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Polymeric ultrafiltration (UF) membranes often used in membrane bioreactor (MBR) prone to be fouled by fouling agents. Therefore, in this paper, the antifouling characteristics of polyvinylidene fluoride (PVDF) UF membranes for wastewater treatment are improved through modifying membranes by O-carboxymethyl chitosan (OCMCS)-functionalized Fe3O4 nanoparticles (OCMCSFe3O4). The modifier agent was manufactured by the adsorption of OCMCS on Fe3O4 nanoparticles, which were synthesized via co-precipitating method. Antifouling performance of membranes was assessed by permeation tests done using activated sludge suspension as a biological foulant, then the calculation of the pure water flux recovery ratio (FRR) and fouling resistance parameters. Also, to investigate the protein rejection of membranes, permeation tests were conducted by the bovine serum albumin (BSA) solution. According to the obtained results, surface hydrophilicity of the embedded membranes was improved in the low concentrations of the modified nanoparticles. However, the high quantity of the OCMCS-Fe3O4 nanoparticles (>0.1 wt. %) in the casting solution lessened membrane performance owing to the agglomeration of the nanoparticles in the polymer matrix. Although, the 1 wt. % OCMCS-Fe3O4 membrane revealed considerably higher PWF and permeation than that of the other membranes. It was because of defects and cracks in the membranes. The 0.05 wt. % OCMCS-Fe3O4/PVDF membrane exhibited the highest FRR (95.7%) and protein rejection value (48%) and the lowest irreversible fouling resistance (Rir) value (4.2%). It is concluded that the blended membranes with modified nanoparticles resulted in a high-flux ultrafiltration membrane comparable with microfiltration membrane, while its separation properties remained similar to UF membrane. [ABSTRACT FROM AUTHOR]

ABSTRACT Membrane bioreactor (MBR) as a hybrid technology for wastewater treatment is becoming more popular for wastewater treatment. However, membrane fouling has hindered the widespread application of MBRs. Many efforts have been done for fouling mitigation. In this study, high flux and antifouling microfiltration membranes with unique surface structure, high surface porosity, and permeability were prepared by electrospinning technique. Initially, the optimum thickness of electrospun polyacrylonitrile (PAN) membranes was determined and then, electrospun PAN membrane at optimum thickness were prepared by embedding para-aminobenzoate alumoxane (PABA) nanoparticles at different concentrations. The effect of PABA nanoparticles on membrane performance was investigated. To investigate the characterization of the prepared membranes Fourier transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy, energy dispersive X-ray spectroscopy, and water contact angle measurement were employed. The flux recovery ratio results revealed that the antifouling properties of the electrospun PAN membrane were enhanced by modification. The 3 wt % electrospun PABA embedded PAN had the best permeability, hydrophilicity, and antifouling properties among the fabricated membranes and showed remarkable reusability during filtration. The results obtained suggested that the high flux and antifouling electrospun PAN membranes embedded PABA nanoparticles could be used as MBR membranes. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 45738. [ABSTRACT FROM AUTHOR]

Abstract: In this study, polyacrylic acid (PAA) and titanium dioxide nanoparticles were used for increasing antifouling characteristic of polyvinylidene fluoride membrane. Two different methods were applied for immobilization of TiO2 on PVDF membrane surface and compared their ability in flux recovery ratio of modified membranes. One method was self-assembling of TiO2 on surface of PAA grafted membrane and another was initially functionalization of TiO2 by acrylic acid monomers and next in situ grafting polymerization of this blend solution, which called “grafting from” technique. SEM images show that TiO2 nanoparticles were dispersed uniformly and completely in “grafting from” method rather than self-assembling procedure. In addition, FT-IR spectroscopy confirmed the presence of PAA and TiO2 nanoparticles on the membrane surface. Antifouling properties were tested by using whey solution. Better resistance to fouling was observed for membranes prepared from functionalized TiO2 due to high grafting yield and low agglomeration of TiO2 in this method. Repeating the fouling process indicates that stability of nanoparticles on membrane surface during operation and cleaning process is high because of covalent attachment of TiO2 to PAA network. [Copyright &y& Elsevier]

Within this research, a one-stage hybrid dual internal circulation airlift A2O (DCAL-A2O) bioreactor was designed and operated to simultaneously remove carbon, nitrogen and phosphorous (CNP) from milk processing wastewater (MPW) in different operational circumstances. The substantial operating variables monitored in this work were including hydraulic retention time (HRT), airflow rate (AFR) and aeration volume ratio (AVR) ranged from 7 to 15 h, 1-3 L/min and 0.324-0.464, respectively. From the view point of economics and process function, the optimum conditions were obtained at the HRT, AFR and AVR of 10 h, 2 L/min and 0.464, respectively. At the optimum conditions TCOD, TN, TP removal efficiencies and effluent turbidity were reported to be 97 %, 90 %, 92 % and 9 NTU, respectively. The impact of wastewater biodegradability (BOD 5 /COD) was evaluated on the bioreactor performance using two other wastewaters i.e. soft drink (SDW) and soybean oil plant wastewaters (SOW) in comparison with the MPW. Removal efficiencies for TCOD and TN exceeding 80 % were observed. The feeding location revealed a prominent impact on the TN and phosphorous removal efficiencies (both ≥80 %) related to the availability degree of the readily biodegradable organic substrate to denitrifiers and PAOs. The rise in HRT, AFR and AVR resulted in reducing microbial secretions as SMP present in sludge and bioreactor effluent as well as loosely bounded EPS (LB-EPS), reported to be 26, 28, 32.5 and 194.4 mg/L TOC, respectively. Different bacteria species were present at optimum conditions confirming concurrent CNP removal in a single body. Finally, the operating cost evaluation verified the effectiveness of the hybrid airlift A2O treating the MPW., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

A new drug delivery system using an asymmetric polyethersulfone (PES) membrane modified by SBA-15 and glutamine-modified SBA-15 (SBA-Q) was prepared in this study by the aim of azithromycin delivery enhancement in both in vitro and ex vivo experiments. The research focused on optimizing membrane performance by adjusting critical parameters including drug concentration, membrane thickness, modifier percentage, polymer percentage, and pore maker percentage. To characterize the fabricated membranes, various techniques were employed, including scanning electron microscopy, water contact angle, and tensile strength assessments. Following optimization, membrane composition of 17% PES, 2% polyvinylpyrrolidone, 1% SBA-15, and 0.5% SBA-Q emerged as the most effective. The optimized membranes demonstrated a substantial increase in drug release (906 mg/L) compared to the unmodified membrane (440 mg/L). The unique membrane structure, with a dense top layer facilitating sustained drug release and a porous sub-layer acting as a drug reservoir, contributed to this improvement. Biocompatibility assessments, antibacterial activity analysis, blood compatibility tests, and post-diffusion tissue integrity evaluations confirmed the promising biocompatibility of the optimized membranes. Moreover, long-term performance evaluations involving ten repeated usages underscored the reusability of the optimized membrane, highlighting its potential for sustained and reliable drug delivery applications., (© 2024. The Author(s).)

In this work, a one-stage dual internal circulation airlift anaerobic/anoxic/aerobic (DCAL-A2O) bioreactor was continuously operated for concurrent removal of nutrients and organics from milk processing wastewater (MPW). Special configuration of the airlift A2O bioreactor created possibility of the formation of desired anaerobic, anoxic and aerobic zones in a single unit. The process functionality of the bioreactor was examined under three influential operating variables i.e. hydraulic retention time (HRT; 7-15 h), air flow rate (AFR; 1-3 L/min) and aerobic volume ratio (AVR; 0.324-0.464). The optimum region was identified at HRT of 13h, AFR of 2L/min and AVR of 0.437, leading to TCOD, TN and TP removal efficiency of 94.5 %, 59.6 %, and 62.2 %, respectively, and effluent turbidity of 8 NTU. The impact of feed biodegradability on the process performance of the bioreactor treating the MPW, soft drink wastewater (SDW) and soybean oil plant wastewater (SOW) was also assessed. From the results, the feed characteristics affected significantly the nutrients removal. Moreover, the feeding location played an effective role in the nutrient removal while treating the MPW at optimum operating conditions. In this study, the change in residual organic matters as soluble microbial products (SMP) was monitored at various operating conditions. In addition, the impact of SMP extracted from sludge, extracellular polymeric substances (EPS) comprising of loosely bound EPS (LB-EPS) and tightly bound EPS (TB-EPS) was analyzed on sludge characteristics as bio-flocculation and settleability properties. According to the obtained data, the increase in operating variables led to the reduction in contents of effluent SMP, sludge SMP, LB-EPS, turbidity, and SVI, thereby, the enhancement in the sludge characteristics. Meanwhile, analysis of microbial communities verified the presence of various functional bacterial species. The cost operating evaluation confirmed the cost effectiveness of the airlift A2O bioreactor in reduction of energy consumption for the MPW treatment., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Polymeric membranes have garnered great interest in wastewater treatment; however, fouling is known as their main limitation. Therefore, the blending of hydrophilic nanoparticles in polymeric membranes' structure is a promising approach for fouling reduction. Herein, a hydrophilic boehmite-tannic acid-graphene quantum dot (BM-TA-GQD) nanoparticle was synthesized and blended in a polyethersulfone polymeric membrane in different percentages. The fabricated membranes were characterized by scanning electron microscopy (SEM), atomic force microscopy (AFM) images, water contact angle, porosity measurement, and antibacterial and antifouling properties. Surface SEM images of the modified membranes showed good dispersion of nanoparticles up to 0.5 wt%, which resulted in hydrophilicity and pure water flux enhancement. Based on AFM images, the mean roughness (Sa) of the fabricated membranes decreased from 2.07 to 0.84 nm for the bare and optimum membranes, respectively. In terms of performance, increasing the nanoparticle percentages up to 0.5 wt% resulted in the flux recovery ratio developing from 44.58% for the bare membrane to 71.35% for the 0.5 wt% BM-TA-GQD/PES membrane (optimum membrane). The antibacterial property of fabricated membranes was studied against biologically treated soft drink industrial wastewater (BTSDIW) as a bacterial source. The results showed that the turbidity of solutions containing permeated wastewater from the modified membranes (0.1, 0.5, and 1 wt% of BM-TA-GQD) was lower than that obtained from the unmodified membrane. These results confirmed the antibacterial properties of fabricated membranes. Finally, the optimal membrane (0.5 wt% BM-TA-GQD) was examined for post-treatment of the BTSDIW. An effluent COD of 13 mg/L and turbidity of 2 NTU showed a successful performance of the filtration process. PRACTITIONER POINTS: Ultrafiltration PES membranes were modified by different loadings of BM-TA-GQD. Hydrophilicity improvement was achieved by adding BM-TA-GQD nanoparticles. Expansion of size and number of macro-voids in modified membranes was confirmed. Membrane roughness was reduced in the BM-TA-GQD blended membranes. The optimum membrane was efficient in COD and turbidity removal., (© 2024 Water Environment Federation.)

This study focuses on the development of an air-lift bio-electrochemical reactor (ALBER) with a continuous feeding regime. The objective is to enhance nitrogen removal from synthetic wastewater with a low carbon-to-nitrogen (C/N) ratio. The chemical oxygen demand (COD) and total nitrogen (TN) of the influent wastewater were 500 and 200 mg/L, respectively. The effect of four independent variables, i.e., temperature, hydraulic retention time (HRT), N-NH 4 + /TN ratio and current density in the range of 16-32 °C, 6-12 h, 25-75%, and 2-10 A/m 2 , respectively, at three levels on the bio-electrochemical reactor performance were investigated during the bio-electrochemical reactor operation. The Face Center Cube (FCC) of response surface methodology (RSM) was used for design of experiments and model of obtained data. The ALBER achieved the maximum TN removal of 73% (146 mg/l) using external voltage and zeolite/plastic medium at temperature of 16 °C, HRT of 6 h, current density of 2 A/m 2 and N-NH 4 + /TN ratio of 75%. The results indicated that shortening the HRT from 12 to 6 h, reducing the temperature from 32 °C to 24 °C, increasing the current density from 2 to 6 A/m 2 and the reduction of nitrate concentration caused an increase in the TN removal. The results indicated that the performance of air-lift bio-electrochemical for nitrogen removal could be attributed to autotrophic denitrification (AD) and simultaneous nitrification/denitrification (SND). The research findings suggest that the ALBER should be further studied for potential use in treating industrial wastewater at low temperatures., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023. Published by Elsevier Ltd.)

The intrinsic hydrophilicity of metal compounds, such as copper ferrite (CuFe 2 O 4 ), and organic compounds, including graphene oxide (GO) and triethylenetetramine (TETA), make them promising adsorbents for heavy metals removal. The presence of lone pairs in these compounds is observed in modified polyethersulfone membranes used for the separation of arsenic (As) and total dissolved solids (TDS), including mono and divalent salts from aqueous solutions. The objective of this study was to investigate the performance of GO-TETA-CuFe 2 O 4 membranes for wastewater treatment applications. The membranes were characterized for their optimal mechanical strength (tensile strength) and high negative charge (zeta potential) on the surface. Separation tests were conducted at different pressures and pH levels to evaluate the membrane's effectiveness in removing contaminants. In addition, the membranes were examined for their antibacterial properties. The modified membrane exhibited superior performance compared with the control membrane, with TDS removal rates of 93.8%, As 3+ removal rates of 81.2%, and As 5+ removal rates of 87.9%. The contact angle of the modified membrane was reduced, resulting in an increase in pure water flux from 13.11 to 27.87 L/m 2 .h. The modified membrane also demonstrated significantly higher resistance to fouling than the control membrane, with a resistance increase from 6.78 × 10 +12 to 2.07 × 10 +12  m -1 . This contributed to the improved separation performance of As and TDS in a cross-flow setup. The results suggest that the GO-TETA-CuFe 2 O 4 modified membrane has great potential for use in water treatment applications. PRACTITIONER POINTS: GO-TETA-CuFe 2 O 4 was successfully used for modification of PES NF membrane structure. The efficiency of blended NF membranes with GO-TETA-CuFe 2 O 4 significantly increased. The modified membranes exhibited significant water flux and antifouling properties. The GO-TETA-CuFe 2 O 4 /PES membranes showed high rejection of heavy metal ions and TDS than PES. The GO-TETA-CuFe 2 O 4 /PES membranes exhibited desirable antibacterial activity., (© 2023 Water Environment Federation.)

Facile techniques to fabricate the nanofiltration membranes with ideal molecular sieving is one of the most interesting subjects in membrane separation technology. In this study, the application of modified graphene oxide (GO) with triethylenetetramine (TETA), CuFe 2 O 4 , and acetic acid (AC) (supported GO-TETA-CuFe 2 O 4 @AC) as a supported protic ionic liquid (PIL) modifier for polyethersulfone (PES) membrane was evaluated to approve the improvement of anti-fouling properties and wastewater rejection of the fabricated membranes. To enhance the key properties of graphene oxide, it was modified by hydrophilic nanomaterials (TETA-CuFe 2 O 4 ). High flux and promising flux recovery ratio (up to 95% compared to the unmodified membrane) can be observed in the modified membranes. The modified membranes by GO-TETA-CuFe 2 O 4 @AC were studied at optimum concentrations (0.5 wt.%) for salt rejection and different dyes. The obtained data indicated that the modified membranes by GO-TETA-CuFe 2 O 4 @AC indicated higher salt removal (up to 97% for BaCl 2 than the unmodified membrane), which was related to the efficient modification. The obtained pure water flux (PWF) for bare and optimal modified membrane from 13.11 to 27.87 kg/m 2 ·h, respectively. To exact evaluate the effect of membrane modification on performance examination, the modified membranes were evaluated for chlorine resistance testing. This study aimed to develop cost-effective nanofiltration (NF) membranes with high anti-fouling properties and to determine the maximum filtration capacity of in-time dyes and salts in effluents. PRACTITIONER POINTS: A GO-TETA-CuFe2O4 mixed matrix membrane was prepared for removal of salts and dyes. The effect of GO-TETA-CuFe2O4 enhanced the hydrophilicity and porosity. The membrane exhibited superior antifouling properties and ions rejection., (© 2022 Water Environment Federation.)

Modified graphene oxide with 5,10,15,20-tetrakis-(4-hexyloxyphenyl)-porphyrin and palladium (II) (signified by GO-CPTMS@Pd-TKHPP) prepared as a novel antifouling polyether sulfone (PES) blended nanofiller membrane. The membrane efficiency has been analyzed such as pure water flux (PWF), hydrophilicity, and antifouling features. By increasing of modified graphene oxide percentage from 0 to 0.1 wt.% in the polymer matrix, the PWF was incremented from 14.35 to 37.33 kg/m 2 ·h at 4 bar. The membrane flux recovery ratio (FRR) has been investigated by applying powdered milk solution; the FRR results indicated that the 0.1 wt.%-modified graphene oxide membrane showed a positive effect on fouling behavior with Rir and FRR value 8.24% and 91.76%, respectively. The nanofiltration membrane performance was assessed applying the Direct Red 16 dye rejection. It was demonstrated that the optimal membranes (0.1 wt.%-modified graphene oxide) had notable dye removal (99.58% rejection). The results are also verified by measuring the scanning electron microscopy (SEM), water contact angle (WCA), and atomic microscopy analysis (AFM)., (© 2021. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Developing an effective and stable separation membrane for water treatment is of much interest while challenging because of the restrictions of membrane fouling and water flux reduction. To minimize this problem, in this work, highly porous and hydrophilic nanostructure of NH 2 -modified MCM-41 (NH 2 -MCM-41) was embedded successfully into the nanofiltration (NF) membrane body via commonly used phase inversion method. The unmodified and modified nanofiller was analyzed by Fourier Transform Infrared (FTIR) spectroscopy, X-Ray powder diffractometry (XRD), field emission scanning electron microscopy (FE-SEM), thermogravimetric analysis (TGA), and nitrogen adsorption-desorption. Furthermore, the modified membranes were characterized through surface and cross section FE-SEM images, the membrane surface roughness, hydrophilicity, antifouling properties and dye rejection. Benefiting from porous networks and enhanced hydrophilicity, the mixed matrix membranes (MMMs) revealed more prominent hydrophilic property as well as higher pure water flux (PWF) compared with naked membrane. The polysulphone (PSf) membrane modified with NH 2 -MCM-41-1.0 exhibited the highest pure water flux (PWF) of 65.43 kg/m 2 .h and superior antifouling characteristics with a flux recovery ratio (FRR) of around 97.0% and an irreversible fouling resistance (R ir ) of 3.2%. Furthermore, the optimal membrane possessed high dye rejection (100%) and antifouling capacity (FRR of 97%) while filtering a field sample, effluent from a local stabilization pond treating municipal wastewater. The fabricated membrane in this study is believed to pave pathways for constructing NF membranes with superior effectiveness for other municipal and industrial wastewaters treatment., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

Polymeric ultrafiltration (UF) membranes often used in membrane bioreactor (MBR) prone to be fouled by fouling agents. Therefore, in this paper, the antifouling characteristics of polyvinylidene fluoride (PVDF) UF membranes for wastewater treatment are improved through modifying membranes by O-carboxymethyl chitosan (OCMCS)-functionalized Fe 3 O 4 nanoparticles (OCMCSFe 3 O 4 ). The modifier agent was manufactured by the adsorption of OCMCS on Fe 3 O 4 nanoparticles, which were synthesized via co-precipitating method. Antifouling performance of membranes was assessed by permeation tests done using activated sludge suspension as a biological foulant, then the calculation of the pure water flux recovery ratio (FRR) and fouling resistance parameters. Also, to investigate the protein rejection of membranes, permeation tests were conducted by the bovine serum albumin (BSA) solution. According to the obtained results, surface hydrophilicity of the embedded membranes was improved in the low concentrations of the modified nanoparticles. However, the high quantity of the OCMCS-Fe 3 O 4 nanoparticles (>0.1 wt. %) in the casting solution lessened membrane performance owing to the agglomeration of the nanoparticles in the polymer matrix. Although, the 1 wt. % OCMCS-Fe 3 O 4 membrane revealed considerably higher PWF and permeation than that of the other membranes. It was because of defects and cracks in the membranes. The 0.05 wt. % OCMCS-Fe 3 O 4 /PVDF membrane exhibited the highest FRR (95.7%) and protein rejection value (48%) and the lowest irreversible fouling resistance (Rir) value (4.2%). It is concluded that the blended membranes with modified nanoparticles resulted in a high-flux ultrafiltration membrane comparable with microfiltration membrane, while its separation properties remained similar to UF membrane.

The aim of current study is to synthesis novel visible driven photocatalysts (L-Histidine (C, N) codoped-TiO 2 -CdS) with different loadings of L-Hisitdine (1, 2, and 3 wt.%) and CdS (1:9, 7:1, and 1:5 mass ratios of CdS to TiO 2 ). Then, their application for photo-degradation of methyl orange (MO) and biologically treated palm oil mill effluent (POME) were studied. The structure, optical properties, and morphology of the prepared nanocomposites were also characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), Fourier transform infrared (FT-IR), photoluminescence spectroscopy (PL), and diffuse reflectance spectra (DRS). DRS results indicated that all the modified samples with different L-Hisitdine and CdS loadings showed a red shift to visible region. The results of photo-degradation experiments showed that L-Hisitdine with a weight fraction of 2% and mass ratio of TiO 2 to CdS of 7:1 were the optimum amount of the modifiers in the photocatalyst network. The PL intensity of the photocatalyst decreased with addition of L-Hisitdine and CdS nanoparticles due to a decrease in e - /h + recombination. The effects of organic pollutant concentration, initial pH, catalyst concentration, and irradiation time on the photo-degradation process of MO and POME were studied using full faced centered central composite design (CCFD) under response surface methodology (RSM). The obtained results showed that MO was completely removed at initial concentration of 10 mg/L, acidic pH, and catalyst loading of 1.5 g/L after 120 min. The complete degradation of biologically treated POME was achieved at original pH, 300 mg/L of chemical oxygen demand (COD) concentration, catalyst loading of 2 g/L, and irradiation time of 2 h., (Copyright © 2019 Elsevier B.V. All rights reserved.)