1. Facile construction of porous carbon fibers from coal pitch for Li-S batteries
- Author
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Junzhuo Guo, Zhiping Lei, Honglei Yan, Weidong Zhang, Zhan-Ku Li, Zhiming Du, Jingchong Yan, Hengfu Shui, Shibiao Ren, Zhicai Wang, and Shigang Kang
- Subjects
Coal pitch ,Carbon fiber ,Li-S batteries ,Lithium polysulfides adsorption ,Catalytic conversion ,Mining engineering. Metallurgy ,TN1-997 - Abstract
Abstract Coal pitch, an important by-product in the coal coking industry with a high output, is a low-cost and high-carbon yield precursor for the manufacturing of high-value carbon materials. Herein, N/O co-doped carbon fiber (CFCP), fabricated by electrospinning using pre-oxidized coal pitch as the precursor, was employed as the sulfur host for Li-S batteries. The presence of more pyrrolic N and graphic N in CFCP than carbon fiber made from polyacrylonitrile benefits the adsorption of lithium polysulfide and the battery’s life. Sulphur-CFCP cathode (S@CFCP) exhibited excellent specific capacity and cyclability, with a specific capacity of 701.1 mAh/g and a low capacity decay rate of 0.088% per cycle over 200 cycles at 2.0 C, respectively. The high ion diffusion rate, low charge transfer resistance, and effective conversion of lithium polysulfides enable the high electrochemical performance of S@CFCP.
- Published
- 2024
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