographic observations, whole-rock geochemistry and LA-ICP-MS zircon U‒Pb ages of these rocks to constrain the Neoarchean geodynamic setting of the QGB. Zircon U‒Pb dating indicates that these metavolcanic rocks formed during 2.57‒2.52 Ga and experienced subsequent regional metamorphism at 2.52‒2.47 Ga. Lithological and geochemical characteristics show that the QGB protoliths were tholeiitic to calc-alkaline basalts, andesites, dacites and rhyolites. The andesite-dacite-rhyolite assemblage exhibits high SiO2 and Mg# values, low Yb and Y contents, strongly fractionated chondrite-normalized REE patterns and depletion in Nb, Ta, Ti and P, resembling Phanerozoic adakites. These geochemical characteristics suggest an origin from the partial melting of a subducted slab interacting with mantle wedge material. The tholeiitic to calc-alkaline basalts exhibit slightly LREE-enriched chondrite-normalized REE patterns and negative Nb and Ti anomalies, like island arc basalts. These basalts might have originated by partial melting of a mantle source affected by metasomatism from subduction-derived fluids and melts. The lithological associations and geochemical characteristics imply that the Qingyuan greenstone belt developed in a continental margin arc setting. [ABSTRACT FROM AUTHOR]

The compositional diversity of primitive arc basalts has long inspired questions regarding the drivers of magmatism in subduction zones, including the roles of decompression melting, mantle heterogeneity, and the amount and composition of slab‐derived materials. This contribution presents the volatile (H2O, Cl, and S), major, and trace element compositions of melt inclusions from basaltic magmas erupted at three volcanic centers in the Washington Cascades: Mount St. Helens (two basaltic tephras, 2.0–1.7 ka), Indian Heaven Volcanic Field (two <600 ka basaltic hyaloclastite tuffs), and Glacier Peak (late Pleistocene to Holocene basaltic tephra from Whitechuck and Indian Pass cones). Compositions corrected to be in equilibrium with mantle olivine display variability in Nb and trace element ratios indicative of mantle source variability that impressively spans nearly the entire range of arc magmas globally. All volcanic centers have magmas with H2O and Cl contributions from the downgoing plate that overlap with other Cascade Arc segments. Volatile abundances and trace element ratios support a model of melting of a highly variably mantle wedge driven by a subduction component of variably saline fluid and/or slab partial melt. Magmas from Glacier Peak in northern Washington have unusually high Th/Yb ratios that are similar to Lassen region basalts, indicating possible contributions of "subcreted" metasediments that geophysical data suggest are not present beneath central Oregon and southern Washington. This data set adds to the growing inventory of primitive magma volatile concentrations and provides insight into spatial distributions of mantle heterogeneity and the role of slab components in the petrogenesis of arc magmas. Key Points: The Washington Cascades sub‐arc mantle is remarkably heterogeneousVolatile contributions from the slab are identifiable across different magma types in the WA CascadesSlab fluids of variable salinity and slab partial melts, non‐uniquely, may contribute to subduction components along the entire arc [ABSTRACT FROM AUTHOR]

The Aruhan granodiorite intrusion in Xiwuqi, Inner Mongolia, is exposed along the central and eastern parts of the Hegenshan suture zone. LA-ICP-MS zircon U-Pb dating shows that the ages of the granodiorite are ranging from 332±3 to 327 ±1 Ma, suggesting emplacement during the Early Carboniferous. The Aruhan granodiorite is characterized by high contents of SiO2 (65.20% to 68.27%), Al2O3 (15.61% to 17.35%), Sr (472x10-6 to 552x10-6) and low contents of MgO (1.16% to 1.61%), Yb (0.86x10-6 to 1.13x10-6), Y (7.29x10-6 to 11.42x10-6, with Na2O/K2O and Sr/Y ratios ranging from 2.56 to 4.35 and 43.45 to 75.68, respectively. The total REE is low (44.73x10-6 to 88.11x10-6), the fractionation of REE is significant [(La/Yb)N = 6.65 ~ 13.85], and the anomaly of Eu (δEu = 0.79 to 1.07) is not obvious. The geochemical characteristics of the whole-rock indicate that the Aruhan granodiorite belongs to typical high-SiO2 island arc adakites (O-type) series, formed in an environment of active continental marginal arc. The source of the maga might be the product of partial melting of subducting oceanic crust with oceanic sediments, which reacts with overlying mantle peridotite. Crystallization differentiation and contamination by crustal materials might occurre during its emplacement. This discovery may support the fact that the central and eastern parts of the Hegenshan Ocean was not yet closed during the Early Car-boniferous. Combined with the regional research, we preliminarily believe that the Hegenshan Ocean may have undergone bidirectional subduction and abatement during the Early Carboniferous, which is different from the previous view that the Hegenshan Ocean underwent unidirectional subduction and abatement northward only. [ABSTRACT FROM AUTHOR]

The Cadomian basement of SW Iberian Massif appears in the so-called Ossa-Morena Complex, which contains several allochthonous terranes that are key for deciphering the evolution of the Gondwana margin during the Neoproterozoic. In this context, the Calzadilla Ophiolite represents the remnants of an oceanic Ediacaran lithosphere formed by a boninitic mafic crust that overlies a serpentinized ultramafic section, the latter being the biggest outcrop of Cadomian serpentinites in Europe. In this work, the petrological and geochemical nature of the mantle section is analysed, as well as the tectonothermal evolution of both, the mafic crust and the ultramafic section. The algebraic analysis of whole rock geochemistry of the serpentinites indicates that the protolith corresponds to harzburgite. The geochemical fingerprint of the serpentinites, as well as the primary spinel crystals composition, shows that peridotites underwent high degrees of partial melting (up to 16%) in a forearc setting. Thermodynamic modelling and average PT methods were applied to serpentinites and mafic dykes from the ultramafic section as well as to amphibolites from the mafic section, both of which experienced progradation up to 4–5 kbar and 525–575°C. According to the data, the protoliths of the Calzadilla Ophiolite were formed in a peri-Gondwanan arc system developed during the subduction of oceanic crust below Gondwana. The roll-back of the subducting slab would induce the opening of the forearc basin at c. 602 Ma, protolith age of amphibolites from crustal section, with an extensive partial melting of the mantle wedge and the formation of boninitic-affinity magmas that constitute the mafic section of the Calzadilla Ophiolite. Metasomatism and serpentinization of the mantle wedge would occur via melt- and fluid–rock interactions. A compression-dominated stage at c. 540 led to the emplacement of the Calzadilla Ophiolite onto the Cadomian magmatic arc, with the development of the amphibolite-facies metamorphic imprint. [ABSTRACT FROM AUTHOR]

Abundant mafic-felsic intrusions distributed in the Altyn Orogen record orogenic histories related to Proto-Tethys and Paleo-Tethys evolution. Zircon U-Pb dating of the intrusive rocks in the eastern Altyn Orogen identifies at least three major tectono-magmatic episodes, yielding ages of ∼426, ∼376–373 and ∼269–254 Ma. The first two emplacement episodes correspond to the post-collisional magmatism in the Altyn Orogen. The ∼426 Ma granitoids possess adakitic characteristics coupled with enriched isotopes, suggesting that they originated from partial melting of thickened lower continental crust induced by upwelling asthenospheric mantle after slab break-off of the South Altyn Ocean Plate. Next, the ∼376–373 Ma mafic-intermediate rocks and coeval granitoids represent a large thermal event that involved mantle melting with induced new juvenile lower continental crust melting in a post-collisional extensional setting. Finally, the ∼254 Ma diabase dykes intruded into the ∼269 Ma granitoids, which were related to the widespread Late Paleozoic magmatism resulting from Paleo-Tethys Ocean subduction. Post-collisional magmatism in the Altyn Orogen significantly enhances understanding of the tectono-magmatic evolution in the northern Tibetan Plateau. The penetrative influence of Paleo-Tethys Ocean subduction was more extensive than previously thought. [ABSTRACT FROM AUTHOR]

The late Neoarchean tonalite – trondhjemite – granodiorite (TTG) and mafic rocks record essential information regarding the early tectonic evolution of the North China Craton, which is crucial for understanding the onset and development of the plate tectonic regime. In this study, we present a comprehensive analysis of petrography, geochronology, and geochemistry of the Guanghua Mélange from the Tonghua area in NE China. The mélange comprises basalt, gabbro, pyroxene diorite, and trondhjemite, and is classified into three groups: basaltic – gabbroic rocks (Group #1), dioritic rocks (Group #2), and trondhjemites (Group #3). Zircon U-Pb analyses indicate that they formed at 2596–2550 Ma, 2531–2515 Ma, and 2502 Ma, respectively, with metamorphism occurring during ~ 2500–2450 Ma. Meanwhile, geochemical data indicate that the calc – alkaline basaltic rocks (Group #1) exhibit slight depletion of Nb or Ta with weakly negative Eu anomalies, suggesting derivation from the lithospheric mantle and formation within a continental arc environment. The pyroxene diorites (Group #2) display similar geochemical characteristics to Group #1, likely formed by partial melting of depleted mantle that underwent sgignificant metasomatism due to variable amounts of slab-derived fluids or melts. The tholeiitic granitoids (Group #3) exhibit strongly fractionated chondrite-normalized REE patterns with high (La/Yb)N and Sr contents, low Y contents, and depletion of Nb, Ta or Ti, resembling adakites generated in arc setting, indicating likely formation through partial melting of subducted oceanic crust. This process was controlled by the initial plate tectonics under a higher geothermal gradient. Consequently, when combined with previous findings, we conclude that an initial subduction of oceanic plate operated in the northeastern North China Craton during the late Neoarchean (>2.55 Ga). Subsequently, it transformed into modern-type plate tectonics during ~ 2.55–2.53 Ga, eventually followed by the continent-continent collision at ~ 2.50–2.45 Ga, resulting in the formation of the Ji – Liao – Ji (Jilin – Liaoning – Hebei) Collision Orogenic Belt. [ABSTRACT FROM AUTHOR]

The petrogenesis and geodynamic implications of the Early Paleozoic adakitic rocks in the east of Inner Mongolia remain topics of debate. This study presents new petrology data through zircon U-Pb age and Lu-Hf isotopic composition, whole-rock major-trace element geochemistry, and Sr-Nd isotopes from adakitic rocks. The zircon U-Pb dating results demonstrate that the formation age is 242.8 ± 1.0 Ma, which is the product of Early Triassic magmatism. Petrology and geochemical study have shown that the granodiorite have high SiO2 (66.93~69.40%), Al2O3 (15.37~15.43%), and MgO (1.35~1.55%), with LREE enrichment and HREE deficit, and they have high Sr, low Y, and high Sr/Y ratios, showing typical signatures of adakitic rocks. The εHf(t) values of zircon vary between +11.3 and +13.8, with low whole-rock (87Sr/86Sr)i (0.703382) and positive εNd(t) values, and the average Mg# of the rock is 56.14, suggesting that adakite derived from partial melting of MORB materials and magma interaction with the mantle. Comprehensive analysis suggests that during the Late Permian to Early Triassic, the subducted slab of the Paleo-Asian Ocean broke off, and the residual oceanic slab preserved in the mantle beneath the subduction zone underwent partial melting, generating adakitic magma. [ABSTRACT FROM AUTHOR]

The lithium cycling in the supra-subduction mantle wedge is crucial for understanding the generation of Li-rich magmas that may potentially source ore deposition in continental arcs. Here, we look from the mantle source perspective at the geological processes controlling the Li mobility in convergent margins, by characterizing a set of sub-arc mantle xenoliths from the southern Andes (Coyhaique, western Patagonia). The mineral trace element signatures and oxygen fugacity estimates (FMQ > + 3) in some of these peridotite xenoliths record the interaction with arc magmas enriched in fluid-mobile elements originally scavenged by slab dehydration. This subduction-related metasomatism was poorly effective on enhancing the Li inventory of the sub-arc lithospheric mantle, underpinning the inefficiency of slab-derived fluids on mobilizing Li through the mantle wedge. However, major and trace element compositions of mantle minerals in other xenoliths also record transient thermal and chemical anomalies associated with the percolation of slab window-related magmas, which exhibit an "adakite"-type geochemical fingerprint inherited by slab-derived melts produced during ridge subduction and slab window opening event. As these melts percolated through the shallow (7.2–16.8 kbar) and hot (952–1054 °C) lithospheric mantle wedge, they promoted the crystallization of metasomatic clinopyroxene having exceptionally high Li abundances (6–15 ppm). Numerical modeling shows that low degrees (< 10%) of partial melting of this Li-rich and fertile sub-arc lithospheric mantle generates primitive melts having two-fold Li enrichment (~13 ppm) compared with average subduction-zone basalts. Prolonged fractional crystallization of these melts produces extremely Li-enriched silicic rocks, which may stoke the Li inventory of mineralizing fluids in the shallow crust. [ABSTRACT FROM AUTHOR]

The subduction and demise of an ocean plate are generally recognized as essential processes that result in the reworking and maturation of the continental crust. The northern Lhasa Terrane in central Tibet represents the forefront of the Lhasa-Qiang-tang collision belt following the closure of the Bangong-Nujiang Ocean. Thus, it is a pivotal location to study the transition processes from oceanic lithosphere subduction to continental collision as well as pertinent crustal growth mechanisms. Here, we present zircon U-Pb dating, whole-rock major and trace element and Sr-Nd isotope, and zircon Hf isotope and trace element data of the Mendang igneous complex, Baingoin County, northern Lhasa Terrane. Geochro-nological results show that the granodiorites, trachydacites, and rhyolites in the Mendang igneous complex formed at ca. 122-116 Ma, 97 Ma, and 73 Ma, respectively. The Early Cretaceous granodiorite samples are peraluminous with high SiO2, Al2O3, and K2O contents, and moderate A/CNK (molar ratio of Al2O3/[CaO + Na2O + K2O]) values, which are similar to those of typical felsic peraluminous I-type granites. The granodiorites are characterized by enrichment in light rare earth elements and large ion lithophile elements (e.g., Rb) and depletion in high field strength elements (e.g., Nb, Ta). They also show the most enriched whole-rock Sr-Nd [(87Sr/86Sr)i = 0.7072-0.7078; eNd(t) = -7.60 to -5.08] and zircon Hf [eHf(t) = -4.46 to +1.02] isotope compositions, indicating that the Early Cretaceous granodiorites were likely derived from an ancient basement under a subduction setting. The trachy-dacites have uniform SiO2, high Al2O3, Sr contents, and Sr/Y values, and low Y and Yb contents, belonging to adakitic rocks. They show more depleted whole-rock Sr-Nd [(87Sr/86Sr)i = 0.7065-0.7066; eNd(t) = -0.56 to -0.22] and zircon Hf [eHf(t) = 4.36-7.84] isotopes than the granodiorites, suggesting that the trachydacites may have generated from partial melting of the juvenile thickened lower continental crust. The rhyolites have the highest SiO2 and K2O contents in the Mendang igneous complex, and significant depletion of Ba, Sr, Eu, P, and Ti. They have slighter more enriched whole-rock Nd [eNd(t) = -3.71 to -1.16] and zircon Hf [eHf(t) = 1.03-4.31] isotope compositions than the trachydacites. These features suggest that the rhyolites were highly fractionated products of the crustal melts. Wholerock Sr-Nd and zircon Hf isotopes of the Mendang igneous complex show a kink trend from enrichment to depletion and then transfer to enrichment again, signifying an increased contribution of juvenile materials in the northern Lhasa Terrane toward progressively replacing the ancient lower crust and accumulating to newly formed crust. The estimated crustal thickness beneath the northern Lhasa Terrane shows a sharp increase from the Early to Late Cretaceous and peak at ca. 97 Ma, whereas it largely decreases in the Late Cretaceous. Integrated with previous studies, we propose that the formation of the Mendang igneous complex (122-73 Ma) elaborately documents the regional tectonic transition from oceanic lithosphere subduction to demise as well as continental crustal differentiation and maturation. The rollback and breakoff of the southward subducted Bangong-Nujiang oceanic slab in the Early Cretaceous initiated diverse magmatism in the northern Lhasa Terrane. During the early Late Cretaceous, the widespread ada-kitic and Mg-rich magmatism was attributed to the delamination of the thickened lithosphere following the final amalgamation of the Lhasa and Qiangtang Terranes. In the late Late Cretaceous, post-collisional extension induced the formation of the rhyolites in the northern Lhasa Terrane. The growth and destruction of the continental crust had certain tempos from the oceanic lithosphere subduction to continental post-collision stage. [ABSTRACT FROM AUTHOR]

Knowledge of the evolution of the Bangong-Nujiang Tethyan Ocean is crucial for reconstructing the paleography of the Tethyan Realm, given its significance as a key component of the eastern Tethys. Nonetheless, there has been uncertainty regarding both the timing and the processes involved in the closure of this ocean. This study focused on a 110-106 Ma igneous complex comprising basalts-basaltic andesites, trachyandesites, and granodiorites from the Sumxi area in the western part of the Qiangtang terrane of west-central Tibet. The basalts-basaltic andesites have SiO2 contents of 52.5-58.7 wt% and MgO contents of 2.89-4.63 wt%, and exhibit some arc-like geochemical signatures. However, these rocks also have elevated Nb contents (>10 ppm) and Nb/La ratios (>0.5), as well as enriched Sr-Nd isotopic composition [eNd(Z) = -7.40 to -6.00], implying that they are products of a mantle source metasomatized by adakitic melts. The trachyandesites are characterized by intermediate compositions (SiO2 = 63.6-65.2 wt%), high Mg number (40-60), and more enriched eNd(t) values (-8.37 to -7.49). Comparing their geochemical composition to that of mélange rocks, it is postulated that these trachyandesites were formed through the partial melting of a mantle source including mélange matrix rocks within a subduction zone. The granodiorites exhibit adakitic geochemical features (Sr = 830.14-1032.70 ppm, Y = 14.8615.37 ppm, Sr/Y = 54-68), indicating that they originated from the partial melting of a thickened lower crust in a continental arc setting. Our results, in combination with a synthesis of tectonomagmatism along the Bangong-Nujiang suture zone, provide con-vincing evidence for subduction of an oceanic plateau and subsequent slab roll-back. The Sumxi igneous complex, with its clear arc affinity, suggests that the Bangong-Nujiang Tethyan Ocean, or at least its western part, remained open until the late Early Cretaceous (ca. 106 Ma). [ABSTRACT FROM AUTHOR]

The Mesoarchean to Neoarchean period (ca. 3.0-2.5 Ga) is the most important stage during the emergence and evolution of plate tectonics. However, plate subduction at this time may have been less stable and perhaps more susceptible to the lubrication effect of sediments than the modern counterpart. Such predictions have not yet been verified by field-based investigations. In this work, we identified two types of rock units (i.e., sanukitoids and associated adakitic suites, exposed in the Eastern Hebei Complex of the North China Craton) and illustrated their petrogenesis and tectonic context through field, geochronologic, geochemical, and isotopic investigations. Laser ablation-inductively coupled plasma-mass spectrometry zircon U-Pb analyses suggest that the two magmatic suites formed within a relatively short time span of ca. 2596-2544 Ma and ca. 2559-2533 Ma, respectively. The sanukitoids are composed of meta-andesites and diorite porphyrites and characterized by relatively high MgO (3.94-5.62 wt%), Mg# (50-61), Cr (73-343 ppm), and Ni (37-111 ppm) values. The adakitic rocks are composed of granodioritegranite gneisses and have relatively high Sr (316-1001 ppm) and low Y (7-13 ppm) and Yb (0.83-1.37 ppm) contents, and relatively high Sr/Y (36-89) and La/Yb (16-45) ratios. Rocks from both suites exhibit depletions of Nb, Ta, and Ti and have similar Sr-Nd-Hf-Zn isotopes: variable (87Sr/86Sr)i (0.7002-0.7053), weakly positive eNd(t) (+0.3 to +1.7) and eHf(t) (+1.8 to +6.8), and slightly heavy d66Zn (0.30‰-0.36‰). These geochemical characteristics indicate that the sanukitoids were derived from the melting of subducted sediments followed by melt-mantle interaction, whereas the adakitic rocks were produced by direct partial melting of subducted plate (including tonalite-trondjhemite-granodiorite melts) under a garnet stability field with minor sediments. Such distinct magmatic rock associations, together with the coeval charnockites and tholeiites with diverse compositions in the adjacent area, can be best explained by a slab breakoff model. Further, events associated with slab breakoff are likely to represent a transition of a quasi-plate tectonic regime, characterized by multiple, continuous, and stagnant attempts to start the modern-style subduction on Earth. In addition, the emergence of sanukitoids and associated magmas symbolized the onset of supracrustal recycling into the mantle. Combined with the Nd-Hf-Zn isotopes of diverse magmatic rocks in the North China Craton that are comparable to other Precambrian magmatic rock suites worldwide, we suggest that supracrustal recycling symbolized the onset of plate tectonics since ca. 3.0 Ga, and by inference played a key role in the development of subduction-driven plate tectonics in addition to Earth's secular cooling. [ABSTRACT FROM AUTHOR]

Qaraie sub-volcanic dome in the west of Zanjan is part of the Urumieh-Dokhtar magmatic arc in the Central Iran zone. Qaraie dome with columnar joints was intruded into the Upper Red Formation sequence and Kahrizbeik granitoid intrusion with Upper Proterozoic age. Based on petrographical studies, this dome is composed of dacite-rhyodacite and consists of plagioclase, biotite, quartz, as well as occasionally hornblende and sanidine phenocrysts within the fine-grained groundmass. These rocks have a porphyritic texture and present vesicular plus flow textures. On the petrological diagrams, rock units of the Qaraie dome have dacite, rhyodacite, and trachy-dacite composition and indicate high-K calc-alkaline to shoshonitic nature. Based on primitive mantle normalized spider diagrams, samples of the Qaraie dome indicate positive anomalies of LILEs (Rb, Ba, Th, U, K, and Cs) along with negative anomalies of HFSEs (Nb, P, and Ti) together with distinctive positive anomaly of Pb. Chondrite-normalized REE patterns demonstrate LREE enrichment and a high ratio of LREE/HREE. Samples from the Qaraie dome demonstrate geochemical similarity with adakites and are classified as high-silica adakites. These rocks resulted from 25% partial melting of the Lower continental crust with garnet-amphibolite composition in a post-collisional setting. Introduction Neogene to Quaternary magmatism in NW of Iran occurred as sub-volcanic and volcanic acidic domes with an adakitic nature. Recent studies on Miocene and post-Miocene magmatic rocks from different parts of Iran have demonstrated that most of the dacitic-rhyodacitic rocks have an adakitic nature (Jahangiri, 2008; Jamshidi et al., 2015; Saadat, 2023). There are some small dacitic domes in the west of Zanjan (from the Qaraie village in the south to the Moghanlou village in the north) that have not been reported in published maps and geological reports. The Qaraie dacitic dome, the largest dome in this area, was marked as Kahrizbeik granitic intrusion in the Mahneshan 1:100000 geological map (Lotfi, 2001). Considering the importance of the Miocene-Pliocene sub-volcanic domes in the evolution of Iran's tectonic-magmatic settings, and their role in the formation of some Au-As mineralizations (e.g., Arabshah, Zarshouran, and Aghdareh in the Takab area; Najafzadeh et al., 2017), studying the Qaraie sub-volcanic dome can provide valuable information for this part of Iran. Regional Geology Based on Iranian tectono-stratigraphic zones, the Qaraie area is located in the Urumieh-Dokhtar magmatic belt within the Central Iran zone. This area is a small part of the Mahneshan 1:100000 geological map (Lotfi, 2001). Based on the prepared 1:25000 geological map for this study, the Qaraie area is composed of Cretaceous sedimentary rocks along with other rock units including the Lower Red Formation, Qom Formation and Upper Red Formation, and Pliocene conglomerate. Kahrizbeik granitoid with Upper Proterozoic age (Lotfi, 2001) is located in the central part of the area. The Qaraie sub-volcanic dome is exposed in the north of the Qaraie village. This sub-volcanic dome intruded into rock units of the Lower Red Formation and Kahrizbeik granitoid intrusion and revealed prismatic structure in marginal parts. There are some outcrops of dacitic sub-volcanic domes in the south of the Moghanlou village intruding into the limestones of the Qom Formation which had an important role in the formation of the Moghanlou Sb deposit (Bavi et al., 2023) Materials and methods This research includes field and laboratory studies. During the fieldwork, different rock units were identified and a geological map with a scale of 1:25,000 was prepared. In this base, 32 samples were collected from the Qaraie dome. Among the mentioned samples, 15 thin sections were examined using a transmitted polarized light microscope in the laboratory of the University of Zanjan. The chemical composition of rock samples (n = 15) was analyzed at the Zarazma Analytical Laboratories, Tehran, Iran using XRF and ICP–MS methods. Results Considering petrographical studies, the Qaraie dome compositionally includes dacite and rhyodacite. These rocks have porphyry along with glomeroporphyritic, vesicular, and flow textures. Dacites consist of plagioclase, biotite, quartz, and sometimes hornblende phenocrysts in the fine-grained groundmass. Sanidine presents along with the mentioned phenocrysts in rhyodacites. Based on geochemical diagrams, Qaraie samples were classified as dacite, rhyodacite, and trachydacite. These rocks have a high-K calc-alkaline to shoshonitic affinity. Based on primitive mantle normalized spider diagrams, these rocks have similar patterns. These diagrams indicate positive anomalies of LILEs along with negative anomalies of HFSEs. Chondrite-normalized REE patterns demonstrate a steep slope pattern with LREE enrichment and a high ratio of LREE/HREE, devoid of specified positive and negative Eu anomaly (Eu/Eu* between 0.94-1.07), (La/Yb)N and (La/Sm)N ratio between 26.72-32.83 and 10.7-11.6, respectively. Dacite-rhyodacites of the Qaraie dome demonstrate geochemical similarity with adakites and are platted in adakite field on Y vs. Sr/Y, La/Yb vs. Sr/Y, and SiO2 vs. MgO diagrams. Based on Sr vs. CaO+Na2O and Sr vs. Na2O+K2O diagrams, the Qaraie samples are classified as high-silica adakites. Discussion and conclusion Geochemical data including LILEs and LREEs enrichment and negative anomalies of HFSEs along with strong positive Pb anomaly demonstrate subduction-related magmatism for the Qaraie sub-volcanic dome. Based on tectonic-magmatic setting discrimination diagrams (Th vs. Ta, Th/Hf vs. Ta/Hf, Th/Ta vs. Yb, and Th/Yb vs. Ta/Yb diagrams), formation of the Qaraie dome has been related to an active continental margin tectonic setting. Based on the (La/Yb)N vs. YbN diagram, the Qaraie adakitic dome resulted from 25% partial melting of garnet-amphibolite. Other diagrams such as SiO2 vs. Ni indicate that the source rocks for the Qaraie adakitic dome resulted from a thick lower continental crust. Considering the Th vs. Th/Ce diagram, the Qaraie adakitic dome was formed in a post-collisional setting.

Rhombic structures have been observed in the Qom-Zefreh-Nayin-Dehsheir-Baft region, specifically along the direction of the dextral faults, which have caused significant changes in strike length. This study investigates the geological features and fault interactions in the region through the examination of aerial images, fault-lithology correlations, petrology, crustal thickness, and seismic studies. The analysis of aerial photos and geological correlations revealed the presence of ophiolites and pluto-volcanics associated with faults and rhombic structures. By conducting field geology and combining various geological studies, a pull-apart basin was identified in the area, contributing to the formation of three rhombic structures. This basin played a crucial role in the genesis of the region's ophiolites and pluto-volcanics. The research suggests that the initial tensional stress leading to the pull-apart basin was caused by the right step of a dextral fault within the Urumieh-Dokhtar magmatic arc. This fault formation occurred due to the oblique Arabian subduction towards the Iranian plateau. During the Zagros orogeny, the stretched area persisted, leading to the formation of oceanic crust in this location. The subduction angle changes from subduction to super-subduction, resulting in the classification of the region into two types: C and E genes. Different types of magma, including alkaline, subalkaline, shoshonite, calcalkaline, and adakitic, were identified in this region. The study highlights the significance of tholeiitic arcs, abyssal features, crust thickness, and seismicity in understanding oblique diagonal subduction models and tensional pull-apart basins, which are crucial in the transition from subduction to super-subduction. This research offers valuable insights into the geological complexities of the region and opens up opportunities for further exploration of similar models. [ABSTRACT FROM AUTHOR]

Rock strength has long been linked to lithospheric deformation and seismicity. However, independent constraints on the related elastic heterogeneity are missing, yet could provide key information for solid Earth dynamics. Using coseismic Global Navigation Satellite Systems (GNSS) data for the 2011 M9 Tohoku-oki earthquake in Japan, we apply an inverse method to infer elastic structure and fault slip simultaneously. We find compliant material beneath the volcanic arc and in the mantle wedge within the partial melt generation zone inferred to lie above ~100 km slab depth. We also identify low-rigidity material closer to the trench matching seismicity patterns, likely associated with accretionary wedge structure. Along with traditional seismic and electromagnetic methods, our approach opens up avenues for multiphysics inversions. Those have the potential to advance earthquake and volcano science, and in particular once expanded to InSAR type constraints, may lead to a better understanding of transient lithospheric deformation across scales. [ABSTRACT FROM AUTHOR]

The Gangdese metallogenic belt in Tibet is an important polymetallic metallogenic belt formed during the subduction of the Neo-Tethys Ocean and subsequent India–Asia collision. Adakitic rocks are widely distributed in this belt and are considered to be closely related to porphyry–skarn Cu-Mo polymetallic mineralization. However, the petrogenesis and geodynamic setting of the Late Cretaceous adakites in the Gangdese belt remain controversial. In this study, we focus on the quartz diorite in the Nuri Cu-W-Mo deposit along the southern margin of the eastern Gangdese belt. LA-ICP-MS zircon U-Pb dating yields a Late Cretaceous age of 93.6 ± 0.4 Ma for the quartz diorite. Whole-rock geochemistry shows that the quartz diorite possesses typical adakitic signatures, with high SiO2, Al2O3, and Sr contents, but low Y and Yb contents. The relatively low K2O content and high MgO, Cr, and Ni contents, as well as the positive zircon εHf(t) values (+6.58 to +14.52), suggest that the adakites were derived from the partial melting of the subducted Neo-Tethys oceanic slab, with subsequent interaction with the overlying mantle wedge. The Late Cretaceous magmatic flare-up and coeval high-temperature granulite-facies metamorphism in the Gangdese belt were likely triggered by Neo-Tethys mid-ocean ridge subduction. The widespread occurrence of Late Cretaceous adakitic intrusions and associated Cu mineralization in the Nuri ore district indicate a strong tectono-magmatic-metallogenic event related to the Neo-Tethys subduction during this period. This study provides new insights into the petrogenesis and geodynamic setting of the Late Cretaceous adakites in the Gangdese belt, and has important implications for Cu polymetallic deposit exploration in this region. [ABSTRACT FROM AUTHOR]

The lithosphere beneath the eastern part of the North China Craton (NCC) is widely recognized as having undergone extensive thinning and destruction since the Mesozoic. Although most models propose that the destruction was related to the Paleo-Pacific subduction, the timing and mechanism of the destruction remains controversial. The Tanlu Fault is the largest deep strike-slip fault zone in eastern China. It is an ideal object to study the destruction of the NCC and the subduction history of the Paleo-Pacific. In this review, we compile the ages and geochemical data of the Mesozoic magmatic rocks along the Tanlu Fault zone, in combination with evidence related to the tectonic evolution of the Tanlu Fault during this time. We further discuss the relationship between subduction of the Paleo-Pacific and the thinning and destruction processes affecting the NCC lithosphere. In the Late Triassic period, adakitic rocks, A-type granites, and mafic rocks generated from depleted asthenosphere were distributed in Liaoning and Shandong provinces along the Tanlu Fault. These magmas were related to an extensional environment caused by exhumation of the Yangtze block after subduction. The magmatic characteristics indicate that the lithospheric mantle began to change from cold and refractory to a hot and active, suggesting that the NCC began to undergo cratonic destruction at this time. The magmatic lull ranging from 200–185 Ma represents the transition for the Tanlu Fault zone tectonic domain from Paleo-Asian Ocean subduction in the north to the Paleo-Pacific subduction in the east. During the Jurassic, the NCC was also affected by subduction and compression of the Mongol – Okhotsk domain in the north and the influence of the Tethys tectonic domain in the south. Under this multi-directional compression, the crust thickened and the subducted slabs were dehydrated and melted, triggering partial melting of the overlying lithospheric mantle, providing a heat source for partial melting of the crust. At the end of the Jurassic, due to the steepening of the subduction angle of the Paleo-Pacific plate and the roll-back of the plate at that time, another magmatic lull (155–145 Ma) occurred in the Tanlu Fault area. In the early Early Cretaceous, due to a change of the Paleo-Pacific subduction direction (from NW to NNW), a large-scale strike-slip movement took place along the Tanlu Fault zone, and the study area began to experience extensive magmatism. At ca. 125 Ma, A-type granites were formed, representing the large-scale extension. At ca. 122 Ma, OIB-like mafic rocks began to intrude, which indicate that the geochemical properties of the lithospheric mantle of the NCC underwent a fundamental transformation at this time. Hence, the lithospheric mantle of the NCC was replaced by new lithospheric mantle. Slab subduction certainly weakened the NCC. However, the studies of mantle peridotite xenoliths in Cenozoic basalts indicate that the large fault zone (Tanlu Fault) was the priority area for lithospheric mantle transformation and replacement. Taking the time and space distribution characteristics of the NCC destruction into consideration, thermochemical erosion was an indispensable destruction model. According to magmatic and structural evidence, the destruction of the NCC was indeed related to the Paleo-Pacific movement. Besides, it should be noted that the Tanlu Fault was also a factor that cannot be ignored. [ABSTRACT FROM AUTHOR]

The magma sources, origins and precise forming ages of the miarolite from Qishan and Kuiqi intrusions are still uncertain. New results reveal that, miarolites from the Qishan and Kuiqi intrusions yield crystallization ages of ∼101 and ∼98 Ma, and they have a high formation temperature (∼910°C) and low oxygen fugacity value, indicating crystallization condition at low pressure in the upper crust with temperature of 678°C. The Qishan and Kuiqi miarolites are characterized by enrichment in SiO2 and high‐K alkali, depletion in Ca and Mg, and belong to the high‐K weak peraluminous rock series. The samples are enriched in HFSEs (i.e., Ta, Zr and Hf) and LILEs (i.e., Ba, P and Sr), depleted in Ba and Sr with the negative anomaly of Eu. In the primitive mantle normalized trace element spider diagram, the samples show a right‐inclined 'seagull‐type' pattern, combined the ratios of (La/Yb)N, 10000 × Al/Ga, Rb/Nb and Nb/Ta etc., they were proved to be alkaline A‐type granite. Combined the characterize of the trace elements, they were derived from clay‐rich source accompanied pelite melting, and subjected to K‐feldspar crystallization fractional. The values of εHf(t) and tDM2 are distributed in the range of –2.8 to 3.3 with ∼1.2 Ga, and –6.0 to 4.0 with ∼1.2 Ga, revealing that they were generated from the Mesoproterozoic Cathaysia basement rocks. The comprehensive research reveals the Kuiqi and Qishan intrusions derived from crust‐mantle mixing and partial melting of the crust, respectively, resulting from lithospheric extension generated by the Paleo‐Pacific Plate subducted into the European–Asian Plate. [ABSTRACT FROM AUTHOR]

Earth's first continental crust is formed by Archaean and mainly consisted of tonalite–trondhjemite–granodiorite with a small amount of diorites (DTTGs), which has an essential role in probing early crust–mantle dynamic regime and in understanding the formation mechanism of continental crust. Here, we present zircon U‒Pb dating and Lu‒Hf isotopes, whole-rock geochemistry, and petrography on DTTGs rocks in the Dunhuang Block. Three episodes of DTTGs were emplaced circa 2.67 Ga, 2.60 Ga, and 2.50 Ga. The circa 2.67 Ga TTGs exhibit high SiO2 contents (68.14–71.70 wt%), low MgO contents (0.65–1.31 wt%), and high ratios of (La/Yb)N (146 on average), with their enriched Nd-Hf isotopes [ƐHf (t) = -5.48–3.19 and ƐNd (t) = -5.77–0.53], indicating origination from partial melting of amphibolites at thickened lower crust. In contrast, the circa 2.60 Ga transitional TTGs exhibit relatively high MgO contents (2.80–3.39 wt%), flat REE (Rare earth element) patterns with moderate ratios of (La/Yb)N (20.49 on average), and dispersed Nd-Hf isotopes [ƐHf (t) = -5.48–3.19 and ƐNd (t)= −3.99–3.08]. Accordingly, circa 2.60 Ga transitional TTGs melts were produced by partial melting of the shallower crust induced by mantle-derived magma upwelling. The circa 2.50 Ga diorites exhibit low SiO2 (55.72–59.11 wt%) but high MgO (3.51–4.52 wt%) contents with positive Nd-Hf isotopes [ƐHf (t) = -0.16–4.17 and ƐNd (t) = 2.00–4.45], suggesting that they originated from partial melting of mantle wedges metasomatized by fluid from subduction slabs. Combined with the detailed petrogenetic studies and crustal thickness variation, we conclude that the complex crust–mantle interaction may be an essential reason for the Neoarchaean diversity of DTTGs from the Dunhuang Block, which experienced prolonged arc accretion before Neoarchaean, followed by delamination between 2.67 and 2.60 Ga and subsequently transitioned to subduction. [ABSTRACT FROM AUTHOR]

Late Palaeozoic evolution of the Chinese Altai-East Junggar orogenic collage is vital for a better understanding of the accretionary evolution in the southern Altaids. This paper reports new geochronological, geochemical, and isotopic data for the magmatic rocks collected from the northern part of the Dulate arc. The ~304.6 Ma tonalite samples present typical adakitic features of high Sr (396–714 ppm), low Y (1.42–2.60 ppm), Yb (0.11–0.24 ppm), and high Sr/Y (177.25–440.23) ratios. Combining high Mg# (55.35–57.21) and depleted isotopic composition (εHf(t): +9.89 to +13.37 and εNd(t): +5.36 to +6.06), we suggest that they were derived from the partial melting of a subducted oceanic slab. The ~299.4 Ma monzogranite samples have high A/CNK values (1.08 to 1.25), CIPW normative corundum contents (1.28–3.25 wt.%), and positive εHf(t) (+5.14 to +8.63) and εNd(t) (+1.08) values, which are similar to S-type granite that may be generated by the melting of greywackes. The monzogranite (~286.9 Ma) and rhyolitic porphyry (~283.9 Ma) are high-K calc-alkaline and similar to the highly fractionated I-type granites with depleted isotopic features (εHf(t): +11.68 to +14.99 and +0.75 to +7.18, εNd(t): +5.91 and +6.18). The monzogranite and rhyolitic porphyry could have been derived from a depleted mantle source, but the rhyolitic porphyry probably suffered partial assimilation of the overlying crust materials. Combining regional rock associations of mafic-ultramafic complexes, adakitic rocks, high-Mg diorites, and A-type granites with close spatial-temporal relationship, we conclude that a mid-oceanic ridge of the Ob-Zaisan Ocean subducted southward beneath the Dulate arc during the latest Carboniferous to Permian. With the opening of the slab window, the upwelling asthenosphere provided high heat flux and triggered various magmatism in the upper plate. We propose that ridge subduction is one of the most effective mechanisms of continental growth in the southern Altaids. [ABSTRACT FROM AUTHOR]

Jurassic-Cretaceous magmatic rocks are widely distributed in the Jiaodong area, North China. These magmatic rocks are closely associated with gold deposits, but their petrogenesis and geodynamic background are still controversial. The Late Jurassic-Early Cretaceous granitic rocks exposed in the Guocheng area, Jiaodong Peninsula are the focus of this paper. Zircon U-Pb dating, Hf-O isotope and whole rock geochemical analysis are used to determine the petrogenesis of these rocks. Combined with previous data, the geodynamic processes of granite formation in different time intervals are investigated which provide new petrological evidence for understanding the magmatic-mineralization and tectonic background of the Jiaodong area. Samples were collected from the Queshan and Shazibu plutons. The Queshan pluton is a mylonite granite, one sample of which yields a 206U-238Pb zircon age of 156 Ma, while the Shazibu pluton is a quartz monzonite, one sample of which records a 206U-238Pb zircon age of 117 Ma. The two plutons have variable zircon Hf-O isotopic compositions: zircon εHf(t) values of the Queshan pluton are −29.2 to −22.8, and δ18O values are 7.30–7.84 ‰, while the Shazibu pluton has relatively high zircon εHf(t) values (−21.6 to −21.0) and δ18O values of 7.48–8.43 ‰. Whole-rock geochemical data shows that the Queshan pluton has high Sr/Y (60.7–169) and (La/Yb)N (34.6–65.9) values and low Y (3.11–10.3 ppm) and Yb (0.29–0.85 ppm) contents, akin to adakites, whereas granites of the Shazibu pluton are A-type with high Zr+Nb+Ce+Y contents (354–420 ppm) and zircon saturation temperatures (752–795°C). Based on the geochemical and isotopic data, the Late Jurassic Queshan pluton is the product of partial melting of thickened lower crust of the North China Block, while the Early Cretaceous Shazibu pluton formed via fractional crystallization of mafic rocks derived from partial melting of the lower crust of the North China Block. Although both plutons were derived from the lower crust of the North China Block, the nature of the lower crust was modified by involvement of more depleted mantle-derived materials during the Early Cretaceous. From the Late Jurassic to the Early Cretaceous, the rock types (from the adakite to A-type granite) and the nature of the magma source suggest a shift in geodynamic processes. Combined with previous research, the Late Jurassic Queshan pluton is proposed to have formed under low-angle subduction of the ancient Pacific Plate, while the Early Cretaceous Shazibu pluton formed subsequently during Pacific Plate rollback and extension. The Early Cretaceous transformation of tectonomagmatic environments provided favourable conditions for the formation of large-scale gold deposits in the Jiaodong region. [ABSTRACT FROM AUTHOR]

A study of tonalite-trondhjemite-granodiorite (TTG) suite and sanukitoids emplaced at different ages in the Archean can constrain the transition of early Earth's tectonic regime, which remains a subject of debate. In this contribution, we report a systematic investigation of an early Neoarchean and late Neoarchean TTG-sanukitoid association from the eastern North China Craton based on mineralogical, petrological, and geochemical evidence. The geochemical features of the 2.7 Ga TTG rocks studied suggest that their magma was primarily generated by partial melting of garnet-amphibolite and eclogite. Moreover, they are characterized by relatively low values of MgO, Mg#, Cr, and Ni, and zircon É›Hf(t) that varies mostly with evolved signature, which suggests that the primary magma of the TTGs was generated in a setting of thickened lower crust. The 2.5 Ga high-K calc-alkaline granitoids studied show an affinity to Archean sanukitoids. Their representative major and trace elemental and isotopic features suggest that they were derived from partial melting of mantle wedge metasomatized by subducted fluids and slaband sediment-derived melts, followed by varying degrees of mineral fractional crystallization. The eastern North China Craton may have developed a continental marginal arc system in the late Neoarchean attached to another craton in the global Kenorland supercontinent, which might have eventually resulted in its final cratonization. The distinct tectonic settings of the two types of granitoids may indicate a transition of the tectonic regime from vertical in the early Neoarchean to horizontal at the end of the late Neoarchean. Moreover, the low Î'18O values found in this study as well as those in other areas of the globe suggest that they were probably related to cold climatic conditions and/or elevated latitudes or altitudes. [ABSTRACT FROM AUTHOR]

The petrogenesis of Nb-enriched basalts (NEBs) is controversial. NEBs are generally considered to form by melting of either a mixed enriched and depleted mantle source or a mantle wedge metasomatized by adakitic melts. Here we present geochronological, petrological, geochemical, and Sr-Nd-Os isotope data for Early Permian volcanic rocks from the Tuotuohe area in the northern Qiangtang Terrane, China. The studied volcanic rocks can be divided into two groups: arc basalts and basaltic andesites in the lower sequence and NEBs in the upper sequence. Zircon grains from one basaltic andesite sample in the lower sequence yielded a concordia age of 302.0 ± 1.1 Ma. The geochemical and isotopic characteristics suggest that the NEBs were derived from a mixed source consisting of enriched mid-oceanic ridge basalts (MORB)- to oceanic-island basalt-like ambient mantle and slab-derived fluids, whereas the arc basalts and basaltic andesites originated from a source made of the MORB-type ambient mantle modified by slab-derived melts. We propose for the first time that the Nb enrichment of the NEBs was most likely inherited from high-Nb ambient mantle and is independent of the addition of slab-derived components. In addition to slab-derived components, the nature of the ambient mantle is also an important factor controlling the diversity of arc magmatism. Our new findings show that the Late Carboniferous-Early Permian magmatism in the northern Qiangtang Terrane was related to northward subduction of the Paleo-Tethys Ocean, suggesting that subduction might have occurred in at least the Early Permian rather than in the previously thought Middle Permian. [ABSTRACT FROM AUTHOR]

The Okinawa Trough is an incipient back-arc basin formed by the subduction of the Philippine Sea Plate beneath the Eurasian Plate and is a natural laboratory for studying basin evolution, magmatism, and crust-mantle interactions during the early stages of back-arc spreading. Back-arc spreading and recent magmatism are occurring mainly in the Middle Okinawa Trough (MOT) and Southern Okinawa Trough (SOT). In order to investigate the magmatism in the Okinawa Trough, volcanic rock samples from the MOT and SOT were analysed for Fe – Sr – Nd – Pb – Hf isotopic compositions. The Fe isotopic compositions of basaltic andesite samples from the SOT are similar to or lower than MORBs. The fluid/melt derived from the subducted slab, especially the fluid dehydrated from slab serpentinites and sediment-derived melts, entered the overlying depleted mantle wedge and participated in magma generation, which resulted in the low δ56Fe values of the SOT basaltic magmas. The δ56Fe values of volcanic rocks from the MOT increase with increasing SiO2 contents, suggesting a gradual enrichment of heavy Fe isotopes during the evolution of the magma as it ascended to the surface. While the Sr – Nd – Pb – Hf isotopic compositions do not vary significantly, suggesting that the different samples are the products of different degrees of crystal fractionation of comagma. The fractional crystallization of olivine, pyroxene, and ilmenite minerals, which enrich in light Fe isotopes, resulted in the gradual increase in Fe isotopic values of magma during its evolution. The dacites and rhyolites from the southernmost Okinawa Trough have the similar δ56Fe values with the basaltic andesite and the basalt from the SOT and MOT, accompanied by significantly lower Nd and Hf isotope ratios relative to basalts, reflecting that the contamination of crustal materials would not change the magma in Fe isotope compositions evidently. Compared with the MOT, the volcanic rocks from the SOT was more affected by subduction components on their underlying mantle, and those from the southernmost experienced more contamination by crustal materials in the evolving magma. [ABSTRACT FROM AUTHOR]

Subduction zone magmatism is a major control of volcanism, the generation of modern continental crust and the formation of economically important porphyry Cu–(Mo–Au) deposits. Reading the magmatic record of individual arc segments and constraining the rates of magmatic changes are critical in order to fully understand and quantify the processes that drive magma evolution in subduction settings during arc growth. This study focuses on the San Francisco Batholith and the Rio Blanco-Los Bronces porphyry deposit cluster in central Chile, which provides an igneous rock record over ~13.5 Myr of arc evolution. We use whole-rock geochemistry, zircon geochronology and Hf isotope geochemistry to track changes in the crustal magmatic system of this arc segment during crustal thickening and porphyry Cu deposit formation. By combining the analytical dataset with Monte Carlo fractional crystallisation and assimilation fractional crystallisation modelling, we test a model for significant crustal involvement during magma evolution. Systematic and continuous increases in Dy/Yb, La/Yb, V/Sc and Sr/Y in the magmas over time indicate a transition in the main fractionation assemblage from plagioclase-dominated to amphibole-dominated that reflects deeper crystallisation and/or a higher meltwater content. Concomitant decreases in εHf and Th/La as well as increasing Ba/Th are best explained by assimilation of progressively deeper crustal lithologies from low (Chilenia) to high Ba/Th (Cuyania) basement terranes. Our study highlights that an increasingly hydrous magma and a deepening locus of crustal magma differentiation and assimilation, driven by crustal thickening contemporaneous with increased tectonic convergence and ingression of the aseismic Juan Fernandez ridge, can account for all investigated aspects of the multi-Myr magmatic evolution leading up to the formation of the Rio Blanco-Los Bronces porphyry Cu deposits. Our findings corroborate the importance of high-pressure differentiation of hydrous magma for the formation of Andean-style porphyry deposits. Once magmas favourable for porphyry Cu mineralisation were generated in the lower crust, multiple episodes of efficient magma migration into the upper crust fed several, discrete, shallow magmatic-hydrothermal systems over ~3.5 Myr to form the world's largest known Cu resource at Rio Blanco-Los Bronces. [ABSTRACT FROM AUTHOR]

Despite significant progress in Arctic geological studies, a number of principal questions concerning the Paleozoic collisional events remain unanswered. Therefore, the Taimyr Peninsula, representing the only outcropped high Arctic region where magmatic complexes, formed by Hercynian collision between the Siberian Craton and the Kara Block, are well exposed, is crucially important. In this paper we report new geochemical and geochronological data for intrusions in the poorly studied northeastern part of the Taimyr Peninsula. The obtained results in combination with published data show that supra-subduction magmatism at the southern active margin of the Kara Block continued from ca. 345 to 285 Ma (Early Carboniferous to Early Permian), and was followed by a post-collisional magmatic pulse that affected the whole Taimyr across terrane boundaries at ca. 280 Ma in the Early Permian. After cessation of the post-collisional magmatism at ca. 265 Ma, the Taimyr experienced extension, and voluminous magmatic series associated with a Siberian mantle plume were formed between 251 and 228 Ma during the Triassic. The studied post-collisional and plume-related intrusions of the Northeastern Taimyr are generally classified as evolved high-K I-type granites with adakitic affinity. The latter is a regional feature because the majority of the analyzed plume-related granitoids are geochemically similar to high potassium continental adakites. It is suggested that the adakitic geochemical characteristics of the plume-related granitoids resulted from melting of hydrated mafic lower crustal protoliths and were controlled by the source lithology. Comparison of the new results with data available for adjacent areas allows for correlation of terranes on a regional scale and sheds light on the evolution of the Arctic continental margins in general. In the Early–Middle Paleozoic, the Kara Block was part of a continental terrane that formed at the northern edge of Baltica as a result of Neoproterozoic Timanian orogeny. In the Early Carboniferous, the southern margin of Kara turned into an active margin, while its inferred continuation in the eastern Uralian margin of Baltica remained a passive margin until the Early Permian. This discrepancy can be explained by dextral displacement of Kara relative to Baltica that took place in the Early Carboniferous and was later accommodated by the formation of the Taimyr collisional belt in the course of the Early Permian collision between Kara and Siberia. After collision, the Taimyr was incorporated into the northern Eurasian margin as an uplifted block that experienced surface erosion and supplied clastic material in surrounding basins. [ABSTRACT FROM AUTHOR]

The Neoproterozoic Bure adakitic rock in the western Ethiopia shield is a newly discovered magmatic rock type. However, the physicochemical conditions during its formation, and its source characteristics are still not clear, restricting a full understanding of its petrogenesis and geodynamic evolution. In this study, in order to shed light on the physicochemical conditions during rock formation and provide further constraints on the petrogenesis of the Bure adakitic rock, we conduct electron microprobe analysis on K-feldspar, plagioclase, and biotite. Additionally, we investigate the trace elements and Hf isotopes of zircon, and the Sr-Nd isotopes of the whole rock. The results show that the K-feldspar is orthoclase (Or = 89.08~96.37), the plagioclase is oligoclase (Ab = 74.63~85.99), and the biotite is magnesio-biotite. Based on the biotite analysis results, we calculate that the pressure during rock formation was 1.75~2.81 kbar (average value of 2.09 kbar), representing a depth of approximately 6.39~10.2 km (average value of 7.60 km). The zircon thermometer yields a crystallization temperature of 659~814 °C. Most of the (Ce/Ce*)D values in the zircons plotted above the Ni-NiO oxygen buffer pair, and the calculated magmatic oxygen fugacity (logfO2) values vary from −18.5 to −4.9, revealing a relatively high magma oxygen fugacity. The uniform contents of FeO, MgO, and K2O in the biotite suggest a crustal magma source for the Bure adakitic rock. The relatively low (87Sr/86Sr)i values of 0.70088 to 0.70275, positive εNd(t) values of 3.26 to 7.28, together with the positive εHf(t) values of 7.64~12.99, suggest that the magma was sourced from a Neoproterozoic juvenile crust, with no discernable involvement of a pre-Neoproterozoic continental crust, which is coeval with early magmatic stages in the Arabian Nubian Shield elsewhere. Additionally, the mean Nd model ages demonstrate an increasing trend from the northern parts (Egypt, Sudan, Afif terrane of Arabia, and Eritrea and northern Ethiopia; 0.87 Ga) to the central parts (Western Ethiopia shield; 1.03 Ga) and southern parts (Southern Ethiopia Shield, 1.13 Ga; Kenya, 1.2 Ga) of the East African Orogen, which indicate an increasing contribution of pre-Pan-African crust towards the southern part of the East African Orogen. Based on the negative correlation between MgO and Al2O3 in the biotite, together with the Lu/Hf-Y and Yb-Y results of the zircon, we infer that the Bure adakitic rock was formed in an arc–arc collision orogenic environment. Combining this inference with the whole rock geochemistry and U-Pb age of the Bure adakitic rock, we further propose that the rock is the product of thickened juvenile crust melting triggered by the Neoproterozoic Pan-African Orogeny. [ABSTRACT FROM AUTHOR]

The Permian to Triassic period represents a pivotal phase in the evolution of the Paleo-Asian Ocean, marked by significant tectonic transitions from subduction, collision, and post-orogenic extension. The timing of closure of the Paleo-Asian Ocean in northeastern China has always been controversial. In this contribution, the petrology, zircon U-Pb geochronology and geochemistry are conducted on granite found in well HFD1, Songliao Basin, eastern part of Central Asian orogenic belt. Zircon U-Pb dating indicates that granite crystallized at 258.9 ± 2.2 Ma, as the product of magmatism occurred in the early Late Permian. The rocks have high SiO2, Al2O3, Na2O content, negative Eu anomaly, light enrichment of rare-earth elements, depletion of heavy rare-earth elements, high Sr (448.29–533.11 ppm, average 499.68 ppm), low Yb (0.49–0.59 ppm, average 0.54 ppm), Y (4.23–5.19 ppm, average 4.49 ppm), and high Sr/Y ratios (98–125, average 112) and can be classified as O-type adakite. This is the first discovery of late Paleozoic adakite in the Songliao Basin and the neighboring areas. The geochemistry of adakite indicates derivation by partial melting of MORB-type subducted oceanic crust, indicating that the subduction of the Paleo-Asian Oceanic lithosphere lasted until at least 258.9 Ma. [ABSTRACT FROM AUTHOR]

The Shuangwang Au deposit (with a gold resource of approximately 70 t Au), is located in the Fenxian-Taibai fore-arc basin in the West Qinling Orogen of central China. Igneous intrusions in the region include the Xiba granitic pluton and granite porphyry and lamprophyre dykes. The Xiba pluton is composed of granodiorite and monzonite granite. The granodiorite is typical I-type granite, and it yields a crystallization age of 221.1 ± 1.2 Ma and a two-stage Hf model age of 1432–1634 Ma. The monzonite granite shows a transitional characteristic between I-type and A-type granite, and it yields a crystallization age of 214.8 ± 1.2 Ma and a two-stage Hf model age of 1443–1549 Ma. The granitoid was derived mainly from a crust–mantle mixed source. The ages indicate that the granodiorite and monzonite granite formed during two different stages. The REE distribution patterns of the Xiba granitoid exhibit significant fractionation between LREE and HREE, showing right-dipping curves, with an enrichment of LREE and a deficit of HREE. The granodiorite displays a light negative Eu anomaly, while the monzonite granite displays an obvious negative Eu anomaly. The granite porphyry dikes are distributed in the No. I breccia and Jiupinggou granite porphyry, and they yield crystallization ages of 219.9 ± 1.5 Ma and 213.1 ± 0.89 Ma, respectively, and two-stage Hf model ages of 1382–1501 Ma and 1373–1522 Ma, respectively. The lamprophyre dikes in the deposit yield a crystallization age of 214.4 ± 2.7 Ma. After the collision event between the Yangtze and the North China Plates along the Qinling orogenic belt, at approximately 220 Ma in the Late Triassic, the detachment of the slab produced the upwelling of the asthenosphere material. Under conditions of mantle heat and tectonic stress, widespread partial melting of the subducted continental crust and the upper lithosphere mantle occurred, forming granitoids with various degrees of adakite characteristics. [ABSTRACT FROM AUTHOR]

The Aqishan-Caixiashan polymetallic ore cluster, located in the eastern Tianshan Orogenic Belt, is part of the southern Central Asian Orogenic Belt (CAOB) and experienced extensive tectono-magmatic events with polymetallic mineralization during the Carboniferous. However, the Carboniferous tectonic affinity and magmatic evolution of the ore cluster are still controversial, which limits further understanding of the tectonic evolution and regional metallogeny. With the aim of solving these problems, we have carried out geochronological and geochemical studies on Carboniferous intrusive rocks and volcanic rocks from the ore cluster. The samples of the Carboniferous magmatic rocks are enriched in LREEs and LILEs but depleted in HFSEs, which attest to the I-type affinity and are similar to those formed in a continental arc. The early Carboniferous granodiorites and granites (350–343 Ma) in the Central Tianshan Block (CTB), with high Mg# values of 37–66, low Y values of 2.3–17.2 ppm, and high Sr/Y ratios (34–85), show characteristics of adakites that are formed by partial melting of delaminated oceanic crust and/or lower crust. Additionally, they have a wide range of εHf(t) values (5.4–15.9), high εNd (t) values (1.78–6.31) and low ISr values (0.705–0.706), indicating a mixed source of depleted mantle and lower crust for its origin. The Late Carboniferous volcanic rocks (314–306 Ma) in the Aqishan-Yamansu Tectonic Belt (AYTB) north of the CTB have obviously negative Nb–Ta-Ti anomalies, as well as high Y contents (12–20 ppm) and low Sr/Y ratios (5.6–29.9) compared to primitive mantle, which has a relatively flat chondrite-normalized REE pattern, resembling arc-related magmas. Additionaly, they have positive values of εHf(t) values (8.7–14.7), high εNd(t) values (3.04–4.45) and low ISr ratios (0.704–0.707), showing a depleted mantle source, which is weakly affected by the contamination of ancient crustal material. Combining this study and previous works, we suggest that the continuous southwards subduction of the North Tianshan Ocean during the Carboniferous generated the continental arc and forearc basin in the northern part of the CTB. The expansion of the Aqishan-Yamansu forearc basin formed intrusions and volcanic formations along the arc belt. The early Carboniferous intermediate-felsic mantle-derived adakitic magmas in the CTB are probably related to regional Zn-Pb enrichment and mineralization, and the Late Carboniferous intrusions and volcanic formations in the AYTB are related to large-scale Fe-Cu-Zn-Pb-Ag mineralization. [ABSTRACT FROM AUTHOR]

The Triassic granitoids in Central Tianshan play a key role in determining the petrogenesis and tectonic evolution on the southern margin of the Central Asian orogenic belt. In this study, we present SHRIMP zircon U‐Pb ages, Hf isotopic and geochemical data on the Xingxingxia biotite granite, amazonite granite and granitic pegmatite in Central Tianshan, NW China. Zircon U‐Pb dating yielded formation ages of 242 Ma for the biotite granite and 240 Ma for the amazonite granite. These granitoid rocks have high K2O with low MgO and CaO contents. They are enriched in Nb, Ta, Hf and Y, while being depleted in Ba and Sr, showing flat HREE patterns and negative Eu anomalies. They have typical A‐type granite geochemical signatures with high Ga/Al (8–13) and TFeO/(TFeO + MgO) ratios, showing an A2 affinity for biotite granite and an A1 affinity for amazonite granite and granitic pegmatite. Zircon εHf(t) values of the granitoids are 0.45–2.66, with Hf model ages of 0.99–1.17 Ga. This suggests that these A‐type granites originated from partial melting of the lower crust. We propose that Xingxingxia Triassic A‐type granites formed under lithospheric extension from post‐orogenic to anorogenic intraplate settings and NE‐trending regional strike‐slip fault‐controlled magma emplacement in the upper crust. [ABSTRACT FROM AUTHOR]

Permian mafic dikes crop out widely within Beishan area in the southernmost Central Asian Orogenic Belt (CAOB). These mantle-derived products provide important clues for elucidating the genesis and geodynamic setting of Permian magmatism. The mafic dikes within the Beishan area display zircons U–Pb ages of 281 ± 4 Ma. Characterized by low SiO2 (44.88–47.73 wt.%) and high Mg# values (62.2–68.6), the type 1 dikes are relatively depleted in light rare earth elements (LREEs; (La/Yb)n = 0.72–1.43) but enriched in large ion lithophile elements (LILEs). They show high positive εNd(t) values (6.6–8.5) with a range of (87Sr/86Sr)i (0.703477–0.705789) ratios. In contrast, the type 2 dikes have higher SiO2 content (47.47–51.13 wt.%) and lower Mg# (40.9–63.0). They are enriched in LREEs ((La/Yb)n = 1.79–5.02) and LILEs, and have lower εNd(t) values (3.8–7.4) with a variable range of (87Sr/86Sr)i (0.702873–0.706949) ratios. Thus, the type 1 dikes resulted from lower degrees of fractional crystallization and contamination than the type 2 dikes. Considering the LILEs and Pb enrichments, high field strength elements depletions, and high Ba/Th (86–460) ratios, the mantle source was metasomatized by subduction-related fluids. These dikes should be derived from high degrees (>20%) of partial melting of a Sr–Nd isotope-depleted, phlogopite-bearing spinel lherzolite lithospheric mantle according to their high Rb/Sr (0.04–0.24), low Ba/Rb (0.9–3.3), low La/Sm, and constant Sm/Yb ratios in addition to Sr–Nd depletion. Combined with the coeval evidence of regional geology and novel tectonic discriminate diagrams, we suggest that the mafic dikes in Beishan area formed in arc-related setting rather than intracontinental setting during the Permian. The metasomatized lithospheric mantle by subduction-related fluids were heated by upwelling asthenosphere mantle triggered by the slab roll-back, resulting in the formation of the parental magma of the mafic dikes. [ABSTRACT FROM AUTHOR]

The Bam area is located north of the Kerman magmatic copper belt (KMCB) in SE Iran. It belongs to the Urumieh-Dothtar magmatic assemblage (UDMA) that hosts many large Cu-porphyry deposits such as Sarchemeh, Iju, Meiduk, Pakram, and Dalli. The area comprises volcanic and volcano-sedimentary rocks of the Eocene intruded by some sub-volcanic patches. Geochemical analyses show that the sub-volcanic rocks are calc-alkaline granodiorites formed on an active continental margin. The rare earth elements (REE) distribution patterns are differentiated (LaN/YbN = 4–31), having weak to moderate Eu negative anomalies (Eu/Eu* = 0.4–0.8) and flat heavy rare earth element (HREE) sections. The MgO, SiO2, La, Yb, Sr, Sm, and Y contents of these rocks are consistent with adakite-like magmas formed by partial melting of thickened lower crust containing no garnet. Negative correlations of Al2O3, Y and Ba with SiO2 and moderate to weak Eu negative anomalies, indicate the role of hornblende, K-feldspar, and plagioclase fractionation in the formation of these rocks. Geochemical features of the Bam sub-volcanic rocks are similar to those of the Cu-porphyry deposits from UDMA and Malmyzh deposit from eastern Russia, indicating fertility of these rocks for Cu mineralization that should be considered in the future explorations. [ABSTRACT FROM AUTHOR]

The possibility that the Proto‐Tethys Ocean may have undergone intra‐oceanic subduction during ocean closure remains poorly constrained due to a lack of geological evidence for a mature intra‐oceanic arc. Here we present new geochemical and geochronological data for potential arc‐related volcanic rocks adjacent to the accretionary complex and forearc basin in the North Qaidam collisional belt, northern Tibetan Plateau. The volcanic rocks are dominated by foliated basalt, andesite, tuff, and minor dacite with zircon U‐Pb ages ranging from 517 to 497 Ma. They show distinctive geochemical characteristics and can be subdivided into three groups: island‐arc intermediate‐basic volcanic rocks, back‐arc basin basalts (BABB), and dacites with intra‐oceanic arc affinity. The island‐arc volcanic rocks have variable εNd(t) values (+1.6 to +7.5) that decrease northward and were generated by partial melting of depleted mantle wedge modified by hydrous fluid and sediment melt. The BABBs have high εNd(t) values (+5.3 to +6.6) and formed through the melting of MORB‐like mantle, whereas the nearby dacites have positive εNd(t) values (+1.9 to +3.6) similar to the surrounding island‐arc volcanic rocks and were derived from partial melting of intra‐oceanic arc crust as a result of BABB underplating. Integrated analysis of the spatial‐temporal distribution of these volcanic rocks and the reconstructed intra‐oceanic arc‐trench system confirms the existence of the earliest Phanerozoic intra‐oceanic arc formed in response to north‐directed intra‐oceanic subduction. This unrecognized subduction of the Proto‐Tethys Ocean in the North Qaidam belt initiated at ca. 530 Ma, matured ca. 520 Ma, and terminated by ca. 480 Ma. Plain Language Summary: Closure of an ocean basin is achieved through subduction of oceanic lithosphere at a continental margin or in an intra‐oceanic setting. Identification and structure of subduction‐related magmatic rocks are critical for fully understanding the complex processes associated with ocean closure and the paleotectonic framework. Geological mapping and geochemical analyses of the Tanjianshan Group in the North Qaidam collisional belt, northern Tibetan Plateau were undertaken. Results demonstrate the presence of relics of the earliest Phanerozoic intra‐oceanic arc and an associated complete arc‐trench system, generated by previously unrecognized intra‐oceanic subduction far from microcontinents that are now adjacent. This study reveals the entire evolution of a missing intra‐oceanic subduction system within the Proto‐Tethys Ocean, which started ca. 530 Ma, matured ca. 520 Ma and ended ca. 480 Ma. Key Points: Relics of the earliest Phanerozoic intra‐oceanic arc discovered in North Qaidam collisional beltProto‐Tethys Ocean in North Qaidam belt experienced north‐directed intra‐oceanic subductionIntra‐oceanic subduction started at ca. 530 Ma and lasted until ca. 480 Ma [ABSTRACT FROM AUTHOR]

The crustal thickening process is the key to understanding global tectonic evolution and climatic patterns. The Sr/Y, (La/Yb)N ratios of granitoids can be used to quantitatively estimate crustal thickness and reconstruct the crustal thickening process. We present the geochemical characteristics, petrogenesis, and geodynamic implications of Eocene dioritic enclaves (monzodiorite), host granitoid rocks (monzonite), and granite dikes of southern Tibet to reveal the crustal thickening process underway during the collision of India and Asia. The Quxu dioritic enclaves were produced by magma mixing and represent mafic end member. The adakitic host rocks were generated by partial melting of lower crust with normal thickness. The high Sr/Y, (La/Yb)N ratios of the Quxu host rocks were inherited from their magma source region. The ∼40% fractional crystallization of amphibole from magma resembling Quxu host rocks formed the Quxu granite dikes. The continuous crustal thickening history determined by the locally weighted regression analysis shows that the crustal thickness of the Lhasa terrane during 50-45 Ma was no more than 36-46 km, and the crust thickened quickly during the syn-collisional period. [ABSTRACT FROM AUTHOR]

Potassium (K) isotopes have been used as a tracer of K recycling in the Earth, but K isotope fractionation during magma evolution is poorly constrained. Here, we present K isotope data for a magmatic suite of alkaline silicate-carbonatite affinity. The suite was formed from liquid-liquid immiscibility and subsequent phlogopite fractionation. The K isotopic signatures of diferent rock types are in the following order: alkaline silicate lavas (δ41K = –0.424 to 0.090‰) > carbonatitic silicate lavas (δ41K = –0.640 to –0.035‰) > carbonatites (δ41K = –0.858 and –0.258‰). Phlogopite phenocrysts in the silicate lavas are isotopically lighter (δ41K = –0.628 to –0.534‰) than the lavas in which they occur (Δ41KPhlogopite-whole rock = –0.502 to –0.109‰). Correlations between δ41K values and chemical proxies of melt immiscibility and phlogopite fractionation indicate that K isotopes are significantly fractionated by both processes at a ~0.6‰ magnitude. Such K isotope variation overlaps the range of δ41K in arc lavas. Compilations of literature data further confirm the critical roles of melt immiscibility and phlogopite fractionation in K isotope variations of high-K lavas (K2O >1 wt%) from post-collision orogenic and intra-continental settings. In comparison, basaltic arc lavas are depleted in K2O (mostly <1 wt%) and lack evidence of significant phlogopite fractionation. The K isotope variations of arc lavas are mainly controlled by their mantle sources, which were metasomatized by melt or fluid released from the subducting slab. Therefore, K recycling and K isotope variation are controlled by distinct mechanisms in diferent tectonic settings. [ABSTRACT FROM AUTHOR]

The Pampean flat slab in central Chile and Argentina is characterized by the inland migration and subsequent cessation of arc volcanism since the mid‐Miocene. Slab flattening also affects the distribution and number of intermediate‐depth earthquakes and the evolution of the overlying continental thermal structure. In this study, we combine thermal‐mechanical models with petrological models to examine temporal changes in pressure, temperature, and composition during flat‐slab subduction and estimate water carrying capacity, predicted melt distributions and predicted changes in melt composition. Model results indicate that the present‐day flattened Nazca plate carries water to ∼700 km inland from the trench and could cause flux melting if the material above the slab remains fertile. Observed slab seismicity matches areas where hydrated materials have ∼>3 wt% H2O in the oceanic crust and mantle lithosphere. Seismicity increases as slab water carrying capacity decreases (slab dehydration). As P‐T conditions and compositions of the rock trapped above the slab change during slab flattening, flux melting switches from a peridotite‐dominated early phase to a combined mid‐ocean ridge basalt/eclogite and peridotite melting at ∼8 Ma. The results provide broad consistency with known earthquake distributions, seismic velocities, and observed temporal and spatial changes in volcanic patterns above the Pampean flat slab and point toward the role of melt depletion in the decrease and ultimate cessation of arc volcanism in this region. Key Points: We estimate the water carrying capacities, melt distributions, and composition during the Pampean flat‐slab subductionThe predicted hydrated areas match the observed slab seismicity in the Pampean regionFlux melting above the flat slab is predicted to migrate inland, providing constraints on the causes of the spatiotemporal changes in magmatism [ABSTRACT FROM AUTHOR]