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Reliable ignition is a fundamental prerequisite for the scramjet engines. In order to improve the reliability of ignition, further enhance the application of spark ignition in engineering, and improve the ignition ability in the field of supersonic combustion, an innovative long electrode distance high-energy spark igniter (LHSI) system was proposed by our research team. To reveal the instantaneous ignition characteristics of the LHSI, a simulation model of the LHSI is established and verified by experiments. Based on this, the formation and development of the initial flame kernel of vaporized kerosene and the ignition characteristics of LHSI in a scramjet combustor were simulated and compared with the conventional high-energy spark igniter (HSI). The analysis revealed that the success of the cavity ignition is greatly influenced by the local equivalent ratio of the initial flow field and the penetration depth of the initial flame kernel. Meanwhile, the fore recirculation zone of the cavity plays a key role in stabilization and development of the initial flame kernel. Compared with the HSI, the LHSI can produce initial flame kernel with higher penetration and greater size, which is the main reason why LHSI has a broader ignition boundary. The simulation results show that the oil-rich and oil-lean ignition boundaries of LHSI are about 17 % and 55 % wider than those of HSI, respectively.

Tantalum is not only one of the critical metals applied in various advanced industries such as electronics, aerospace, military, and medical applications, but also is considered a conflict mineral, posing a threat to its global supply security. China plays a significant role in the tantalum industrial chain; however, the complete picture of its anthropogenic tantalum cycle remains unknown. This study investigates the tantalum cycles in China from 2000 to 2021 by conducting a dynamic material flow analysis. The results reveal that China's domestic tantalum consumption surged from 91 tons in 2000 to 580 tons in 2021. China heavily relied on importing tantalum minerals to support its domestic production, with a trade dependence rate of 90 %. Moreover, the trade volume of tantalum-related commodities experienced substantial growth from 2000 to 2014 and then fluctuated, with tantalum concentrates as the primary imported goods and electronic products as the primary exported goods. Approximately 24.9 % of the overall tantalum demand was met with secondary tantalum, in which 80 % of such secondary material being recovered during the refining and production stages. Policy recommendations are proposed accordingly, including diversifying tantalum mineral resources and increasing the recovery rates from end-of-life products. These policies can significantly contribute to achieving sufficient tantalum supply and maintaining sustainable tantalum supply chain in China.

Vacuole membrane protein 1 (VMP1) is an integral membrane protein that plays a pivotal role in cellular processes, particularly in the regulation of autophagy. Autophagy, a self-degradative mechanism, is essential for maintaining cellular homeostasis by degradation and recycling damaged organelles and proteins. VMP1 involved in the autophagic processes include the formation of autophagosomes and the subsequent fusion with lysosomes. Moreover, VMP1 modulates endoplasmic reticulum (ER) calcium levels, which is significant for various cellular functions, including protein folding and cellular signaling. Recent studies have also linked VMP1 to the cellular response against viral infections and lipid droplet (LD). Dysregulation of VMP1 has been observed in several pathological conditions, including neurodegenerative diseases such as Parkinson’s disease (PD), pancreatitis, hepatitis, and tumorogenesis, underscoring its potential as a therapeutic target. This review aims to provide an overview of VMP1’s multifaceted roles and its implications in disease pathology.

Manganese is a strategic metal that has been widely applied in the steelmaking industry and the emerging energy batteries industry. China is the largest manganese importer and consumer, but the critical features of its manganese metabolisms, including its supply and demand, trade, and waste management, remain unclear. By applying dynamic material flow analysis (DMFA) method, this research investigates the evolution of China’s anthropogenic manganese flows and stocks during the period of 2000 to 2021. We found that the demand for manganese had increased almost tenfold in China from 2000 to 2021, mainly used for steelmaking, while the surging demand for manganese in energy batteries had gradually increased. However, China highly relied on importing manganese concentrates due to its limited manganese resources. The cumulative in-use manganese stocks also increased by tenfold and reached approximately 168 million tons (Mt). In addition, manganese flow from the end-of-life (EoL) final products reached 12 Mt in 2021, but few of them were recycled, implying a huge recycling potential. These findings provide valuable insights to prepare more appropriate manganese resource management policies, such as improving domestic mining technologies, enhancing manganese recycling, and diversifying the supply of manganese resources, so that the overall manganese resource efficiency can be improved.

The North Mountain landslide in Lijie Town has been in a long-term creeping deformation state and has experienced multiple landslide and debris flow disasters. Monitoring the surface deformation of landslide to grasp the surface deformation pattern of disaster body is a reliable basis for realizing early warning prediction of geological disaster. In this paper, a machine learning model is introduced to predict the relevant data, and a long and short-term memory network is used to predict the landslide deformation by monitoring the displacement data of North Mountain in Lijie, and the prediction results are compared with the actual data and analyzed. In this paper, root mean square error , mean absolute error , coefficient of determination and explainable variance are used to evaluate the prediction results, among which the coefficient of determination and explainable variance reach 0.99. It shows that the long short-term memory network used in this paper achieves good prediction performance in the prediction of landslide deformation in the North Mountain of Lijie.

The Bailongjiang River Basin is a high-risk area for debris flow in China. On 17 August 2020, a debris flow occurred in the Shuimo catchment, Wen County, which blocked the Baishui River, forming a barrier lake and causing significant casualties and property damage. In this study, remote sensing, InSAR, field surveys, and unmanned aerial vehicle (UAV) techniques were used to analyze the causal characteristics, material source characteristics, dynamic processes, and disaster characteristics after the debris flow. The results showed that the Shuimo catchment belongs to low-frequency debris flows, with a recurrence cycle of more than 100 years and concealed features. High vegetation coverage (72%) and a long main channel (11.49 km) increase the rainfall-triggering conditions for debris flow occurrence, making it more hidden and less noticed. The Shuimo catchment has a large drainage area of 31.26 km2, 15 tributaries, significant elevation differences of 2017 m, and favorable hydraulic conditions for debris flow. The main sources of debris flow material supply are channel erosion and slope erosion, which account for 84.4% of the total material. The collapse of landslides blocking both sides of the main channel resulted in an amplification of the debris flow scale, leading to the blockage of the Baishui River. The scale of the accumulation fan is 28 × 104 m3, and the barrier lake area is 37.4 × 104 m2. The formation mechanism can be summarized as follows: rainfall triggering → shallow landslides → slope debris flow → channel erosion → landslide damming → dam failure and increased discharge → deposition and river blockage. The results of this study provide references for remote sensing emergency investigation and analysis of similar low-frequency and concealed debris flows, as well as a scientific basis for local disaster prevention and reduction.

Abstract Human skin comprises multiple hierarchical layers that perform various functions such as protection, sensing, and structural support. Developing electronic skin (E‐skin) with similar properties has broad implications in health monitoring, prosthetics, and soft robotics. While previous efforts have predominantly concentrated on sensory capabilities, this study introduces a hierarchical polymer system that not only structurally resembles the epidermis‐dermis bilayer structure of skin but also encompasses sensing functions. The system comprises a polymeric hydrogel, representing the “dermis”, and a superimposed nanoporous polymer film, forming the “epidermis”. Within the film, interconnected nanoparticles mimic the arrangement of interlocked corneocytes within the epidermis. The fabrication process employs a robust in situ interfacial precipitation polymerization of specific water‐soluble monomers that become insoluble during polymerization. This process yields a hybrid layer establishing a durable interface between the film and hydrogel. Beyond the structural mimicry, this hierarchical structure offers functionalities resembling human skin, which includes (1) water loss protection of hydrogel by tailoring the hydrophobicity of the upper polymer film; (2) tactile sensing capability via self‐powered triboelectric nanogenerators; (3) built‐in gold nanowire‐based resistive sensor toward temperature and pressure sensing. This hierarchical polymeric approach represents a potent strategy to replicate both the structure and functions of human skin in synthetic designs.

Abstract The long‐term stability issue of halide perovskite solar cells hinders their commercialization. The residual stress–strain affects device stability, which is derived from the mismatched thermophysical and mechanical properties between adjacent layers. In this work, we introduced the Rb2CO3 layer at the interface of SnO2/perovskite with the hierarchy morphology of snowflake‐like microislands and dendritic nanostructures. With a suitable thermal expansion coefficient, the Rb2CO3 layer benefits the interfacial stress relaxation and results in a compressive stress–strain in the perovskite layer. Moreover, reduced nonradiative recombination losses and optimized band alignment were achieved. An enhancement of open‐circuit voltage from 1.087 to 1.153 V in the resultant device was witnessed, which led to power conversion efficiency (PCE) of 22.7% (active area of 0.08313 cm2) and 20.6% (1 cm2). Moreover, these devices retained 95% of its initial PCE under the maximum power point tracking (MPPT) after 2700 h. It suggests inorganic materials with high thermal expansion coefficients and specific nanostructures are promising candidates to optimize interfacial mechanics, which improves the operational stability of perovskite cells.

Driven by the minimization of total energy, the multi-domain morphology is preferred in as-grown ferroelectrics to reduce the depolarization and strain energy during the paraelectric to ferroelectric phase transition. However, the complicated multi-domain is not desirable for certain high-performance ferroelectric electro-optic devices. In this work, we achieve a reproducible and stable large-area monodomain in as-grown bulk ferroelectric single crystal [Formula: see text]. The monodomain dominates the entire single crystal, which is attributed to the internal charge carriers from the photoexcited disproportionation reaction of Sn ions. The charge carriers effectively screen the depolarization field and therefore decrease the depolarization energy and facilitate the formation of monodomain. This work offers a potential approach for engineering bulk ferroelectrics with a stable monodomain, which is desirable for the high-performance ferroelectric electro-optic devices.

The ventrolateral periaqueductal gray (VLPAG) is thought to be the main PAG column for bladder control. PAG neurons (especially VLPAG neurons) and neurons in the pontine micturition center (PMC) innervating the bladder detrusor have anatomical and functional synaptic connections. The prevailing viewpoint on neural control of the bladder is that PAG neurons receive information on the decision to void made by upstream brain regions, and consequently activate the PMC through their direct projections to initiate urination reflex. However, the exact location of the PMC-projecting VLPAG neurons, their activity in response to urination, and their whole-brain inputs remain unclear. Here, we identified the distribution of VLPAG neurons that may participate in control of the bladder or project to the PMC through retrograde neural tracing. Population Ca2+ signals of PMC-projecting VLPAG neurons highly correlated with bladder contractions and urination as shown by in vivo recording in freely moving animals. Using a RV-based retrograde trans-synaptic tracing strategy, morphological results showed that urination-related PMC-projecting VLPAG neurons received dense inputs from multiple urination-related higher brain areas, such as the medial preoptic area, medial prefrontal cortex, and lateral hypothalamus. Thus, our findings reveal a novel insight into the VLPAG for control of bladder function and provide a potential therapeutic midbrain node for neurogenic bladder dysfunction.

Recycling steel scraps by the use of electric arc furnace is one of the most promising approaches for the steel industry to achieve net-zero emissions. Due to the uneven distribution of global steel scraps, many countries are actively involving in the global steel scraps trade. Steel scraps contain a range of critical elements, which may be transferred across borders through international trade of steel scraps. However, existing studies have paid little attention to the global flows of steel scraps and its embodied alloy elements (AEs). This study maps the journey of global steel scraps and the embodied AEs for the period of 2000–2021 for the first time by employing trade-linked material flow analysis and social network analysis. The results indicate that the global steel scraps trade had increased during the study period, with a few core countries (such as USA, Germany, and Turkey) leading the global steel scraps network. Also, critical metals had been transferred across borders in the form of AEs through the trade of steel scraps, especially from global north countries to global south countries. The largest AE flows include Chromium (Cr), nickel (Ni), manganese (Mn) and molybdenum (Mo) flows. Other AE flows, such as cobalt (Co), vanadium (V), and niobium (Nb) flows, were less, but with high values or being regarded scarce. From a global perspective, steel scraps trade and recycling can contribute to the decarbonization efforts of the global steel industry and address resource shortages in some countries. Therefore, it is urgent to promote the overall resource efficiency of steel scraps and the embodied AEs by various efforts.

Investment is an essential engine of economic growth and a major source of China’s CO2 emission. It is therefore crucial to explore the gravity movement and decoupling state of China’s CO2 emission embodied in fixed capital formation (FCF). This study aims to estimate China’s CO2 emissions embodied in various categories of FCF by using input–output tables. The gravity model and Shapley decomposition method are used to explore the gravity movement and regional contributions for China’s CO2 emissions embodied in FCF. Then, the Tapio decoupling model and logarithmic mean Divisia index (LMDI) method are combined to uncover the decoupling relationship between CO2 emissions and economic growth embodied in FCF and the corresponding driving factors. The results show that China’s CO2 emissions embodied in FCF experienced a rapid increase during 2002–2012 and remained almost stable during 2012–2017. The gravity center for CO2 emissions embodied in FCF moved toward northwest during 2002–2015, with the northwestern region and middle Yellow River region being the main engine regions. The relations between CO2 emissions and added values embodied in various categories of FCF were weak decoupling during 2002–2017. Investment scale was the major factor inhibiting the decoupling, while embodied energy intensity was the major factor promoting the decoupling. Finally, several policy recommendations are proposed based on these findings.

Randomly distributed topological defects created during the spontaneous symmetry breaking are the fingerprints to trace the evolution of symmetry, range of interaction, and order parameters in condensed matter systems. However, the effective mean to manipulate topological defects into ordered form is elusive due to the topological protection. Here, we establish a strategy to effectively align the topological domain networks in hexagonal manganites through a mechanical approach. It is found that the nanoindentation strain gives rise to a threefold Magnus-type force distribution, leading to a sixfold symmetric domain pattern by driving the vortex and antivortex in opposite directions. On the basis of this rationale, sizeable mono-chirality topological stripe is readily achieved by expanding the nanoindentation to scratch, directly transferring the randomly distributed topological defects into an ordered form. This discovery provides a mechanical strategy to manipulate topological protected domains not only on ferroelectrics but also on ferromagnets/antiferromagnets and ferroelastics. [ABSTRACT FROM AUTHOR]