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The red hypergiant VY CMa is famous for its very visible record of high mass loss events. Recent CO observations with ALMA revealed three previously unknown large scale outflows (Paper I). In this paper we use the CO maps to investigate the motions of a cluster of four clumps close to the star, not visible in the optical or infrared images. We present their proper motions measured from two epochs of ALMA images and determine the line of sight velocities of the gas in emission at the clumps. We estimate their masses and ages, or time since ejection, and conclude that all four were ejected during VY CMa's active period in the early 20th century. Together with two additional knots observed with HST, VY CMa experienced at least six massive outflows during a 30 year period with a total mass lost greater than 0.07 Msun. The position-velocity map of the $^{12}$CO emission reveals previously unnoticed attributes of the older outer ejecta. In a very narrow range of Doppler velocities, $^{12}$CO absorption and emission causes some of this outer material to be quite opaque. At those frequencies the inner structure is hidden and we see only emission from an extended outer region. This fact produces a conspicuous but illusory dark spot if one attempts to subtract the continuum in a normal way., Comment: To appear in the Astronomical Journal

Imaging and spectroscopy of the knots, clumps, and extended arcs in the complex ejecta of VY CMa confirm a record of high mass loss events over the past few hundred years. HST/STIS spectroscopy of numerous small knots close to the star allow us to measure their radial velocities from the strong K I emission and determine their separate motions, spatial orientations, and time since ejecta. Their ages concentrate around 70, 120, 200 and 250 years ago. A K I emission knot only 50 mas from the star ejected as recently as 1985 -- 1995 may coincide with an H2O maser. Comparison with VY CMa's historic light curve from 1800 to the present, shows several knots with ejection times that correspond with extended periods of variability and deep minima. The similarity of this correspondence in VY CMa with the remarkable recent dimming of Betelgeuse and an outflow of gas is apparent. The evidence for similar outflows from the surface of a more typical red supergiant suggests that discrete ejections are more common and surface or convective activity is a major source of mass loss for red supergiants., Comment: Accepted for publication in the Astronomical Journal

HST/STIS spectra of the small clumps and filaments closest to the central star in VY CMa reveal that the very strong K I emission and TiO and VO molecular emission, long thought to form in a dusty circumstellar shell, actually originate in a few small clumps 100's of AU from the star. The K I lines are 10 to 20 times stronger in these nearest ejecta than on the star. The observations also confirm VO as a circumstellar molecule. In this letter we discuss the spectra of the features, their motions and ages, and the identification of the molecular emission. The strength of the atomic and molecular features in the small clumps present an astrophysical problem for the excitation process. We show that the clumps must have a nearly clear line of sight to the star's radiation., Comment: To appear in the Astrophysical Journal

We performed a molecular line survey of 82 high-mass protostellar objects in search for inflow signatures associated with high-mass star formation. Using the H$^{13}$CO$^+$ (1$-$0) line as an optically thin tracer, we detected a statistically significant excess of blue asymmetric line profiles in the HCO$^+$ (1$-$0) transition, but nonsignificant excesses in the HCO$^+$ (3$-$2) and H$_2$CO (2$_{12}$$-$1$_{11}$) transitions. The negative blue excess for the HCN (3$-$2) transition suggests that the line profiles are affected by dynamics other than inflow motion. The HCO$^+$ (1$-$0) transition thus seems to be the suitable tracer of inflow motions in high-mass star-forming regions, as previously suggested. We found 27 inflow candidates that have at least one blue asymmetric profile and no red asymmetric profile, and derived the inflow velocities to be 0.23$-$2.00 km s$^{-1}$ for 20 of them using a simple two-layer radiative transfer model. Our sample is divided into two groups in different evolutionary stages. The blue excess of the group in relatively earlier evolutionary stages was estimated to be slightly higher than that of the other in the HCO$^+$ (1$-$0) transition., Comment: 35 pages, 4 figures, Published in ApJS

The study of the rotational spectrum of NaCN (X $^1$A') has recently been extended in frequency and in quantum numbers. Difficulties have been encountered in fitting the transition frequencies within experimental uncertainties. Various trial fits traced the difficulties to the incomplete diagonalization of the Hamiltonian. Employing fewer spectroscopic parameters than before, the transition frequencies could be reproduced within experimental uncertainties on average. Predictions of $a$-type $R$-branch transitions with $K_a \le 7$ up to 570 GHz should be reliable to better than 1 MHz. In addition, modified spectroscopic parameters have been derived for the 13C isotopic species of NaCN., Comment: 5 pages, no figure, J. Mol. Spectrosc., appeared; CDMS links updated

12C/13C isotopologue abundance anomalies have long been predicted for gas-phase chemistry in molecules other than CO and have recently been observed in the Taurus molecular cloud in several species hosting more than one carbon atom, i.e. CCH, CCS, CCCS and HC$_3$N. Here we work to ascertain whether these isotopologic anomalies actually result from the predicted depletion of the 13C+ ion in an oxygen-rich optically-shielded dense gas, or from some other more particular mechanism or mechanisms. We observed $\lambda$3mm emission from carbon, sulfur and nitrogen-bearing isotopologues of HNC, CS and \HH CS at three positions in Taurus(TMC1, L1527 and the ammonia peak) using the ARO 12m telescope. We saw no evidence of 12C/13C anomalies in our observations. Although the pool of C+ is likely to be depleted in 13C 13C is not depleted in the general pool of carbon outside CO, which probably exists mostly in the form of C^0. The observed isotopologic abundance anomalies are peculiar to those species in which they are found., Comment: Accepted for publication in The Astrophysical Journal (mail journal)

An emerging theme in modern astrophysics is the connection between astronomical observations and the underlying physical phenomena that drive our cosmos. Both the mechanisms responsible for the observed astrophysical phenomena and the tools used to probe such phenomena - the radiation and particle spectra we observe - have their roots in atomic, molecular, condensed matter, plasma, nuclear and particle physics. Chemistry is implicitly included in both molecular and condensed matter physics. This connection is the theme of the present report, which provides a broad, though non-exhaustive, overview of progress in our understanding of the cosmos resulting from recent theoretical and experimental advances in what is commonly called laboratory astrophysics. This work, carried out by a diverse community of laboratory astrophysicists, is increasingly important as astrophysics transitions into an era of precise measurement and high fidelity modeling., Comment: 61 pages. 11 figures; to appear in Reports on Progress in Physics

A sensitive (1{\sigma} rms at 1 MHz resolution ~3 mK) 1 mm spectral line survey (214.5-285.5 GHz) of VY Canis Majoris (VY CMa) and IRC+10216 has been conducted to compare the chemistries of oxygen and carbon-rich circumstellar envelopes. This study was carried out using the Submillimeter Telescope (SMT) of the Arizona Radio Observatory (ARO) with a new ALMA-type receiver. This survey is the first to chemically characterize an O-rich circumstellar shell at millimeter wavelengths. In VY CMa, 128 emission features were detected arising from 18 different molecules, and in IRC+10216, 720 lines were observed, assigned to 32 different species. The 1 mm spectrum of VY CMa is dominated by SO2 and SiS; in IRC +10216, C4H and SiC2 are the most recurrent species. Ten molecules were common to both sources: CO, SiS, SiO, CS, CN, HCN, HNC, NaCl, PN, and HCO+. Sulfur plays an important role in VY CMa, but saturated/unsaturated carbon dominates the molecular content of IRC+10216, producing CH2NH, for example. Although the molecular complexity of IRC+10216 is greater, VY CMa supports a unique "inorganic" chemistry leading to the oxides PO, AlO, and AlOH. Only diatomic and triatomic compounds were observed in VY CMa, while species with 4 or more atoms are common in IRC+10216, reflecting carbon's ability to form strong multiple bonds, unlike oxygen. In VY CMa, a new water maser (v_2=2) has been found, as well as vibrationally-excited NaCl. Toward IRC+10216, vibrationally-excited CCH was detected for the first time., Comment: 21 pages, 3 figures, accepted for publication in Astrophysical Journal Letters

The BL Lac object S5 0716+71 was observed in a global multi-frequency campaign to search for rapid and correlated flux density variability and signatures of an inverse-Compton (IC) catastrophe during the states of extreme apparent brightness temperatures. The observing campaign involved simultaneous monitoring at radio to IR/optical wavelengths centered around a 500-ks INTEGRAL pointing (November 10-17, 2003). We present the combined analysis and results of the cm- to sub-mm observations including a detailed study of the inter- to intra-day variability and spectral characteristics of 0716+714. We further constrain the variability brightness temperatures (T_B) and Doppler factors (delta) comparing the radio-bands with the hard X-ray emission (3-200 keV). 0716+714 was in an exceptionally high state (outburst) and different (slower) phase of short-term variability. The flux density variability in the cm- to mm-bands is dominated by a correlated, ~4 day time scale amplitude increase of up to ~35% systematically more pronounced towards shorter wavelengths. This contradicts expectations from standard interstellar scintillation (ISS) and suggests a source-intrinsic origin of the variability. The derived lower limits to T_B exceed the 10^12 K IC-limit by up to 3-4 orders of magnitude. Assuming relativistic boosting, we obtain robust and self-consistent lower limits of delta >= 5-33, in good agreement with delta_VLBI obtained from VLBI studies and the IC-Doppler factors delta_IC > 14-16 obtained from the INTEGRAL data. Since a strong contribution from ISS can be excluded and a simultaneous IC catastrophe was not observed, we conclude that relativistic Doppler boosting naturally explains the apparent violation of the theoretical limits within standard synchrotron-self-Compton (SSC) jet models of AGN., Comment: 20 pages, accepted for publication in A&A

We present an interferometric and single dish study of small organic species toward Comets C/1995 O1 (Hale-Bopp) and C/2002 T7 (LINEAR) using the BIMA interferometer at 3 mm and the ARO 12m telescope at 2 mm. For Comet Hale-Bopp, both the single-dish and interferometer observations of CH3OH indicate an excitation temperature of 105+/-5 K and an average production rate ratio Q(CH3OH)/Q(H2O)~1.3% at ~1 AU. Additionally, the aperture synthesis observations of CH3OH suggest a distribution well described by a spherical outflow and no evidence of significant extended emission. Single-dish observations of CH3CN in Comet Hale-Bopp indicate an excitation temperature of 200+/-10 K and a production rate ratio of Q(CH3CN)/Q(H2O)~0.017% at ~1 AU. The non-detection of a previously claimed transition of cometary (CH2OH)2 toward Comet Hale-Bopp with the 12m telescope indicates a compact distribution of emission, D<9'' (<8500 km). For the single-dish observations of Comet T7 LINEAR, we find an excitation temperature of CH3OH of 35+/-5 K and a CH3OH production rate ratio of Q(CH3OH)/Q(H2O)~1.5% at ~0.3 AU. Our data support current chemical models that CH3OH, CH3CN and (CH2OH)2 are parent nuclear species distributed into the coma via direct sublimation off cometary ices from the nucleus with no evidence of significant production in the outer coma., Comment: accepted for publication in ApJ

The Odin satellite has been used to search for the 118.75-GHz line of molecular oxygen (O2)in the Galactic centre. Odin observations were performed towards the Sgr A* circumnuclear disk (CND), and the Sgr A +20 km/s and +50 km/s molecular clouds using the position-switching mode. Supplementary ground-based observations were carried out in the 2-mm band using the ARO Kitt Peak 12-m telescope to examine suspected SiC features. A strong emission line was found at 118.27 GHz, attributable to the J=13-12 HC3N line. Upper limits are presented for the 118.75-GHz O2 (1,1-1,0) ground transition line and for the 118.11-GHz 3Pi2, J=3-2 ground state SiC line at the Galactic centre. Upper limits are also presented for the 487-GHz O2 line in the Sgr A +50 km/s cloud and for the 157-GHz, J=4-3, SiC line in the Sgr A +20 and +50 km/s clouds, as well as the CND. The CH3OH line complex at 157.2 - 157.3 GHz has been detected in the +20 and +50 km/s clouds but not towards Sgr A*/CND. A 3-sigma upper limit for the fractional abundance ratio of [O2]/[H2] is found to be X(O2) < 1.2 x 10exp(-7) towards the Sgr A molecular belt region., Comment: Accepted for publication in A&A. 6 journal pages, 5 figures

The circumstellar envelopes of carbon-rich AGB stars show a chemical complexity that is exemplified by the prototypical object IRC +10216, in which about 60 different molecules have been detected to date. Most of these species are carbon chains of the type CnH, CnH2, CnN, HCnN. We present the detection of new species (CH2CHCN, CH2CN, H2CS, CH3CCH and C3O) achieved thanks to the systematic observation of the full 3 mm window with the IRAM 30m telescope plus some ARO 12m observations. All these species, known to exist in the interstellar medium, are detected for the first time in a circumstellar envelope around an AGB star. These five molecules are most likely formed in the outer expanding envelope rather than in the stellar photosphere. A pure gas phase chemical model of the circumstellar envelope is reasonably successful in explaining the derived abundances, and additionally allows to elucidate the chemical formation routes and to predict the spatial distribution of the detected species., Comment: 4 pages, 4 figures; to appear in Astrophysics and Space Science, special issue of "Science with ALMA: a new era for Astrophysics" conference, November, 13-17 2006, ed. R. Bachiller

The detection of NaCl at large radii in the Egg Nebula, CRL 2688, requires densities of 10^7 - 10^8 cm^-3 in a thick shell of r ~ a few X 10^17 cm. To explain these results, a mechanism is needed for producing high densities at a considerable distance from the central star. In two dimensional simulations of the interaction of the fast wind with an ambient medium, the material becomes thermally unstable. The resulting clumps can achieve the requisite conditions for NaCl excitation. We present 2D models with simple physics as proof-of-principle calculations to show that the clumping behavior is robust. Clumping is a natural outcome of cooling in the colliding wind model and comparable to that inferred from observations., Comment: 12 pages, 3 figures. Accepted for publication in the Astrophysical Journal Letters

A low noise (1(sigma) rms approx. 3 mK) 1. nun spectral survey (214.5-285.5 GHz) of the oxygen-rich supergiant VY Canis Majoris and the carbon-rich asymptotic giant branch star IRC +10216 has been conducted using the Arizona Radio Observatory's 10 m Submillimeter Telescope. Here the complete data set is presented. This study, carried out with a new ALMA-type receiver, marks the first continuous band scan of an O-rich circumstellar envelope, and the most sensitive survey to date of IRC +10216. In VY CMa, 130 distinct molecular lines were detected, 14 of which cannot be identified; in IRC +10216, 717 lines were observed, with 126 features remaining unidentified. In the 1 mm bands of VY CMa and IRC +10216, emission is present from 18 and 32 different chemical compounds, respectively, with 10 species common to both sources. Many narrow emission lines were observed in both circumstellar shells, arising from vibrationally excited molecules and from refractory-containing species. Line profiles in VY CMa also exhibit a variety of different shapes, caused by the complex, asymmetric outflow of this object. The survey highlights the fact that C-rich and O-rich circumstellar envelopes are chemically interesting, and both are sources of new interstellar molecules. The high number of unidentified lines and the unreliable, rest frequencies for known species such as NaCN indicate the need for additional laboratory spectroscopy studies.

A sensitive (1sigma rms at 1 MHz resolution approx.3 mK) 1 mm spectral line survey (214.5-285.5 GHz) of VY Canis Majoris (VY CMa) and IRC +10216 has been conducted to compare the chemistries of oxygen- and carbon-rich circumstellar envelopes. This study was carried out using the Submillimeter Telescope of the Arizona Radio Observatory with a new Atacama Large Millimeter Array type receiver. This survey is the first to chemically characterize an O-rich circumstellar shell at millimeter wavelengths. In VY CMa, 128 emission features were detected arising from 18 different molecules; and in IRC +10216, 720 lines were observed, assigned to 32 different species. The 1 mm spectrum of VY CMa is dominated by SO, and SiS; in IRC +10216, C4H and SiC2 are the most recurrent species. Ten molecules were common to both sources: CO, SiS, SiO, CS, CN, HCN, HNC, NaCl, PN, and HCO(+). Sulfur plays an important role in VY CMa, but saturated/ unsaturated carbon dominates the molecular content of IRC +102.16, producing CH2NH, for example. Although the molecular complexity of IRC +10216 is greater, VY CMa supports a unique "inorganic" chemistry leading to the oxides PO, AlO, and AlOH. Only diatomic and triatomic compounds were observed in VY CMa, while species with four or more atoms are common in IRC +10216, reflecting carbon's ability to form multiple strong bonds, unlike oxygen. In VY CMa, a new water maser (v2 = 2) has been found, as well as vibrationally excited NaCl. Toward IRC +10216, vibrationally excited CCH was detected for the first time.

With the advent of SOFIA, Herschel, and SAFIR, new wavelength regions will become routinely accessible for astronomical spectroscopy, particularly at submm frequencies (0.5-1.1 THz). Molecular emission dominates the spectra of dense interstellar gas at these wavelengths. Because heterodyne detectors are major instruments of these missions, accurate knowledge of transition frequencies is crucial for their success. The Ziurys spectroscopy laboratory has been focusing on the measurement of the pure rotational transitions of astrophysically important molecules in the sub-mm regime. Of particular interest have been metal hydride species and their ions, as well as metal halides and cyanides. A new avenue of study has included metal bearing molecular ions.

For the past 35 years, radio astronomy has revealed a rich organic chemistry in the interstellar gas, which is exceptionally complex towards active star-forming regions. New solar systems condense out of this gas and may influence the evolution of life on newly formed planets. Much of the biologically important functionality is present among the some 130 gas-phase molecules found to date, including alcohols, aldehydes, ketones, acids, amines, amides and even the simplest sugar - glycolaldehyde. Still, many unidentified interstellar radio signals remain, and their identification relies on further laboratory study. The molecules hydroxyacetone and lactic acid are relatively small organic molecules, but possess rather complex rotational spectra owing to their high asymmetry. Hydroxyacetone is particularly problematic because it possess a very low barrier to internal rotation, and exhibits strong coupling of the free-rotor states with the overall rotation of the molecule. As in the case of acetamide, a full decomposition method was employed to order the resultant eigenstates onto normal asymmetric top eigenvectors.

With the advent of SOFIA and Herschel, new spectral windows will be opened for spectroscopy in the sub-millimeter region. To conduct science in this band, laboratory measurements must be carried out to provide accurate transition frequencies for molecular identification and physical interpretation. We are presently conducting such measurements using gas-phase submm direct absorption techniques. Of particular interest are simple molecules containing iron-peak elements, including carbides, and metal hydride ions (MH+), both which possess favorable transitions at submm wavelengths.