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In this study, a novel approach is to apply polyaspartic acid (PASP) as an eco-friendly regulator for the flotation of coking coal, which is different from the conventional use of oil collectors only. Flotation trails showed that adding PASP contributes to a two-way improvement in the yield and ash content of clean coal. SEM-EDS observations directly revealed that adding PASP significantly reduces the coating of high-ash fine slimes on the surface of low-ash coal particles. Contact angle detections and zeta potential analysis presented that the preferential adsorption of PASP hardly affects the adsorption of sodium oleate (NaOL) on the surface of low-ash coal particles but significantly weakens the adsorption of NaOL on the surface of high-ash fine slimes, leading to a remarkably hydrophobic difference. Particle interaction energy calculations verified that adding PASP enlarges the energy barrier between low-ash coal particle and high-ash fine slime. Hence, it can be arrived that the preferential adsorption of PASP affects the adsorption of NaOL on the surface of high-ash fine slime, widens the hydrophobic difference, enlarges the energy barrier between low-ash coal particle and high-ash fine slime, reduces the high-ash fine slime coating, therefore leading to a better flotation performance of lean coal. [ABSTRACT FROM AUTHOR]

A stable attachment between bubbles and solid particles is essential for flotation. Therefore, it is particularly necessary to study the dynamic process that occur in the attachment of bubbles to a solid surface. In this paper, Teflon and plexiglass plates were used as hydrophobic and hydrophilic solid surfaces, respectively, and solid surfaces with roughness of 0.018 μm to 5.33 μm were prepared by polishing with sandpaper. The influence of roughness on the dynamic process in bubble attachment to solid surfaces with different hydrophobicity was studied via a high-speed camera (750 frames per second). It was found that roughness played a positive role in the attachment to the hydrophobic Teflon surface while a negative role in the attachment to the hydrophilic plexiglass surface in terms of the bubble's attachment to the solid plates. For a smooth Teflon surface, the formation of three–phase contact (i.e., the drainage of wetting film) took up to 95 ms, whereas for a very rough Teflon surface it took only 5 milliseconds. On the contrary, the high roughness prevented the bubble from attaching to the hydrophilic plexiglass surface. It was concluded that the increased roughness of Teflon plates was conductive to air entrapment in surface irregularities, inducing the rapid rupture of the wetting film on a very rough Teflon surface, while the increased roughness of the plexiglass plates resulted in "water pockets" in surface grooves, making the wetting film on the plexiglass surface stable. [ABSTRACT FROM AUTHOR]

Recent studies have reported that particle-bubble clusters formed and are deduced to play a potentially important role in high-intensity conditioning (HIC). In this study, the effect of particle size and shear parameter on the characteristic of particle-bubble cluster in HIC of coal was investigated in details. Results showed that, for coal of +75 μm fraction, the number of bubbles and the mean bubble diameter generated by pusher blade and sawtooth-disk blade were close. By contrast, the effect generated by four-pitched blade was inferior. The number of bubbles is fairly related with particle size. Under the same conditions, compared to that of +75 μm fraction, the number of bubbles attached to the coal surface of 45 ~ 75 μm is 1 to 2 orders of magnitude less. The mean diameter of the bubbles also tends to decrease in the same way. Particle-bubble cluster was also found in the fraction of −45 μm coal. Compared to the other two blades, the number of bubbles generated by pusher blade was the largest. In summary, pusher blade produced the best performance of cluster formation for each particle size fraction. This study is expected to provide guidance for the optimization of shear parameters for cluster formation during HIC. [ABSTRACT FROM AUTHOR]

This study examined the incompatibility of high-intensity conditioning (HIC) conditions required for fine and coarse coal particles. The effects of speed and time of stirring on the recovery of coarse and fine particles were investigated by using three different flotation processes. The results showed that the coarse particle recovery of surface cleaning (SC) flotation reached the maximum value of 69.71% at the stirring condition combination of '1400 rpm +2 min.' However, the coarse particle recovery reached the maximum value of ~69.37% at a stirring condition combination of '1600 rpm +3 min' or '2000 rpm +2 min' in HIC flotation. Achieving the same coarse particle recovery, SC flotation consumes less energy than HIC flotation. The maximum recovery of fine particle 65.37% was achieved at a stirring condition combination of '1600 rpm +2 min' in HIC flotation. SC failed to promote the recovery of fine particles and even produced some negative effects in some cases. Fine particles consume less energy than coarse particles with respect to their maximum recovery. In addition, the optimum stirring speed and time for SC were 1400 rpm and 2 min, respectively, while 2000 rpm and 3 min for HIC, respectively. The optimum energy requirements involving stirring speed and time for SC do not match that for reagent dispersion and particle-reagent collision. The best flotation result achieved by HIC is a compromise of the above three aspects. It is suggested that SC, reagent dispersion, and particle-reagent collision should be carried out separately. [ABSTRACT FROM AUTHOR]